Cu 1: Cho hn hp A gm c NaCl, NaBr v NaI.

Ho tan 5,76 gam A vo nc ri cho tc dng vi lng d dung dch nc brom, sau phn ng hon ton thu c 5,29 gam mui khan. Mt khc khi ho tan 5,76 gam A vo nc ri cho mt lng kh Clo i qua sau phn ng c cn thu c 3,955 gam mui khan, trong c cha 0,05 mol NaCl. 1. Vit cc PTHH ca cc phn ng xy ra. 2. Tnh % v khi lng cc cht trong hn hp A. Cu 2: xc nh thnh phn dung dch A cha cc ion Na+, Cl-, Br-, I-, ngi ta lm 3 th nghim sau:
- TN 1: ly 20 ml dung dch A, c cn thu c 1,732 gam mui khan - TN 2: ly 20 ml dung dch A, lc k vi nc brom d, sau c cn th thu c 1,685 gam mui khan. - TN 3: ly 20 ml dung dch A, sc kh clo cho ti d, sau c cn th thu c 1,4625 gam mui khan. a) Tnh nng mol ca mi ion trong dung dch A. b) T 1m3 dung dch A c th iu ch c bao nhiu gam brom, iot? Cu 3: Cho 3 gam km tc dng vi 18,69 ml dung dch axit clohidric 14,6% (d = 1,07g/ml). Kh sinh ra c dn qua 4 gam ng (II) oxit nung nng. Tnh th tch ti thiu dung dch axit sunfuric nng 19,6% (d = 1,14g/ml) cn phi ly tc dng vi hn hp thu c nhm tch ng ra khi hn hp. C bao nhiu gam ng c tch ra? Cu 4: a) iu ch kh clo bng cch in phn dung dch mui n NaCl bo ha c mng ngn. Tnh khi lng mui n cha 98% NaCl iu ch 560 lt kh clo (kc). b) Nu dng axit HCl c v MnO2 th khi lng mi cht l bao nhiu iu ch c th tch clo trn? Cu 5: C cc ha cht: axit HCl c, MnO2, KMnO4 hy iu ch kh clo trn? a) Nu 2 cht oxi ha c khi lng bng nhau, th phn ng no cho lng clo nhiu hn? b) Nu 2 cht oxi ha c s mol bng nhau, th phn ng no cho lng clo nhiu hn? Cu 6: Cho 1 lt H2 tc dng vi 0,672 lt Cl2 (kc) ri ha tan sn phm vo 19,27 gam nc, thu c dung dch A. Ly 5 gam dung dch A cho tc dng vi AgNO 3 d, thu c 0,7175 gam kt ta. Tnh hiu sut ca phn ng gia H2 v Cl2. Cu 7: Trong cng nhip, ngi ta in phn dung dch mui n NaCl bo ha sn xut clo. Hy vit phng trnh phn ng xy ra trong hai trng hp: a) C mng ngn gia anot v catot ca bnh in phn b) Khng c mng ngn Cho bit vai tr ca mng ngn amiang trong trng hp trn. Cu 8: C 4 l mt nhn ng ring r tng dung dch ca 4 cht sau: HCl, NaCl, BaCl2, NaClO. Trnh by phng php ha hc nhn bit 4 cht . Cu 9: Cho mangan ioxit tc dng hon ton vi 20 gam dung dch HCl 36,5%. Dn kh sinh ra li qua 500 ml dung dch KOH 2M nhit thng. a)Tnh nng dung dch cc mui sau phn ng b) sau phn ng cn d KOH khng? Nng l bao nhiu? Coi th tch dung dch thay i khng ng k. Cu 10: t hai bnh trn hai a cn, mi bnh cha 100 gam dung dch HCl 20%. Cn v tr thng bng. Cho 20 gam km vo bnh th nht v cho 20 gam magie cacbonat vo bnh th hai. a) Cn s v tr no sau khi kt thc phn ng b) Cn c thng bng khng nu c bnh th hai c bt nhng qu bng cao su thu kh thot ra? Cu 11: Cho hn hp a gm bt Cu v bt Al tc dng hon ton vi kh clo d. Sau phn ng thu c 2,24 gam cht rn. Nu cho hn hp A tc dng vi dung dch HCl 0,1M (d) th thu c 0,224 lt kh (kc) v mt cht khng tan. a) Hy vit cc phng trnh phn ng. b) Tnh t l phn trm v khi lng ca Cu v Al trong hn hp A? c)Tnh th tch dung dch HCl 0,1M tham gia phn ng Cu 12: Nung 3,195 gam hn hp KCl v KClO3 vi mt lng cht xc tc MnO 2, thu c cht kh v mt cht rn. Ha tan cht rn vo nc, ly nc lc cho tc dng vi dung dch AgNO3 d th thu c 4,305 gam kt ta. a) Vit phng trnh phn ng xy ra. b) Tnh thnh phn phn trm v khi lng ca mi cht trong hn hp u. c) Tnh th tch kh thu c kc. Cu 13: Cho mt mui halogen ca mt kim loi ha tr II. Ha tan a gam mui vo nc ri chia thnh hai phn bng nhau. - Phn mt cho tc dng vi dung dch AgNO3 d, thu c 5,74 gam kt ta. - Nhng 1 thanh Fe vo phn hai. Sau khi kt thc phn ng, thanh st nng thm 0,16 gam. a) Xc nh cng thc ha hc ca mui. b) Tnh khi lng a gam mui em ha tan. Cu 14: Ha tan 8 gam hn hp gm st v mt kim loi ha tr II vo dung dch HCl d, thu c 4,48 lt kh H2 (kc). Mt khc, ha tan 4,8 gam kim loi ha tr II cn gn n 500 ml dung dch HCl 1M.

