de Thi HSG Hoa BacLieu

S GD&T BC LIU
K THI HSG BSCL LN TH 16 - NM 2009
thi ngh
(Gm 9 cu)
Mn: Ha hc
Thi gian: 180 pht (Khng k thi gian giao )
:
Cu I: (2,5 )
1. Trong s cc hp cht cacbonyl halozenua COX2 , ngi ta ch c th iu ch c 3 cht
cacbonyl halozenua l : cacbonyl florua COF2 , cacbonyl clorua COCl2 , cacbonyl bromua
COBr2
a.V sao khng iu ch c COI2 ?
b. So snh gc lin kt ca cc phn t cacbonyl halozenua trn ?
c. Sc kh COCl2 qua dung dch NaOH nhit thng.Vit phng trnh phn ng xy
ra ?
2. Hy chng minh rng phn th tch b chim bi cc n v cu trc (cc nguyn t) trong
mng tinh th kim loi thuc cc h lp phng n gin, lp phng tm khi, lp phng
tm din tng theo t l 1 : 1,31 : 1,42.
Cu II: (3,0 )
1. Ha tan sn phm rn ca qu trnh nu chy hn hp bt mt khong cht en,
kalihydroxit v kali clorat, thu c dung dch A c mu lc m. Khi trong khng kh
chuyn dn thnh mu tm.Qa trnh cn chuyn nhanh hn nu sc kh clo vo dung dch
A hay khi in phn dung dch A .
Hy nu tn khong cht? Vit cc phng trnh phn ng xy ra trong cc th nghim trn?
2.Dung dch A c to thnh bi CoCl2 0,0100 M ; NH3 0,3600 M v
H2O2 3,00.10 3 M.
a.. Tm thnh phn gii hn ca dung dch A ?
b. Tm pH ca dung dch A ?
Cho: pKa: NH4+ 9,24
Eo: Co3+/Co2+ 1,84V; H2O2/2OH 0,94V; Ag+/Ag 0,799V.

