THI CUC THI TRC NGHIM TRC TUYN 2010 Mn thi: Ha hc Thi gian lm bi : 90 pht Ngi ra : Nguyn Tn Trung

(Trung tm luyn thi Vnh Vin) Cho bit khi lng nguyn t (theo vC) ca cc nguyn t : H = 1; He=4; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; As = 75; Br = 80; Rb = 85,5; Ag = 108; Ba = 137; Cd= 112
------------------------------------------------------------------------------------------------------------------------------------------

Cu 1: Cho hn hp H2 , CO (d) i vo ng s nung nng ng hn hp X gm Al 2 O 3 , MgO, Fe 3 O 4 , CuO thu c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi s cc phn ng xy ra hon ton. Phn khng tan Z gm A. Mg, Fe, Cu C. Mg, Al, Fe, Cu B. MgO, Fe, Cu D. MgO, Fe 3 O 4 , Cu

Cu 2: X, Y, Z, T l 4 andehit lin tip trong dy ng ng, trong MT = 2,4M X . t chy hon ton 0,1 mol Z ri hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 d thy khi lng dung dch sau s: A.Tng 18g B. Tng 13,2g C. Gim 11,4g D. Gim 30g

Cu 3: Hydrat ha C 2 H 2 c xc tc Hg2+ thu c hn hp X c t khi hi so vi He l 10,1. Hiu sut phn ng l: A.40% B.60% C.75% D.80%

Cu 4:Thanh Graphit c ph mt lp mng Kim Loi M. Nu nhng thanh Graphit trn vo dung dch Cu(NO 3 ) 2 d. Sau phn ng thy khi lng thanh Graphit gim 0,12 gam. Nu nhng thanh Graphit vo dung dch AgNO 3 d. Sau phn ng thy khi lng thanh Graphit tng 0,26 gam. Kim loi M l: A. Zn B. Pb C. Fe D. Cd

Cu 5: Cho 16,8 gam Fe vo dung dch cha 0,6 mol H2SO4 ; thy phn ng xy ra va v ch sinh ra 1 cht kh. Sn phm ca th nghim l: A. FeSO 4 , H 2 C. FeSO 4 , Fe 2 (SO 4 ) 3 , SO 2 B. FeSO 4 , SO 2 D. Fe 2 (SO 4 ) 3 , SO2

Cu 6: Cho 39,2 gam axit phosphoric phn ng vi dung dch cha 44 gam NaOH. Khi lng mui thu c l: A. 60,13 gam B. 63,4 gam C. 66,2 gam D. 67,34 gam

Cu 7: t chy hn hp 2 hydrocacbon ng ng c s mol bng nhau, thu c CO 2 v hi nc c n CO2 : n H2O = 2 : 3 . Cng thc phn t 2 hydrocacbon ln lt l: A. C 2 H 6 v C 4 H 10 C. CH 4 v C 2 H 6 B. C 2 H 6 v C 3 H 8 D. CH 4 v C 3 H 8

Cu 8: Cho x mol P 2 O 5 vo dung dch cha y mol NaOH. Sau phn ng thu c dung dch gm 2 mui NaH 2 PO 4 v Na 2 HPO 4 . Biu thc lin h x, y l: A. x < y < 2x B.y = 2x C. 2x < y < 4x D. y = 4x

Cu 9: T hn hp (CuO, MgO, Al 2 O 3 ) iu ch Al, Mg, Cu, c th s dng thm dy ha cht no di y (cc dng c thit b coi nh c )? A. H 2 SO 4 , NH 3 C. HNO 3 (c), NaOH, CO Cu 10: Kt lun ng l: A.Trong hp cht oxi lun c s oxi ha -2 B. Trong hp cht H lun c s oxi ha +1 C. S oxi ha ca nguyn t trong hp cht lun khc 0 D. C n H 2n+1 Cl l mt este v c. Cu 11: Trong cc cht : H2 O, HCl, NaOH, NaCl, CH 3 COOH , CuSO 4 , HClO 3 , CH 3 OCH 3 . Tng s cht in ly yu l: A.2 B.3 C.4 D.5 B.NaOH, NH 3 D. NaOH, HCl, CO 2

