TRNG THPT VIT YN 2

THI TH I HC KHI A,B LN 2 NM HC 2011-2012

MN THI : HA HC
Thi gian lm bi:90 pht;
(50 cu trc nghim)
M thi 132

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40;
Mn = 55; Fe = 56; Cu = 64; Zn = 65; Cl=35,5; Br = 80; Ag = 108; Ba = 137; Si = 28; P = 31 ;.
Cu 1: Cho 0,25 mol hn hp hai anehit cng dy ng ng vo bnh ng AgNO3 d trong NH3 thy
to ra 86,4 gam Ag, khi lng bnh tng 11,7 gam. Hai anehit l:
A. (CHO)2 v HCHO
B. CH3CHO v C3H7CHO
C. HCHO v C2H5CHO
D. HCHO v C3H7CHO
Cu 2: Supephotphat n c iu ch t mt loi bt qung c cha 73% Ca3(PO4)2, 26% CaCO3 v
1% SiO2. Khi lng dung dch H2SO4 65% ti thiu cn dng tc dng ht vi 100 kg bt qung l
A. 100 kg.
B. 153,85 kg.
C. 71,63 kg.
D. 110,2 kg.
Cu 3: Cho 4,45 gam mt -amino axit X (cha 1 nhm NH2 v 1 nhm COOH) tc dng vi HCl to ra
6,275 gam mui. Cng thc cu to ca X l
A. CH3CH(NH 2 )COOH
B. CH3CH(NH2 )CH2COOH .
C. NH 2 CH 2 COOH
D. CH3CH2CH(NH2 )COOH .
Cu 4: Hn hp X gm BaO, FeO v Al2O3. Ho tan X trong lng d nc thu c dung dch Z v
phn khng tan Y. Sc kh CO2 d vo Z thy c kt ta. Cho kh CO d qua Y nung nng c cht
rn T. Cho T tc dng vi dung dch NaOH d, thy tan mt phn, cn li cht rn G. Cc cht Y, Z, T, G
ln lt l
A. FeO, Ba(AlO2)2, Al, Fe.
B. (FeO + Al2O3), Ba(AlO2)2, (Fe + Al2O3), Fe.
C. (FeO + Al2O3), NaAlO2, (Fe + Al2O3), Fe
D. (FeO + Al2O3), Ba(AlO2)2, (Fe + Al), Fe.
Cu 5: Ha tan m gam FeSO4 vo nc c dung dch X. Cho nc Clo d vo dung dch X, sau khi
phn ng kt thc thu c dung dch B. C cn dung dch B thu c m+6,39 gam hn hp 2 mui
khan. Nu ha tan m gam FeSO4 vo dung dch H2SO4 long d th dung dch thu c ny lm mt mu
va bao nhiu ml dung dch KMnO4 1M?
A. 48 ml.
B. 40 ml.
C. 36 ml.
D. 28 ml.
+
2+
2+
3+
2+
Cu 6: Cho dy cc cht v ion: Cl2 , F2 , H2O, SO2 , Na , Ca , Fe , Al , Mn , S2- , Cl-.S cht v ion trong
dy u c tnh oxi ho v tnh kh l
A. 4.
B. 6.
C. 5.
D. 3.
Cu 7: Cho t t n ht 300 ml dung dch HCl 1M vo 100 ml dung dch Na2CO3 2M, thu c V lt
kh (ktc) v dung dch Y. Thm Ba(OH)2 d vo dung dch Y, c m gam kt ta. Gi tr ca V v m
ln lt l:
A. 3,36 v 19,7.
B. 3,36 v 9,85.
C. 2,24 v 19,7.
D. 4,48 v 0,0.
Cu 8: A c cng thc phn t C3H5Br3, tc dng vi dung dch NaOH un nng c sn phm B va
c phn ng vi Na va c phn ng trng gng. Oxi ha B bng CuO, un nng c mt cht tp
chc. Cng thc cu to ca A l:
A. CH3-CBr2-CH2Br
B. CH2Br-CHBr-CH2Br
C. CH3-CHBr-CHBr2
D. CH2Br-CH2-CHBr2
Cu 9: Mnh no sau y ng ?
