S GIO DC V O TO NAM NH THI TH I HC LN II NM 2011 TRNG THPT L HNG PHONG Mn thi: HO HC ( Thi gian lm bi: 90 pht, khng k thi

i gian pht .) I. PHN CHUNG CHO TT C TH SINH (40 cu t cu 1 n cu 40) Cu 1: Chia m gam hn hp M gm hai ancol n chc k tip trong dy ng ng thnh 2 phn bng nhau. Cho phn mt tc dng vi Na (d), c 3,36 lt kh hiro (ktc). Cho phn hai phn ng hon ton vi CuO nhit cao, c hn hp M1 cha hai anehit (ancol ch bin thnh anehit). Ton b lng M1 phn ng ht vi AgNO3 trong NH3, thu c 86,4 gam Ag. Gi tr ca m l A. 24,8 gam B. 30,4 gam C. 15,2 gam D. 45,6 gam Cu 2: Chia 156,8 gam hn hp L gm FeO, Fe3O4, Fe2O3 thnh hai phn bng nhau. Cho phn th nht tc dng ht vi dung dch HCl d c 155,4 gam mui khan. Phn th hai tc dng va vi dung dch M l hn hp HCl, H2SO4 long thu c 167,9 gam mui khan. S mol ca HCl trong dung dch M l A. 1,75 mol B. 1,50 mol C. 1,80 mol D. 1,00 mol Cu 3: Hn hp bt X gm BaCO3, Fe(OH)2, Al(OH)3, CuO, MgCO3. Nung X trong khng kh n khi lng khng i c hn hp rn A1. Cho A1 vo nc d khuy u c dung dch B cha 2 cht tan v phn khng tan C1. Cho kh CO d qua bnh cha C1 nung nng c hn hp rn E (Cho cc phn ng xy ra hon ton). E cha ti a: A. 1 n cht v 2 hp cht. B. 3 n cht. C. 2 n cht v 2 hp cht. D. 2 n cht v 1 hp cht. Cu 4: Cho a gam Na vo 160 ml dung dch gm Fe2(SO4)3 0,125M v Al2(SO4)3 0,25M. Tch kt ta ri nung n khi lng khng i th thu c 5,24 gam cht rn. Gi tr a no sau y l ph hp? A. 9,43. B. 11,5. C. 9,2. D. 10,35. Cu 5: Cho hn hp Na, Al, Fe, FeCO3, Fe3O4 tc dng vi dung dch NaOH d, lc ly kt ta ri chia lm 2 phn. Phn 1 em tc dng vi dung dch HNO3 long d. Phn 2 em tc dng vi dung dch HCl d. S phn ng oxi ha kh xy ra l: A. 5. B. 6. C. 8. D. 7. Y Z. Cho cc cht sau y: etilen, etyl clorua, ancol etylic. S s nhiu Cu 6: Cho s dng: X nht th hin mi quan h gia cc cht trn l A. 3 B. 4 C. 5 D. 6 Cu 7: Cho cc cht sau: propyl clorua, anlyl clorua, phenyl clorua, natri phenolat, anilin, mui natri ca axit amino axetic, ancol benzylic. S cht tc dng c vi dung dch NaOH long khi un nng l A. 3. B. 4. C. 2. D. 1. Cu 8: Mt hn hp X gm Na, Al v Fe (vi t l mol Na v Al tng ng l 5:4) tc dng vi H 2O d th thu c V lt kh, dung dch Y v cht rn Z. Cho Z tc dng vi dung dch H2SO4 long d th thu c 0,25V lt kh (cc kh o cng iu kin). Thnh phn % theo khi lng ca Fe trong hn hp X l A. 14,4% B. 33,43% C. 20,07% D. 34,8%. Cu 9: Oxi ho 25,6 gam CH3OH (c xc tc) thu c hn hp sn phm X. Chia X thnh hai phn bng nhau Phn 1 tc dng vi AgNO3 d trong NH3 un nng