Cu 12: Cho hn hp A cha bt kim loi gm a mol Fe v b mol Al vo dung dch hn hp x mol AgNO 3 ; y mol Cu(NO 3 ) 2 . Sau khi kt thc phn ng thu c dung dch D v rn E. Cho E phn ng vi HCl c c mol kh. Bit a > b > c. Biu thc lin h a, b, c, x, y l: A. 2a+ 3b = x + 2y C. 3a + 3b = x +2y B. 2a + 3b = x + 2y + 2c D. 3(a-c) + 3b = x + 2y

Cu 13: Cho 9,76 gam hn hpA: Fe 3 O 4 v Fe phn ng vi dung dch H 2 SO 4 long rt d, thu c dung dch B v 1,12 lt H 2 (iu kin chun). Th tch dung dch KMnO 4 0,25M cn phn ng ht dung dch B l A. 40ml B. 58ml C. 64ml D. 72 ml

Cu 14:Nhng cht trong dy no sau y u tc dng c vi ru etylic ? A. HCl; HBr ;CH 3 COOH ; Natri, H 2 SO 4 c B. CH 3 COOH ; Natri ; HCl ; C 6 H 5 OH C. HBr ; CH 3 COOH ; Natri ; CH 3 OCH3 . D. HCl ; HBr ; CH 3 COOH ; NaOH Cu 15: Ha tan hon ton 1,405 gam hn hp gm Fe2 O 3 , Fe 3 O 4 , FeO trong 250 ml axit H 2 SO 4 0,1M (va ). Sau phn ng, hn hp mun sunfat khan thu c khi c cn dung dch c khi lng l: A.2,405g B.4,405g C.5,21g D.3,405g

Cu 16:t chy hn hp X c H 2 , ankan A, anken B. t chy 0,38 mol hn hp X thu 11,2 lt CO 2 (iu kin chun) v 14,04 gam H 2 O. KLPT trung bnh ca hn hp X c gi tr l: A.16,6 B.18,8 C.19,9 D.22,2

Cu 17:Cho hn hp bt kim loi gm 1,4 gam Fe, 0,24 gam Mg phn ng tc dng vi 200ml dung dch Cu(NO 3 ) 2 0,15M. Sau phn ng thu c rn B. Cho B phn ng ht vi HNO 3 thy c V lt NO (iu kin chun) thot ra. Gi tr V l: A.0,56 B. 0,672 C. 0,896 D.1,12

Cu 18: Dehidro ha 8,8g C 3 H 8 , hiu sut 90% thu c hn hp A. KLPT trung bnh ca hn hp l: A.26,56 B.34,4 C.15,55 D.23,15

Cu 19:Hn hp X c C 2 H 2 , C 2 H 4 , H 2 un nng vi Ni, phn ng hon ton thu 5,6l hn hp A c M hhA = 12,2. t chy hn hp X thu tng lng CO2 v H 2 O l: A. 29,3g B. 17,6g C. 9g D.11,7g

Cu 20:Phn ng no di y vit khng ng? A. FeS 2 + 2HCl FeCl 2 + H 2 S + S B. CuS+ 2HCl CuCl 2 + H 2 S C. Cl 2 + Ca(OH) 2 CaOCl 2 + H 2 O D. Fe + 2 H 2 SO 4 FeSO 4 + SO 2 + 2 H2 O Cu 21:t chy hn hp G c ankan A v ankin B, thu 0,7mol H 2 O v cn 1,15mol O 2 . Bit mol CO 2 = 8/3 mol hn hp G. Vy hn hp G l: A. 25,55 B. 33,33 C. 41,14 D. 36,66

Cu 22: Cho hn hpA gm 2,4 gam kim loi M v 5,4 gam Al phn ng va vi 6,72 lt (iu kin chun) hn hp gm Cl 2 , O 2 ; thu c 25,2 gam rn. Nu cho hn hp A trn phn ng vi dung dch hn hp Cl (d); thu c V lt kh (iu kin chun). Gi tr V l: A.6,72 B.8,96 C.11,2 D.16,8

Cu 23:Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung dch H 2 SO 4 long, thu c 1,344 lt hiro ( iu kin chun) v dung dch cha m gam mui. Gi tr ca m l: A. 8,98 B. 9,52 C. 7,25 D. 10,27

Cu 24:Cracking hon ton 1 ankan A thu c hn hp X c t khi hi so vi hydro l 14,5. CTPT A l: A. C 5 H 12 B. C 4 H 10 C. C 3 H 8 D. C 6 H 14