A. Glucoz l hp cht a chc.
B. Tinh bt v xenluloz l ng phn ca nhau v cng c cng thc phn t (C 6H10O5)n.
C. Saccaroz v mantoz l ng phn ca nhau.
D. Tinh bt v xenluloz l polisaccarit, chng u d ko thnh si.
Cu 10: Cho x mol Fe vo dung dch cha y mol AgNO 3 v z mol Cu(NO3)2. Sau phn ng thu c dung
dch cha hai cation (khng tnh ion H+) v hn hp 2 kim loi. Quan h gia x, y v z l
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A. y < 2x < y + 2z.

B. y < 3x < y + 2z.
C. z < 2x < z + 2y.
D. 2z < 3x < y + 2z.
Cu 11: Mc ni tip ba bnh in phn: bnh 1 cha dung dch CuCl2, bnh 2 cha dung dch Na2SO4
v bnh 3 cha dung dch AgNO3 ri tin hnh in phn bng dng in mt chiu. Sau mt thi gian
thy anot ca bnh 1 thot ra V1 lt hn hp hai kh c khi so vi khng kh l 2 (cho bit Mkhng kh
29) , cn anot bnh 2 thot ra V2 lt kh, anot bnh 3 thot ra V3 lit kh. Cc th tch kh o cng iu
kin. Cho bit t l th tch
V1 : V2 : V3 l :
A. V1:V2:V3 = 2:1:1
B. V1:V2:V3 = 6:5:5
C. V1:V2:V3 = 4:3:3
D. V1:V2:V3 = 3:2:2
Cu 12: T l v s nguyn t ca hai ng v A v B trong t nhin ca nguyn t X l 27 : 23. ng v A
c 35 proton v 44 ntron, ng v B c nhiu hn ng v A 2 ntron. Nguyn t khi trung bnh ca
nguyn t X l
A. 79,92.
B. 79,35.
C. 81,86.
D. 80,01.
Cu 13: Cho cc cht sau: metanol, anilin, etyl benzoat, phenol, axit butiric, natri phenolat, phenylamoni
clorua, etylenglicol, allyl bromua, o-metylphenol. Hi c bao nhiu cht tc dng c vi dung dch
NaOH ( nhit thng hoc un nng)?
A. 6.
B. 7.
C. 3.
D. 4.
Cu 14: Cho 15,4 gam hn hp gm ancol etylic v etylen glicol tc dng va vi Na thu c 4,48 lt
kh H 2(ktc) v hn hp mui . khi lng mui thu c l:
A. 24,2 gam.
B. 22,2 gam
C. 15,2 gam.
D. 24,4 gam
Cu 15: Hn hp X gm mt anken v hiro c t khi so vi H2 bng 6,4. Cho X i qua niken nung nng
thu c hn hp Y c t khi so vi H2 bng 8 (gi thit hiu sut phn ng l 100%). CTPT ca anken
l
A. C4H8.
B. C5H10.
C. C2H4.
D. C3H6.
Cu 16: X l hexapeptit AlaGlyAlaValGlyVal; Y l tetrapeptit GlyAlaGlyGlu .Thy phn hon ton
m gam hn hp gm X v Y trong mi trng axit thu c 4 loi aminoaxit trong c 30 gam glixin v
28,48 gam alanin. m c gi tr l :
A. 73,4 gam
B. 77,6 gam
C. 87,4 gam
D. 83,2 gam
Cu 17: Cho 15,6 gam hn hp X gm 2 ancol n chc, bc 1 hoc bc 2 qua ng cha 35,2 gam CuO (d),
nung nng. Sau khi phn ng hon ton thu c 28,8 gam cht rn v hn hp hi Y c t khi so vi hiro l
A. 27,5.
B. 13,75.
C. 55,0.
D. 11,0.
Cu 18: Trong s cc hiroxit sau: Fe(OH)3, Cu(OH)2, Zn(OH)2, Sn(OH)2, Pb(OH)2, Cr(OH)2, Cr(OH)3
c bao nhiu cht l lng tnh?