thu c m gam Ag. Phn 2 tc dng va vi 100ml dung dch KOH 1M. Hiu sut qu trnh oxi ho CH3OH l 75%. Gi tr ca m l A. 64,8. B. 32,4. C. 129,6. D. 108. Cu 10: t chy 0,2 mol hp cht A thuc loi tp chc thu c 26,4 gam kh CO2, 12,6 gam hi H2O, 2,24 lt kh nit (ktc) v lng O2 cn dng l 0,75 mol. S ng phn ca A tc dng c vi dung dch NaOH v HCl l A. 2. B. 4. C. 3. D. 5. Cu 11: S ng phn l hp cht thm c cng thc phn t C8H10O tc dng c vi NaOH l A. 9. B. 6. C. 7. D. 8. ; (II) Fe3O4 + H2SO4 (c) ; Cu 12: Cho cc phn ng: (I) Fe + HCl (III)KMnO4 + HCl ; (IV) FeS2 + H2SO4 (long) ; (IV) Al + H2SO4 (long) ; S phn ng m H+ ng vai tr l cht oxi ho l: A. 3 B. 2 C. 4 D. 1 1

Cu 13: Hn hp X c C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m gam hn hp X thu c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X thc hin phn ng trng bc thy c p gam Ag kt ta. Gi tr ca p l A. 9,72. B. 8,64. C. 10,8. D. 2,16. Cu 14: Cc nhn nh sau: 1)Axit hu c l axit axetic. 2)Gim n l dung dch axit axetic c nng t 2% 5%. 3)Khi cho 1 mol axit hu c (X) tc dng vi Na d, s mol H 2 sinh ra bng s mol X v khi t chy axit X th thu c n(H2O) : nCO2 =1. Vy X l axit no n chc no. 4)Khi t chy hirocacbon no th ta c n(H2O) : nCO2 >1. Cc nhn nh sai l: A. 1, 2, 3, 4. B. 2, 3, 4. C. 1, 2, 3. D. 1, 3, 4. Cu 15: Cho s phn ng sau X + H2SO4 (c, nng) Fe2(SO4)3 + SO2 + H2O S cht X c th thc hin phn ng trn l A. 4. B. 6. C. 5. D. 7. Cu 16: C 4 dung dch long ca cc mui: BaCl2, ZnCl2, FeCl2, FeCl3. Khi sc kh H2S d vo cc dung dch mui trn th s trng hp c phn ng to kt ta l A. 3. B. 2. C. 1. D. 4. Cu 17: Cho V lt hn hp kh A gm clo v oxi tc dng va ht vi hn hp B gm 0,2 mol Al v 0,1 mol Mg th thu c 25,2 gam hn hp mui clorua v oxit ca 2 kim loi. S mol ca Cl2 c trong V lt hn hp kh A l A. 0,15. B. 0,3. C. 0,2. D. 0,25. Cu 18: Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng, d. S phn ng thuc loi phn ng oxi ha kh l A. 7 B. 8 C. 10 D. 9 Cu 19: Cho bt Fe vo dung dch NaNO3 v H2SO4. n phn ng hon thu c dung dch A, hn hp kh X gm NO v H2 c v cht rn khng tan. Bit dung dch A khng cha mui amoni. Trong dung dch A cha cc mui: A. FeSO4, Fe(NO3)2, Na2SO4, NaNO3. B. FeSO4, Fe2(SO4)3, NaNO3, Na2SO4. C. FeSO4, Na2SO4. D. FeSO4, Fe(NO3)2, Na2SO4. Cu 20: Hn hp X c 2 hirocacbon ng ng lin tip, c t khi hi so vi H2 bng 15,8. Ly 6,32 gam X li vo 200 gam dung dch cha xc tc thch hp th thu c dung dch Z v thy thot ra 2,688 lt kh kh Y iu kin tiu chun c t khi hi so vi H2 bng 16,5. Bit rng dung