S GIO DC V O TO NGH AN

TRNG THPT NG HIU

THI TH TUYN SINH I HC NM 2012

MN HA HC; Khi A,B

Thi gian lm bi: 90 pht, khng k thi gian pht
M thi 109

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit nguyn t khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn =
55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108.

I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)

Cu 1: X l mt tripeptit c to thnh t 1 aminoaxit no, mch h c 1 nhm -COOH v 1 nhm -NH2 .t
chy hon ton 0,3 mol X cn 2,025 mol O2 thu c sn phm gm CO2 ,H2O , N2. Vy cng thc ca amino
axit to nn X l
A. H2NC2H4COOH
B. H2NC3H6COOH
C. H2N-COOH
D. H2NCH2COOH
Cu 2: Nhm m tt c cc cht u tc dng vi dung dch AgNO3/NH3 l
A. C2H2, C2H5OH, glucoz, HCOOH.
B. C3H5(OH)3, glucoz, CH3CHO, C2H2.
C. C2H2, C2H4, C2H6, HCHO.
D. Glucoz, C2H2, C2H5CHO, HCOOH.
Cu 3: Hp cht hu c X c cng thc phn t C4H6O2. Bit t X c th iu ch cao su buna theo s : X
+ H2
H2O
Tr ng h p

Y
C
Cao su buna. S cng thc cu to c th c ca X l?
Ni,to
xt,to
A. 4
B. 3
C. 1
D. 2
Cu 4: Cho 0,2 mol mt anehit n chc, mch h X phn ng va vi 300 ml dung dch cha AgNO3
2M trong NH3. Sau khi phn ng xy ra hon ton thu c 87,2 g kt ta. Cng thc phn t ca anehit l
A. C4H3CHO
B. C4H5CHO
C. C3H3CHO
D. C3H5CHO
Cu 5: t chy hon ton 29,6 gam hn hp X gm CH3COOH,CxHyCOOH,v (COOH)2 thu c 14,4 gam
H2O v m gam CO2. Mt khc, 29,6 gam hn hp X phn ng hon ton vi NaHCO3 d thu c 11,2 lt
(ktc) kh CO2.Tnh m: A. 33 gam
B. 48,4 gam C. 44g
D. 52,8 g
Cu 6: Cho 150 ml dung dch Ba(OH)2 1M vo 250 ml dung dch Al2(SO4)3 x(M) thu c 42,75 gam kt ta.
Thm tip 200 ml dung dch Ba(OH)2 1M vo hn hp phn ng th lng kt ta thu c l 94,2375 gam.
Gi tr ca x l A. 0,45 B. 0,3
C. 0,15
D. 0,25
Cu 7: Mt vt bng gang trong khng kh m, vt s b n mn in ho hc. Qu trnh xy ra cc
dng l
A. 2H2O + O2 + 4e 4OH-. B. Fe2+ +2e Fe. C. Fe Fe2++2e. D. C C2+ +2e.
Cu 8: Dung dch X cha 0,1 mol Cl-, 0,2 mol SO42-, 0,2 mol Na+, x mol H+. Dung dch Y cha 0,5 mol K+,
0,2 mol NO3-, 0,1 mol Ba2+, y mol OH-. Trn 2 dung dch X v Y thu c 2 lt dung dch Z, pH ca dung dch
Z l: A. 12
B. 13
C. 11
D. 1
Cu 9: C 3 dung dch hn hp X (NaHCO3 v Na2CO3); Y (NaHCO3 v Na2SO4); Z (Na2CO3 v Na2SO4). Ch
dng thm 2 dung dch no di y nhn bit c 3 dung dch trn?
A. NaOH v NaCl. B. HNO3 v Ba(NO3)2. C. NH3 v NH4Cl. D. HCl v NaCl.
Cu 10: Cp cht no sau y khng phi l ng phn ca nhau?
A. Saccaroz v mantoz.
B. Vinylaxetat v metylacrylat
C. Glucoz v fructoz
D. Tinh bt v xenluloz
Cu 11: Cho cc dd sau: CH3COOH, C2H4(OH)2, C3H5(OH)3, glucoz, saccaroz, C2H5OH. S lng dd c
th ho tan c Cu(OH)2 l: A. 4.
B. 5.
C. 6.
D. 3.
Cu 12: Cho cc kh sau: CO2, H2S, O2, NH3, Cl2, HI, SO3, HCl. S cht khng dng H2SO4 c lm kh
c l?
A. 2
B. 4
C. 3
D. 5
Cu 13: Cho 14,2 gam P2O5 vo 500 ml dung dch NaOH 1M. Dung dch thu c cha cht tan no?
A. Na2HPO4, NaH2PO4 B. NaOH, Na3PO4 C. Na3PO4, Na2HPO4 D. Na2HPO4, H3PO4
Trang 1/7 - M thi 109

