GV: Trn Vn Tn (T: 0984532986)

N LUYN THI H CHT LNG CAO

H v tn HS:

I) V D MINH HO BI GING
V d 1: Ho tan hon ton 19,2 gam Cu vo dung dch HNO3 long. Khi NO thu c em oxi ho thnh NO2 ri
sc vo nc cng vi dng kh O2 chuyn ht thnh HNO3. Th tch kh O2 (ktc) tham gia phn ng qu
trnh trn l
A. 2,24 lt.
B. 3,36 lt.
C. 4,48 lt.
D. 6,72 lt.
V d 2: Ho tan hon ton m gam Al vo dung dch HNO3 rt long th thu c hn hp gm 0,015 mol kh N2O
v 0,01 mol kh NO (phn ng khng to NH4NO3). Gi tr ca m l
A. 13,5.
B. 1,35.
C. 0,81.
D. 8,1.
V d 3: Cho m gam Cu phn ng ht vi dung dch HNO3 thu c 8,96 lt (ktc) hn hp kh NO v NO2 c khi
lng l 15,2 gam. Gi tr ca m l
A. 25,6.
B. 16.
C. 2,56.
D. 8.
V d 4: Cho 1,4 gam kim loi X tc dng vi dung dch HCl thu c dung dch mui trong kim loi c s oxi
ho +2 v 0,56 lt H2 (ktc). Kim loi X l
A. Mg.
B. Zn.
C. Fe.
D. Ni.
V d 5: Ho tan hon ton m gam Fe vo dung dch HNO3 long, d thu c 0,448 lt kh NO duy nht (ktc).
Gi tr ca m l
A. 11,2.
B. 1,12.
C. 0,56.
D. 5,60.
V d 6: Cho m gam hn hp Al v Fe phn ng hon ton vi dung dch HNO3 long thu c 2,24 lt NO duy
nht (ktc). Mt khc, cho m gam hn hp ny phn ng vi dung dch HCl thu c 2,80 lt H2 (ktc). Gi tr ca
m l
A. 8,30.
B. 4,15.
C. 4,50.
D. 6,95.
V d 7: Ho tan 3,04 gam hn hp bt kim loi Fe v Cu trong dung dch HNO3 long, thu c 0,896 lt kh NO
duy nht (ktc). Xc nh thnh phn trm khi lng ca mi kim loi trong hn hp.
V d 8: Ho tan hon ton m gam Al vo dung dch HNO3 rt long thu c hn hp kh gm 0,15 mol N2O v
0,1 mol NO. Gi tr ca m l
A. 13,5.
B. 1,35.
C. 0,81.
D. 8,1.
V d 9: Cho 19,2 gam Cu vo 1 lt dung dch hn hp gm H2SO4 0,5M vi KNO3 0,2M. Th tch kh NO duy
nht duy nht (ktc) thu c ktc l
A. 1,12 lt.
B. 2,24 lt.
C. 4,48 lt.
D. 3,36 lt.
V d 10: t 12,8 gam Cu trong khng kh. Ho tan hon ton cht rn thu c vo dung dch HNO3 0,5M thu
c 448 ml kh NO duy nht. Th tch dung dch HNO3 ti thiu cn dng ho tan cht rn.
V d 11: Ho tan hon ton m gam bt Al vo dung dch HNO3 d ch thu c 8,96 lt hn hp kh X gm NO v
N2O (ktc) c t l mol l 1 : 3. Gi tr ca m l
A. 24,3.
B. 42,3.
C. 25,3.
D. 25,7.
II) BI TP T LUYN
Cu 1: Cho m gam bt st vo dung dch HNO3 long d, ta thu c 8,96 lt hn hp hai kh NO2 v NO ( ktc)
v c t khi so vi O2 bng 1,3125. Thnh phn phn trm kh NO v NO2 trong hn hp theo th tch v Gi tr
ca m l
A. 25%; 75%; 1,12.
B. 25%; 75%; 11,2.
C. 35%; 65%; 11,2.
D. 45%; 55%; 1,12.
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N LUYN THI H CHT LNG CAO

Cu 2: Cho mt lung kh CO i qua ng s ng 0,04 mol hn hp X gm FeO v Fe2O3 t nng. Sau khi kt
thc th nghim thu c cht rn Y gm 4 cht nng 4,784 gam. Kh i ra khi ng s cho hp th vo dung dch
Ca(OH)2 d th thu c 4,6 gam kt ta. Phn trm khi lng FeO trong X l
A. 68,03%.
B. 31,03%.
C. 13,03%.
D. 68,97%.
Cu 3: Mt hn hp gm bt 2 kim loi Mg v Al c chia thnh hai phn bng nhau.
