Bi 1. Tnh th tch kh Cl2 thu c ( ktc) khi cho 15,8 gam KMnO4 tc dng vi axit HCl m c d? (5,6lit) Bi 2.

iu ch mt dung dch axit HCl bng cch ho tan 2 mol hiro clorua vo nc. sau un axit thu c vi MnO2 d. Kh clo thu c c tc dng vi 28 gam Fe hay khng? Bi 3. Ho tan 1 mol hiro clorua vo nc. Cho vo dd 300 gam dung dch NaOH 10%. Dung dch thu c c mi trng g? Bi 6. Cho 69,8 gam MnO2 tc dng vi HCl c d. Kh clo sinh ra cho i qua 500 ml dd NaOH 4M nhit thng. a) Vit cc phn ng xy ra trong th nghim? b) Tnh nng mol ca dung dch mui thu c, coi th tch dung dch thay i khng ng k? * Bi 7. C mt hn hp gm NaCl v NaBr, trong NaBr chim 10% v khi lng. Ho tan hn hp vo nc ri cho kh clo li qua dd cho n d. Lm bay hi dd cho n khi thu c mui khan. Khi lng hh u thay i bao nhiu %? ** Bi 8. C mt hn hp gm NaI v NaBr. Ho tan hn hp trong nc. cho Br 2 d vo dung dch. Sau khi phn ng thc hin xong, lm bay hi dung dch, lm kh sn phm th thy khi lng sn phm th thy khi lng sn phm nh hn khi lng hn hp hai mui ban u l m gam. Ho tan sn phm trong nc v cho clo li qua cho n d. li lm bay hi dd v lm kh cht cn li ngi ta thy khi lng cht thu c nh hn khi lng mui phn ng l m gam. Xc nh thnh phn % khi lng NaBr ban u? Bi 9. ra nh sng mt bnh thu tinh cha 2 l Cl2 v 1 lt H2. Sau mt thi gian c 30% th tch Cl2 tham gia phn ng, ta thu c 1 hn hp A. a) Tnh t l % th tch ca mi kh trong hn hp A sau phn ng? b) Cho hn hp A li qua nc ngoi nh sng. Tnh th tch cc kh thu c sau phn ng. Bi 10. Cho dung dch AgNO3 d vo 500g dd c cha 26,6g hh NaCl v KCl thu c 57,4g kt ta. Tnh nng % ca mi mui trong dung dch ban u? Bi 11. ho tan hon ton mt hh gm Zn v ZnO, ngi ta phi dng 100,8 ml dd HCl 36,5% c khi lng ring D = 1,19g/ml phn ng lm thot ra 8,96l kh ktc. Tnh khi lng v % khi lng ca Zn v ZnO trong hh ban u Bi 12. Ho tan hon ton 7,8g hh Al v Mg trong dd HCl. Sau phn ng thy khi lng dd tng 7g. tnh khi lng mi kim loi trong hh? Bi 13. lm sch 5g Br2 c ln tp cht l Cl2 ngi ta phi dng mt lng dd cha 1,6g KBr. Sau phn ng lm bay hi dd th thu c 1,155g mui khan. Hy xc nh t l % khi lng Cl2 trong Br2 em phn ng? Bi 14. iu ch 5,6l kh Cl2 ngi ta cho thuc tm rn tc dng vi 130ml dd HCl c khi lng ring D = 1,123g/ml. a) tnh khi lng thuc tm dng? b) Tnh nng % ca dung dch HCl dng bit rng hiu sut phn ng l 80%. Bi 15. Khi cho 0,54g kim loi c ho tr khng i tc dng ht vi dung dch HCl thu c 672 cm3 kh ktc. Hy xc nh kim loi dng ? Bi 16. Cho 300ml dd cha 51g AgNO3 vo 200ml dd cha 23,8g KBr. Lc b kt ta, trong nc lc c nhng cht no? Tnh nng mol/l ca mi cht? ( coi th tch dd khng thay i) Bi 17. Cho 36,8g hh CaO v CaCO3 ho tan trong 5l dd HCl ( va ) th c 4,48l CO2 thot ra ktc. a) Tnh thnh phn % khi lng mi cht trong hh ban u? b) Xc nh nng mol/l ca dung dch HCl dng? c) Xc nh nng mol/l ca mui thu c. Gi s th tch dd khng thay i. Bi 18. Th vin bi st nng 5,6g hnh cu vo 200ml dung dch HCl. Sau khi ng knh vin bi cn li bng ng knh ban u th kh ngng thot ra. Tnh nng mol/l ca dd HCl dng ? S: 0,875M. Bi 19. Ho tan mg hh Fe v kim loi M ho tr II ng trc H2 trong dy hot ng ho hc vo dung dch HCl d thu c 4,48l H2 ktc. Mt khc ho tan ht 4,8g M th dng cha n 500ml HCl 1M. Tm kim loi M Bi 20. Trn ln 150 ml dung dch HCl 10% ( khi lng ring D = 1,047g/ml ) vi 200ml dung dch HCl 2M c dung dch A. Ho tan 2,7 g hn hp Fe v Zn vo 400 ml dd A th phn ng xy ra va . Tnh nng mol/l ca dung dch A v % khi lng ca Zn c trong hh? Bi 21. Cho 30,64g hh NaCl v KCl tc dng vi H2SO4 c d un nng. Kh sinh ra c dn vo nc c 600ml dung dch HCl 0,8M. Tnh % khi lng mi mui trong hh ban u. Cho bao nhiu g hh Al v Fe vo 600 ml dung dch HCl trn c 26,41g mui khan. Bit phn ng xy ra va .
Bi 22. Cho cht oxi ho MnO2 tc dng vi axits HCl m c un nng th thu c kh Cl2 a) Cho lng kh Cl2 to thnh phn ng vi dung dch NaI thu c 12,7g I2. tnh khi lng Cl2 thu c. b) Tnh khi lng HCl b oxi ho

