Chuyn oxy-lu hunh

LTH 2012 BI TP CHNG OXI-LU HUNH. 1. Hon thnh chui: ZnS SO2 H2S Na2S NaHS Na2SO4. 2. Hon thnh s bin ho sau: S FeS SO2 Na2SO3 NaHSO3 BaSO3 3. Hon thnh phng trnh phn ng: a) FeS2 SO2 SO3 H2SO4 CuSO4 CuCl2 AgCl Cl2 Kaliclorat. b) Na2S CuS SO2 H2SO4 Na2SO4 NaCl HCl Cl2. c) FeS H2S FeS Fe2O3 FeCl3 Fe2SO4 FeCl3 d) Km Km sunfua Hidrsunfua Lu hunh Kh sufur Caxisunfit Canxihidrsunfit Canxisunfit Canxiclorua. 4. Thc hin cc phn ng ca cc chui bin ho sau: a) FeS SO2 SO3 H2SO4 CuSO4 CuS CuO CuSO4. b) H2SO4 S MgS H2S Na2S CuS CuO CuCl2 NaCl Cl2. c) S SO2 NaHSO3 Na2SO3 Na2SO4 NaCl AgCl Cl2 H2SO4 HCl Cl2 CaOCl2. 5. ch dng thm mt ha cht hy phn bit cc ch sau: a. 5 dung dch: K2SO4, FeCl2, Na2SO3, NH4HS, FeCl3. b. KOH, NaCl, MgCl2, AgNO3, HCl, HI. 6. Bng phng php ho hc hy phn bit cc dung dch sau: Na2SO4, Na2SO3, H2SO4 , HCl. 7. Nhn bit cc trng hp sau: c. Dung dch: Na2SO4, NaOH, H2SO4 , HCl. d. K2S, Na2SO4, KNO3, KCl e. Na2S, Na2SO3, NaHSO3, Na2SO4. 8. Bng phng php ho hc hy phn bit cc kh sau: O2, O3, H2S, SO2. 9. Bng phng php ho hc hy phn bit cc dung dch sau : NaCl, BaCl2, Na2CO3, Na2SO3 10.Bng phng php ho hc hy phn bit cc dung dch sau : Na2S, Na2SO3, Na2SO4, BaCl2. 11. Ch dng thm mt thuc th (khng dng cht ch th mu), hy nhn bit cc dung dch sau: Natri sunfat, Axit sunfuric, Natri cacbonat, Axit clohidric. 12. Bng pp ha hc hy phn bit cc dd sau: a) KCl, K2CO3, MgSO4, Mg(NO3)2. b) Na2SO4, NaNO3, Na2CO3, NaCl. c) Na2SO3, Na2S, NaCl, NaNO3. d) HCl, H2SO4, BaCl2, Na2CO3. e) AgNO3, Na2CO3, NaCl, K2SO4. f) HCl, H2SO4, BaCl2, K2CO3. g) Na2SO4, Na2CO3, BaCl2, NaNO3, BaCl2, AgNO3. h) HCl, Na2SO4, NaCl, Ba(OH)2. 13. Phn bit cc kh mt nhn sau: a) O2, SO2, Cl2, CO2. b) Cl2, SO2, CO2, H2S, O2, O3. c) SO2, CO2, H2S, H2, N2, Cl2, O2. d) O2, H2, CO2, HCl. 14. Vit phng trnh phn ng chng minh: H2S l mt axit v l mt cht kh. 15. Ti sao iu ch Hidrsunfua t sun fua kim loi th ta thng dng axit HCl m khng dng H2SO4 m c? 16. Ti sao pha long axit H2SO4 ta phi cho t t H2SO4 vo nc v khuy iu m khng lm ngc li. 17. Ti sao khi iu ch H2S ta khong dng mui sunfua ca Pb, Cu, Ag? 18. iu ch mt axit ta thng dng nguyn tc: dng mt axit mnh y axt yu ra khi mui, nhng cng c trng hp ngc li, hy chng minh. 19. Mt thanh st lu trong khng kh sau mt thi gian khng cn sng bng m m c nhng vt ca g st? 20. Dn kh clo vo dung dch Na2CO3 c kh CO2 thot ra, nu thay kh clo bng: SO2, SO3, H2S th c hin tng nh th khng? 21. Vit phng trnh chng minh SO2 va c tnh oxiha va c tnh kh. 22. Vit 5 pt chng minh O2 l mt cht oxiha 23. Vit 5 pt iu ch O2. 24. Phn bit O2 v O3. 25. Vit 2 pt chng minh S l mt cht oxiha, 2 pt chng minh S l cht kh. 26. Cch thu gom Hg ri rt. 27. Vit 3 pt m trong H2S l cht kh, 2 pt m trong H2S l mt axit. 28. Vit cc phng trnh phn ng chng t H2S l mt axit yu nhng l cht kh mnh. 29. Vit 3 pt chng minh SO2 l mt cht kh, 1 pt chng minh SO2 l mt cht oxi ha, 2 pt chng minh SO2 l mt oxit axit. 30. iu ch SO2 t Cu, Na2SO3. GV: Nguyn Th Thu Hng-Trng THPT Minh Khai-Quc Oai

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Chuyn oxy-lu hunh LTH 2012 31. So snh tnh cht ca dd HCl v dd H2SO4 long. 32. Nu tnh cht ho hc ging v khc nhau ca H 2SO4 long v H2SO4 c. Vit cc phng trnh phn ng minh ho, t rt ra kt lun g i vi tnh cht ho hc ca H2SO4 33. Giy qu tm tm t bng dung dch KI ng sang mu xanh khi gp Ozn. Gii thch hin tng v vit phng trnh phn ng. 34. Nu dng FeS c ln Fe iu ch H2S th c tp cht no trong H2S? Nu cch nhn ra tp cht . 35. Vit phng trnh phn ng(nu c) khi cho H2SO4 long tc dng vi: Mg, Cu, CuO, NaCl, CaCO3, FeS. [Zn, Ag, Fe2O3, KNO3, Na2CO3, CuS]. 36. Vit phng trnh phn ng khi H2SO4 long v H2SO4 c nng tc dng vi cc cht sau: Fe, Cu, FeO, Na2CO3. T cc phn ng trn rt ra kt lun g vi axit sunfuric. 37. Vit cc phng trnh phn ng khi cho H2SO4 c nng tc dng vi : Cu, S, NaCl, FeS. 38. Vit phng trnh phn ng khi cho kh Sunfur tc dng vi : H2S, O2, CaO, dung dch NaOH, dung dch Brm. Hy cho bit tnh cht ca kh Sunfur trong tng phn ng . 39. Kh H2 c ln mt t H2S, c th dng dung dch no sau y loi b H2S ra khi H2: dung dch natrihidrxit, dung dch hidrclorua, dung dch chnitrat 40. Trnh by hai phng php iu ch Hidrsufua t cc cht sau: S, Fe, axit HCl. 41. Vit phng trnh iu ch H2SO4 t qung pyrit. 42. T S, KCl, Al2O3 v H2O hy iu ch KOH, KClO3, AlCl3, phn n, phn kp? 43. T qung pyrit st, mui n v nc, vit phng trnh iu ch: Fe(OH)3, Na2SO3, NaSO4. 44. T qung pyrit st, mui n, khng kh, nc, khng kh; hy vit phng trnh iu ch: Fe2(SO4)3, Na2SO4, nc Javen, Na2SO3, Fe(OH)3, Natri, Natriclorat, NaHSO4, NaHSO3. 45. T mui n, nc, H2SO4 c. Vit cc phng trnh phn ng (ghi iu kin phn ng nu c) iu ch: Kh Cl 2, H2S, SO2 , nc Javen, Na2SO4 46. T qung pyrit st, mui n v nc, vit phng trnh iu ch: Fe(OH)3, Na2SO3, NaSO4. 