khuongduy_1088

098 363 1982

O2 , S C BN V NNG CAO
I. Chui phn ng :
Cu 1: Hon thnh cc phng trnh phn ng sau:

a. S SO2 S H2S H2SO4 SO2 Na2SO3 SO2 SO3 H2SO4 FeSO4 Fe(OH)2 FeSO4 BaSO4. b. Na2S H2S K2S H2S FeS H2S S H2S SO2 H2SO4 SO2 Na2SO3 SO2 S ZnS. c. H2SO4 SO2 H2SO4 Fe2(SO4)3 Fe(OH)3 Fe2(SO4)3 K2SO4 BaSO4.
Cu 2 : Vit cc phng trnh phn ng thc hin cc bin ha sau : FeS SO2 SO3 H2SO4 CuSO4 BaSO4 S H2S SO2 Cu 3: Hon thnh chui phn ng sau : S H2S SO2 KHSO3 K2SO3 SO2 CaSO3 Cu 4: Hon thnh cc phng trnh phn ng theo s :

a. Hidrosunfua lu hunh kh sunfur axir sunfuric lu hunh ioxit canxi sunfit kh sunfur lu hunh hidrosunfua axit sunfuric. b. Kali permanganat oxi kh sunfur lu hunh trioxit axit sunfuric st (II) sunfat st (II) hydroxyt st (II) oxit st (III) sunfat st (III) hydroxyt st (III) clorrua.
Cu 5: Hon thnh s bin ha sau :

1. H2S + O2 A (rn) + B (lng) 2. MnO2 + HCl D + E + B 1. G + Ba H + I D + I G II. Nhn bit

Cu 1: Nhn bit cc dung dch mt nhn:

2. A + 4. B +

O2 t C C + D F + G

d. H2S, H2SO4, HNO3, HCl. Cu 2: Ch dng mt thuc th hy nhn bit cc dung dch: Na2S, Na2SO3, BaCl2, NaCl. Cu 3: Ch dng mt thuc th hy nhn bit cc dung dch: H2SO4, BaCl2, NaCl, Na2SO3, Na2S. Cu 4: Nhn bit cc cht kh: b. Cl2, H2S, O3, O2. Cu 5: Trnh by phng php phn bit 4 cht rn : NaCl, Na2CO3, BaSO4, BaCO3 vi iu kin ch dng thm dung dch HCl long.

a. H2SO4, HCl, NaOH, Na2SO4, HNO3. b. NaI, NaCl, Na2SO4, Na2S, NaNO3.

c. K2SO3, K2SO4, K2S, KNO3.

a. SO2, H2S, O2,Cl2.

III. Bi tp vit PTP v iu ch cht

Cu 1: Vit 2 phng trnh chng minh: a. SO2 ng vai tr l cht oxi ha. SO2 ng vai tr l cht kh. b. H2S l cht kh. H2SO4 c l cht oxi ha. c. S l cht kh. S l cht oxi ha. d. Ozon c tnh oxi ha mnh hn oxi. Cu 2: T FeS2, naCl, O2 v H2O. Vit cc pt phn ng iu ch: Fe2(SO4)3, Na2SO4, nc iaven, Na2SO3, Fe(OH)3. Cu 3: T KCl, Cu, S v H2O. Vit cc phng trnh iu ch FeCl2, CuCl2, H2S, CuSO4, FeSO4, Fe2(SO4)3. Cu 4: Chia dung dch axit sunfuric lm ba phn bng nhau. Dng dung dch natri hydroxyt trung ha va phn th nht. Vit cc phng trnh phn ng. Trn phn th hai v ba vo nhau ri rt vo dung dch thu c mt lng ng bng lng dung dch dng phn th nht. Vit cc phng trnh phn ng xy ra v gi tn sn phm.