Co3+ + 6NH3
Co(NH3)63+ ; 1 = 10 35,16
Co2+ + 6NH3
Co(NH3)62+ ; 2 = 104,39
RT
F ln = 0,0592 lg
Cu III: (2,0 )
Phn ng trong pha kh 250C : 2N2O5 4NO2 + O2
C hng s tc bng 1,73.10-5s-1
a. Hy cho bit bc ca phn ng v vit phng trnh ng hc m t tc ph thuc vo
nng cht?
b. Tnh tc tiu th N2O5 v tc to thnh NO2 , O2. .Tm tc ca phn ng xy ra
trong bnh c dung tch 100 ml cha N2O5 p = 0,10 atm ; 250C.
c. S phn t N2O5 b phn hy?
Cu IV: (2,0 )
Cho cc phng trnh nhit ha hc sau y:
(1) 2 ClO2 (k) + O3 (k)
Cl2O7 (k)
H0 = - 75,7 kJ
(2)
O3 (k)
O 2 (k) + O (k)
H0 = 106,7 kJ
(3) 2 ClO3 (k) + O (k)
Cl2O7 (k)
H0 = - 278 kJ
(4)
O2 (k)
2 O (k)
H0 = 498,3 kJ.
Hy xc nh nhit ca phn ng sau:
1
(5)
ClO2 (k) + O (k)
ClO3 (k).
Cu V: (2,0 )
Dung dch A gm FeSO4 0,020 M; Fe2(SO4)3 v H2SO4.
a. Ly chnh xc 25,00 ml dung dch A, kh Fe 3+ thnh Fe2+; chun Fe2+ trong hn hp (
iu kin thch hp) ht 15 ml K 2Cr2O7 0,02 M. Hy vit phng trnh ion ca phn ng
chun . Tnh nng M ca Fe2(SO4)3 trong dung dch A.
b.Tnh nng M ca H2SO4 trong dung dch A, bit dung dch ny c pH = 1,00.
Cho pKa: HSO4- 1,99;
2+
+
Fe3+ + H2O
FeOH + H pKa = 2,17;
+
+
Fe2+ + H2O
FeOH + H pKa = 5,69.
Eo : Fe3+/ Fe2+ 0,771 V; Ag+/Ag 0,799 V; (RT/F)ln = 0,0592 lg.
Cu VI: (2,0 )
Anlylmagie bromua (A) phn ng vi acrolein to thnh cht B, sau khi thy phn B s c
sn phm C duy nht. un nng C nhn c cht D. Cho D phn ng vi C6H5Li thu c
sn phm E. un nng E khi c vt iot th c F c cng thc C12H14.
1. Hon thnh s dy phn ng trn (vit cng thc cu trc ca cc cht hu c trn t C
n F).
2. Ghi k hiu c ch cc giai on ca phn ng di dng cc mi tn trong s , tr giai
on to thnh F.
3. Cho bit cu hnh bn ca F.
Cu VII (2,5 im)
Sau khi x l hn hp li ng hoc v tru c cha pentozan (C 5H8O4)n vi dung dch axit clohiric 12%
ri tin hnh chng ct, nhn c cht lng A (C5H4O2) mu vng c mi thm. Cho A phn ng vi
KOH ri axit ha th nhn c B (C5H4O3) v C (C5H6O2).
a. Vit phng trnh phn ng thu phn pentozan to thnh A v cng thc ca A, B, C.
b. Vit phng trnh phn ng ca B tc dng vi C khi c xc tc axit.
c. Hy trnh by iu kin nitro ho A nhn c D (C5H3NO4).
Cu VIII (2,0 im)
Vit cng thc theo cu trc ca s phn ng sau:
axit propiolic CH3OH
HCOOOH
(CH3CO)2O d
, dien
S cis buta 13
A
B
C
D
135 0 C
H+
H2O
piridin
NBS
H2O
F xiclohexanon
E
G
+
CCl
4
CH3COOAg
Cu IX (2,0 im)
Vit s phn ng oxi ha D-glucoz bng dung dch brom v dung dch HNO3 to thnh
hai axit tng ng.Vit cng thc Haworth cc mono v di -lacton ca hai axit ; gi tn cc
lacton ?
---Ht---
S GD&T BC LIU
K THI HSG BSCL LN TH 16 - NM 2009
thi ngh
(Gm 9 cu)
Mn: Ha hc
Thi gian: 180 pht (Khng k thi gian giao )
2
HNG DN CHM:
Cu I: (2,5 )
1. Trong s cc hp cht cacbonyl halozenua COX2 , ngi ta ch c th iu ch c 3 cht
COBr2
a.V sao khng iu ch c COI2 ?
ra ?
tm din tng theo t l 1 : 1,31 : 1,42.
Cu II: (3,0 )
H2O2 3,00.10 3 M.
Cho: pKa: NH4+ 9,24

Co3+ + 6NH3
Co(NH3)63+ ; 1 = 10 35,16
Co2+ + 6NH3
Co(NH3)62+ ; 2 = 104,39
RT
F ln = 0,0592 lg
Cu III: (2,0 )
nng cht?
Cu IV: (2,0 )
(1) 2 ClO2 (k) + O3 (k)
Cl2O7 (k)
H0 = - 75,7 kJ
(2)
O3 (k)
O 2 (k) + O (k)
H0 = 106,7 kJ
(3) 2 ClO3 (k) + O (k)
Cl2O7 (k)
H0 = - 278 kJ
(4)
O2 (k)
2 O (k)
H0 = 498,3 kJ.
(5)
ClO2 (k) + O (k)
ClO3 (k).
Cu V: (2,0 )
3

iu kin thch hp) ht 15 ml K 2Cr2O7 0,02 M. Hy vit phng trnh ion ca phn ng
2+
+
Fe3+ + H2O
+
+
Fe2+ + H2O
Cu VI: (2,0 )
n F).
on to thnh F.
Cu VII (2,5 im)
Cu VIII (2,0 im)
HCOOOH
(CH3CO)2O d
, dien
S cis buta 13
A
B
C
D
+
0
135 C
H
H2O
piridin
NBS
H2O
F xiclohexanon
E
G
+
CCl
4
CH3COOAg
Cu IX (2,0 im)
lacton ?
S GD&T BC LIU
K THI HSG BSCL LN TH 16

NM HC 2007-2008
HNG DN CHM THI NGH
Mn thi: HA HC
Cu I: (2,5 )
1.Trong s cc hp cht cacbonyl halozenua COX2 , ngi ta ch c th iu ch c 3 cht
COBr2
4
a. V sao khng iu ch c COI2 ?