A. 2.
B. 3.
C. 5.
D. 4.
Cu 19: C 5 cc dung dch ring bit, trong khng kh cha: H2SO4 (1), AgNO3 (2), FeCl3, ZnCl2,
HCl c ln AlCl3, H2SO4 c ln CuSO4. Nhng vo mi dung dch mt thanh kim loi thic (Sn) nguyn
cht. S cc xy ra s n mn in ho l
A. 2.
B. 4.
C. 3.
D. 1.
Cu 20: t chy hon ton 0,15 mol hn hp hai ankan thu c 9,45 g H2O. Cho sn phm chy vo
dung dch Ca(OH)2 d th khi lng kt ta thu c l
A. 52,5 g.
B. 15 g.
C. 37,5 g.
D. 42,5 g.
Cu 21: t chy hon ton hn hp gm 2 este cng hai chc, no cn va V lt O2 ( ktc) thu c
0,6 mol CO2 v 0,5 mol H2O. Gi tr ca V l
A. 19,04.
B. 12,32.
C. 14,56.
D. 13,44.
Cu 22: C bao nhiu este c CTPT C4H6O2 c to nn bng phn ng este ha gia ancol v axit
cacboxylic?
A. 4. B. 5. C. 3.
D. 2.

3+
2+
2+
Cu 23: Dung dch X cha anion Cl v 2x mol Fe , x mol Zn , x mol Cu . Chia dung dch X thnh 3
phn nh nhau. in phn phn (1) n khi nc b in phn c 2 in cc th anot thu c 1,12 lt kh
(ktc). Khi cho phn (2) tc dng vi dung dch NaOH d, lc kt ta em nung n khi lng khng i
c a gam cht rn Y; cho phn (3) X tc dng vi dung dch NH3 d, lc kt ta em nung n khi lng
khng i c b gam cht rn Z. Gi tr a, b ln lt l
A. 3,21 v 2,41.
B. 1,2 v 4,8.
C. 2,4 v 1,6.
D. 2,4 v 3,2.
Cu 24: Hn hp X c C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy
m gam hn hp X thu c 3,06 gam H 2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X thc hin
phn ng trng bc thy c p gam Ag kt ta. Gi tr ca p l
A. 8,64.
B. 10,8.
C. 9,72.
D. 2,16.
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Cu 25: t chy hon ton a mol mt hirocacbon X mch h thu c b mol CO2 v c mol nc, bit a
= b c. Mt khc, cho a mol X vo dung dch brom d thy
A. c nhiu hn 2a mol Br2 phn ng
B. c 2a mol Br2 phn ng
C. c a mol Br2 phn ng
D. dung dch brom khng nht mu
Cu 26: Hn hp X gm 3 kim loi Al,Fe v Ba .Chia X lm 3 phn bng nhau
Phn 1:Tc dng vi H2O d thu c 0,896 lt kh (ktc).Phn 2 tc dung vi ddNaOH d thu c
1,568lt kh (ktc) .Phn 3:tc dng vi HCl d thu c 2,24 lt kh H2 (ktc)
Khi lng mi kim loi trong hn hp l:
A. 4,11gam Ba; 3,24 gam Al v 5,04 gam Fe
B. 4,11 gam Ba; 3,24 gam Al v 5,6 gam Fe
C. 4,11 gam Ba; 2,7 gam Al v 5,6 gam Fe
D. 4,11 gam Ba; 5,7 gam Al v 5,04 gam Fe
Cu 27: Cho cn bng sau trong bnh kn: 2NO2

N2O4.

(mu nu )
(khng mu).
Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c:
A. H > 0, phn ng thu nhit.
B. H > 0, phn ng to nhit.
C. H < 0, phn ng to nhit.
D. H < 0, phn ng thu nhit.
Cu 28: in phn nng chy hon ton mui clorua ca mt kim loi kim thu c 1,792 lt kh (ktc)
anot v 6,24 g kim loi catot. Mui em in phn l
A. NaCl.
B. RbCl.
C. KCl.
D. LiCl.
Cu 29: C bao nhiu ng phn cu to c cng thc C4H8O2 bit chng u c phn ng trng bc A.