Cu 25: Ha tan ht 1,3g kim loi M trong dung dch HNO 3 , c dung dch A duy nht. Cho NaOH d vo dung dch A, un nh, thy c 0,112 lt kh X. Kim loi M l: A. Zn B. Al C. Mg D. Pb

Cu 26: Kh nc hn hp 2 ru thu c 2 anken. te ha hon ton hn hp 2 ru thu c 3 te, trong c mt te l C 5 H 12 O. te c KLPT ln nht l: A. 74 B. 88 C. 102 D. 130

Cu 27: Hn hp A gm: 0,12 mol C 2 H 2 v 0,18 mol H 2 . Cho A qua Ni nung nng, phn ng khng hon ton v thu c hn hp kh B. Cho B qua bnh dung dch Br 2 d, thu

c hn hp X: 0,06 mol C 2 H 6 v 0,02 mol H 2 . Sau th nghim thy bnh Br2 tng m gam. Gi tr m l: A. 1,64 B. 1,6 C. 1,4 D. 2,3

Cu 28: Trong cc dung dch HNO3 , KCl, K 2 SO 4 , Ca(OH) 2 , KHSO 4 , Mg (NO 3 ) 2 , dy gm cc cht u tc dng c vi dung dch Ba (HCO 3 ) 2 l: A. HNO 3 , Ca(0H) 2 , KHSO 3 , Mg(NO 3 ) 2. B. KCl, K 2 SO 4 , Ca(OH) 2. C. HNO 3 , Ca(OH) 2 , KHSO 4 , K2SO 4. D. HNO 3 , KCl, K 2 SO 4 Cu 29:T cc cht HBr, C 2 H 5 OH; C 2 H 4 , Br 2 , C 2 H 6 . S phn ng to ra C2 H 5 Br l: A. 1 B. 2 C. 3 D. 4

Cu 30:Cho 1,8 gam hn hpX gm 2 amin n no tc dng ht vi dung dch HCl; thu c 3,26 gam hn hp 2 mui c s mol bng nhau. Thnh phn % theo khi lng ca amin c KLPT ln l: A.50% B.65,6% C. 66,7% D.75%

Cu 31: Trn dung dch cha a mol NaAlO 2 vi dung dch cha b mol H 2 SO 4 . thu c kt ta th cn c t l: A. a:b> 1:2 B. a:b < 1:4 C. a:b< 1:2 D. a:b>1:4

Cu 32: Cho 250 ml dung dch KOH 0,5M, NaOH 0,5M vo 100 ml dung dch Al 2 (SO 4 ) 3 C (mol/l); thu c kt ta A. Nung A, thu c 2,55 gam rn D. Gi tr C l: A. 0,25 B. 0,375 C. 0,75 D. 0,5

Cu 33: t chy 1,68 lt hn hp CH 4 , C 2 H 4 (iu kin chun) c t khi hi so vi hydro bng 10. Dn ht kh thu c cho vo bnh dung dch Ca(OH)2 d; Sau phn ng thu c m gam kt ta. Gi tr m l: A. 5 B. 10 C. 12,5 D. 15

Cu 34:Dung dch A lm qu tm ha xanh, dung dch B khng i mu. Trn dung dch A vi dung dch B; thy xut hin kt ta. Hai dung dch l: A. NaOH, K 2 SO 4 B. KOH, BaCl 2

C. K 2 CO 3 , Ba(NO 3 ) 2

D. Na 2 CO3 , Fe(NO 3 ) 2

Cu 35:Cho dung dchA gm Na 2 SO 4 0,01mol, Na 2 CO 3 0,01mol tc dng va vi dung dchB gm Ba(NO3 ) 2 0,005mol v Pb(NO 3 ) 2 ; thu c m gam kt ta. Gi tr m l: A. 10,7 B. 5,35 C. 8,025 D. 18,06

Cu 36:Cho 0,8 mol CO 2 hp thu vo a mol KOH thu c dung dch c 2 mui. Gi tr a l: A. 0,8< a <1,6 B. 0,8 a<1,6 C. 0,8<a 1,6 D. 1<a<2

Cu 37:Cho hn hp FeO, CuO, Fe 3 O 4 (c mol bng nhau) phn ng ht vi dung dch HNO 3 thu 0,09mol NO 2 v 0,05mol NO. S mol mi cht l: A. 0,24 B. 0,08 C.0,12 D. 0,16