ra ?
tm din tng theo t l 1 : 1,31 : 1,42
Hng dn gii: 1a ( 0,5 ) + 1b ( 0,5 ) + 1c ( 0,5 ) + 2 ( 1 )
1.a. phn t COX2 , khi tng kich thc v gim m in ca X lm gim bn ca
lin kt C-X . Do phn t COI2 rt khng bn , v khng tn ti .
1.b. Phn t COX2 phng, nguyn t trung tm C trng thi lai ho sp2
X
O=C
X
o
Gc OCX > 120 cn gc XCX < 120 v lin kt C=O l lin kt i, cn lin kt C-X l
lin kt n.Khi m in ca X tng th cp electron lin kt b ht mnh v pha X. Do
gc XCX gam, gc OCX tng.
1.c. Sc kh COCl2 qua dung dch NaOH nhit thng ta c phn ng:
COCl2 + 4 NaOH
Na2CO3 + 2 NaCl + 2 H2O
2. Phn th tch b chim bi cc nguyn t trong mng tinh th cng chnh l phn th tch
m cc nguyn t chim trong mt t bo n v ( mng c s).
- i vi mng n gin:
1
+ S nguyn t trong 1 t bo: n = 8 x = 1
8
+ Gi r l bn knh ca nguyn t kim loi, th tch V1 ca 1 nguyn t kim loi l:
4
V1 =
x r3 (1)
3
+ Gi a l cnh ca t bo, th tch ca t bo l:
V2 = a3 (2)
Trong t bo mng n gin, tng quan gia r v a c th hin trn hnh sau:
r
a
a
hay a = 2r (3).
Thay (3) vo (2) ta c: V2 = a3 = 8r3 (4)
Phn th tch b chim bi cc nguyn t trong t bo l:
V1 4
r3 : 8r3 =
=
= 0,5236
V2 3
6
-i vi mng tm khi:
1
4
+ S nguyn t trong 1 t bo: n = 8 x + 1 = 2. Do V1 = 2 x ( ) r3 .
8
3
+ Trong t bo mng tm khi quan h gia r v a c th hin trn hnh sau:
Do : d = a 3 = 4r. Suy ra a = 4r/ 3

Th tch ca t bo:
V2 = a3 = 64r3/ 3 3
Do phn th tch b chim bi cc nguyn t trong t bo l:
V1 8 r 3 3 3
=
= 0,68
V2
3 x 64 r 3
i vi mng tm din:
1
1
+ S nguyn t trong 1 t bo: n = 8 x + 6 x = 4. Do th tch ca cc nguyn t trong
8
2
t bo l:
4
V1 = 4 x r3
3
+ Trong t bo mng tm din quan h gia bn knh nguyn t r v cnh a ca t bo c
biu din trn hnh sau:
d
T d ta c:
d = a 2 = 4r, do a = 4r/ 2
Th tch ca t bo:
V2 = a3 = 64r3/2 2
Phn th tch b cc nguyn t chim trong t bo l:
V1
16 r 3 2 3
=
= 0,74
V2
3x 64 r 3
Nh vy t l phn th tch b chim bi cc nguyn t trong 1 t bo ca cc mng n gin,
tm khi v tm din t l vi nhau nh 0,52 : 0,68 : 0,74 = 1 : 1,31 : 1,42.
Cu II: (3,0 ) =
1 ( 1 ) + 2 ( 1 )
Hng dn gii:
Khong cht en: MnO2 mangandioxit.
Cc phn ng xy ra:
3MnO2 + 6KOH + KClO3 = 3K2MnO4 + 3H2O + KCl
(1)
3K2MnO4 + 2H2O = 2KMnO4 + MnO2 + 4KOH
(2)
2KOH + CO2 = K2CO3
(3)
6
Phn ng ny lm cn bng (2) chuyn dch dn sang phi:

2K2MnO4 + Cl2 = 2KMnO4 + 2KCl
in
2K2MnO4 + 2H2O phn
2KMnO4 + 2KOH + H2
H2O2 3,00.10 3 M.
Cho: pKa: NH4+ 9,24

Co3+ + 6NH3
Co(NH3)63+ ; 1 = 10 35,16
Co2+ + 6NH3
Co(NH3)62+ ; 2 = 10 4,39
RT
F ln = 0,0592 lg
Hng dn gii:
1.
CoCl2
Co2+
+
2Cl
0,0100 M
----0,0100 M
To phc ca ion coban vi NH3
Co2+
+ 6 NH3
Co(NH3)62+
0,0100 M 0,3600M
----0,3000 M
0,0100 M
= 104,39
Oxi ha Co(NH3)62+ bi H2O2.