10
B. 5
C. 7
D. 4
Cu 30: trung ho 4,44 gam mt axit cacboxylic X n chc cn 60 ml dung dch NaOH 1M. Cng
thc ca axit X l
A. C3H7COOH.
B. C2H5COOH.
C. HCOOH.
D. CH3COOH.
Cu 31: X l mt trong cc mui: Al(NO3)3, AgNO3, Cu(NO3)2, MgCO3, Ba(HCO3)2, NH4HCO3,
NH4Cl. Nung X cho n khi lng khng i thu c cht rn Y, cht rn Y ny ho tan c trong
nc to thnh dung dch Z. C bao nhiu mui X tho mn cc tnh cht trn?
A. 3.
B. 2.
C. 4.
D. 1.
Cu 32: Cp t no sau y thuc loi poliamit:
A. t visco; t axetat
B. t enang; t capron
C. t nilon-6; t clorin
D. t nilon-6,6; t lapsan
Cu 33: Ho tan ht 16,3 gam hn hp kim loi gm Mg, Al v Fe trong dung dch H2SO4 c, nng (d)
thu c 0,55 mol SO2. C cn dung dch sau phn ng, khi lng cht rn khan thu c l
A. 103,65 gam.
B. 48,9 gam.
C. 138,2 gam.
D. 69,1 gam.
Cu 34: Hn hp kh X gm hiro, etan v axetilen. Cho t t 6,0 lt X i qua bt Ni nung nng th thu
c 3,0 lt mt cht kh duy nht (cc th tch kh c o ktc). T khi hi ca X so vi hiro bng
A. 15.
B. 7,5.
C. 30.
D. 9,67.
Cu 35: Hp cht X c cng thc cu to thu gn : CH3CH2CH2CH(C2H5)CH3. Tn gi theo danh php
thay th ca X l
A. 3-metylhexan.
B. 2-etylpentan.
C. 4-etylpentan.
D. 4-metylhexan.
Cu 36: S ng phn va tc dng vi dung dch HCl v dung dch NaOH c cng thc phn t C3H7O2N
(khng tnh cc cht c lin kt -NH-CO-)?
A. 4
B. 3
C. 6
D. 2
Cu 37: Thm 150 ml dung dch NaOH 2M vo cc ng 100 ml dung dch AlCl3 nng xM, khuy
u thu c 0,1 mol kt ta. Thm tip 100 ml dung dch NaOH 2M vo cc, khuy u th thu c
0,14 mol kt ta. Gi tr ca x l
A. 1,2. B. 2,0. C. 0,8. D. 1,6.
Cu 38: Cho cc cht : saccaroz, glucoz , frutoz, etyl format , axit fomic v anehit axetic. Trong cc cht
trn, s cht va c kh nng tham gia phn ng trng bc va c kh nng phn ng vi Cu(OH) 2 iu kin
thng l :
A. 2
B. 4
C. 5
D. 3
Cu 39: Trn V1 lit dung dch c pH = 9 vi V2 lit dung dch c pH=12 c dung dch c pH=10. Coi
th tch dung dch thu c bng tng th tch cc dung dch em trn v khng c phn ng ha hc xy
ra. T l V1:V2 l:
A. 11 : 100
B. 110 : 1
C. 2 : 1 D. 100 : 11
Cu 40: Cho m gam Fe vo dung dch cha ng thi H2SO4 v HNO3 thu c dung dch X v4,48 lt
NO(duy nht). Thm tip H2SO4 vo X th li thu c thm 1,792 lt kh NO duy nht na v dung dch Y.
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Dung dch Y ho tan va ht 8,32 gam Cu khng c kh bay ra (cc kh o ktc). Khi lng ca Fe cho
vo l A. 16,8 gam. B. 16,24 gam. C. 11,2 gam. D. 9,6 gam.