dch Z cha anehit vi nng C%. Gi tr ca C% l: A. 1,305% B. 1,407% C. 1,043% D. 1,208% Cu 21: C cc nhn nh sau y: 1)Nguyn tc sn xut gang l kh st bng CO nhit cao. 2)Nguyn tc sn xut thp l kh cc tp cht trong gang. 3)Tnh cht ha hc ca Fe2+ l tnh kh. 4)Nc cng l nc c cha ion Ca2+, Mg2+ di dng mui Cl-, HCO3-, SO42-. S nhn nh ng l A. 2. B. 3. C. 0. D. 1. Cu 22: C cc nhn nh sau: 1)Cu hnh electron ca ion X2+ l 1s22s22p63s23p63d6. Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc chu k 4, nhm VIIIB. 2)Cc ion v nguyn t: Ne , Na+ , F c im chung l c cng s electron. 3)Khi t chy ancol no th ta c n(H2O) : n(CO2)>1. 4)Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l K, Mg, Si, N. 5)Tnh baz ca dy cc hiroxit: NaOH, Mg(OH)2, Al(OH)3 gim dn. Cho: N (Z = 7), F (Z=9), Ne (Z=10), Na (Z=11), Mg (Z=12), Al (Z=13), K (Z = 19), Si (Z = 14). S nhn nh ng: A. 3. B. 5. C. 4. D. 2.

Cu 23: Hn hp X gm 3 ancol n chc A, B, C trong B, C l 2 ancol ng phn. t chy hon ton 0,08 mol X thu c 3,96 gam H2O v 3,136 lt kh CO2 (ktc). S mol ancol A bng 5/3 tng s mol 2 ancol (B + C). Khi lng ca B, C trong hn hp l: A. 3,6 gam B. 0,9 gam C. 1,8 gam D. 2,22 gam Cu 24: Cho m in ca cc nguyn t nh sau: O(3,44), Cl(3,16), Mg(1,31), C(2,55), H(2,2) Trong cc phn t: MgO, CO2, CH4, Cl2O. S cht c kiu lin kt cng ha tr c cc l A. 2. B. 3. C. 1. D. 4. Cu 25: t chy hon ton 0,1 mol ancol no, mch h X cn va 5,6 lt oxi (ktc). X cng vi axit HOOCC6H4COOH l 2 monome c dng iu ch polime, lm nguyn liu sn xut t: A. Nilon-6,6. B. Lapsan. C. Capron. D. Enang Cu 26: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n khi phn ng xy ra hon ton, thu c cht rn v hn hp kh Y c thnh phn th tch: N2 = 84,77%; SO2 = 10,6% cn li l O2. Thnh phn % theo khi lng ca FeS trong X l A. 68,75% B. 59,46% C. 26,83% D. 42,3% Cu 27: Cho 32,8 gam hn hp gm axit glutamic v tyrosin (t l mol 1:1) tc dng vi 500ml dung dch NaOH 1M, phn ng hon ton thu c dung dch Y. C cn cn thn dung dch Y thu c m gam cht rn khan. Gi tr ca m l A. 49,2 B. 52,8 C. 43,8 D. 45,6 Cu 28: Cho cc cht v ion sau y: NO2 , Br2, SO2, N2, H2O2, HCl, S. S cht v ion c c tnh oxi ha v tnh kh l A. 7. B. 4. C. 6. D. 5. Cu 29: Cho qu tm vo ln lt cc dung dch: CH3COOK, FeCl3, NH4NO3, K2S, Zn(NO3)2, Na2CO3. S dung dch lm i mu giy qu l A. 4 B. 6 C. 5 D. 3 Cu 30: Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang. Nhng loi t no thuc loi t nhn to l: A. T nilon 6,6 v t capron. B. T tm v t enang. C. T visco v t