- Phn 1: Cho tc dng vi dung dch HCl d thu c 3,36 lt H2.
- Phn 2: Ho tan ht trong dung dch HNO3 long, d thu c V lt kh khng mu, ho nu trong khng kh. Cc
th tch o ktc. Gi tr ca V l
A. 2,24.
B. 3,36.
C. 4,48.
D. 5,6.
Cu 4: Dung dch X gm AgNO3 v Cu(NO3)2 c cng nng . Ly mt lng hn hp gm 0,03 mol Al; 0,05
mol Fe cho vo 100 ml dung dch X cho ti khi phn ng kt thc thu c cht rn Y cha 3 kim loi. Cho Y vo
dung dch HCl d gii phng 0,07 gam kh. Nng mol ca hai mui trong dung dch X l
A. 0,3M.
B. 0,4M.
C. 0,42M.
D. 0,45M.
Cu 5: Cho 1,35 gam hn hp Cu, Mg, Al tc dng vi dung dch HNO3 d c 896 ml (ktc) hn hp kh gm
NO v NO2 c M = 42. Tng khi lng mui nitrat sinh ra l
B. 10,08 gam.
C. 5,07 gam.
D. 8,15 gam.
A. 9,41 gam.
Cu 6: Ho tan ht 4,43 gam hn hp Al v Mg trong HNO3 long thu c dung dch X v 1,568 lt (ktc) hn
hp hai kh (u khng mu) c khi lng 2,59 gam trong c mt kh b ho nu trong khng kh. S mol
HNO3 phn ng l
A. 0,51 mol.
B. 0,45 mol.
C. 0,55 mol.
D. 0,49 mol.
Cu 7: Ho tan hon ton m gan hn hp gm 3 kim loi bng dung dch HNO3 thu c 1,12 lt hn hp kh X
(ktc) gm NO v NO2. T khi hi ca X so vi hiro bng 18,2. Th tch ti thiu dung dch HNO3 37,8% (d =
1,242 g/ml) cn dng l
A. 20,18 ml.
B. 11,12 ml.
C. 21,47 ml.
D. 36,7 ml.
Cu 8: Ha tan hon ton 12 gam hn hp Fe v Cu (t l mol 1 : 1) bng axit HNO3 thu c V lt (ktc) hn hp
kh X gm NO, NO2 v dung dch Y (ch cha hai mui v axit d). T khi ca X so vi H2 bng 19. Gi tr ca V l
A. 2,24.
B. 5,6.
C. 4,48.
D. 3,36.
Cu 9: t chy 5,6 gam bt Fe trong bnh ng O2 thu c 7,36 gam hn hp X gm Fe2O3, Fe3O4 v Fe. Ho
tan hon ton lng hn hp X bng dung dch HNO3 thu c V lt (ktc) hn hp kh Y gm NO v NO2. T khi
ca Y so vi H2 bng 19. Gi tr ca V l
A. 0,672.
B. 0,336.
C. 0,448.
D. 0,896.
Cu 10: Cho a gam hn hp X gm oxit FeO, CuO, Fe2O3 c s mol bng nhau tc dng hon ton vi lng va
dung dch HNO3 khi un nng nh, thu c dung dch Y v 3,136 lt kh (ktc) hn hp kh Z gm NO v NO2
c t khi so vi H2 l 20,143. Gi tr ca a l
A. 74,88 gam.
B. 52,35 gam.
C. 61,79 gam.
D. 72,35 gam.
Cu 11: Oxi ho hon ton 0,728 gam bt Fe ta thu c 1,016 gam hn hp 2 oxit (hn hp X). Ho tan hn hp
X bng dung dch axit nitric long, d.