Cu 14: Hn hp X gm 1 hirocacbon th kh v H2 c t khi so vi H2 bng 4,8. Cho X i qua Ni nung

nng n khi phn ng xy ra hon ton thu c hn Y c t khi so vi CH4 bng 1. Cng thc phn t ca
hirocacbon trong hn hp X l? A. C3H4 B. C2H2 C. C2H4
D. C3H6
Cu 15: Ho tan 6,0 gam hn hp X gm Mg, Al, Zn trong dung dch HNO3 va , sau phn ng hon ton
thu c dung dch Y v hn hp gm 0,02 mol NO v 0,02 mol N2O. Lm bay hi dung dch Y thu c
25,4 gam mui khan. S mol HNO3 b kh trong phn ng trn l:
A. 0,08 mol
B. 0,06 mol
C. 0.09 mol
D. 0,07 mol
Cu 16: Trong cc phn t sau: CO2, SO2, H2SO4 , HNO3 , s phn t c cng thc cu to biu din theo quy
tc bt t c c lin kt n, i, v lin kt cho nhn l: A. 2 B. 3
C. 4
D. 1
Cu 17: Dung dch NaHCO3 ln tp cht l Na2CO3. thu c NaHCO3 tinh khit ngi ta lm nh sau:
A. Cho tc dng vi dung dch HCl ri c cn
B. Sc kh CO2 d vo ri c cn dung dch p sut thp.
C. Cho tc dng vi CaCl2 ri c cn
D. Sc kh SO2 d vo ri c cn dung dch p sut thp.
Cu 18: Trong cc dung dch sau: BaCl2, Br2, KMnO4, H2S , Ca(OH)2, s dung dch c th dng phn bit 2
kh CO2 v SO2 l: A. 1
B. 2
C. 5
D. 3
Cu 19: Cho 0,4 mol hn hp X gm 2 ancol no, n chc, bc 1, l ng ng k tip un nng vi H2SO4
c 140oC thu c 7,704 gam hn hp 3 ete. Tham gia phn ng ete ho c 50% lng ancol c khi
lng phn t nh v 40% lng ancol c khi lng phn t ln. Tn gi ca 2 ancol trong X l
A. propan-1-ol v butan-1-ol.
B. etanol v propan-1-ol.
C. pentan-1-ol v butan-1-ol.
D. metanol v etanol.
Cu 20: Ha tan hon ton 4g hn hp MCO3 v MCO3 vo dung dch HCl thy thot ra V lt kh ktc.
Dung dch thu c em c cn c 5,1g mui khan. Gi tr ca V l:
A. 1,68
B. 3,36
C. 1,12
D. 2,24
Cu 21: Mt hp cht c cng thc MX. Tng s cc ht trong hp cht l 84, trong s ht mang in
nhiu hn s ht khng mang in l 28. Nguyn t khi ca X ln hn ca M l 8. Tng s cc ht trong X 2nhiu hn trong M2+ l 16. Cng thc MX l: A. MgO B. MgS
C. CaO
D. CaS
Cu 22: Cho cc qu trnh ho hc sau:
- Nung hn hp KClO3 v MnO2 c kh X.
- Cho KMnO4 tc dng vi HCl c c kh Y.
- Cho FeS tc dng vi H2SO4 long oc kh Z
- t chy ZnS c kh T.
Cho cc kh trn tc dng vi nhau tng i mt, s trng hp xy ra phn ng l:
A. 6
B. 5
C. 4
D. 7
Cu 23: H2SO4 long c th tc dng vi tt c cc cht thuc dy
A. Zn(OH)2, CaCO3, CuS, Al, Fe2O3.
B. CaCO3, Fe(NO3)3, Al(OH)3, MgO, Zn.
C. Fe3O4, BaCl2, NaCl, Al, Cu(OH)2.
D. Fe(OH)2, Fe(NO3)2 Na2CO3, Fe, CuO, NH3.
Cu 24: Cho 2,73 gam 1 kim loi tan ht trong nc thu c 1 dung dch c khi lng ln hn khi lng
nc dng l 2,66 gam . Kim loi dng l A. Li
B. Na
C. K
D. Ba
Cu 25: C 4 dung dch ring bit: a) HCl, b) CuCl2, c) FeCl3, d) HCl c ln CuCl2. Nhng vo mi dung
dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ho l : A. 1. B. 3. C. 2.
D. 0.
Cu 26: Khi x phng ha hon ton 1,26 g mt cht bo cn 45 ml dung dch KOH 0,1M. Ch s x phng
ha ca cht bo l
A. 300
B. 250
C. 150
D. 200
2+
Cu 27: Mui Fe lm mt mu dung dch KMnO4 trong mi trng axt to ra ion Fe3+. Cn ion Fe3+ tc