IV. Xc nh cht
Cu 1: Cho 3,36 lt O2(ktc) phn ng hon ton vi mt kim loi ha tr (III) thu c 10,2g oxit. Xc nh tn kim loi. Cu 2: t chy hon ton 0,84g mt kim loi ha tr (II) ht vi 0,168 lt kh O2 (ktc). Xc nh tn kim loi. Cu 3: t chy hon ton 2,88g mt kim loi ht vi oxi thu c 4,8g oxit. Xc nh tn kim loi. Cu 4: Cho 2,8g mt kim loi ha tr (III) tc dng ht vi dung dch axit sunfuric c nng thu c 1,68 lt kh SO2 ktc. Xc nh tn kim loi. Cu 5: Cho 12,15g mt kim loi tc dng ht vi 1000ml dung dch axit sunfuric 1,35M. Xc nh tn kim loi.

khuongduy_1088 098 363 1982 Cu 6: Ha tan hon ton 1,44g kim loi ha tr (II) bng 250ml dung dch H2SO4 0,3M. Sau phn ng phi dng ht 60ml dung dch NaOH 0,5M trung ha lng axit cn d. Xc nh tn kim loi. Cu 7: 6,3 gam mt kim loai X co hoa tri khng i tac dung hoan toan vi 0,15 mol O 2. Cht rn thu c sau phan ng em hoa tan vao dung dich HCl ( d) thy thoat ra 1,12 lit khi H2 ktc. Xac inh kim loai X. Cu 8: Cho 1,2 gam kim loi X ha tr II vo 150ml dung dch H2SO4 long 0,3M, X tan ht, sau ta cn thm 60ml dung dch KOH 0,5M trung ha axit d. Xc nh kim loi X. Cu 9: t chy hon ton 6,8 gam mt cht th thu c 12,8 gam SO 2 v 3,6 gam nc. Xc nh cng thc ca cht em t. Kh SO2 sinh ra cho i vo 50ml dung dch NaOH 25% ( d= 1,28g/l). Hi mui no c to thnh ? Tnh nng % ca n trong dung dch thu c ? Cu 10: Ha tan 28,4g mt hn hp gm hai mui cacbonat ca hai kim loi ha tr II, bng dung dch HCl d thu c 10 lt kh 54,6oC v 0,8064 atm v dung dch X. 1. Hy tnh tng s gam ca hai mui trong dung dch X. 2. Xc nh hai kim loi, nu hai kim loi thuc 2 chu k lin tip, cng mt phn nhm. 3. Tnh % khi lng mi mui trong hn hp u. Cu 11: Hn hp Y gm 2 mui cacbonat ca hai kim loi kim th. Trong mui th nht kim loi chim 28,57% khi lng v trong mui th hai kim loi chim 40% khi lng. 1. Xc nh tn hai mui.

2. Cho 31,8g vo hn hp Y vo 800ml dung dch HCl 1M. sau phn ng thu c dung dch Z. Trong Z c d axit
khng? Xc nh lng kh CO2 c th thu c (khng dng so liu th nghim cu 3).

3. Cho vo Z mt lng dung dch NaHCO3 d th thu c 2,24 lt kh CO2 (ktc). Tnh khi lng mi mui trong
Y.

V. BT cht d cht phn ng ht.

Cu 1: Nung hn hp gm 3,2g S v 4,2g Fe trong bnh kn n phn ng hon ton. Tnh khi lng cc cht sau png ? Cu 2: Nung hn hp gm 3,2g S v 1,3g Zn trong bnh kn n phn ng hon ton. Tnh khi lng cc cht sau png ? Cu 3: un nng hn hp gm 11,2g bt st v 3,2g bt lu hunh, cho sn phm to thnh vo 500ml dung dch HCl th thu c hn kh v dung dch A. a. Tnh thnh phn % v th tch mi cht kh trong hn hp. b. trung ha HCl cn d trong dung dch A phi dng 250ml dung dch NaOH 0,1M. Tnh nng mol/l ca dung dch HCl dng. Cu 4: Nung 5,6 g bt st v 13g km vi mt lng d lu hunh. Sn phm cu phn ng cho tan hon ton trong dung dch axit clohidric. Kh sinh ra dn vo dung dch Pb(NO3)2 . a. Vit cc phng trnh phn ng xy ra?

b. Tnh th tch dung dch Pb(NO3)2 (D = 1,1g/ml) cn hp th hon ton lng kh sinh ra.
Cu 5: Cho 8,96 lt kh (ktc) H2S vo mt bnh ng 85,2g Cl2 ri vo bnh ng mt lt nc phn ng xy ra hon ton. a. Trong bnh cn kh g? Bao nhiu mol?

b. Tnh khi lng H2SO4 sinh ra.