a) Th tch kh NO duy nht thu c ( ktc) l
A. 2,224 ml.
B. 22,4 ml.
C. 33,6 ml.
D. 44,8 ml.
b) Cng hn hp X trn trn vi 5,4 gam bt Al ri tin hnh phn ng nhit nhm (hiu sut 100%). Ho tan
hn hp thu c sau phn ng bng dung dch HCl d. Th tch kh bay ra ( ktc) l
A. 6,608 lt.
B. 0,6608 lt.
C. 3,304 lt.
D. 33,04 lt.
Cu 12: Trn 0,81 gam bt Al vi hn hp bt Fe2O3 v CuO ri tin hnh phn ng nhit nhm thu c hn hp
X. Ho tan hon ton hn hp X trong dung dch HNO3 un nng thu c V lt kh NO (sn phm kh duy nht,
ktc). Gi tr ca V l
A. 0,224 lt.
B. 0,672 lt.
C. 2,24 lt.
D. 6,72 lt.
Cu 13: Cho 8,3 gam hn hp X gm Al v Fe theo t l mol l 1 : 1 vo 100 ml dung dch Y gm Cu(NO3)2 v
AgNO3. Sau khi phn ng kt thc thu c cht rn A gm 3 kim loi. Ho tan hon ton cht rn A vo dung

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N LUYN THI H CHT LNG CAO

dch HCl d thy c 1,12 lt kh thot ra (ktc) v cn li 28 gam cht rn khng tan B. Nng mol ca dung dch
Cu(NO3)2 v AgNO3 ln lt l
A. 2M v 1M.
B. 1M v 2M.
C. 0,2M v 0,1M.
D. 0,5M v 0,5M.
Cu 14: Ho tan 15 gam hn hp X gm hai kim loi Mg v Al vo dung dch Y gm HNO3 v H2SO4 c thu
c 0,1 mol mi kh SO2, NO, NO2, N2O. Phn trm khi lng Al v Mg trong hn hp ln lt l
A. 63% v 37%.
B. 36% v 64%.
C. 50% v 50%.
D. 46% v 54%.
Cu 15: Trn 60 gam bt Fe vi 30 gam bt lu hunh ri un nng (khng c khng kh) thu c cht rn X.
Ho tan X bng dung dch HCl d c dung dch Y v kh Z. t chy Z cn V lt O2 (ktc). Bit cc phn ng
xy ra hon ton. Gi tr ca V l
A. 11,2.
B. 21.
C. 33.
D. 49.
Cu 16: Hn hp X gm hai kim loi R1 v R2 c ho tr x, y khng i (R1 v R2 khng tc dng vi nc v
ng trc Cu trong dy hot ng ho hc ca kim loi). Cho hn hp X phn ng hon ton vi dung dch HNO3
d thu c 1,12 lt kh NO duy nht. Nu cho lng hn hp X trn phn ng hon ton vi dung dch HNO3 th
thu c bao nhiu lt N2. Cc th tch kh o ktC.
A. 0,224 lt.
B. 0,336 lt.
C. 0,448 lt.
D. 0,672 lt.
Cu 17: Cho 1,35 gam hn hp Cu, Mg, Al tc dng ht vi dung dch HNO3 thu c hn hp kh gm 0,01 mol
NO v 0,04 mol NO2. Sau khi c cn dung dch thu c cc mui khan c khi lng l
A. 10,08 gam.
B. 6,59 gam.
C. 5,69 gam.
D. 5,96 gam.
Cu 18: Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ho tan ht hn hp X trong dung
dch HNO3 d, thy thot ra 0,56 lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m l
A. 2,52.
B. 2,22.
C. 2,62.
D. 2,32.
Cu 19: C mt hn hp gm hai kim loi X v Y ng trc H trong dy in ho v c ho tr khng i trong
cc hp cht. Ly m gam hn hp 2 kim loi ri chia thnh 2 phn bng nhau.
- Phn 1: Ho tan hon ton trong dung dch cha axit HCl v H2SO4 long to ra 3,36 lt kh H2.