2 Co(NH3)62+
Co(NH3)63+ + e
H2O2 + 2e
2OH
2 Co(NH3)6
2+
+ H 2 O2
2 Co(NH3)6
3+
2 (0,94 o
E2 )
+ 2OH ; K = 10
0,0592
Th kh chun ca cp Co(NH3)63+/Co(NH3)62+ :
Co(NH3)63+
Co3+ + e
Co2+ + 6 NH3
Co3+ + 6 NH3
Co2+
Co(NH3)62+
Co(NH3)63+ + e
Co(NH3)62+
11
K1 = 10
2
0,0592
K2 = 10
0,0592
oE
o
1
2
2 = E 1 + 0,0592 lg
o
E2 = 1,84 + 0,0592 (4,39 35,16) = 0,0184 (V)
K2 = K 1
2 (0,94 o
E2 )
K = 10
oE
;
;
;
oE
2
1
1031
0,0592
2 Co(NH3)62+ + H2O2
2 Co(NH3)63+ + 2OH ; K = 1031
0,0100M
0,0030M
0,0040M
----0,0060M
0,0060 M
Thnh phn gii hn hn hp A
Co(NH3)62+
0,0040 M
(1)
Co(NH3)63+
0,0060 M
NH3
0,3000 M
(1)
OH
0,0060 M
Tm pH ca dung dch:
7
S phn li ca cc phc cht trong dung dch khng ln v ln v c NH3 d.

Tnh pH theo cn bng:
C
[ ]
NH3
+
0,3000
(0,3000 - x)
H2O
NH4+
x
OH
6.10-3
-3
(6.10 + x)
(2)
x (0,0060 += 104,76
x = 7,682.10 4 << 0,3000 M
x)
3
[OH
] = 6,768.10
pH = 11,8305
0,3000
- x => pOH = 2, 1695
Cu III: (2,0 )
nng cht?
Hng dn gii:
a) Phn ng trong pha kh 250C : 2N2O5 4NO2 + O2
dC
1 dC
1 dC
phn ng = N2O5 = + NO2 = + O2
(1)
2
dt
4
dt
dt
nN2O5
0,1
P
b) pi V = ni RT C N2O5 =
= i = 0, 082 298 = 4,092.10-3(mol.l-1)
V
RT
phn ng = k C N2O5 = 1,73.10-5 4,092.10-3 = 7,079. 10-8 mol. l-1.s-1.
T phng trnh 2N2O5 (k) 4NO2 (k) + O2 (k) v phng trnh tc (1)
nn tiu th (N2O5) =
dC N O
2 5
dt
= 2V phn ng = 2 7,079. 10-8= 1,4158.10-7mol.l-1.s-1.
Du tr ch N2O5 b mt i.
hnh thnh (NO2)= 4 phn ng = 4 7,079. 10-8 = 2,831.10-7 mol.l-1.s-2.
hnh thnh (O2) = phn ng = 7,079. 10-8 mol.l-1.s-2
c. S phn t N2O5 b phn hy = tiu th (N2O5) Vbnh t N0(s avogadrro)
= 1,4158.10-7 0,1 1 6,023.1023 = 8,5274.1015 phn t
Cu IV: (2,0 )
(1) 2 ClO2 (k) + O3 (k)
Cl2O7 (k)
(2)
O3 (k)
O 2 (k) + O (k)
(3) 2 ClO3 (k) + O (k)
Cl2O7 (k)
(4)
O2 (k)
2 O (k)
(5)
ClO2 (k) + O (k)
ClO3 (k).
Hng dn gii:
Kt hp 2 pt (1) v (3) ta c
ClO2 (k) + 1/2 O3 (k)
1/2 Cl2O7 (k)
1/2 Cl2O7 (k)
ClO3 (k) + 1/2 O (k)
H0
H0
H0
H0
= - 75,7 kJ
= 106,7 kJ
= - 278 kJ
= 498,3 kJ.
H0 = - 37,9 kJ
H0 = 139 kJ
(6) ClO2 (k) + 1/2 O3 (k)
ClO3 (k) + 1/2 O (k)
H0 = 101,1 kJ
ClO2 (k) + 1/2 O3 (k)
1/2 O2 (k) + 1/2 O (k)
ClO3 (k) + 1/2 O (k)