47. T qung pyrit st, mui n, khng kh, nc, khng kh; hy vit phng trnh iu ch: Fe 2(SO4)3, Na2SO4, nc Javen, Na2SO3, Fe(OH)3, Natri, Natriclorat, NaHSO4, NaHSO3. 49. T piryt st, khng kh, nc, mui n (iu kin v cht xc tc c ); hy iu ch: Fe2(SO4)3, FeCl3. 1. Bi tp v H2SO4 Dng bi tp v axit sunfuric long V d 1. Cho 20 gam hn hp Cu v Al phn ng vi dung dch H2SO4 d, thu c 13,44 lt kh (ktc). Tnh % theo khi lng Al v Cu trong hn hp ln lt l. A. 44%, 66% B. 54%, 46% C. 50%, 50%. D. 94%, 16%. V d 2. Cho 21 gam hn hp Zn v CuO vo 600ml dung dch H 2SO4 0,5 M, D=1,1gam/ml. Phn ng va thu c dung dch X gm ZnSO4 v CuSO4. 1. % khi lng Zn v CuO trong hn hp A. 62%, 38% B. 54%, 46% C. 50%, 50%. D. 94%, 16%. 2. Nng phn trm ca gm ZnSO4 v CuSO4 trong dung dch X l A. 1,62%, 2,38% B. 4,73%, 2,35% C. 2,15%, 1,2%. D. 2,34%, 1,16%. V d 3. Cho 0,52 gam hn hp 2 kim loi Mg, Al tan hon ton trong dung dch H 2SO4 long d thu c 0,336 lt kh ktc. Khi lng mui sunfat thu c l: A. 1,24 gam B. 6,28 gam C. 1,96 gam D. 3,4 gam. V d 4. Cho 2,81 gam hn hp A gm 3 oxit kim loi MgO, ZnO, Fe2O3 ho tan va trong 300 ml dung dch H2SO4 0,1M. C cn dung dch sau phn ng, khi lng gam cc mui sunfat khan thu c l: A. 5,21 gam B. 4,25 gam C. 5,14 gam D. 4,55 gam Dng bi tp v axit sunfuric c V d 1. Cho 13,6 gam hn hp Mg, Fe phn ng hon ton vi H 2SO4 c nng d thu c 8,96 lt SO 2 sn phm kh duy nht ktc. Khi lng mi kim loi trong hn hp ban u l? A. 2,4 gam Mg, 11,2 gam Fe B. 4,4 gam Mg, 9,2 gam Fe C. 4,8 gam Mg, 8,8 gam Fe D. 5,8 gam Mg, 7,8 gam Fe V d 2. Cho 10 gam hn hp Cu v CuO vo dung dch H2SO4 c nng thu c 2,24 lt SO2 sn phm kh duy nht ktc. Tnh % khi lng ca Cu trong hn hp ban u. V d 3. Cho 11 gam hn hp Al, Fe phn ng hon ton vi H2SO4 c nng d thu c 10,08 lt SO2 sn phm kh duy nht ktc v dung dch A. Tnh % khi lng mi kim loi trong hn hp ban u? Cho NaOH d vo dung dch A thu c m gam mt kt ta, nung kt ta ngoi khng kh n khi lng khng i thu c a gam cht rn. Tnh m, a. V d 4. Cho 9,6 gam kim loi R tan hon ton trong H2SO4 c nng d thu c 3,36 lt SO2 . Kim loi R l A. Al B. Cu C. Fe D. Zn V d 5. Ha tan hon ton 0,1 mol mi cht Fe, FeS, v FeS 2 trong dung dch H2SO4 c nng thu c V lt (ktc) SO2 sn phm kh duy nht.Gi tr ca V l A. 30,24 lt B. 20,24 lt C. 33,26 lt D. 44,38 lt V d 6. kh hon ton 3,04 gam hn hp X gm FeO, Fe 3O4, Fe2O3, cn 0,05 mol H2. Mt khc ha tan hon ton 3,04 gam hn hp X trong dung dch H2SO4 c nng th thu c th tch V ml SO2 (ktc)(sn phm kh duy nht). Gi tr V(ml) l: GV: Nguyn Th Thu Hng-Trng THPT Minh Khai-Quc Oai

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Chuyn oxy-lu hunh LTH 2012 A. 112 ml B. 224 ml C. 336 ml D. 448 ml V d 7. Ho tan hon ton 49,6 gam hn hp X gm Fe, FeO, Fe2O3 v Fe3O4 bng H2SO4 c, nng thu c dung dch Y v 8,96 lt kh SO2(ktc). Thnh phn phn trm v khi lng ca oxi trong hn hp X v khi lng mui trong dung dch Y ln lt l: A. 20,97% v 140 gam. B. 37,50% v 140 gam. C. 20,97% v 180 gam D.37,50% v 120 gam. V d 8. Ha tan m gam Al vo dung dch H2SO4 c nng thu c 4,48 lt (ktc) hn hp hai kh SO2 v H2S c t l th tch 1 : 1. Gi tr ca m l A. 9 gam B. 27 gam C. 12 gam D. 6 gam V d 9. Cho m gam Zn vo dung dch H2SO4 c nng thu c 6,72 lt hn hp hai kh SO2 v H2S (ktc) c t khi so vi H2 l 24,5. Tnh gi tr ca m v lng mui to thnh trong dung dch sau phn ng. V d 10. Cho 7,7 gam hn hp Mg, Zn tan hon ton vi dung dch H2SO4 c nng d thu c dung dch X v 0,1 mol SO 2, 0,01 mol S v 0,005 mol H2S. Tnh khi lng mi kim loi trong hn hp. V d 11. Ha tan 30 gam hn hp mt s kim loi vo dung dch H2SO4 c nng d thu c dung dch X v 0,15 mol SO2, 0,1mol S v 0,005 mol H2S. Xc nh s mol H2SO4 tham gia phn ng v khi lng mui to thnh sau phn ng? 1. Cho 12 gam hn hp hai kim loi Cu, Fe tan hon ton trong H 2SO4 c, nng, d thu c 5,6 lt SO2 sn phm kh duy nht . Tnh % theo khi lng ca Cu v Fe trong hn hp l A. 53,33%, 46,47% B. 33,33%, 66,47% C. 43,33%, 56,47% D. 50,00%, 50,00%. 2. Cho 5,4 gam kim loi R tan hon ton trong H 2SO4 c nng, phn ng kt thc thu c 6,72 lt SO 2 sn phm kh duy nht ktc. Tm kim loi R v tnh khi lng mui to thnh sau phn ng? A. Al, 34,2 gam. B. Fe, 34,2 gam. C. Zn, 34,2 gam. D. Cu, 24,5 gam. 3. Nung x mol Fe v 0,15 mol Cu trong khng kh mt thi gian thu c 31,2 gam hn hp cht rn. Ho tan hon ton hn hp cht rn trn bng H2SO4 c, nng, d thu c dung dch Y v 6,72 lt kh SO2(ktc). Gi tr ca x mol l: A. 0,7 mol B. 0,3 mol C. 0,45 mol D. 0,8 mol 4. cho 12,096 gam Fe nung trong khng kh thu c m 1 gam cht rn X gm Fe v cc oxit ca n. Cho m 1 gam cht rn X trn vo dung dch H2SO4 c nng thu c 1,792 lt kh SO2 duy nht (ktc) v dung dch mui Y. C cn dung dch mui Y cn nng m2 gam cht rn khan. 1. Gi tr ca m1 l: A. 14 gam B. 16 gam. C. 18 gam D. 22,6 gam 2. Gi tr ca m2 l: A. 43,6 gam. B. 43,2 gam. C. 42,0 gam D. 46,8 gam 5. Cho 11 gam hn hp Al, Fe phn ng hon ton vi H 2SO4 c nng d thu c 4,032 lt hn hp hai kh SO2 v H2S (ktc) c t khi so vi H2 l 24,5 v dung dch A. Cho NaOH d vo dung dch A thu c m gam mt kt ta, nung kt ta ngoi khng kh n khi lng khng i thu c a gam cht rn. 1. Tnh % khi lng mi kim loi trong hn hp ban u? A. 53,33%, 46,47% B. 33,33%, 66,47% C. 43,33%, 56,47% D. 50,00%, 50,00%. 