Cu 41: C bao nhiu phn ng trong cc phn ng sau u thy to ra kt ta, sau kt t a c th b ha
tan ht.
(1) AlCl3 + NaOH
(2) AlCl3 + NH3 + H2O
(3)NaAlO2 + HCl + H2O (4) NaAlO2 + CO2 + H2O
(5) ZnCl2 + NaOH
(6) ZnCl2 + NH3 + H2O
(7) CO2 + Ca(OH)2 (8) SO2 + Ca(OH)2
(9)CuCl2 + NH3 + H2O
(10) FeCl3 + NH3 + H2O
A. 5 phn ng
B. 6 phn ng
C. 8 phn ng
D. 7 phn ng
Cu 42: Cho cc ancol v amin sau: (1) etanol; (2) propan-2-ol; (3) propan-2-amin; (4) imetylamin;
(5)ancol tert-butylic (6) trimetylamin; (7) tert-butylamin; Nhng cht c cng bc l
A. (1), (2) v (3) ; (4) v (5) ; (6) v (7).
B. (1), (4) v (2) ; (3) v (5) ; (6) v (7).
C. (1), (3) v (7) ; (2) v (4) ; (5) v (6).
D. (1), (2) v (5) ; (3) v (4) ; (6) v (7).
Cu 43: Trong cc pht biu sau y v cng ca nc :
1) un si nc ta ch loi c cng tm thi.
2) C th dng Na2CO3 loi c cng tm thi v cng vnh cu.
3)C th dng HCl loi cng ca nc.
4) C th dng Ca(OH)2 vi lng va loi cng ca nc.
S pht biu ng : A. 3
B. 4. C. 1
D. 2
Cu 44: Cho 2,24 gam bt Fe vo 200 ml dung dch hn hp gm AgNO3 0,1M v Cu(NO3)2 0,1M. Sau
phn ng hon ton thu c cht rn c khi lng l
A. 6,12 gam.
B. 4,00 gam.
C. 5,20 gam.
D. 3,44 gam.
Cu 45: S ng phn ancol bc 2 c cng thc phn t ancol C4H10O l
A. 1
B. 2
C. 3
D. 4
Cu 46: C 6 dung dch long ca cc mui NaCl, Ba(NO3)2, AgNO3, CuSO4, FeCl2, ZnCl2. Khi sc kh
H2S vo cc dung dch mui trn, c bao nhiu trng hp c phn ng to ra kt ta?
A. 1
B. 3
C. 2
D. 4
Cu 47: Trong s cc ion sau, ion c cu hnh electron ca Ne l
2+
2+
2+

A. Ca
B. Mg
C. Be
D. Cl
Cu 48: Dy cc ion c sp xp theo chiu tnh oxi ho tng dn l :
2+
2+
2+
3+
+
3+
2+
2+
2+
+
3+
3+
A. Ni , Fe , Cu , Fe , Ag , Au .
B. Fe , Ni , Cu , Ag , Fe , Au
.
2+
2+
2+
+
3+
3+
2+
2+
2+
3+
+
3+
C. Ni , Fe , Cu , Ag , Fe , Au
.
D. Fe , Ni , Cu , Fe , Ag , Au .
Cu 49: Dy cht no c sp xp theo chiu tng dn tnh axit:
A. H3PO4, H2SiO3, H2SO4
B. HClO2, HClO3, HClO4
C. HI, HBr, HCl
D. HCl, H2S, NH3
Cu 50: Hn hp hai ancol no mch h A, B. A km B mt nguyn t cacbon. Nu cho hn hp gm 1 mol
A vi 2 mol B phn ng ht vi Na c 2 mol H 2. Nu cho hn hp gm 2 mol A vi 1 mol B phn ng
ht vi Na c 2,5 mol H2. t chy hon ton 1 mol hn hp A, B c 58,24 lt CO2 (ktc). Cng thc
ca A v B ln lt l
A. C2H5OH v C3H6(OH)2.
B. C2H4(OH)2 v C3H7OH.
C. C2H4(OH)2 v C3H5(OH)3.
D. CH3OH v C2H4(OH)2.
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