Bi 23. Xc nh nng mol ca dung dch KI. Bit rng 200ml dd tc dng ht vi kh Cl2 th gii phng 76,2 g I2. Bi 24. Xc nh nng % ca dung dch KBr. Bit rng 4,48 l kh Cl 2 ktc tc dng vi KBr c trong 88,87 ml dd KBr ( khi lng ring D=1,34g/ml) Bi 25. Dung dch A cha ng thi 2 axit HCl v H2SO4. trung ho 40 ml dd A cn dng va 60ml dung dch NaOH 1M. C cn dd sau khi tring ho thu c 3,76 gam hh mui khan. Xc nh nng mol ca tng axit trong hn hp A? **Bi 26. A v B l 2 dd axit HCl c nng mol khc nhau. Trn ln 1l A vi 3l B ta thu c dd D. trung ho 10ml dd D cn 15ml dung dch NaOH 0,1M. Nu trn 3l A vi 1l B ta thu c 4 l dd E. Cho 80ml dd E tc dng vi AgNO3 d thu c 2,87g kt ta. Tnh nng mol ca cc dd A, B, D, E? **Bi 27. Cho 11,2 lt hh kh gm Cl2 v O2 ktc tc dng va ht vi 16,98g hh gm Mg v Al to ra 42,34g hh mui clorua v oxit ca 2 kim loi . a) Tnh thnh phn % v th tch ca tng cht trong hh A. b) Tnh thnh phn % ca mi cht trong B. Bi 28. tnh nng mol/l ca dung dch thu c khi trn ln 200 ml dd HCl 2M vi 300ml dd HCl 4M. *Bi 29. Trn V1 l dd A cha 9,125g HCl vi V2 l dd B cha 5,475g HCl ta c 2l dd C. tnh nng mol ca cc dd A, B, C bit hiu s nng mol/l ca dung dch A v B l 0,4. Bi 30. Cho 16,59 ml dd HCl 20% ( D = 1,1g/ml) vo dd cha 51g AgNO3. a) Tm th tch dd NaCl 26% ( D = 1,2g/ml ) dng kt ta lng AgNO3 cn d. b) Tnh khi lng kt ta t lng AgNO3 ni trn. Bi 31. Cho 16ml dung dch HCl nng x mol/l gi l dung dch A, ngi ta thm nc vo dung dch A c 200ml dd A nng 0,1 mol/l. Hy xc nh x? Bi 33. Cho V lt dd HCl 2M tc dng vi ag Na 2CO3 thu c 4,48 lt CO2 ktc. Lng axit d trung ho bi 150 ml dd NaOH 1M th va . Tm a v V? Bi 34. Cho 100g dd HCl tc dng vi dd AgNO3 d th thu c 14,35g kt ta a) Tm nng % ca HCl. b) trung ho hon ton 10g dd axit trn cn bao nhiu ml dd NaOH 20% ( D = 1,2g/ml). Bi 35. Tnh nng mol/l ca dd axit HCl 18% ( D = 1,09 g/ml) ? Bi 36. Cho 50g CaCO3 tc dng va vi dd HCl 20% ( D = 1,2g/ml) a) Tnh th tch dd ca axit cn dng? b) Tnh nng % ca cht tan trong dung dch sau phn ng? Bi 38. Cho 25 g dd cha 3,25 g hh gm NaBr v CaCl2 tc dng vi 108 ml dung dch AgNO3 0,5M. Sau khi loi b kt ta ngi ta thm axit HCl vo dung dch thu c th li c thm 0,574 g kt ta na. Tm khi lng ca mi mui trong hh ban u? Bi 39. Mun c 5l dd HCl 1,2M th phi dng bao nhiu l dung dch HCl 2M v bao nhiu l dd HCl 1M.