2. Khi lng mui to thnh trong dung dch A. A. 34,2 gam B. 54,2 gam. C. 38,5 gam D. 22,6 gam 3. Gi tr m, a ln lt l A. 26,3 gam, 8 gam B. 26,8 gam, 8 gam C. 26,3 gam, 18 gam D. 45,3 gam, 27 gam 6. Cho 4,5 gam mt kim loi R tan hon ton trong H2SO4 c nng d thu c 2,24 lt hn hp hai kh SO2 v H2S (ktc) c t khi so vi H2 l 24,5 v dung dch X. Tm kim loi R v khi lng mui to thnh trong dung dch sau phn ng. A. Al, 28,5 gam. B. Al, 34,2 gam. C. Fe, 28,5 gam. D. Cu, 32,0 gam. 7. Cho 6,8 gam hn hp X gm Mg v Fe vo dung dch H2SO4 long th thu c 3,36 lit kh bay ra (kc). a) Tnh % khi lng mi kim loi trong X? b) Nu cho hn hp trn tc dng vi H2SO4 , nng.Tnh VSO2 (kc)? S: a. 17,65% ; 82,35% ; VSO2 = 4,48 lit. 8. Cho 35,2 gam hn hp X gm Fe v CuO tc dng va vi 800 gam dung dch H2SO4 long th thu c 4,48 lit kh (kc) v dung dch A. a) Tnh % khi lng mi cht trong X. b) Tnh C% dung dch H2SO4 dng. c) Tnh khi lng cc mui trong dung dch A. S: a. Fe :31,82% ; CuO : 68,18%. b. C% = 6,125. c. mFeSO4 = 30,4 g : mCuSO4 = 48 g. 9. Cho 55 gam hn hp 2 mui Na 2SO3 v Na2CO3 tc dng ht vi H2SO4 long thu c hn hp kh A c t khi hi i vi hiro l 24.Tnh % khi lng mi mui trong hn hp u. GV: Nguyn Th Thu Hng-Trng THPT Minh Khai-Quc Oai T 0986.939.308 3

Chuyn oxy-lu hunh LTH 2012 S: 22,9% ; 77,1% 10. Cho m(gam) hn hp G cha Mg v ZnS tc dng 250 gam dung dch H2SO4 c 34,51 gam hn hp kh A gm H2 v H2S c t khi hi so vi oxi l 0,8. a.Tnh % khi lng mi kim loi trong G. b.Tnh nng dung dch axit dng. S: a. 8,03 ; 91,97 b. 9,016%. 11. Cho 40 gam hn hp Fe Cu tc dng va vi dung dch H2SO4 98% nng thu c 15,68 lit SO2 (kc). a.Tnh % khi lng mi kim loi trong hn hp? b.Tnh khi lng dung dch H2SO4 dng? 12. Cho 20,8 gam hn hp Cu v CuO tc dng va dung dch H2SO4 , nng thu c 4,48 lit kh (kc). a. Tnh % khi lng mi kim loi trong hn hp? b.Tnh khi lng dung dch H2SO4 80% cn dng v khi lng mui sinh ra. 13. Cho 7,6 gam hn hp gm Fe, Mg, Cu vo dung dch H2SO4 , ngui d th thu c 6,16 lit kh SO2 (kc). Phn khng tan cho tc dng vi dung dch HCl d thu c 1,12 lit kh (kc).Tnh % khi lng hn hp u. S: Fe : 36,8% ; Mg : 31,58% ; Cu: 31,62%. 14. Cho 10,38 gam hn hp gm Fe, Al v Ag chia lm 2 phn bng nhau: Phn 1: Tc dng vi dung dch H2SO4 long d thu c 2,352 lit khi (kc). Phn 2: Tc dng vi dung dch H2SO4 , nng d thu c 2,912lit kh SO2 (kc). Tnh khi lng tng kim loi trong hn hp ban u. S: mFe = 3,36 gam ; mAl = 2,7 gam ; mAg = 4,32 gam. 15. Nung nng hn hp gm 11,2 gam bt Fe v 3,2 gam bt lu hunh. Cho sn phm to thnh vo 200 ml dung dch H 2SO4 th thu c hn hp kh A bay ra v dung dch B( Hp = 100%). a. Tm % th tch ca hn hp A. b. trung ha dung dch B phi dng 200 ml dung dch KOH 2M.Tm CM ca dung dch H2SO4 dng. S: a. H2S: 50%; H2: 50%. b. 2M. 16. Cho 12,6 gam hn hp A cha Mg v Al c trn theo t l mol 3:2 tc dng va vi dung dch H2SO4 c, nng thu c kh SO2 (kc). a. Tnh % khi lng mi kim loi trong hn hp A? b. Tnh VSO2 ( 270 C; 5 atm). c. Cho ton b kh SO2 trn vo 400 ml dung dch NaOH 2,5 M. Tnh CM cc cht trong dung dch thu c. S: a. 57,14% ; 42,86%. 2,95 lit. 17. Cho H2SO4 long d tc dng vi 6,66 gam hn hp gm 2 kim loi A,B u ho tr II thu c 0,1 mol kh ng thi khi lng gim 6,5 g. Ho tan phn rn cn li bng H2SO4c, nng th thu c 0,16 gam SO2. a) nh tn 2 kim loi A, B ( gi s MA > MB ). b) Tnh thnh phn khi lng v thnh phn % khi lng ca chng c trong hn hp.Cho phng php tch ri tng cht sau y ra khi hn hp A, B, oxit B v ASO4 ( mui sunfat 18. Ha tan 3,38g oleum A vo nc ngi ta phi dng 800 ml dd KOH 0,1M trung ha dd A. Xc nh cng thc phn t ca oleum A. 19. Tm lng nc nguyn cht cn thm vo mt lt dd H2SO4 98% d = 1,84 g/ml thu c dd mi c nng 10% 20. Khi cho H2SO4 hp th SO3, ngi ta thu c 1 oleum cha 71% SO3 theo khi lng. Xc nh cng thc phn t ca oleum A. 21. Nu trn 1,5 lt dd H2SO4 2M vi 2,5 lt dd H2SO4 2,4M. Hi dd thu c c nng l bao nhiu? 22. Trn 2 th tch H2SO4 0,2M vi 3 th tch dd H2SO4 0,5M th dd H2SO4 thu ccnng bao nhiu? 23. Hn hp X gm Fe v Fe3O4 c chia thnh 2 phn bng nhau Phn 1: tc dng vi 90 ml dd H2SO4 long 1M Phn 2: tc dng vi dd H2SO4 c nng d thu c 560 ml kh SO2 ktc Vit cc ptp xy ra. Tnh khi lng mi cht trong X? 25. Cho 855 (g) dung dch Ba(OH) 2 20% vo 500 (g) dung dch H2SO4. Lc b kt ta, trung ho nc lc, ngi ta phi dng 200 (ml) dung dch 2,5 (M). Tnh C% ca dung dch H2SO4. S: 24,5%. 26 Cho 25,38 (g) BaSO4 c ln BaCl2. Sau khi lc b cht rn, ngi ta cho vo nc lc dung dch H2SO4 1 (M) n th thu c 2,33 (g) kt ta. a) Tm % khi lng BaCl2. b) Tnh th tch dung dch H2SO4. S: a. 8,2% b. 0,01 lit 27. Chia 600 ml dung dch H2SO4 thnh 3 phn u nhau.Dng 250ml dung dch NaOH 25% (d=1,28) th trung ho 1 phn ca dung dch. a) Tm CM ca dung dch H2SO4. b) Hai phn cn li ca dung dch H2SO4 c rt vo 600 ml dung dch NaOH 5M.Tm CM ca cc cht c trong dung dch thu c . S: a. 5M b. NaHSO4 1M c. Na2SO4 1M. 28. Ho tan 4,8 gam mt kim loi M ho tr II va tc dng vi 392 gam dung dch H2SO4 10%. Xc nh M. 29. Cho 40 gam hn hp A cha Cu v Al tc dng vi dung dch H2SO4 d thu c 22,4 lit kh (kc). Tnh % khi lng mi kim loi? 30. Cho 36 gam hn hp X cha Fe2O3 v CuO tc dng va vi dung dch H2SO420% thu c 80 gam hn hp mui. GV: Nguyn Th Thu Hng-Trng THPT Minh Khai-Quc Oai