Cu 38:Trong pin ha hc Zn-Cu, ti in cc A. Zn xy ra qu trnh oxi ha B. Zn xy ra qu trnh kh C. Cu xy ra qu trnh oxi ha D. Cu xy ra qu trnh kh Cu 39: t ht 1,24 gam hn hp A gm Mg, Al, Zn trong oxi d, thu c 1,56 gam oxit. Nu cho 1,24 gam hn hp A phn ng vi HCl d, thu c V lt H 2 (iu kin chun). Gi tr V l A. 2.24 B. 4,48 C.0,448 D.0,672

Cu 40: Cracking butan vi hiu sut 75%, thu c V lt hn hp kh A (gm 7 cht). Dn ht hn hpA vo bnh ng dung dch Br 2 d. Sau khi phn ng kt thc thy c 25 lt kh thot ra khi bnh Br2 . Gi tr V l: A. 43,75 B.54,6 C.62,5 D.72,75

Cu 41: Nung mt hn hp rn gm a mol Ag 2 O v b mol Zn trong bnh kn cha khng kh (d). Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia a v b l: A. a=b B. a=2b C.b=2a D. b= 4

Cu 42: Ha tan ht 1 lng Al cn V ml dung dch HNO 3 4M thu c 0,896 lt (iu kin chun) hn hp G NO, NO 2 , t khi hi ca G so vi hydro bng 17. Gi tr V l A. 10 B. 20 C. 45 D. 25

Cu 43: C phn ng Cu + X + a KHSO 4 CuSO 4 + K 2 SO 4 + Na 2 SO 4 + NO + H 2 O, khi cn bng th h s a l: A. 2 B. 4 C. 6 D. 8

Cu 44: Cho 2,28 g X c CTPT C 3 H 8 O 5 N 2 (l mui ca -amino axit v HNO 3 ) phn ng vi 200ml dung dch NaOH 0,2M Sau phn ng c cn thu c m gam rn Y. Gi tr m l: A. 3,61 B. 2,61 C. 3,88 D. 3,34

Cu 45: Cho 1,52 gam hn hpX gm 2 amin n chc, no tc dng vi 200ml dung dch HCl C (mol/l); thy phn ng xy ra va v thu c 2,98 gam mui. Nu t ht 1,52g hn hp X ri ngng t nc; thu c V lt kh (iu kin chun). Gi tr V l: A. 1,344 B. 1,792 C. 2,24 D. 3,36

Cu 46: Cho 9,2 gam Na vo dung dch K 2 CO 3 d. Sau phn ng thu c V lt kh (iu kin chun). Gi tr V l: A. 4,48 B. 3,36 C.2,24 D.1,68

Cu 47: Cho 4,88 gam hn hpA: Fe 3 O 4 v Fe phn ng vi dung dch H 2 SO 4 long rt d, thu c dung dch B v 0,56 lt H 2 (iu kin chun). Th tch dung dch KMnO 4 0,25 M ti thiu cn phn ng ht dung dch B l: A. 20 ml B. 32 ml C. 40 ml D. 75 ml

Cu 48: Cho 8,4 gam Cacbonat M phn ng ht vi dung dch HCl d. Sau phn ng c cn dung dch thu c 9,5 gam rn. Kim loi M l : A. Mg B. Ca C. Ba D. Fe

Cu 49: Trn 100 ml dung dch X cha HCl 0,02 M v H 2 SO4 0,04 M vi 100 ml dung dch Y cha NaOH 0,04 M v Ba(OH) 2 0,02 M thu c dung dch Z. pH ca dung dch Z l: A. pH = 0,7 B. pH = 1 C. pH=2 D. pH=1,7

Cu 50: C 3 dung dch KOH, Fe(NO 3 ) 2 , NaNO 3 . phn bit 3 dung dch trn ta dng l: A. Ba B. Na C. Mg D. Al

Cu

p n

Cu

p n

Cu

p n

Cu

p n

Cu

p n

01 02 03 04 05 06 07 08 09 10

B C D D B B D C D D

11 12 13 14 15 16 17 18 19 20

A B C A D C A D A B

21 22 23 24 25 26 27 28 29 30

D B A B A C A C C B

31 32 33 34 35 36 37 38 39 40

A B B C B A C A C A

41 42 43 44 45 46 47 48 49 50

A D D D B A B A C D