Cu40 : Chia 2,29 gam hn hp ba kim loi: Zn, Mg, Al thnh hai phn bng nhau. Ho tan hon ton phn mt trong dung dch HCl gii phng 1,456 lt kh ktc v to ra a gam hn hp mui clorua. Oxi ho hon ton phn hai thu c b gam hn hp ba oxt. Gi tr ca a, b ln lt l: A. 5,67g v 2,185 g. B. 6,905 g v 3,33 g. C. 5,76 g v 2,185 g. D. 5,76 g v 3,225 g. Cu41: t 5,4 gam Al trong kh clo thu c 18,18 gam cht rn X. Cho hh X vo dd AgNO 3 d thu c m gam kt ta. Vy m l :A. 75,78 gam B. 77,58 gam. C. 78,75 gam D. 77,85 gam. Cu42: Cho cc cht sau y: FeCl3, Cl2, HCl, HF, H2S, Na2SO4. Cht no c th tc dng vi dung dch KI to ra I2:A. HF v HCl. B. Cl2, HCl. C. Na2SO4 v H2S. D. FeCl3 v Cl2. 43. Ha tan 10g hn hp A gm Fe v Fe2O3 (Fe=56; O=16) vo dung dch HCl va c 1.12lt hydro(ktc). %m st trong A l A). 19%. B). 72%. C). 28%. D). 27%. 44. Cho 250ml dung dch AgNO3 nng x (M)vo dung dch NaI d, c 58.75g kt ta. Gi tr ca x l(Ag=108; I=127)A). 2. B). 4. C). 3. D). 1. 45. Cho dung dch AgNO3 va vo dung dch A cha NaCl v NaBr,(Ag=108; N=14; O=16; Cl=35,5; Br=80) c lng kt ta nng bng lng AgNO3. %m NaCl trong A l A). 27.84%. B). 72.16%. C). 72.40%. D). 27.60%.

1) Can bang cac phan ng oxi hoa kh sau:

