K THI CHN HC SINH GII LN TH NHT NM HC 2008-2009 MN: HO 11 Cu I: 1.

Ho tan 2,09 gam mt Na c ln Na2O vo nc v pha long thnh mt lt th pH ca dung dch thu c (dd X) bng 13,08. Tnh % v khi lng ca Na2O trong mu Na? Tnh th tch dung dch HCl 0,1 M cn thm vo 200ml dung dch X c dung dch c pH = 2. 2/ Thu phn hon ton 4,17 gam halogenua ca photpho ngi ta thu c hn hp 2 axit (axit ca photpho vi s oxi ho tng ng v axit khng cha oxi ca halogen). trung ho hon ton hn hp ny cn dng 32 gam dung dch NaOH 20%. Xc nh cng thc ca halogen . Cu II: 1/ Cho mt lung khng kh cha hi H2O, H2S, CO2 i t t qua ln lt cc dung dch CuSO4 d, dung dch NaOH c, dung dch H2SO4 c nhn c hn hp kh A. Cho kh A tip xc vi v bo Mg 600C nhn c hn hp rn B. Cho B vo nc th c sn phm g to ra? Vit phng trnh ho hc ca phn ng xy ra. 2/ Cho 6,08 gan hn hp Cu v CuO c t l tng ng l 1:3 vo 500 ml dung dch HNO 3 0,32 M thot ra V1 lt kh NO2, thm tip 760 ml dung dch HCl 4/3M vo th li thot ra thm V2 lt kh NO na. Tip tc thm 24 gam Mg th thy thot ra V3 lt kh hn hp kh N2 v H2, lc dung dch cui cng thu c cht rn X. a/ Vit phng trnh phn ng v tnh V1, V2, V3 (ktc), gi thit cc phn ng xy ra hon ton. b/ Tnh thnh phn ca X. CuIII: 1/ Khi cracking hon ton mt th tch ankan X thu c 4 th tch hn hp kh Y (cc th tch kh o cng iu kin nhit v p sut); T khi hi ca Y so vi H2 bng 12,5. Tm cng thc phn t ca X? X tc dng vi Cl2 c chiu sng to ra 3 loi dn xut monocle, cho bit cng thc cu to thu gn nht ph hp ca X, gi tn. 2/t chy hon ton 3,78 gam mt hp cht hu c X th ch thu c 11,88 gam CO2 v 4,86 gam H2O. X tc dng vi HBr th ch thu c 1 sn phm duy nht l Y trong phn t c cha 43,64% cacbon v khi lng.Xc nh cng thc cu to thu gn nht, tn gi ca X,Y. Cu IV: 1/Mt bnh kn dung tch khng i cha hn hp kh A gn O2 v mt hirocacbon X (l cht kh iu kin tiu chun), trong ) O2 chim 90% th tch ca A, 0C th p sut trong bnh l 4/3 atm. Bt tia la in X chy hon ton, lm lnh bnh v 0C th p sut trong bnh cn 1atm. a/Xc nh cng thc phn t ca X, bit khi lng kh O2 phn ng ln hn lng kh O2 d. b/Xc nh cng thc cu to v gi tn ca X, bit X mch h v tt c cc nguyn t cacbon trong phn t u c cng trng thi lai ho. c/un nng X vi xc tc thch hp th thu c polime v mt sn phm ph Y. Hiro ho hon ton Y th c etylxiclohexan. Xc nh cng thc cu to ca Y v vit phng trnh ho hc ca cc phn ng xy ra. 2/Hirocacbon mch h A c cha 5,88 hiro vkhi lng, MA<120. Khi thay th ht cc nguyn t H linh ng trong phn t A bng nhng nguyn t kim loi M thu c mui B c cha 76,6% kim loi. Bit rng M trong mui B c s oxi ho l +1. Xc nh M, cng thc cu to ca A v B, bit phn t A c tnh i xng.

TRNG THPT CHUYN NGUYN HU K THI CHN HC SINH GII LN TH 2 NM HC: 2008-2009 MN : HO HC Thi gian lm bi: 90 pht( khng k thi gian giao ) THI CHNH THC Cu I. 1. Dung dch A cha FeCl3, AlCl3, NH4Cl, CuCl2 (nng mi cht xp x 0,1M) a. Dung dch A c mi trng g? Gii thch? b. Dn kh H2S li qua dung dch A n bo ho thu c dung dch B, kt ta C. Cho bit thnh phn ca cc cht trong B, C. c. Thm dn dung dch NH3 vo dung dch A cho n d c hin tng g xy ra. Vit cc phng trnh phn ng gii thch. 2. Ch dung mt kim loi, hy nhn bit cc dung dch sau: NH4NO3, (NH4)2SO4, NaNO3,AlCl3, MgCl2, FeCl3. Cu II. 1. Khi cho propilen vo dung dch axit HBr c ho tan NaCl, CH3OH c th to ra nhng cht g? Vit PTP? 2. Vit cng thc cu to ca sn phm chnh sinh ra trong mi phn ng di y: a. CH3CH2CH = CHCH3 + HBr ----->(xt: H2O) b. CH3CH2CH = CH2 + HBr (kh) ----->(xt:O2) c. CH2=CH-CH2-CCH + Br2 ----->(xt: CCl4(1:1)) d. CH2=CH-CH2-CCH + H2 -----> (xt: Pd(1:1),t) e. CH3-CH=CH2 + ClI -----> f. CH3-CH=CH2 + Cl2 -----> Cu III. 1. Mt nguyn t X c trong thnh phn ca hp cht v c A v B. Hai cht A, B lm i mu giy qu m khc nhau. Cht A c th chy trong sn phm ca hp cht B to nn t mt trong cc sn phm l n cht X. Sn phm to nn kh A kt hp vi B th iu kin thng,nhng khi un nng mnh sn phm th to n cht X, n cht Y v H2O. Khi t chy A trong Y cng thu c cht X. Nu t cht A c xc tc th sn phm thu c c cng thc XY. Khi d cht Y th thu c hn hp,hn hp ny to nn khi B ho tan trong nc. Xc nh A,B, X, Y. Vit cc phn ng ho hc xy ra. 2. Cho hn hp A gn 0,15 mol Mg v 0,35 mol Fe phn ng vi V lt dung dch HNO3 1M thu c dung dch B v 3,36 lt hn hop C gm 2 kh khong mu ho nu ngoi khng kh c t khi so vi H2 l 17,333 v cn li 2,8g kim loi. Xc nh th tch mi kh trong C v V lt dung dch HNO3 dung. (bit cc kh u o ktc)

Cu IV. Tin hnh 2 phn ng, trng hp Stiren C6H5CH=CH2 (phn ng 1) v trng hp Stiren vi Buta-1,3-ien thnh caosu Buna-S (phn ng 2). Sau phn ng (1) ly ton b hn hp thu c cho vo 100ml dung dch brom 0,15M, thm KI d vo thy to ra iot t do, lng iot ny tc dng va vi 40ml dung dch Na2S2O3 0,125M (cho Na2S4O6). Trong phn ng trng hp Stiren vi Buta-1,3-ien c to ra mt sn phm ph A do phn ng gia mt phn t

Stiren v mt phn t Buta-1,3-ien. A l cht lng c th cng mt phn t brom, mt khc 1 mol A c th cng 4 mol H2 (Ni,t) sinh ra sn phm ixiclohexyl C6H11-C6H11 1. Vit cc phng trnh phn ng trng hp. 2. Tnh lng Stiren khng tham gia phn ng (1). 3. Xc nh CTPT, CTCT ca A v phn ng to thnh A