S Gio dc v o to

Hi Dng
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CHNH THC

K THI CHN HC SINH GII TNH HI DNG

Lp 12 THPT nm hc 2010 2011
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Mn thi : Ha hc
Thi gian lm bi: 180 pht
( thi gm 02 trang)

Cu 1: (2 im)

1. Cho cc l mt nhn ng cc dung dch sau: MgCl2, FeCl3, ZnSO4, AlCl3, CuCl2, FeCl2.
Chn mt thuc th, hy trnh by phng php phn bit cc dung dch trn.

2. Trn 3 dung dch axit HCl 0,2M; HNO3 0,1M v H2SO4 0,15M vi th tch bng nhau thu
c dung dch A. Cho V ml dung dch B (cha NaOH 0,2 M v Ba(OH)2 0,05M) vo
400 ml dung dch A thu c (V + 400) ml dung dch D (c pH = 13) v m gam kt ta.
Tnh V, m?
3. Hon thnh cc phng trnh phn ng:

a. CaOCl2 + HCl
b. NO2 + KOH

c. KMnO4 + HCl
d. H2S + FeCl3

e. FeSO4 + KMnO4 + H2SO4

Cu 2: (2 im)

1. Hp cht A c cng thc phn t C2H8N2O3. Cho 2,16 gam A tc dng vi dng vi dung
dch NaOH un nng (va ) c dung dch B v kh D c mi c trng.
Vit cng thc cu to c th c ca A v tnh khi lng mui c trong B.
2. Sp xp cc cht sau theo chiu tng dn tnh axit (c gii thch):
CH3COOH, C6H5OH, C6H5CH2OH, ClCH2COOH, C2H5OH, p-CH3C6H4OH.

3. Vit cc phng trnh phn ng (ghi r iu kin) iu ch cao su Buna (poli buta-1,3-dien) t
metan v t tinh bt (cc cht v c, cc iu kin c ).
Cu 3: (2 im)

1. Cho 360 ml dung dch NaOH 1M vo 500 ml dung dch AlCl3 aM, thu c 3m gam kt
ta. Mt khc, cho 480 ml dung dch NaOH 1M vo 500 ml dung dch AlCl3 aM thu c
2m gam kt ta. Tnh a?

2. A v B l cc hp cht hu c mch h cha C, H, O u c khi lng phn t l 58

.v.C. Cho 8,7 gam hn hp X (gm A v B) tc dng vi dung dch AgNO 3 d trong
NH3 thu c 45,36 gam kt ta.
Xc nh cng thc cu to c th c ca A, B v tnh phn trm khi lng mi cht trong X.

Cu 4: (2 im)
Cho m gam hn hp X (gm Fe3O4 v Cu) vo 500 ml dung dch HNO3 aM c dung
dch Y; 4,48 lt (ktc) hn hp kh Z (gm NO v NO2, dZ/H = 19) v 6 gam mt kim loi khng
2

tan.
Cho dung dch NaOH d vo dung dch Y, lc tch kt ta v nung trong khng kh n
khi lng khng i c 80 gam cht rn T. Bit cc phn ng xy ra hon ton.
a. Vit cc phng trnh phn ng.

b. Tnh a v phn trm khi lng cc cht trong X.

Cu 5: (2 im)
Cho m gam hn hp A gm hai cht hu c (X v Y, MX < My) tc dng va vi 150
ml dung dch NaOH 1M thu c dung dch cha hn hp mui (R1COONa v R2COONa) v
ancol ROH (trong R1, R2, R l cc gc hidrocacbon, tng s cacbon trong R1 v R bng s
cacbon trong R2). Cho ancol thu c tc dng vi Na d thu c 1,68 lit H2 (ktc).
t chy hon ton 5,42 gam A trong oxi d ri dn sn phm chy ln lt qua bnh 1
ng P2O5, bnh 2 ng dung dch Ca(OH)2 d, thy khi lng bnh 1 tng 4,14 gam; bnh 2 c
28 gam kt ta. Mt khc, cho 10,84 gam A tc dng vi lng KOH va thu c 10,64
gam hn hp mui.
a. Tm cng thc cu to ca ROH

b. Xc nh CTCT c th c ca X, Y v phn trm khi lng ca chng trong A.

****
Cho nguyn t khi cc nguyn t: H = 1, C = 12, N = 14, O = 16, Na = 23, K = 39;
Mg = 24, Al = 27, Ca = 40, Fe = 56, Cu = 64, Ag = 108.
---------------------------------------------- Ht --------------------------------------------H v tn th sinh:S bo danh:.
Ch k gim th s 1:.Ch k gim th s 2:.