KMnO4 + HCl KCl + MnCl2 + Cl2 + H2O KClO3 + HCl KCl + Cl2 + H2O KOH + Cl2 KCl + KClO3 + H2O Cl2 + SO2 + H2O HCl + H2SO4 Fe3O4 + HCl FeCl2 + FeCl3 + H2O CrO3 + HCl CrCl3 + Cl2 + H2O Cl2 + Ca(OH)2 CaCl2 + Ca(OCl)2 + H2O 2) a) T MnO2, HCl ac, Fe hay viet cac phng trnh phan ng ieu che Cl2, FeCl2 va FeCl3. b) T muoi an, nc va cac thiet b can thiet, hay viet cac phng trnh phan ng ieu che Cl2 , HCl va nc Javel . 3) Hay viet cac phng trnh phan ng chng minh rang axit clohiric co ay u tnh chat hoa hoc cua mot axit. 4) Viet 1 phng trnh phan ng chng to axit HCl co tnh oxi hoa, 1 phng trnh phan ng chung to HCl co tnh kh. 5) Cho cac chat sau: KCl, CaCl2 , MnO2 , H2SO4 ac. Tron 2 hoac 3 chat vi nhau. Tron nh the nao e tao thanh hiro clorua? Tron nh the nao e tao thanh clo? Viet phng trnh phan ng. 6) Viet 3 phng trnh phan ng ieu che sat (III) clorua. 7) Neu hien tng xay ra khi a ra ngoai anh sang ong nghiem cha bac clorua co nho them t giot dung dch quy tm. Giai thch. 8) Axit HCl co the tac dung nhng chat nao sau ay? Viet phan ng xay ra: Al, Mg(OH)2 , Na2SO4 , FeS, Fe2O3 , Ag2SO4 , K2O, CaCO3 , Mg(NO3)2 . 9) Viet phng trnh phan ng xay ra khi cho lan lt cac chat trong nhom A {HCl, Cl 2} tac dung vi lan lt cac chat trong nhom B {Cu, AgNO3 , NaOH, CaCO3}. 10) T KCl, H2SO4 ac, MnO2 , Fe, CuO, Zn, hay ieu che FeCl3 , CuCl2 , ZnCl2 . 11) T NaCl, H2O, Fe va cac thiet b can thiet, hay ieu che FeCl3 , FeCl2 , Fe(OH)2 , Fe(OH)3. 12) Nhan biet cac dung dch mat nhan sau bang phng phap hoa hoc: a) KOH, K2SO4 , KCl, K2SO4 , KNO3 b) HCl, NaOH, Ba(OH)2 , Na2SO4 c) HCl, HNO3 , H2SO4 , HBr d) KCl, K2SO4 , KNO3 , KI e) BaCl2 , K2SO4 , Al(NO3)3 , Na2CO3 13) Nhan biet cac dung dch sau bang phng phap hoa hoc: a) NaNO3 , NaCl, HCl. b) NaCl, HCl, H2SO4 14) ien cac hp chat cha clo vao cac ky t A, B cho phu hp: a) A1 + H2SO4 = B1 + Na2SO4 b) A2 + CuO = B2 + CuCl2 c) A3 + CuSO4 = B3 + BaSO4 d) A4 + AgNO3 = B4 + HNO3 a) b) c) d) e) f) g)

e) A5 + Na2S = B5 + H2S f) A6 + Pb(NO3)2 = B6 + KNO3 g) A7 + Mg(OH)2 = B7 + H2O h) A8 + CaCO3 = B8 + H2O + CO2 i) A9 + FeS = B9 + H2S 15) Thc hien chuoi phan ng sau: a) NaCl HCl Cl2 HClO HCl AgCl Ag CuCl2 HCl b) KMnO4 Cl2 CuCl2 FeCl2 HCl HCl CaCl2 Ca(OH)2 c) KCl HCl Cl2 Br2 I2 FeCl3 AgCl Ag 16) Viet phng trnh phan ng xay ra khi cho cac chat trong nhom A lan lt tac dung cac chat trong nhom B. a) A: HCl, Cl2 B: KOH ac (to), dung dch AgNO3 , Fe, dung dch KBr b) A: HCl, Cl2 B: KOH (to thng), CaCO3 , MgO , Ag 17) Ke ten mot so muoi cua axit cha oxi cua clo. Neu phng phap chung e ieu che chung? Viet phng trnh phan ng minh hoa cho tng chat. 18) Viet phng trnh phan ng thc hien chuoi bien hoa sau: a) Kali clorat kali clorua hiro clorua ong (II) clorua bari clorua bac clorua clo kali clorat b) Axit clohiric clo nc Javen clorua voi clo brom iot c) CaCO3 CaCl2 NaCl NaOH NaClO NaCl Cl2 FeCl3 AgCl 19) So sanh tnh chat hoa hoc cua flo, brom va iot vi clo. 20) Viet cac phng trnh phan ng e chng to quy luat: hoat ong hoa hoc cua cac halogen giam dan theo chieu tang ien tch hat nhan nguyen t cua chung. Giai thch? 21) Tai sao co the ieu che nc clo nhng khong the ieu che nc flo? 22) Hiro florua thng c ieu che bang cach cho axit sunfuric ac tac dung vi canxi florua. Hay tnh khoi lng canxi florua can thiet e ieu che 2,5 (kg) dung dch axit flohiric 40%. 23) Thc hien chuoi phan ng sau: a) I2 KI KBr Br2 NaBr NaCl Cl2 HI AgI HBr AgBr b) H2 F2 CaF2 HF SiF4 c) KMnO4 Cl2 KClO3 KCl HCl CuCl2 AgCl Cl2 clorua voi d) HBr Br2 AlBr3 MgBr2 Mg(OH)2 I2 NaI AgI 24) Nhan biet cac hoa chat mat nhan sau: a) Dung dch: HCl, KCl, KBr, NaI. b) Dung dch: I2 , Na2CO3 , NaCl, NaBr. c) Dung dch: KOH, HCl, HNO3 , K2SO4 , BaCl2 . d) Chat ran: CaCO3 , K2CO3 , NaCl, KNO3 . e) Chat ran: AgCl, KCl, BaCO3 , KI.