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Chuyn oxy-lu hunh LTH 2012 a) Tnh % khi lng tng cht trong hn hp X. b) Tnh khi lng dung dch H2SO4 dng. S: a. 44,4% ; 55,6% b. mdd = 269,5gam 2. Bi tp v SO2, H2S V d 1. Cho 1,68 lt SO2 (ktc) sc vo bnh ng 250 ml dung dch NaOH d. Tnh nng mol ca dung dch mui thu c. V d 2. Cho 28 lt SO2 (ktc) dn vo bnh ng 300gam dung dch KOH 23%. Tnh nng phn trm ca dung dch mui thu c. V d 3. Cho 448 ml SO2 vo bnh cha 100ml dung dch NaOH 0,25M. Tnh khi lng mui to thnh? V d 4. Sc V lt kh SO2 vo bnh cha 200 ml dung dch Ca(OH)2 1M thu c 12 gam kt ta. Tnh V? V d 5. Ha tan mt hn hp gm 0,1 mol mi cht FeS, CuS v ZnS trong dung dch H 2SO4 long d, kh thot ra cho hp th ht vo 250ml dung dch NaOH 1M, to m gam mui. Tnh m. 1. Cho 5,6 lit kh SO2 (kc) vo: a) 400 ml dung dch KOH 1,5 M. b) 250 ml dung dch NaOH 0,8 M. c) 200 ml dung dch KOH 2 M. Tnh nng cc cht trong dung dch thu c . d) 200 ml dung dch Ba(OH)2 ta c 44,125 (g) hn hp BaSO3 v Ba(HCO3)2. Tnh nng dung dch Ba(OH)2. 2. t chy hon ton 8,98 lit H2S (kc) ri ho tan tt c sn phm sinh ra vo 80 ml dung dch NaOH 25% ( d= 1,28 g/ml). Tnh C% ca dung dch mui thu c. 3. t chy hon ton 12,8 gam lu hunh. Kh sinh ra c hp th ht bi 150 ml dung dch NaOH 20% (d= 1,28 g/ml). Tm C M, C% ca cc cht trong dung dch thu c sau phn ng. S: Na2SO3 : 2,67 M ; 23,2%. NaOH : 2,67 M ; 7,35%. 4. t chy hon ton 6,72 lit ( kc) H2S. a) Tnh lng SO2 thu c. b) Cho lng SO2 ni trn i qua 37,5 ml dung dch NaOH 25% (d=1,28) th mui g to thnh. Tnh C% mui trong dung dch thu c . c) Nu cho lng SO2 thu c trn a) i vo 500 ml dung dch KOH 1,6 M th c mui g c to thnh .Tnh C M cc cht trong dung dch sau phn ng. S: a. 19,2 gam ; b. 46.43% ; c. 0,6 M ; 0,4M. 5. Dn V lt (ktc) kh SO2 vo dung dch Ba(OH)2 thy xut hin 21,7gam kt ta. Lc b kt ta, phn nc lc cn li em un nng th thu thm 21,7 gam kt ta na. Gi tr ca V l A. 6,72 lt B. 4,48 lt C. 2,24 lt D. 3,36 lt 6. Dng mt lng dung dch Ca(OH)2 va hp th V lt kh SO2 (ktc) thu c 6 gam kt ta. Lc b kt ta cho tip mt lng dung dch Ca(OH)2 d vo phn nc lc th thu thm 3 gam kt ta na. Gi tr ca V l A. 6,72 lt B. 4,48 lt C. 2,24 lt D. 3,36 lt 3. Bi tp v O2 v O3 1. Mt mu km b oxi ha mt phn thnh oxit. Ly 4,06g mu km ny cho tc dng vi dung dch HCl 2M thy thot ra 1,12 lt kh. a) Tnh % ZnO trong mu. b) Tnh Vdd HCl cn ha tan ht mu km 2. Khi t 18,4g hn hp gm km v nhm th cn va 5,6 lt kh oxi (kc).Tnh % khi lng mi kim loi c trong hn hp. 3. T khi hi ca 1 hn hp A gm ozon v oxi i vi hidro l 18. a) Xc nh % theo th tch ca mi kh trong hn hp u. b) Tnh dA/oxi 4. Nhit phn 273,4g hn hp KClO 3 va KMnO4 th thu c 49,28 lt kh oxi ktc. Xc nh thnh phn % theo khi lng hai mui ban u. 4. Bi tp v mui sunfua V d 1. Nung hn hp A gm 11,2 gam Fe v 4,8 gam S trong mi trng kn khng c khng kh n khi phn ng xy ra hon ton thu c hn hp cht rn B. Cho B vo dung dch HCl d thu c hn hp kh C. -Vit phng trnh ha hc xy ra v xc nh cc cht trong B, C. -Tnh % v khi lng cc cht trong B v % th tch cc cht trong C. V d 2. Nung hn hp X gm Zn v S trong mi trng kn khng c khng kh n khi phn ng xy ra hon ton thu c hn hp cht rn B. Cho B vo dung dch HCl d th cn li 1 cht rn khng tan C nng 6 gam v thu c 4,48 lt (ktc) kh D c t khi so vi hidro l Tnh khi lng cc cht trong X?. V d 3. Nung hn hp Z gm Zn v S trong mi trng kn khng c khng kh n khi phn ng xy ra hon ton thu c hn hp cht rn F. Khi cho F vo dung dch HCl d th cn li 1 cht rn khng tan G nng 1,6 gam v thu c 8,96 lt (ktc) hn hp kh D c t khi so vi hidro l 13. Tnh khi lng hn hp Z v hiu sut phn ng gia Zn v S?. V d 4. un nng hon ton hn hp gm st v lu hunh. em ha tan cht rn sau phn ng trong dung dch HCl d thy c 4,48 lt (ktc) kh thot ra. Nu em lng kh ny cho vo dung dch Pb(NO 3)2 d th cn li 2,24 lt (ktc) kh. Tnh % khi lng ca st v lu hunh trong hn hp ban u v khi lng kt ta to thnh trong dung dch Pb(NO3)2. V d 5. Hn hp X (gm m1 gam bt Fe v m2 gam bt S trn u) em nung nhit cao khng c mt oxi thu c hn hp Y. Ha tan Y bng dung dch HCl d thu c 0,8 gam cht rn A, dung dch B v kh D (c t khi so vi H 2 bng 9). Dn kh D li t t qua dung dch CuCl2 d thy to thnh 9,6 gam kt ta. Tnh m1 v m2. GV: Nguyn Th Thu Hng-Trng THPT Minh Khai-Quc Oai