1/2 O3 (k)
H0 = 101,1 kJ
H0 = -53,3 kJ
(7) ClO2 (k) + 1/2 O2 (k)
ClO3 (k)
H0 = 47,8 kJ
ClO3 (k) + 1/2 O (k)

1/2 O2 (k)
ClO2 (k) + 1/2 O3 (k)
O (k)
H0 = 101,1 kJ
H0 = - 249,1 kJ
(5) ClO2 (k) + O (k)

ClO3 (k)
H0 = - 201,3 kJ.
Cu V: (2,0 )
iu kin thch hp) ht 15 ml K2Cr2O7 0,02 M. Hy vit phng trnh ion ca phn ng
2+
+
Fe3+ + H2O
+
+
Fe2+ + H2O
Hng dn gii:
2
3. a) Phn ng chun : Cr2O 7 + 6 Fe2+ + 14 H+ 2 Cr3+ + 6 Fe3+ + 7 H2O

3.10-4mol 18.10-4mol
18.10-4mol
nFeSO 4 (ban u) = 5.10-4 mol
18.104 5.104
= 0,026 M
2
4
3
CFe (SO ) =
2 x 0,025
b) Trong dd A c: Fe2+ 0,020 M; Fe3+ 0,052M; H+ (C, M); HSO 4 (C, M); cc cn bng:
+
2 H2 O
Kw = 10-14 (1)
H3O + OH
+
+
-5,96
Fe2+ + 2 H2O
(2)
FeOH + H3O Ka1 = 10
3+
2+
+
-2,17
Fe + 2 H2O
(3)
FeOH + H3O Ka2 = 10
HSO 4 + H2O
+ H3O+ Ka = 10-1,99 (4).
SO 4
So snh ta thy (3) v (4) l ch yu v tng ng nhau. p dng /lut bo ton proton, ta c
2
[H3O+] = CH + [FeOH2+] + [SO 4 ]

2+
(a)
+
2+
3+
T (3) c [FeOH ] / [Fe ] = Ka2 / [H3O ] [FeOH ] / CFe = Ka2 / Ka2 + [H3O+]
3+
= 10-2,17 / (10-2,17 + 10-1,07) [FeOH2+] = 0,0736 CFe = 0,0736 . 0,052 = 3,8272.10-3M
2
T/ t, t (4) c [SO 4 ] / [HSO 4 ] = Ka / [H3O+]

2
3+
[SO 4 ] / CHSO 4 = 10-1,99/ (10-1,99 + 10-1,07) [SO 4 ] = 0,107 C;

3+
P/ trnh (a) tr thnh [H3O+] = C + 0,0736 CFe + 0,107 C
(b).
101 3.8272 x103

T (b) CH SO = C =
= 0,08743M CH 2 SO 4 = C = 0,08743 M.
1 + 0,1
Cu VI: (2,0 )
n F).
on to thnh F.
2
Hng dn gii:
+
CH2=CH-CH2-MgBr
+
CH2 =CH-CH =O
thu ph
n
AN
cng 1, 4
H3O+
CH2=CH-CH2-CH2-CH=CH2-OMgBr
B
CH2=CH-CH2-CH2-CH=CH-OH
tautome ho
CH2=CH-CH2-CH2-CH2-CH=O
D
Hoc:
CH2=CH-CH2-MgBr
AN
H2O
+
CH2=CH-CH2-CH-CH=CH2
CH2=CH-CH2-CH-CH=CH2
cng 1, 2
-MgBr(OH)
CH2=CH-CH=O
B OMgBr
C
OH
H bin
OH
t
Chuyn v 3, 3
C6H5
H
OLi
OH
H2O
xeto-enol
D
C6H5
H
E OH
C6H5Li
AN
Vt iot, to
- H2O
C6H5
F c cu hnh E bn hn cu hnh Z
Cu VII (2,5 im)
Hng dn gii:
1. Trong li ng v v tru c cha pentozan,khi un nng vi dung dch HCl 12% chuyn
thnh pentoz ri tch nc cho fufurol
10
CHO
- 3H2O
(CHOH)3
(C5H8O4)n HCl 12%
CH2OH
2
O A
CHO
O C
COOK
O
b.
KOH
H3O+
A(C5H4O2)
CH2OH
COOK
COOH
B
COOH +
CHO
CH2OH
H+
COOCH2
c. nitro ho A cn phi bo v nhm anehit bng (CH3CO)2O