HALOGEN

25) a) b) c) d) e) f) 26) a)

Viet phng trnh ma trong o: Clo the hien tnh oxi-hoa . Clo va the hien tnh oxi-hoa va the hien tnh kh. HCl the hien tnh oxi-hoa. HCl the hien tnh kh HF the hien tnh chat ac biet cua mot axit . HCl the hien tnh axit. Viet phng trnh chng minh: Tnh oxi hoa cua cac halogen giam dan t Flo en Iot. b) Viet hai phng trnh chng minh Cl2 co tnh oxihoa. Viet hai phng trnh trong o Cl2 va the hien tnh oxihoa va the hien tnh kh. c) Viet phng trnh trong o co axt clohidric tham gia vi vai tro la chat oxihoa, chat kh, la mot phan ng trao oi. 27) Hay cho biet: a) Tai sao khi ieu che HCl t NaCl ta phai dung NaCl dang tinh the va H2SO4 am ac b) Tai sao nc clo co tnh tay mau nhng e lau ngoai khong kh khong con tnh chat nay. c) Tai sao ta co the ieu che HF, HCl t muoi tng ng va axt H 2SO4 am ac ma khong ieu che c HBr, HI bang cach nay. d) Nc clo la g? Tai sao nc clo co tnh tay mau? Neu e lau ngoai khong kh th nc clo con tnh tay mau khong? e) Nc Javen la g? Clorua voi? Kaliclorat? f) Tai sao khong dung bnh thuy tinh e ng dung dch HF? g) Tai sao ieu che Cl2, Br2, I2 t HX va MnO2 ma khong dung cac tng t e ieu che F2? e ngh phng phap ieu che F2. h) Tai sao ieu che c nc clo ma khong ieu che c nc flo? i) Tai sao khong dung bnh thep am e ng kh clo? j) Khi ieu che Cl2 t NaCl bang phng phap ien phan dung dch th thiet b phai co mang ngan, tai sao? k) Tai sao dung dd HF e khat kieng? l) Bang cach nao co the phat hien trong bnh ng kh HCl co lan kh Cl2? 28) Giai thch cac hien tng sau: a) M bnh ng kh hidroclorua trong khong kh am th xuat hien khoi. b) Cho mau giay quy tm am vao bnh ng kh clo th luc au quy chuyen sang mau o sau o chuyen sang mau trang (khong mau), tai sao? c) Dan kh clo qua bnh ng dung dch KI co ho tinh bot th dung dch dan chuyen sang mau xanh ac trng. d) Cho bot CuO (mau en) vao dung dch HCl th dung dch dan chuyen sang mau xanh. 29) Quan sat hien tng, giai thch hien tng, viet phng trnh phan ng: a) Khi kh Clo suc qua dung dch hon hp KI va ho tinh bot. b) a ong nghiem ng AgCl co vai giot quy tm ra ngoai anh sang. c) Dan kh Cl2 lan lt vao cac dung dch: NaCl, KI co ho tinh bot, NaBr. Neu thay bang Br2. 30) Viet phan ng khi cho kh Clo tac dung vi Fe, H2O, KOH. T cac phan ng hay cho biet vai tro cua Clo. 31) Viet phng trnh phan ng (neu co) a) Cho Cl2 gap lan lt cac chat sau: Kh H2S, dung dch H2S, NaBr, HI, CaF2, Al, Cu, Fe, NH3 dung dch Na2SO3, dung dch Na2S, dung dch KOH. b) Cho HCl gap lan lt cac chat sau: CaCO3, KOH, NaClO, KClO3, MnO2, KMnO4, AgNO3, NaBr, CuO, Mg, Fe, Cu. c) Cho axt H2SO4 am ac tac dung lan lt vi cac muoi khan sau: CaF2, NaCl, NaBr, KI. Neu thay bang dung dch H2SO4 va dung dch cac muoi o th co xay ra phan ng hay khong? d) CO2 tac dung vi dung dch CaOCl2,