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Chuyn oxy-lu hunh LTH 2012 V d 6. Cho 2,52 gam hn hp FeS v FeS2 vo bnh cha oxi d, un nng. Sau khi phn ng hon ton thu c 0,784 lt kh SO 2 thot ra. Tnh th tch oxi dng. A. 2,538 lt B. 1,535 lt C. 1,204 lt D. 2,402 lt V d 7. Hn hp X gm 0,2 mol FeS v 0,1 mol CuS. S mol H2SO4 c nng cn dng ha tan ht hn hp X l A. 1,0 mol B. 2,0 mol C. 2,4 mol D. 1,4 mol 1. Nung hn hp A gm Fe v S sau mt thi gian ri ngui thu c hn hp B. Nu cho B vo dd HCl d, thu c 2,24 lt C (ktc) m dC/H2 = 13. Tnh khi lng mi kim loi trong hn hp ban u. 2. ung nng hn hp gm 5,6g bt st v 1,6g bt lu hunh, thu c hn hp X. Cho hn hp X phn ng hon ton vi 500ml dd HCl thu c hn hp kh Y v dd Z. a) Tnh thnh phn phn trm theo th tch ca mi kh trong hn hp Y b)Tnh khi lng cc cht trong hn hp X 3. Cho hn hp gm Fe v FeS tc dng vi dd HCl d, thu c 2,464 lt hn hp kh (ktc). Cho hn hp ny i qua dd Pb(NO 3)2 d thu c 23,9 g kt ta mu en. a) Vit phng tnh ha hc ca cc phn ng xy ra. b) Hn hp kh thu c gm nhng kh no? Th tch mi kh l bao nhiu? c)Tnh khi lng ca Fe v FeS c trong hn hp ban u 4. Nung nng 8 gam hn hp Mg v S thu c hn hp A. Cho A vo dung dch HCl d thu c 4,48 lt hn hp kh B (ktc). Bit phn ng xy ra hon ton. 1. % theo khi lng mi cht trong hn hp ban u. A. 60%Mg v 40%S. B. 50%Mg v 540%S. C. 40%Mg v 60%S. D. 65%Mg v 35%S. 2. Tnh t khi hi ca B i vi H2. A. 7 B.8 C. 15 D.9 3. Dn hn hp B vo 75 cm3 dung dch NaOH 2M th thu c mui g? nng bao nhiu gam. A. 7,8gam Na2S, 5,6 gam NaHS B. 8,6 gam NaHS C. 7,8gam Na2S D. 3,6 Na2S, 5,6 gam gam NaHS 5. un nng 5,6 gam bt st v 1,6 gam bt lu hunh trong mi trng khng c khng kh, thu c hn hp cht rn X. Cho hn hp X ny phn ng hon ton vi 500 ml dung dch HCl, thu c hn hp kh A v dung dch B (hiu sut ca phn ng l 100%). 1. % theo th tch mi cht trong hn hp kh A. A. 50%H2S v 50%H2. B. 75%H2S v 25%H2. C. 55%H2S v 45%H2. D. 60%H2S v 40%H2. 2. Bit rng cn dng 125ml dung dch NaOH 0,1M trung ha HCl d cn d trong dung dch B. Hy tnh nng mol ca dung dch HCl dng. A. 0,125M. B. 0,425M. C. 0,225M. D. 0,135M. 6. Cho m gam hn hp X gm Zn v S vo bnh khng c khng kh, nung bnh sau mt thi gian thu c cht rn A. Ha tan cht rn A bng dung dch HCl thu d thu c 8,96 lt (ktc) kh B v 1,6 gam cht rn D khng tan. Bit t khi ca B so vi hiro bng 7. Hiu sut ca phn ng to thnh cht rn A l A. 30% B. 45% C. 50%. D. 75%. 7. Ha tan ht hn hp gm a mol FeS 2 v 0,1 mol Cu2S trong dung dch HNO3 long, ch thu c hai mui sunfat v c kh NO thot ra. Tr s ca a l: A. 0,2 B. 0,15 C. 0,25 D. 0,35. 8. Cho a mol hn hp FeS v FeS 2 vo bnh cha oxi d, un nng. Sau khi phn ng hon ton thu c cht rn Y. Sau phn ng a nhit ban u thy s mol kh gim i 0,3 mol so vi s mol kh ban u. Gi tr ca a l A. 0,4 B. 0,5 C. 0,6 D. 0,7 5. Bi tp lin quan n tnh oxi ha-kh ca SO2 v H2S V d 1. Cho phn ng 2H2S + SO23S + 2H2O Khi cho 6,8 gam H2S tc dng vi SO2 d (Cho hiu sut phn ng H=100%) Khi lng S to thnh l. A. 6,4 gam B. 3,4 gam C. 3,2 gam D. 9,6 gam V d 2. Ha tan V lt SO2 trong nc thu c dung dch X. Cho brom vo dung dch X cho n khi xut hin mu dung dch brom, sau thm tip dung dch BaCl2 cho n d, lc v lm kh kt ta thu c 1,165 gam cht rn. Gi tr ca V l A. 0,112 lt B. 0,224 lt C. 0,448 lt D. 0,336 lt V d 3. Ha tan ht 17,55 gam hn hp Mg, Al trong 150 gam dung dch H2SO4 98% thu c dung dch X v hn hp kh Y gm H2S v SO2. Cho Y li chm qua bnh ng dung dch KMnO 4 d thy c 4,8 gam kt ta xut hin, lc tch kt ta, cho nc lc tc dng vi dung dch BaCl2 d thu c 52,425 gam kt ta na. Nng phn trm ca H 2SO4 trong X v phn trm khi lng ca Mg trong hn hp ban u ln lt l A. 19,86% v 61,54% B. 19,86% v 64,58% C. 18,93% v 61,54% D. 18,93% v 61,54% 1. Ha tan hon ton V lt kh SO2 (kc) vo nc, cho nc brm vo dung dch n khi brom khng cn mt mu th tip tc cho dung dch BaCl2 vo n d, lc ly kt ta cn c 1,165g. Tnh V lt kh SO2. A. 0,112 lt B. 0,224 lt C. 0,336 lt D. 0,448 lt GV: Nguyn Th Thu Hng-Trng THPT Minh Khai-Quc Oai

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Chuyn oxy-lu hunh LTH 2012 2. Cho 1,72 gam hp kim Ag-Cu tc dng vi dung dch H 2SO4 c, nng. Kh SO2 thu c tc dng vi nc clo d, phn ng xy ra theo phng trnh: SO2 + Cl2 + 2H2O 2HCl + H2SO4 Dung dch thu c sau khi phn ng vi clo cho tc dng ht vi dung dch BaCl2 0,15M thu c 3,495 gam kt ta. 1. Th tch dung dch BaCl2 cn dng. A. 200 ml B. 300 ml C. 400 ml D. 500 ml 2. Thnh phn % khi lng ca Ag-Cu trong hp kim. A. 62,8%, 37,2% B. 50%, 50% C. 45,5%, 54,5% D. 52,5%,47,5% 6. Dng ton lin quan n hiu sut V d 1. T 300 tn qung pirit st cha 80% FeS2 ngi ta sn xut c bao nhiu tn H2SO4 98%, bit rng hao ht trong qu trnh sn xut l 10%. A. 320 tn B. 360 tn C. 400 tn D. 420 tn. V d 2. Cn bao nhiu tn qung pirit st cha 35,6% FeS2 sn xut 700 tn H2SO4 70%, bit rng hao ht trong qu trnh sn xut l 40%. A. 1404,5 tn B. 1360,2 tn C. 1400,8 tn D. 4200,5 tn. V d 3. T 2 tn qung pirit st cha 75% FeS2 nguyn cht cn li l cc tp cht khng cha lu hunh ngi ta