nilon-6,6. D. T visco v t axetat. Cu 31: Cho phn ng sau: 2SO2(k) + O2(k) 2SO3(k) ; H < 0 cn bng trn chuyn dch theo chiu thun th: (1): tng tng nhit , (2): tng p sut, (3): h nhit , (4): dng xc tc l V2O5, (5): Gim nng SO3. Bin php ng l: A. 1, 2, 5. B. 2, 3, 5. C. 1, 2, 3, 4, 5. D. 2, 3, 4, 5. Cu 32: T etilen v benzen, cht v c v iu kin phn ng c . Tng s phn ng t nht c th iu ch c polibutaien, polistiren, poli (butaien - stiren), poli (vinyl clorua) l A. 11. B. 12. C. 9. D. 10. Cu 33: X phng ha hon ton 100gam cht bo c ch s axit bng 7 cn a gam dung dch Na0H 25%, thu c 9,43gam glyxerol v b gam mui natri. Gi tr ca a, b ln lt l: A. 49,2 v 103,37 B. 51,2 v 103,145 C. 51,2 v 103,37 D. 49,2 v 103,145 0 Cu 34: Tch s ion ca nc mt s nhit nh sau: 20 C l 7,00.10-15, 250C l 1,00.10-14, 300C l 1,50.10-14. S in ly ca nc l A. thu nhit B. ta nhit hay thu nhit ty theo iu kin phn ng C. ta nhit D. khng xc nh ta nhit hay thu nhit Cu 35: t chy hon ton mt lng hn hp hai este n chc no, mch h cn 3,976 lt oxi (ktc) thu c 6,38 gam CO2. Cho lng este ny tc dng va vi KOH thu c hn hp hai ancol k tip v 3,92 gam mui ca mt axit hu c. Cng thc ca hai cht hu c trong hn hp u l: A. HCOOC3H7 v HCOOC2H5 B. CH3COOCH3 v CH3COOC2H5 C. C2H5COOC2H5 v C2H5COOCH3 D. CH3COOC2H5 v CH3COOC3H7 Cu 36: Xt cc cht: imetylete (1), ancol metylic (2), ancol etylic (3), axit axetic (4), axeton (5). Cc cht trn c xp theo nhit si tng dn (t tri sang phi) l: A. 1, 5, 2, 3, 4 B. 2, 3, 4, 5, 1 C. 5, 1, 2, 3, 4 D. 1, 2, 3, 4, 5 3

Cu 37: Cho lung kh CO d i qua hn hp BaO, Al 2O3 v FeO t nng thu c cht rn X1. Ho tan cht rn X1 vo nc thu c dung dch Y1 v cht rn E1. Sc kh CO2 d vo dung dch Y1 thu c kt ta F1. Ho tan E1 vo dung dch NaOH d thy b tan mt phn v cn cht rn G1. Cho G1 vo dung dch AgNO3 d (Coi CO2 khng phn ng vi nc). Tng s phn ng xy ra l A. 7. B. 8. C. 6. D. 9. Cu 38: Cho 25,65 gam mui gm H2NCH2COONa v H2NCH2CH2COONa tc dng va vi 250 ml dung dch H2SO41M. Sau phn ng c cn dung dch th khi lng mui do H2NCH2COONa to thnh l: A. 29,25 gam B. 18,6 gam C. 37,9 gam D. 12,4 gam Cu 39: Nung m gam hn hp X gm KClO3 v KMnO4 thu c cht rn Y v O2. Bit KClO3 phn hy hon ton, cn KMnO4 ch b phn hy mt phn. Trong Y c 0,894 gam KCl chim 8,132% theo khi lng. Trn lng O2 trn vi khng kh theo t l th tch VO2 : VKK =1:3 trong mt bnh kn ta thu c hn hp kh Z. Cho vo bnh 0,528 gam cacbon ri t chy ht cacbon, phn ng hon ton, thu c hn hp kh T gm 3 kh O2, N2, CO2, trong CO2 chim 22,92% th tch. Gi tr m (gam) l A. 12,59 B. 12,53 C. 12,70 D. 12,91 Cu 40: Cht hu c X mch h, khng cha lin kt (-O-O-) v c cng thc phn t l C3H6On. Bit X ch cha mt loi nhm chc. S ng phn cu to c th c ca X l A. 4. B. 6. C. 7. D. 5. II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A.Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Dng mt lng dung dch H2SO4 nng 20%, un nng ha tan va a mol CuO. Sau phn ng lm ngui dung dch n 1000C th khi lng tinh th CuSO4.5H2O tch ra khi dung dch l 30,7 gam. Bit rng tan ca dung dch CuSO4 1000C l 17,4 gam. Gi tr ca a l A. 0,1. B. 0,15. C. 0,2. D. 0,25. Cu 42: C dung dch X gm (KI v mt t h tinh bt). Cho ln lt tng cht sau: O3, Cl2, H2O2, FeCl3, AgNO3 tc dng vi dung dch X. S cht lm dung dch X chuyn sang mu xanh l A. 4 cht B. 5 cht C. 3 cht D. 2 cht Cu 43: Ha tan hon ton 3,76 gam hn hp: S, FeS, FeS 2 trong HNO3 d c 0,48 mol NO2 v dung dch X. Cho dung dch Ba(OH)2 d vo X, lc kt ta nung n khi lng khng i th khi lng cht rn thu c l: A. 17,545 gam B. 18,355 gam C. 15,145 gam D. 2,4 gam Cu 44: Ngi ta c th iu ch cao su Buna t g theo s sau: TH Xenluloz 35% glucoz 80% C2H5OH 60% Buta-1,3-ien Cao su Buna Khi lng xenluloz cn sn xut 1 tn cao su Buna l A. 25,625 tn. B. 37,875 tn. C. 5,806 tn. D. 17,857 tn. Cu 45: Hn hp A gm 0,1 mol anehit metacrylic v 0,3 mol kh hiro. Nung nng hn hp A mt thi gian, c mt cht xc tc Ni, thu c hn hp hi B gm hn hp cc ancol, cc anehit v hiro. T khi hi ca B so vi He bng 95/12. Hiu sut ca phn ng hiro ha anehit metacrylic l: A. 100% B. 70% C. 65% D. 80% Cu 46: Cho 6,0 gam Mg tc dng ht vi dung dch HCl 18,25% (va ). Sau phn ng thu c dung dch mui A v hiro that ra. Bit phn ng xy ra hon ton. Vy nng phn trm ca dung dch mui s l: A. 22,41% B. 22,51% C. 42,79% D. 42,41% Cu 47: C 5 kh ng ring bit trong 5 l l Cl 2, O2, HCl, O3, SO2. Hy chn trnh t tin hnh no trong cc trnh t sau phn bit cc kh: A. Qu tm m, dung dch KI/h tinh bt, Cu un nng. B. Dung dch AgNO3, dung dch KI/h tinh bt, dng u que m cn tn . C. Nhn bit mu ca kh, dung dch AgNO3, dung dch KI, dng u que m cn tn . D. Dung dch H2S, dung dch AgNO3, dung dch KI. Cu 48: T butan, cht v c v iu kin phn ng c . S phng trnh phn ng ti thiu iu ch glixerol l A. 5. B. 4. C. 7. D. 6. Cu 49: Tm pht biu sai trong cc pht biu sau : 4