Cu 6: Mt hn hp kh gm H2S v H2 c s mol theo t l 2:1. Chia 6,72 lt hn hp kh trn thnh 2 phn bng nhau. Phn 1: em t chy hon ton. Phn 2: sc vo dung dch Pb(NO3)2 20%. a. Tnh th tch oxi cn dng t chy phn 1. b. Tnh khi lng dung dch Pb(NO3)2 dng phn ng vi phn 2. Cu 7. Cho 6,72 gam Fe tc dng hon ton vi 30 gam dung dch H2SO4 98% c nng thu c V lt SO2 ( ktc ) v dung dch X. Tnh V v khi lng mui trong X ? Cu 8. Cho 11,2 gam Fe tc dng hon ton vi 49 gam dung dch H2SO4 90% c nng thu c V lt SO2 ( ktc ) v dung dch X. Tnh V v khi lng mui trong X ?

VI. Xc nh mui to thnh t phn ng ca H2S v SO2 vi baz tan

Cu 1. Dn ton b 2,24 lt kh H2S vo 100 ml dung dch KOH 1,6M. Tnh khi lng mui sau phn ng ? Cu 2: Cho 150 g dung dch H2S 3,4% tc dng vi 250 ml dd NaOH 1M. Tnh khi lng mui to thnh sau phn ng. Cu 3: Dn 4,48 lt kh SO2 (ktc) vo 300 ml dung dch NaOH 1M. Tnh khi lng mui to thnh sau phn ng?

khuongduy_1088 098 363 1982 Cu 4: Dn kh sunfur c khi lng 6,4g vo 250g dung dch KOH 12%. Tnh khi lng mui to thnh sau phn ng? Cu 5: Dn 6,720 ml kh SO2 (ktc) vo 500ml dung dch NaOH, sau phn ng thu c mui trung ha. Tnh nng mol ca NaOH v nng mol mui ? Cu 6. Hp th hon ton 2,24 lt kh SO2 ( ktc ) vo 100 ml dung dch Ca(OH)2 0,8M thu c m gam kt ta. Tnh m ? Cu 7. Hp th hon ton 3,36 lt kh SO2 ( ktc ) vo 125 ml dung dch Ba(OH)2 1M thu c m gam kt ta. Tnh m ? Cu 8. Hp th hon ton V lt kh SO2 ( ktc ) vo 200 ml dung dch Ca(OH)2 1M thu c 12 gam kt ta. Tnh V ? Cu 9. Hp th hon ton V lt kh SO2 ( ktc ) vo 300 ml dung dch Ba(OH)2 0,8M thu c 21,7 gam kt ta. Tnh V ? Cu 10. Hp th hon ton 5,6 lt kh SO2 ( ktc ) vo 200 ml dung dch Ca(OH)2 aM thu c 6 gam kt ta. Tnh a ? Cu 11. Hp th hon ton 8,96 lt kh SO2 ( ktc ) vo 500 ml dung dch Ca(OH)2 aM thu c 24 gam kt ta. Tnh a ? Cu 12. Tnh th tch ti thiu ca dung dch A ( gm NaOH 1M v KOH 1,5M ) hp th hon ton 5,6 lt SO2 ( ktc ) ?