iu ch c 2 tn dung dch H2SO4 98%. Tnh hiu sut ca phn ng iu ch. A. 70 % B. 80 % C. 90 % D. 100 %. V d 4. Mt loi qung c cha 80% lu hunh. Tnh th tch dung dch H 2SO4 98% (D=1,84gam/ml) c iu ch t 3,2 tn qung trn. Bit hiu sut ca phn ng iu ch l 80%. A. 4347,8 lt B. 4380,8 lt C. 6358,8 lt D. 8963,8 lt V d 5. Tnh khi lng H2SO4 thu c khi sn xut t 44 tn qung pirit st cha 80% FeS2 bit Hiu sut ca cc giai on l 70%. A. 24,65 tn B. 2,465 tn C. 19,72 tn D. 40,25 tn. 1. T 1,6 tn qung pirit st cha 60% FeS 2 nguyn cht cn li l cc tp cht khng cha lu hunh c th sn xut c bao nhiu tn dung dch H2SO4 98%. Bit hiu sut ca qu trnh sn xut l 60%. A. 0,96 tn B. 0,98 tn C. 0,90 tn D. 0,88 tn 2. C mt loi qung pirit st cha 96% FeS 2 nguyn cht. Mi ngy ngi ta cn sn xut 100 tn dung dch H 2SO4 98%. Bit hiu sut ca qu trnh sn xut l 90%. Tnh khi lng qung pirit st dng A. 69,44 tn B. 68,44 tn C. 67,44 tn D. 70,44 tn. 7. Dng ton pha trn dung dch V d 1. Trn ln m1 gam dung dch H2SO4 30% vi m2 gam dung dch H2SO4 15% c 300 gam dung dch H2SO4 25%. Cc gi tr m1 v m2 l A. 100 v 200. B. 200 v 100. C. 300 v 100. D. 150 v 150. V d 2. Cn V1 ml dung dch H2SO4 2,5M v V2 ml dung dch H2SO4 1M khi pha trn chng vi nhau thu c 600ml dung dch H 2SO4 1,5M. Cc gi tr V1 v V2 l: A. 200 v 400. B. 200 v 300 C. 300 v 300 D. 150 v 450. V d 3. Cn dng bao nhiu ml nc pha long 100 ml dung dch H2SO4 98% (D = 1,84g/ml) thnh dung dch H2SO4 20%. A. 700,2. B. 720,5 C. 717,6 D. 650,5. V d 4. Ha tan 200 gam SO3 vo m gam dung dch H2SO4 49% thu c dung dch H2SO4 78,4%. Gi tr ca m l A. 400. B. 300 C. 450 D. 500. V d 5. Trn m1 gam tinh th CuSO4. 5H2O vi m2 gam dung dch CuSO4 8% c 140 gam dung dch CuSO4 16%, Gi tr m1 v m2 ln lt l: A. 20 v 120. B. 200 v 10 C. 30 v 110 D. 15 v 150. V d 6. Trn 100 ml dung dch H2SO4 20% (D=1,14gam/ml) v 100 gam dung dch BaCl2 5,2%. Tnh nng dung dch H2SO4 sau khi trn A. 2,66%. B. 3,22% C. 1,52% D. 1,50% 1. Trn ln 200 gam dung dch H2SO4 30% vi 200 gam dung dch H2SO4 20%. Nng % ca dung dch H2SO4 thu c l A. 25,0%. B. 22,5% C. 25,5% D. 23,0% 2. Cn dng bao nhiu ml nc pha long 100ml dung dch H2SO4 98% (D=1,84g/ml) thnh dung dch H2SO4 20%. A. 717,6ml. B. 632,2 ml C. 561,5 ml D. 355,8ml 3. Cho 10,6 gam Na2CO3 vo 12 gam dung dch H2SO4 98% th s thu c bao nhiu gam dung dch. A. 18,2 gam B. 15,2 gam C. 35,2 gam D. 42,0 gam 4. Lm bay hi nc 500 ml dung dch A 20% (d=1,2g/ml) ch cn 300 gam dung dch. Tnh nng phn trm ca dung dch ny. A. 25%. B. 40% C. 25,5% D. 30% 7. Dng ton tm cng thc phn t *Lp CTPT da vo % khi lng cc nguyn t v bit khi lng phn t M. V d 1: Xc nh CTPT ca hp cht A bit thnh phn % cc nguyn t ln lt l: %H = 2,04%; %S = 32,65%; %O = 65,31%. Bit khi lng phn t M = 98gam/mol A. H2SO4. B. H2S C. H2SO3 D. SO2 * Lp CTPT da vo t l khi lng gia cc nguyn t v bit khi lng phn t M. V d 2: Hp cht C c khi lng phn t M = 98g/mol, gm nguyn t H, S, O c t l khi lng mH : mS : mO = 1 : 16 : 32. GV: Nguyn Th Thu Hng-Trng THPT Minh Khai-Quc Oai T 0986.939.308 7

Chuyn oxy-lu hunh LTH 2012 A. H2SO4. B. H2S C. H2SO3 D. SO2 * Lp CTPT da vo thnh phn % khi lng nguyn t. V d 3: Tm cng thc phn t ca hp cht A gm 40%Cu, 20%S, 40%O. Bit A c khi lng phn t l MA = 160gam/mol. * Lp CTPT da vo phng trnh phn ng. V d 4: Cho 6,5 gam kim loi R (II) tc dng va vi dung dch H2SO4 long d thu c mui ca kim loi v 0,2 gam kh H2. Tm kim loi R. V d 5: t chy hon ton 3,4 gam hp cht A thu c 2,24 lt kh SO2 (ktc) v 1,8 gam H2O. Cng thc phn t ca A l A. H2SO4. B. H2S C. H2SO3 D. SO2 V d 6. Cho 2,16 gam mt kim loi M ha tr II vo 250ml dung dch H2SO4 0,45M, M tan ht. trung ha dung dch thu c cn 90ml dung dch KOH 0,5M. Xc nh tn kim loi M. A. Cu B. Mg C. Fe D. Ca V d 7. Hn hp A gm hai kim loi X, Y thuc hai chu k lin tip thuc phn nhm chnh nhm II. Ha tan hon ton 2,64 gam hn hp A vi dung dch H2SO4 long d thu c 2,016 lt kh ktc. Xc nh X v Y. A. Mg, Ca B. Ca, Ba C. Ca, Sr D. Na, Ca V d 8. Ha tan 33,8 gam oleum H2SO4.nSO3 vo nc, sau cho tc dng vi lng d BaCl 2 thy c 93,2 gam kt ta. Cng thc chung ca oleum l: A. H2SO4.SO3 B. H2SO4.2SO3 C. H2SO4.3SO3 D. H2SO4.4SO3 V d 9. Ha tan hon ton a gam mt oxit st bng dung dch H 2SO4 c nng d thu c 2,24 lt kh SO 2 (ktc) v trong dung dch c cha 120 gam mt mui st duy nht. Cng thc ca oxit st l. A. Fe2O3 B. FeO C. Fe3O4 D. FeO2 1. Hp cht A c khi lng phn t l MA = 80gam/mol, c to nn t nguyn t S v O, bit t l mS:mO = 2:3 A. SO3 B. SO2 C. S2O7 D. SO4 2. Hp cht B c to nn t nguyn t Cu, S, O bit t l khi lng gia cc nguyn tt m Cu : mS : mO = 2 : 1 : 2, c khi lng phn t l M B = 160gam/mol. A. CuSO4 B. CuSO3 C. Cu2SO4 D. CuS2O 3. Khi ha tan mt oxit kim loi ha tr II bng mt lng va dung dch H2SO4 10% thu c dung dch mui c nng 11,8%. Hy xc nh cng thc ca oxit trn. A. MgO B. CaO C. CuO D. BaO 4. Ha tan 1,8 gam mui sunfat ca mt kim loi M thuc nhm IIA vo H2O sau