- Phn 2: Tc dng hon ton vi dung dch HNO3 thu c V lt kh NO (sn phm kh duy nht).
Bit cc th tch kh o ktC. Gi tr ca V l
A. 2,24 lt.
B. 3,36 lt.
C. 4,48 lt.
D. 6,72 lt.
Cu 20: Cho m gam bt Fe vo dung dch HNO3 ly d, sau phn ng thu c 8,96 lt (ktc) hn hp kh NO v
NO2 v c t khi so vi O2 bng 1,3125. Thnh phn phn trm th tch kh NO v NO2 trong hn hp v gi tr
ca m l
A. 25% v 75%; 1,12 gam.
B. 25% v 75%; 11,2 gam.
C. 35% v 65%; 11,2 gam.
D. 45% v 55%; 1,12 gam.
Cu 21: Cho 3 kim loi Al, Fe, Cu vo 2 lt dung dch HNO3 phn ng va thu c 1,792 lt kh X (ktc) gm
N2 v NO2 c t khi so vi He bng 9,25. Nng mol/l ca dung dch HNO3 ban u l
A. 0,28M.
B. 1,4M.
C. 1,7M.
D. 1,2M.
Cu 22: Khi cho 9,6 gam Mg tc dng ht vi dung dch H2SO4 m c, thy c 49 gam H2SO4 tham gia phn
ng to mui MgSO4, H2O v sn phm kh X. X l
A. SO2.
B. S.
C. H2S.
D. H2.
Cu 23: m gam bt st ngoi khng kh sau mt thi gian s chuyn thnh hn hp X c khi lng l 75,2
gam gm Fe, FeO, Fe3O4 v Fe2O3. Cho hn hp X phn ng ht vi dung dch H2SO4 c, nng thu c 6,72 lt
SO2 (ktc). Gi tr ca m l
A. 56.
B. 11,2.
C. 22,4.
D. 25,3.
Cu 24: Cho 13,92 gam Fe3O4 tc dng hon ton vi dung dch HNO3, sau phn ng thu c dung dch X v
0,448 lt kh NxOy (sn phm kh duy nht, o ktc). Khi lng HNO3 nguyn cht tham gia phn ng l
A. 35,28 gam.
B. 33,48 gam.
C. 12,6 gam.
D. 17,64 gam.

Cu 25: Cho hn hp X gm FeS2, Cu2S, Fe3O4 (c cng s mol) tc dng hon ton vi dung dch H2SO4 c,
un nng, thu c dung dch v 14,56 lt kh duy nht SO2 (ktc). S mol ca mi cht trong hn hp l
A. 0,05 mol.
B. 0,06 mol.
C. 0,065 mol.
D. 0,075 mol.
Cu 26: Chia m gam hn hp X gm Al, Fe thnh hai phn bng nhau:
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N LUYN THI H CHT LNG CAO

- Phn 1: Ho tan hon ton trong dung dch HCl d thu c 7,28 lt H2
- Phn 2: Ho tan hon ton trong dung dch HNO3 long, d thu c 5,6 lt NO (sn phm kh duy nht).
Bit cc th tch kh o ktc. Khi lng Fe, Al c trong hn hp X ln lt l
A. 5,6 gam v 4,05 gam.
B. 16,8 gam v 8,1 gam.
C. 5,6 gam v 5,4 gam.
D. 11,2 gam v 4,05 gam.
Cu 27: Mt hn hp gm 4 kim loi: Mg, Ni, Zn v Al c chia thnh 2 phn bng nhau:
- Phn 1: cho tc dng vi HCl d thu c 3,36 lt H2.