VII. Kim loi + H2SO4

Cu 1: Cho 12 g hn hp gm Al, Cu tc dng ht vi 500ml dung dch H2SO4 long thu c 11,2 lit kh (ktc).

a. Tnh khi lng mi kim loi v tnh nng mol H2SO4.

b. Tnh nng mol mui thu c sau phn ng. Cu 2: Cho 31,5 g hn hp gm Mg, Zn tc dng ht vi 300g dung dch H2SO4 long thu c 17,92 lit kh (ktc).

a. Tnh khi lng mi kim loi v tnh nng % H2SO4. b. Tnh nng mol H2SO4 (D= 0,5g/ml).
Cu 3: Cho 25,95g hn hp gm Zn, ZnO tc dng ht vi 250g dung dch H2SO4 long thu c 7840 ml kh (ktc).

a. Tnh % mi cht trong hn hp v tnh nng % H2SO4.

b. Tnh nng % mui. Cu 4: Cho 39,2 g hn hp gm Fe, Cu tc dng ht vi 800ml dung dch H2SO4 c ngui thu c 11760ml kh (ktc).

a. Tnh thnh phn % theo khi lng mi kim loi v tnh nng mol H2SO4.
b. Ly ht lng mui trn cho tc dng vi 500ml dung dch NaOH 1,25 M. Tnh nng mol cc cht thu c sau phn ng. Cu 5: Cho 15,15 g hn hp gm Fe, Al tc dng ht vi 500g dung dch H2SO4 c nng thu c 13440ml kh (ktc).

a. Tnh thnh phn % theo khi lng mi kim loi. Tnh nng % H2SO4. b. Dn ton b lng kh sinh ra qua 300g dung dch NaOH 11,4% Tnhkhi lng mui to thnh sau phn ng.
Cu 6: Cho 6,48g hn hp gm FeO, Ag tc dng ht vi 800ml dung dch H2SO4 c nng thu c 1,344lt kh (ktc).

a. Tnh thnh phn % theo khi lng mi kim loi. Tnh nng mol H2SO4.
b. Ly ht lng mui trn cho tc dng vi 500ml dung dch NaOH 1,25 M. Tnh nng mol cc cht thu c sau phn ng. Cu 7: Cho mg hn hp gm Fe, Zn, Cu tc dng ht vi dung dch H2SO4 long thu c 13,44 lt kh (ktc) v 9,6g cht rn. Mt khc cng ly mg hn hp ni trn cho tc dng ht vi dung dch H2SO4 c ngui thu c 7,84 lt kh (ktc). Tnh m? Tnh thnh phn % theo khi lng mi kim loi. Cu 8: Cho 35,2g hn hp Fe v Cu vo dung dch H2SO4 long th thu c 8960ml kh (ktc). a. Tnh khi lng mi kim loi.

b. -

Cho cng lng hn hp trn vo dung dch H2SO4 c nng. Tnh khi lng dung dch H2SO4 c 78% dng. Phn 1: Tc dng vi dung dch H2SO4 long d th c 3,528 lt H2v 3,24g mt cht rn. Phn 2: Tc dng vi dung dch H2SO4 c nng d.

Cu 9: Chia 15,57g hn hp gm Al, Fe, Ag lm 2 phn bng nhau:

khuongduy_1088 a. Tnh khi lng mi kim loi. a. Tnh khi lng mi kim loi.

098 363 1982 b. Tnh th tch SO2 thu c phn 2. (cc th tch o ktc).

Cu 10: Cho 19,8g hn hp Al,Cu, CuO tc dng va vi 147g dung dch H2SO4 c 60% nng thu c 8,96 lt kh (kc). b. Tnh nng % cc cht trong dung dch thu c sau phn ng.