dng vi I to ra I2 v Fe2+ . Sp xp cc cht oxi ho Fe3+, I2 v MnO4 theo th t sau:

A. I2 > MnO4 > Fe3+. B. MnO4 > Fe3+ > I2 . C. Fe3+ > I2 > MnO4 . D. I2 < MnO4 < Fe3+.
Cu 28: Hp cht hu c X mch h c phn t khi l 56 vC. Bit khi t chy X bng oxi thu c sn
phm ch gm CO2 v H2O, X lm mt mu dung dch brom. S cng thc cu to tha mn X l:
A. 4
B. 5
C. 2
D. 3
Cu 29: tng hp 180 kg poli (metyl metacrylat) th khi lng axit tng ng cn dng l bao nhiu kg?
(Nu hiu sut ca qu trnh este ho v trng hp ln lt l 60%, 80%).
A. 456,450
B. 215,340
C. 322,500
D. 74,304
Trang 2/7 - M thi 109

Cu 30: Cho hn hp kim loi gm 8,1g Al v 6,85 g Ba tc dng vi nc d. Sau khi phn ng xy ra hon
ton khi lng cht rn cn li l A. 7,70g
B. 2,70g
C. 5,40g
D. 2,30g
Cu 31: Cho m gam dung dch HCl nng C% tc dng ht vi mt lng hn hp kim loi gm Mg v Zn
(dng d) thy khi lng H2 bay ra l 0,005m gam. Nng C% ca dung dch HCl l:
A. 18,25%
B. 1,973%
C. 20%
D. 19,73%
Cu 32: Ancol v amin no sau y cng bc?
A. (CH3)3COH v (CH3)3CNH2
B. (CH3)2CHOH v (CH3)2CHNH2.
C. (C6H5)2NH v C6H5CH2OH.
D. C6H5NHCH3 v (CH3)2CHOH.
Cu 33: Dy chuyn ha no sau y khng ng ?
o

600 C
+ Cl2 ,as
X3
A. C2H2
C6H6Cl6
Cho t tnh
o

+ Br2 , as, t C
+ NaOH,t
B. Toluen

X4
ancol benzylic
HONO2 /H2SO4
Br2 /Fe,to
C. Benzen X1
m-bromnitrobenzen
o

+ Cl2 ,450 C
+ NaOH,t
D. C3H6
X2
propan-1,2-iol
Cu 34: Cho cc cht sau: CH3COOCH2CH2Cl, ClH3N-CH2COOH, C6H5Cl (thm), HCOOC6H5 (thm),
C6H5COOCH3 (thm), HO-C6H4-CH2OH (thm), CH3CCl3. CH3COOC(Cl2)-CH3. C bao nhiu cht khi tc
dng vi NaOH c d, nhit v p sut cao cho sn phm c 2 mui? A. 6
B. 7 C. 5 D. 4
Cu 35: Ngi ta iu ch anilin bng cch nitro ho 400 gam benzen ri kh hp cht nitro sinh ra bng
hiro mi sinh. Nu hiu sut mi giai on t 75% th khi lng anilin thu c l
A. 357,69 gam.
B. 362,70 gam.
C. 268,27 gam.
D. 847,86 gam.
Cu 36: Trong cc dung dch sau: (1) saccaroz, (2) 3-monoclopropan1,2-iol (3-MCPD), (3) etilenglycol ,
(4) ipeptit, (5) axit fomic, (6) tetrapeptit, (7) propan-1,3-iol. S dung dich c th ha tan Cu(OH)2 l:
A. 6
B. 4
C. 5
D. 3
Cu 37: Vt bng st nguyn cht khi tip xc vi cht no sau y trong khng kh m th n s b n mn:
A. Cu
B. Al
C. Zn
D. Mg
Cu 38: Este sau khi thy phn trong mi trng kim (dd NaOH), thu c hn hp sn phm gm 2 cht
u tham gia phn ng trng gng l
A. HCOOCH2CH=CH2. B. CH3COOCH2CH3 C. HCOOCH=CH-CH3 D. HCOOCH2CH3
Cu 39: phn bit phenol, anilin, benzen, stiren ngi ta ln lt s dng cc thuc th l
A. qu tm, dung dch brom.
B. dung dch NaOH, dung dch brom.
C. dung dch brom, qu tm.
D. dung dch HCl, qu tm.
Cu 40: C cc nhn xt sau: 1- Cht bo thuc loi cht este. ; 2- T nilon-6,6, t nilon-6, t nilon-7 ch iu ch
bng phn ng trng ngng. ; 3- Vinyl axetat khng iu ch c trc tip t axit v ru tng ng. ; 4- Nitro
benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen. ; 5- toluen phn ng vi nc brom
d to thnh 2,4,6-tribrom clorua toluen.; Nhng cu ng l:
A. 1, 2, 3, 4.
B. 1, 3, 4.
C. 1, 2, 3, 4, 5.
D. 1, 2, 4.