pha long cho 50ml dung dch. phn ng ht vi dung dch ny cn 20 ml dung dch BaCl2 0,75M. Cng thc ca mui v nng ca dung dch mui sau khi pha ch? A. Mg, 0,3M B. Zn, 0,5M C. Cu, 0,15M D. Ca, 0,5M 5. Mt oxit to bi Mn v O, trong t l khi lng ca Mn v O l 55: 32. Xc nh cng thc phn t ca oxit. A. MnO2 B. Mn2O3 C. Mn2O7 D. Mn2O5 6. Cho 3,9 gam kim loi X ha tr II vo 250 ml dung dch H2SO4 0,3M. trung ha lng axit d cn dng 60 ml dung dch KOH 0,5M. Kim loi X l A. Mg B. Zn C. Mn D. Cu 7. t chy hon ton 3,4 gam hp cht A thu c 6,4 gam SO2 v 1,8 gam H2O. Cng thc phn t ca A l A. H2SO4. B. H2S C. H2SO3 D. SO2 8. Ha tan 6,76 gam oleum H2SO4.nSO3 vo nc ta c 200 ml dung dch H 2SO4.Trung ha hon ton 10 ml dung dch ny cn va 16 ml dung dch NaOH 0,5M. Cng thc chung ca oleum l: A. H2SO4.SO3 B. H2SO4.2SO3 C. H2SO4.3SO3 D. H2SO4.4SO3 CHUYN : NHM OXI- LU HUNH Cu 1: Cho 855g dd Ba(OH)2 10% vo 200g dung dch H2SO4. Lc tch b kt ta. trung ho nc lc ngi ta phi dng 125ml dung dch NaOH 25%, d= 1,28. Nng phn trm ca dung dch H2SO4 l: A. 63 B.25 C.49 D.83 Cu 2: cu hnh lp electron ngoi cng ca cc nguyn t nhm oxi l: A. ns2np6 B. ns2np5 C.ns2np4 D. (n-1)d10ns2np6 Cu 3: trong cc hp cht ho hc s oxi ho thng gp ca lu hunh l: A. 1,4,6 B. -2,0,+2,+4,+6 C.-2,0,+4,+6 D. kt qu khc Cu 4: Cho st kim loi tc dng vi oxi khng kh thu c hn hp cht rn A. Cho A tc dng vi dd H2SO4 long d thu c dung dch B. Cho dd B tc dng vi dd NaOH d thu c kt ta C, nung C trong khng kh ti khi lng khng i c chy rn D. D cha cht no sau y: A. Fe, FeO B. FeO, Fe2O3 C. FeO D.Fe2O3 Cu 5: Dy cht no sau y gm cc cht ch c tnh oxi ho: A. O3, H2SO4, F2 B. O2, Cl2, H2S C. H2SO4, Br2, HCl D. c A,B,C u ng Cu 6: h s ca phn ng:FeS + H2SO4 c, nng Fe2(SO4)3 + SO2 + H2O l: A. 5,8,3,2,4 B. 4,8,2,3,4 C. 2,10,1,5,5 D. c A,B,C u sai Cu 7: H s ca phn ng: FeCO3 + H2SO4 Fe2(SO4)3 +SO2 + CO2 +H2O A. 2,8,1,3,2,4 B. 4,8,2,4,4,4 C. 8,12,4,5,8,4 D.kt qu khc GV: Nguyn Th Thu Hng-Trng THPT Minh Khai-Quc Oai T 0986.939.308 8

Chuyn oxy-lu hunh LTH 2012 Cu 8: H s ca phn ng:P + H2SO4 H3PO4 + SO2 + H2O A. 2, 3,2,1,2 B. 2,4,2,5,1 C. 2,5,2,5,2 D. kt qu khc Cu 9: cho 11,2 g st tc dng vi dung dch H2SO4 c nng th s mol e nhng ca Fe cho axit l: A. 0,6 B. 0,4 C.0,2 D.0,8 Cu 10: Trong phn ng no cht tham gia l axit Sunfuric c? A. H2SO4 + Na2SO3 Na2SO4 + SO2+ H2O B. H2SO4 + Fe3O4 FeSO4 + Fe2(SO4)3+ H2O C. H2SO4 + Fe(OH)2 Fe2(SO4)3+ SO2 + H2O D. C Av C Cu 11: Cho ln lt cc cht sau : MgO, NaI, FeS, Fe3O4, Fe2O3, FeO, Fe(OH)2, Fe(OH)3, FeSO4, Fe2(SO4)3 tc dng vi dung dch H2SO4 c, nng. S phn ng oxi ho - kh l:A. 9 B. 8 C. 7 D. 6 Cu 12: Ho tan hon ton 2,81g hn hp gm Fe2O3, MgO, ZnO trong 500ml ddH2SO40,1M(va ).Sau phn ng,c cn dung dch thu c mui khan c khi lng l: A. 6.81g B. 4,81g C.3,81g D.5,81g Cu 13: Nguyn tc pha long axit Sunfuric c l: A.Rt t t axit vo nc v khuy nh B. Rt t t nc vo axit v khuy nh C. Rt t t axit vo nc v un nh D. Rt t t nc vo axit v un nh Cu 14:Cho pthh: H2SO4 c, nng + KBr A+ B +C+ D. A, B, C,D l dy cht no sau y: A.HBr, SO2, H2O, K2SO4 B. SO2, H2O, K2SO4, Br2 C. SO2, HbrO, H2O, K2SO4 D. , H2O, K2SO4, Br2, H2S Cu 15: Dy cht no sau y ch c tnh oxi ho? A. O2, SO2, Cl2, H2SO4 B. S, F2, H2S, O3 C. O3, F2, H2SO4, HNO3 D.HNO3, H2S, SO2, SO3 Cu 16: Dy cht no sau y va c tnh kh va c tnh oxi ho? A. Cl2, SO2, FeO, Fe3O4 B.SO2, Fe2O3, Fe(OH)2, H2S C. O2, Fe(OH)3, FeSO4, Cl2D. Fe, O3, FeCO3, H2SO4 Cu 17: Ion X2- c cu hnh electron lp ngoi cng l 3s23p6 . X l nguyn t no trong bng h thng tun hon? A. Oxi B. Lu hunh C.Selen D.Telu Cu 18: Trong phng th nghim ngi ta iu ch oxi bng cch: A. in phn nc B. nhit phn Cu(NO3)2 C. chng ct phn on khng kh lng D. nhit phn KClO3 c xc tc MnO2 Cu 19: Lu hunh si 4500C, nhit no lu hunh tn ti di dng phn t n nguyn t? A. 4500C B. 14000C. C. . 17000C D. nhit phng Cu 20: Cho pthh: SO2 + KmnO4 +H2OK2SO4 + MnSO4 +H2SO4 Sau khi cn bng h s ca cht oxi ho v cht kh l: A. 5 v 2 B. 2 v 5 C. 2 v 2 D. 5 v 5 Cu 21: ho tan st II sunfua vo dd HCl thu c kh A. t hon ton kh A thu c kh C c mi hc. kh A,C ln lt l:A. SO2, hi S B. H2S, hi S C. H2S, SO2 D. SO2, H2S Cu 22: Axit Sunfuric c phn ng vi cht no sau y (c un nng) sinh ra kh SO2? 