(CH3CO)2O
CHO
CH(OCOCH3)2
Thc hin phn ng nitro ho, sau thu phn phc hi nhm -CHO
CH(OCOCH3)2
HNO3
O2N
CH(OCOCH3)2
H3O+
O2N
CHO
D
Cu VIII (2,0 im)

HCOOOH
(CH3CO)2O d
, dien
S cis buta 13
A
B
C
D
+
0
135 C
H
H2O
piridin
NBS
H2O
F xiclohexanon
E
G
+
CCl
CH3COOAg
Hng dn gii:
COOH
COOH
COOCH3 HO
COOH
C
HO
CH3COO
COOCH3
CH3COO
CH3COO
COOCH3
CH3COO
D
HO
COOH
HO
Br
HO
COOH
O
F
OH
Cu IX (2,0 im)
lacton ?
11
Hng dn gii:
Cc sn phm oxi ho D-glucoz v cc lacton ca tng ng.
O
COOH
CHO
OH
OH
HO
OH
OH
CH2OH
HNO3
COOH
OH
HO
OH
OH
COOH
Br2
HO
H2O
OH
O
OH
OH
OH
D- -gluconolacton
OH
HO
CH2OH
CH2OH
axit gluconic
COOH
OH
O
CH2OH
OH
O
OH
OH
COOH
O
OH HO
OH
O
O
O
O
O
OH
1,4-lacton ca axit glucaric
1,4:3,6-dilactonca axit glucaric
3,6-lacton ca axit glucaric
OH
---Ht---
12

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S GD&T BC LIU

K THI HSG BSCL LN TH 16 - NM 2009

Eo: Co3+/Co2+ 1,84V; H2O2/2OH 0,94V; Ag+/Ag 0,799V.

K THI HSG BSCL LN TH 16 - NM 2009

Eo: Co3+/Co2+ 1,84V; H2O2/2OH 0,94V; Ag+/Ag 0,799V.

a. Ly chnh xc 25,00 ml dung dch A, kh Fe 3+ thnh Fe2+; chun Fe2+ trong hn hp (

K THI HSG BSCL LN TH 16

a. V sao khng iu ch c COI2 ?

Na2CO3 + 2 NaCl + 2 H2O

Do : d = a 3 = 4r. Suy ra a = 4r/ 3

3MnO2 + 6KOH + KClO3 = 3K2MnO4 + 3H2O + KCl

3K2MnO4 + 2H2O = 2KMnO4 + MnO2 + 4KOH

2KOH + CO2 = K2CO3

Phn ng ny lm cn bng (2) chuyn dch dn sang phi:

Eo: Co3+/Co2+ 1,84V; H2O2/2OH 0,94V; Ag+/Ag 0,799V.

Oxi ha Co(NH3)62+ bi H2O2.

S phn li ca cc phc cht trong dung dch khng ln v ln v c NH3 d.

= 2V phn ng = 2 7,079. 10-8= 1,4158.10-7mol.l-1.s-1.

(6) ClO2 (k) + 1/2 O3 (k)

ClO3 (k) + 1/2 O (k)

ClO3 (k) + 1/2 O (k)

(7) ClO2 (k) + 1/2 O2 (k)

ClO3 (k) + 1/2 O (k)

(5) ClO2 (k) + O (k)

3. a) Phn ng chun : Cr2O 7 + 6 Fe2+ + 14 H+ 2 Cr3+ + 6 Fe3+ + 7 H2O

[H3O+] = CH + [FeOH2+] + [SO 4 ]

T/ t, t (4) c [SO 4 ] / [HSO 4 ] = Ka / [H3O+]

[SO 4 ] / CHSO 4 = 10-1,99/ (10-1,99 + 10-1,07) [SO 4 ] = 0,107 C;

P/ trnh (a) tr thnh [H3O+] = C + 0,0736 CFe + 0,107 C

101 3.8272 x103

(C5H8O4)n HCl 12%

c. nitro ho A cn phi bo v nhm anehit bng (CH3CO)2O

Cu VIII (2,0 im)

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