PHN RING (10 cu)

Th sinh ch c lm mt trong hai phn (phn A hoc phn B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Hn hp A gm CuSO4; FeSO4; Fe2(SO4)3 c phn trm khi lng ca S l 22%. Ly 50g hn hp A
ha tan vo nc, sau thm dung dch NaOH d, kt ta thu c em nung ngoi khng kh ti khi
lng khng i. Lng oxit sinh ra em kh hon ton bng CO thu c m gam hn hp kim loi. Gi tr
ca m l: A. 17 g
B. 18 g
C. 19 g
D. 20 g
Cu 42: t chy hon ton hn hp X gm 2 este no, n chc mch h k tip nhau trong dy ng ng
thu c 3,6g H2O v V lt CO2 (ktc). Gi tr ca V l: A. 2,24
B. 3,36
C. 1,12
D. 4,48
Cu 43: S hp cht (cha C, H, O) c khi lng mol M = 60; phn ng c vi natri kim loi l
A. 3
B. 2
C. 4
D. 5
Cu 44: Cht (Y) c cng thc phn t C3H9NO2, d phn ng vi axit ln baz. Trn 1,365 gam (Y) vi
100ml dung dch NaOH 0,2M ri un nng nh, c kh thot ra lm xanh giy qu tm m v dung dch (A), c
cn dng dch (A) thu c a gam cht rn. Gi tr ca a l: A. 1,43
B. 1,66
C. 1, 25
D. 2,30
Trang 3/7 - M thi 109