Xc nh tn kim loi v thnh phn phn trm v khi lng ca hn hp.

Cu 15: Khi cho 0,54 gam kim loi M c ha tr khng i tc dng ht vi axit HBr, thu c 672 cm3 kh H2 (kc).
a) Xc nh kim loi M b) Tnh th tch dung dch HBr 1M tham gia phn ng vi M. c) Khi lng mui to thnh sau phn ng l bao nhiu gam, nu hiu sut l 90%. Cu 16: Cho hn hp NaI v NaBr ha tan vo nc, thu c dung dch A. Cho vo dung dch A mt lng brom va , thu c mui X c khi lng nh hn khi lng ca hn hp mui ban u l a gam. Ha tan X vo nc c dung dch B. Sc kh clo va vo dung dch B, thu c mui Y c khi lng nh hn khi lng ca mui X l 2a gam. Xc nh thnh phn % theo khi lng ca cc cht trong hn hp mui ban u (coi nh Cl2, Br2, I2 khng phn ng vi nc) Cu 17: 1/ Mui n clorua (NaCl) b ln cc tp cht l Na2SO4, MgCl2, MgSO4, CaCl2, CaSO4, Ca(HCO3)2, Mg(HCO3)2. Hy trnh by phng php ha hc tch ring NaCl tinh khit. 2/ Hon thnh cc phng trnh phn ng dng phn t v ion rt gn theo s chuyn ha sau: dd FeCl3 + Na2CO3 + H2O KAlO2 + NH4Cl + H2O Cu + NaNO3 + HCl FeCl2 + HCl + O2 Cu 18: Khi nung nng mui kaliclorat th mt phn mui phn hy cho oxi, mt phn to thnh mui kali peclorat v kali clorua. a) Vit cc phng trnh phn ng phn hy mui kali clorat (cn bng phng trnh bng phng php thng bng electron) b) Tnh khi lng cc cht rn cn li sau khi nung 44,1 gam kali clorat. Bit rng c 6,72 lt kh oxi thot ra, kali clorat phn hy hon ton. Cu 19: cho kh clo iu ch c bng cch ch ha 69,6 gam mangan ioxit vi axit clohidric c (va ) i qua 500 ml dung dch NaOH 4M. Xc nh nng mol ca cc mui c to thnh. Cu 20: C mt hn hp gm: st, st (II) oxit v st (III) oxit. Ly 1 gam hn hp cho tc dng vi HCl c 112 ml H2 (kc). Nu kh 1 gam hn hp bng hidro, to thnh 0,2115 gam nc. Cu 21: Cho sn phm thu c khi un nng hn hp 5,6 gam bt st v 1,6 gam bt lu hunh vo 500 ml dung dch HCl, thu c hn hp kh v dung dch A (hiu sut 100%). a) Tnh % th tch hn hp kh b) trung ha axit HCl cn d trong dung dch A phi dng 125 ml dung dch NaOH 0,1M. Tnh nng mol ca dung dch HCl dng.