HALOGEN

HALOGEN e) Dung dch HCl am ac tac dung vi CaOCl2 co nhiet. 32) Cho cac chat sau : KCl, MnO2, CaCl2, H2SO4 . em tron 2 hoac 3 chat vi nhau nh
the nao e thu c kh Hidroclorua ? kh Clo ? Viet cac phng trnh phan ng. 33) Dung phan ng hoa hoc nao e sap xep c tnh chat ac trng o gia cac halogen ? 34) Bang phng phap hoa hoc hay phan biet cac dung dch sau (ch dung 1 thuoc th): a) HCl, AgNO3, KBr, KI, CaF2, KOH. b) HCl, AgNO3, HBr, HI, KOH, nc clo. c) HCl, AgNO3, HBr, KI, HF, KOH. d) HCl, HI, NaCl, KBr, KOH, CaF, Nc Clo (c dung thuoc th tuy y). 35) Ch dung mot thuoc th nhan biet cac dung dch sau: a) HCl, MgCl2, KBr, KI, NaOH, AgNO3, CaF2. b) NH4Cl, FeCl3, MgBr2, KI. 36) Hoan thang cac phng trnh phan ng sau ( ghi ro ieu kien) ( 2) ( 4) (5) ( 6) a) NaCl (1) HCl FeCl2 ( 3) FeCl3 AgCl Cl2 Clorua voi ( 2) ( 4) ( 6) b) NaCl (1) Cl2 KClO3 ( 3) KCl HCl ( 5) FeCl3 NaCl ( 2) ( 4) (5) ( 6) c) KClO3 (1) Cl2 Clorua voi ( 3) Cl2 NaClO Cl2 nc clo ( 2) ( 4) d) Natriclorua (1) Hidroclorua Magieclorua ( 3) Kaliclorua Kh clo (5) ( 6) Kaliclorat Kalipeclorat MnO2 Cl2 HCl Cl2 NaClO NaCl Cl2. NaCl NaOH NaCl HCl Cl2 KClO3 KCl KNO3. KMnO4 Cl2 NaCl HCl CuCl2 NaCl Cl2 NaClO NaCl HCl. MnO2 Cl2 HCl NaCl Cl2 Br2 KClO3 KCl Cl2 NaCl HCl k) A C E NaCl NaCl NaCl NaCl B D F 1 2 3 l) KMnO4 Cl2 NaCl HCl 4 FeCl2 5 nc Javen m) NaCl 1 HCl 2 Cl2 3 HCl 4 CuCl2 5 nc clo 1 2 n) NaCl Cl2 HCl 3 FeCl3 4 Fe(NO3)3 5 Nc Javen ( 2) ( 4) o) Natriclorua (1) Hidroclorua Magieclorua ( 3) Kaliclorua Kh clo (5) ( 6) Kaliclorat Kalipeclorat 37) Cho biet cac chat sau co cung ton tai hay khong? Tai sao? a) Cl2 & dung dch H2S b) NaCl & Br2 c) Cl2 & dung dch KI d) HCl & Na2CO3 e) Cl2 & kh H2S f) N2 & Cl2 h) CuO & dd HCl g) dd HCl& AgNO3 i) Cl2 & dd NaBr j) dd NaOH & Cl2 k) dd HCl& Fe3O4 l) Ag2O & dd HCl 38) T NaCl, H2SO4, Fe Viet phng trnh phan ng ieu che FeCl3, FeCl2. 39) T KCl va H2O viet phng trnh ieu che: nc Javen, Kalipeclorat 40) T MnO2, NaCl, H2O viet phng trnh ieu che HCl va O2 .

e) f) g) h) i) j)