Cu 45: Ln men glucoz ri cho ton b lng CO2 sinh ra hp th vo dung dch nc vi trong to thnh
10 gam kt ta. Khi lng dung dch so vi ban u gim 1,2 gam. Vi hiu sut ca qu trnh ln men l
90%, khi lng (gam) glucoz cn dng l: A. 40,0
B. 16,2
C. 80,0
D. 20,0
Cu 46: Cho Fe3O4 vo dung dch HCl va thu c dung dch X. Hy cho bit trong cc ha cht sau: Cu, Mg,
Ag, AgNO3, Na2CO3, NaHCO3, NaOH, NH3, c bao nhiu ha cht tc dng c vi dung dch X.
A. 5
B. 6
C. 7
D. 8
Cu 47: Ho tan m gam Na vo dung dch cha 0,1 mol Ca(OH)2 thu c dung dch X. Hp th hon ton
4,48 lt (ktc) kh CO2 vo dung dch X thu c 5,0 gam kt ta. Gi tr ca m l:
A. 1,15
B. 4,6
C. 2,3
D. 3,45
Cu 48: in phn 100ml dung dch Y gm KCl 0,1M v Cu(NO3)2 0,2M vi cng dng in 5A trong
579 giy, in cc tr, mng ngn xp. Gi s nc bay hi khng ng k. gim khi lng ca dd sau
khi in phn l: A. 1,475 gam.
B. 1,59 gam. C. 1,67 gam. D. 1,155 gam.
Cu 49: X phng ho 6,6 gam hn hp hai este CH3CH2COOCH3 v CH3COOC2H5 cn dng 150 ml dung
dch NaOH x M. Gi tr ca x l A. 1
B. 0,5
C. 1,5
D. 2
+
2+
2+
Cu 50: Mt loi nc cng cha cc ion : Na , Ca , Mg , Cl , HCO3 . C th dng ha cht no sau y
lm mm nc cng? A. HCl B. Ca(OH)2
C. Na2CO3
D. un nng.
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Trong cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa. S dung dch c
PH<7 l:
A. 4
B. 5
C. 2
D. 3
Cu 52: Nung m gam hn hp A gm Fe v Cu (trong Fe chim 36,84% v khi lng) trong oxi thu
c 36,8 gam hn hp cht rn Y. Ho tan hon ton Y trong V ml dung dch HNO3 2M ly d 25% so vi
lng phn ng thu c 0,2 mol hn hp NO, NO2 c t khi so vi H2 bng 19 (bit NO v NO2 l sn
phm kh duy nht, ktc). Gi tr ca m v V ln lt l:
A. 30,4 v 875
B. 30,4 v 375
C. 29,5 v 875
D. 29,5 v 375
Cu 53: t chy hon ton 0,2 mol hn hp X gm 2 axit no A v B cn 2,24 lt kh O 2(ktc). Cng thc cu
to ca hai axit A v B l:
A. HCOOH v CH3COOH
B. HCOOH v HOOC-COOH
C. CH3COOH v HOOC-COOH
D. CH3COOH v HOOC-CH2-COOH
Cu 54: Cho s chuyn ho sau:
Tinh bt
X
Y
axit axetic
X, Y ln lt l:
A. glucz, etyl axetat
B. Glucz, anhit axetic
C. Glucz, ancol etylic
D. ancol etylic, anhit axetic
Cu 55: C 5 dung dch ng ring bit trong 5 ng nghim (NH4)2SO4, FeCl2, Cr(NO3)3, K2CO3, Al(NO3)3.
Cho Ba(OH)2 n d vo 5 dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l:
A. 3
B. 5
C. 4
D. 2
Cu 56: C dung dch hn hp AlCl3, CuCl2, ZnCl2. Dng ho cht no dng tch ly c mui AlCl3 m
khng thay i khi lng?
A. NaOH v HCl
B. Na2CO3 v HCl
C. Al v HCl
D. NH3 v HCl
Cu 57: Cho s phn ng:
+Cl2, 5000C
+Cl2+H2O
+ NaOH
+ Cu(OH)2
Propilen
X1
X2
X3
X 4 . S phn ng oxi ho
-kh l: A. 1
B. 3
C. 4
D. 2
Cu 58: C bao nhiu ng phn cu to mach h ca C5H8 khi tc dng vi H2 d(Ni, t0) thu c sn phm
l isopentan? A. 3 B. 1
C. 4
D. 2
Cu 59: Dng mui it hng ngy phng nga dch bnh bu c. Mui it l:
A. NaCl + NaI
B. I2 + NaCl
C. NaCl + KI + KIO3
D. NaI + MgCl2
Cu 60: Cho 11,8 gam hn hp X gm 3 amin: Propyl amin, etyl metyl amin, trimetyl amin.Tc dng va
vi V ml dung dch HCl 1M. Gi tr ca V l: A. 250 B. 200
C. 100
D. 150
----------- HT ----------

Trang 4/7 - M thi 109

S GIO DC V O TO NGH AN

TRNG THPT NG HIU

P N THI TH TUYN SINH I HC NM 2012

MN HA HC; Khi A,B

Thi gian lm bi: 90 pht, khng k thi gian pht

Trang 5/7 - M thi 109

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dapan
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dapan
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cauhoi
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58

dapan
B
B
A
A
C
A
C
C
C
D
A
B
A
D
B
B
A
B
D
D
A
A
B
D
C
B
B
A
D
D
D
A
B
C
A
C
D
B
C
D
D
A
C
C
C
B
A
C
B
A
C
C
D
D
C
D
B
D

made
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470
470

cauhoi
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58

dapan
A
D
B
B
D
A
C
D
C
D
B
D
B
B
D
D
D
D
B
C
A
B
B
C
B
B
D
D
D
B
B
A
A
A
C
B
C
C
A
A
C
C
C
B
A
C
A
C
D
A
A
C
A
D
B
A
C
A

Trang 6/7 - M thi 109

109
109

59
60

C
B

257
257

59
60

B
D

382
382

59
60

A
B

470
470

59
60

C
D

Trang 7/7 - M thi 109