1, Cu 2, NaOH 3, Al 4, C 5, ZnO 6, HCl 7, HI A. 1,2,3,4,5 B.1,3,4,6,7 C. 1,3,4,7 D. tt c Cu 23: C 3 ng nghim ng cc kh SO2, O2, CO2. Dng phng php thc nghim no sau y nhn bit cc cht trn:A. Cho tng kh li qua ddCa(OH)2 d, dng u que m cn tn B. Cho tng kh li qua dd H2S , dng u que m cn tn C. Cho hoa hng vo cc kh , dng u que m con tn D. B v C ng Cu 24: C 5 kh ng trong 5 l ring bit l Cl2, O2, HCl, O3, SO2. Hy chn trnh t tin hnh no sau y phn bit cc kh: A. Nhn bit mu ca kh, dng dung dch AgNO3,dung dch HNO3 c, dng u que m cn tn , dung dch KI. B. Dung dch H2S, dung dch AgNO3, dung dch KI C. dung dch AgNO3, dung dch KI, dng u que m cn tn D. Tt c u sai Cu 25: Cho 4,6g Na kim loi tc dng vi mt phi kim to mui v phi kim trong hp cht c s oxi ho l -2 , ta thu c 7,8g mui, phi kim l phi kim no sau y:A. Clo B. flo C. Lu hunh D. kt qu khc Cu 26: C 3 bnh, mi bnh ng mt dung dch sau: HCl, H2SO3, H2SO4. Nu ch dng thm mt cht lm thuc th th c th chn cht nop sau y phn bit cc dung dch trn : A. Bari hiroxit B. Natri hirxit C. Bari clorua D. Av C u ng Cu 27: Cho hn hp gm Fe v FeS tc dgn vi dung dch HCl d, thu c 2,464 lt hn hp kh X(ktc). Cho hn hp kh ny qua dung dch Pb(NO3)2 d thu 23,9g kt ta mu en . th tch cc kh trong hn hp kh X l:A. 0,224lt v 2,24 lt B. 0,124lt v 1,24 lt C. 0,224lt v 3,24 lt D. Kt qu khc Cu 28: Hp th hon ton 12,8g SO2 vo 250ml dung dch NaOH 1M. Khi lng mui to thnh sau phn ng l: A. 15,6g v 5,3g B. 18g v 6,3g C. 15,6g v 6,3g D. Kt qu khc Cu 29: ho tan 3,38g oleum X vo nc ngi ta phi dng 800ml dd KOH 0,1 M trung ho dd X. Cng thc phn t oleum X l cng thc no sau y:A. H2SO4.3SO3 B. H2SO4.2SO3 C. H2SO4.4SO3 D.H2SO4nSO3 Cu 30: C 200ml dd H2SO4 98% (D = 1,84 g/ml). Ngi ta mun pha long th tch H2SO4 trn thnh dung dch H2SO4 40% th th tch nc cn pha long l bao nhiu A. 711,28cm3 B. 533,60 cm3 C. 621,28cm3 D. 731,28cm Cu 31: T 1,6 tn qung c cha 60% FeS2, ngi ta c th sn xut c khi lng axit sunfuric l bao nhiu? GV: Nguyn Th Thu Hng-Trng THPT Minh Khai-Quc Oai

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Chuyn oxy-lu hunh LTH 2012 A. 1558kg B. 1578kg C. 1548kg D. 1568kg Cu 32: C mt loi qung pirit cha 96% FeS2. Nu mi ngy nh my sn xut 100 tn axit sunfuric 98% th lng qung pirit trn cn dng l bao nhiu ?Bit hiu sut iu ch H2SO4 l 90% A. 69,44 tn B. 68,44tn C. 67,44 tn D. 70,44tn Cu 33: Ho tan mt oxit kim loi X ho tr II bng mt lng va ddH2SO4 10% ta thu c dung dch mui c nng 11,97%. X l kim loi no sau y:A. Ca B. Fe C. Ba D. Mg Cu 34: Cho H2SO4 long d tc dng vi 6,660 hn hp 2 kim loi X v Y u ho tr II, ngi ta thu c 0,1 mol kh, ng thi khi lng hn hp gim 6,5g. ho tan phn cn li bng H2SO4 c nng ngi ta thy thot ra 0,16g kh SO2. X,Y l nhng kim loi no sau y:A. Hg v Zn B. Cu v Zn C. Cu v Ca D.Kt qu khc Cu 35: Cho 31,4g hn hp hai mui NaHSO3v Na2CO3vo 400g dung dchdd H2SO49,8%, ng thi un nng ddthu c hn hp kh A c t khi hi so vi hir bng 28,66v mt ddX. C%cc cht tan trong dd ln lt l: A. 6,86% v 4,73% B.11,28% v 3,36% C. 9,28% v 1,36% D. 15,28%v 4,36% Cu 36: Ho tan 9,875g mt mui hirrcacbonat (mui X)vo nc v cho tc dng vi mt lng H2SO4 va , ri em c cn th thu c 8,25g mt mui sunfat trung ho khan. Cng thc phn t ca mui Xl : A.Ba(HCO3)2 B.NaHCO3 C.Mg(HCO3)2 D. NH4HCO3 Cu 37: Cho 33,2g hn hp X gm Cu, Mg, Al tc dng va vi dung dch HCl thu c 22,4 lt kh ktc v cht rn khng tan B. Cho B ho tan hon ton vo dung dch H2SO4 c, nng d thu c 4,48 lt kh SO2(ktc). Khi lng mi kim loi trong hn hp X ln lt l: A. 13,8g; 7,6; 11,8 B. 11,8; 9,6; 11,8 C.12,8; 9,6; 10,8 D. kt qu khc Cu 38: Cho 12,8g Cu tc dng vi H2SO4 c nng d , kh sinh ra cho vo 200ml dung dch NaOH 2M. Hi mui no c to thnh v khi lng l bao nhiu A. Na2SO3v 24,2g B.Na2SO3 v 25,2g C. NaHSO315g v Na2SO326,2g D.Na2SO3 v 23,2g Cu 39: Ho tan hon ton 12,1 g hn hp Xgm Fe v kim loi M ho tr II trong dd H2SO4 long th thu c 4,48 lt kh H2(ktc) .Cng cho lng hn hp trn ho tan hon ton vo H2SO4 c nng , d th thu c 5,6 lt kh SO2 (ktc). M l kim loi no sau y:A. Ca B. Mg C.Cu D. Zn Cu 40: Cho11,2g Fe v 2,4g Mg tc dng vi dung dch H2SO4 long d sau phn ng thu c ddA v V lt kh H2 ktc. Cho ddNaOH d vo ddA thu c kt taB lc B nung trong khng kh n khi lng khng i c mg cht rn. 1/ V c gi tr l:A. 2,24lt B. 3,36 lt C. 5,6l D. 4,48l E. 6,72l 2/ khi lng cht rn thu dc lA. 18g B.20g C.24g D.36g E.40 Cu 41: phn bit 4 bnh mt nhn ng rieng bit cc kh CO2, SO3, SO2 v N2, mt hc sinh d nh dng thuc th(mt cch trt t) theo 4 cch di y cch no ng A.ddBaCl2, ddBrom, ddCa(OH)2 B.ddCa(OH)2, ddBa(OH) 2, ddbrom C. qu tm m, dd Ca(OH)2, ddBr2 D. ddBr2, ddBaCl2, que m Cu 42: Cho phn ng ho hc sau: HNO3 + H2SNO+ S +H2O H s cn bng ca phn ng lA. 2,3,2,3,4 B. 2,6,2,2,4 C. 2,2,3,2,4 D. 3,2,3,2,4 Cu 43: Cho kh CO i qua ng s cha 3,2g Fe2O3un nng, sau phn ng thu c hn hp rn Xgm Fe v cc oxit. Ho tan hon ton X bng H2SO4c nng thu c ddY. C can ddY , lng mui khan thu c la: A.4g B.8g C.20g D.48g Cu 44: Ho tan hon ton 3,22g hn hp X gm Fe, Mg Zn bng mt lng va H2SO4 long thy thot 1,344l H2 ktc v dung dch cha m gam mui. Gi tr ca m l:A. 10,27g B.8.98 C.7,25g D. 9,52g Cu 45: Ho tan 0,54 g KL c ho tr n khng i trong 100 ml dd H2SO4 0,4 M . trung ho lng H2SO4 d cn 200 ml dd NaOH 0,1 M . Vy ho tr n v KL Ml : A. n=2 , Zn B. n=2, Mg C.n=1, K D. n=3 , Al Cu 46: Cng mt lng R khi ho tan ht bng d2 HCl & H2SO4 ,n th lng SO2 gp 48 ln H2 sinh ra.Mt khc khi lng mui Clorua bng 63,5% khi lng mui sunphat .R l: A. Mg B. Fe C. Al D.Zn

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