A. Nhit si ca ankanol cao hn so vi ankanal c phn t khi tng ng. B. Phenol l cht rn kt tinh iu kin thng. C. Metylamin l cht lng c mi khai, tng t nh amoniac. D. Etylamin d tan trong H2O. Cu 50: Cho cc cht sau: C2H5OH, C6H5OH, C6H5NH2, dung dch C6H5ONa, dung dch NaOH, dung dch CH3COOH, dung dch HCl. Cho tng cp cht tc dng vi nhau c xc tc, s cp cht c phn ng xy ra l A. 12 B. 8 C. 9 D. 10 B.Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho NH3 d vo ln lt cc dung dch sau: CrCl3, CuCl2, ZnCl2, AgNO3, NiCl2. S trng hp kt ta hnh thnh b tan l A. 4. B. 3. C. 1. D. 5. Cu 52: Mt bnh kn dung tch 1 lt cha 1,5 mol H2 v 1,0 mol N2 (c xc tc v nhit thch hp). trng thi cn bng c 0,2 mol NH3 to thnh. Mun hiu sut t 25 % cn phi thm vo bnh bao nhiu mol N2? A. 1,5 B. 2,25 C. 0,83 D. 1,71 Cu 53: Cho 12gam hn hp Fe v Cu vo 200ml dung dch HNO 3 2M, thu c mt cht kh (sn phm kh duy nht) khng mu, ha nu trong khng kh, v c mt kim loi d. Sau cho thm dung dch H 2SO4 2M, thy cht kh trn tip tc thot ra, ho tan ht kim loi cn 33,33ml. Khi lng kim loi Fe trong hn hp l A. 8,4 gam B. 5,6 gam C. 2,8 gam D. 1,4 gam Cu 54: Thy phn hon ton mt lng mantoz, sau cho ton b lng glucoz thu c ln men thnh ancol etylic th thu c 100 ml ru 460. Khi lng ring ca ancol l 0,8gam/ml. Hp th ton b kh CO2 vo dung dch NaOH d thu c mui c khi lng l: A. 84,8 gam. B. 42,4 gam. C. 212 gam. D. 169,6 gam. Cu 55: Cho cc cht sau y: 1)CH3COOH, 2)C2H5OH, 3)C2H2, 4)CH3COONa, 5)HCOOCH=CH2, 6)CH3COONH4. Dy gm cc cht no sau y u c to ra t CH 3CHO bng mt phng trnh phn ng l: A. 1, 2, 3, 4, 5, 6. B. 1, 2, 6. C. 1, 2. D. 1, 2, 4, 6. Cu 56: Cho bit th in cc chun ca cc cp oxi ho kh: 2H+/H 2; Zn2+/Zn; Cu2+/Cu; Ag+/Ag ln lt l 0,00V; -0,76V; +0,34V; +0,80V. Sut in ng ca pin in ho no sau y ln nht? A. Cu + 2Ag+ Cu2+ + 2Ag. B. 2Ag + 2H+ 2Ag+ + H2. C. Zn + Cu2+ Zn2+ + Cu. D. Zn + 2H+ Zn2+ + H2. Cu 57: Cc kh thi cng nghip v ca cc ng c t, xe my...l nguyn nhn ch yu gy ra ma axit. Nhng thnh phn ha hc ch yu trong cc kh thi trc tip gy ra ma axit l: A. SO2, CO, NO. B. SO2, CO, NO2. C. NO, NO2, SO2. D. NO2, CO2, CO. Cu 58: Cho isopren tc dng Br2 theo t l mol 1:1 thu c ti a x dn xut mono brom. un nng ancol bc 2 C5H12O vi H2SO4 c 1800C thu c ti a y sn phm hu c. Mi lin h gia x, y l : A. x - y = 1 B. x = y C. y - x = 1 D. y - x = 2 Cu 59: Cho cc cht sau: axit glutamic; valin, lysin, alanin, trimetylamin, anilin. S cht lm qu tm chuyn mu hng, mu xanh, khng i mu ln lt l A. 2, 1,3. B. 1, 2, 3. C. 3, 1, 2. D. 1, 1, 4. Cu 60: Cho s phn ng sau :

Cng thc cu to ca Y l A. CH2=C(CH3)-COOC6H5. C. C6H5COOCH=CH2.

B. CH2=CH-COOC6H5. D. CH2=C(CH3)-COOCH2-C6H5. HT