VIII. Xc nh nng ca H2SO4

Cu 1: Cho 855g dung dch Ba(OH)2 10% vo 200g dung dch H2SO4. Lc b kt ta, trung ha nc lc phi dng 125 ml dung dch NaOH 25% (D= 1,28g/ml). Tnh nng % H2SO4 trong dung dch ban u. Cu 2: Mt dung dch A cha HCl v H2SO4 theo t l mol 3:1, 100 ml dung dch A trung ha 50ml dung dch NaOH c cha 20g NaOH / lt. Tnh nng mol ca mi axit. Cu 3: 100ml dung dch X cha H2SO4 v HCl theo t l mol 1:1. trung ha 100ml dung dch X cn 400ml dung dch NaOH 5% (D = 1,2g/ml). a. Tnh nng mol ca mi axit trong dung dch X. b. C cn dung dch sau phn ng. Cho bit tng khi lng mui thu c. Cu 4: a. Cn hoa tan bao nhiu gam SO3 vao 100 gam dung dich H2SO4 10% c dung dich co nng 20%. b. Cn bao nhiu gam SO3 vao dung dich H2SO4 10% c 100 gam dung dich 20% IX. So snh lng to thnh v ban u Cu 1. So sanh th tich khi oxi thu c ( cng mt iu kin ) khi phn huy hoan toan KMnO4, KClO3, H2O2 trong cac trng hp sau: a. Ly cung khi lng cac cht em phn huy. b. Ly cung mol cac cht em phn huy. Cu 2. Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl c. Xc nh cht to ra lng kh Cl2 nhiu nht Cu 2:

1. t 2 cc A, B c khi lng bng nhau ln a cn : Cn thng bng. Cho 10,6 gam Na 2CO3 vo cc A v 11,82
gam BaCO3 vo cc B, sau thm 12 gam dung dch H 2SO4 98% vo cc A. Cn mt thng bng. Nu thm t t mt lng dung dch HCl 14,6% vo cc B cho ti khi cn thng bng tr li th tn bao nhiu gam dung dch HCl 14,6% ? Gi s nc v HCl bay hi khng ng k.

2. Sau khi cn thng bng, ly 2 lng cac cht trong cc B cho vo cc A, cn mt thng bng.
a. Hi phi thm bao nhiu gam nc vo cc B cho cn thng bng tr li ? b. Nu khng dng nc m dng dung dch HCl 14,6% th phi dng bao nhiu gam dung dch HCl ?

Cu 3: Cho 2 cc A, B bng nhau. t A, B ln 2 a cn, cn thng bng. Thm vo cc A 126g K2CO3 v cc B 85 gam AgNO3. 1. Thm 100 gam dung dch H2SO4 19,6% vo cc A v 100 gam dung dch HCl 36,5 % vo cc B. Phi thm bao nhiu gam nc vo cc A hay cc A cn thng bng? 2. Sau khi cn thng bng, ly 2 cc B cho vo cc A. Phi thm vo cc B bao nhiu gam nc cn thng bng ? X. Bi tp tng hp
Cu 1: Cn bao nhiu gam tinh th CuSO4.5H2O va bao nhiu gam dung dich CuSO4 8% iu ch 280 gam dd CuSO4 16% Cu 2: Ngi ta san xut H2SO4 t qung pyrit. Nu dung 300 tn qung pyrit co 20% tap cht thi san xut c bao nhiu tn dung dich H2SO4 98%. Bit rng hao hut trong san xut la 10% Cu 3: Cho 4,98 gam hn hp Na2SO4, Na2SO3, NaHSO3 vao dung dich H2SO4 d thu c 0,672 lit khi bay ra ktc. Nu cho 2,49 gam hn hp y vao 100ml dung dich NaOH thi phan ng xay ra va u. a. Vit cac phng trinh xay ra. b. Tinh % theo khi lng hn hp u Cu 4: a. Dung 100g qung pyrit cha 72%FeS2 iu ch H2SO4. Cho toan b axit thu c tac dung vi Cu iu ch CuSO4.5H2O. Tinh khi lng CuSO4.5H2O thu c, bit hiu sut cua ca qua trinh la 80%.
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khuongduy_1088 098 363 1982 b. tr nm thc vt, ngi ta dung dung dich CuSO4 0,8%. Tinh khi lng dung dich CuSO4 0,8% pha ch c t lng CuSO4.5H2O cu a.