- Phn 2: ho tan ht trong HNO3 long d thu c V lt mt kh khng mu ho nu trong khng kh (cc th
tch o ktc). Gi tr ca V l
A. 2,24.
B. 3,36.
C. 4,48.
D. 5,6.
Cu 28: Cho 3,35 gam hn hp gm Mg, Al, Cu, tc dng hon ton vi dung dch H2SO4 c, nng, d c 2,8
lt kh SO2 (ktc). Khi t 3,35 gam hn hp trn trong kh clo d th khi lng mui clorua thu c l
A. 10,225 gam.
B. 12,225 gam.
C. 8,125 gam.
D. 9,255 gam.
Cu 29: Ho tan hon ton 19,2 gam hn hp Cu, Zn vo dung dch H2SO4 c nng c 0,14 mol SO2; 0,64 mol
S v dung dch mui sunfat. Thnh phn trm khi lng ca Cu trong hn hp ban u l
A. 50,39%.
B. 54,46%.
C. 50,15%.
D. 49,61%.
Cu 30: Ho tan 6,25 gam hn hp Zn v Al vo 275 ml dung dch HNO3 thu c dung dch X (khng cha mui
amoni), cht rn Y gm cc kim loi cha tan ht cn nng 2,516 gam v 1,12 lt hn hp kh Z ( ktc) gm NO
v NO2. T khi ca hn hp Z so vi H2 l 16,75. Nng mol ca HNO3 v khi lng mui khan khi c cn
dung dch sau phn ng ln lt l
A. 0,65M v 11,794 gam.
B. 0,65M v 12,35 gam.
C. 0,75M v 11,794 gam.
D. 0,55M v 12,35 gam.
Cu 31: Ho tan hon ton hn hp 9,75 gam Zn v 2,7 gam Al vo 200 ml dung dch cha ng thi HNO3 2,5M
v H2SO4 0,75M ch thu c kh NO (sn phm kh duy nht) v dung dch X ch gm cc mui. C cn dung
dch X thu c khi lng mui khan l
A. 57,85 gam.
B. 52,65 gam.
C. 45,45 gam.
D. 41,25 gam.
Cu 32: Cho a gam nhm tc dng vi b gam Fe2O3 thu c hn hp X. Ho tan X trong HNO3 d, thu c 2,24
lt (ktc) mt kh khng mu ho nu trong khng kh. Khi lng nhm dng l
A. 2,7 gam.
B. 5,4 gam.
C. 4,0 gam.
D, 1,35 gam.
Cu 33: Cho dng kh CO i qua ng s cha 0,12 mol hn hp gm FeO v Fe2O3 nung nng, phn ng to ra
0,138 mol CO2. Hn hp cht rn cn li trong ng nng 14,352 gam gm bn cht. Ho tan ht hn hp bn cht
ny vo dung dch HNO3 d c V lt kh NO (sn phm kh duy nht, o ktc). Gi tr ca V l
A. 0,224.
B. 0,672.
C. 2,248.
D. 6,854.
Cu 34: Cho mt lung kh CO i qua ng s ng Fe2O3 nung nng. Sau mt thi gian thu c 44,64 gam hn
hp X gm Fe, FeO, Fe2O3, Fe3O4. Cho X tc dng va vi dung dch HNO3 0,1M th thu c dung dch Y v
3,136 lt kh NO (sn phm kh duy nht, o ktc). Th tch dung dch HNO3 dng l
A. 1,94 lt.
B. 19,4 lt.
C. 15 lt.
D. 1,34 lt.
Cu 35: Trn 0,54 gam bt Al vi hn hp vi hn hp bt Fe2O3 v CuO ri tin hnh phn ng nhit nhm trong
iu kin khng c khng kh mt thi gian, thu c hn hp cht rn X. Ho tan hon ton X trong dung dch
HNO3 c nng, d th th tch NO2 (sn phm kh duy nht, o ktc) thu c l
A. 0,672 lt.
B. 0,896 lt.
C. 1,12 lt.
D. 1,344 lt.
Cu 36: Ho tan 1,52 gam hn hp Fe v Cu vo 200 ml dung dch HNO3 vo 200 ml dung dch HNO3, sau khi
phn ng xy ra hon ton thu c dung dch X, 224 ml kh NO (sn phm kh duy nht, o ktc) v cn li
0,64 gam cht rn khng b ho tan. Nng mol ca dung dch HNO3 l
A. 0,1M.
B. 0,2M.
C. 0,25M.
D. 0,5M.
Cu 37: Hn hp X gm Fe v Cu vi t l phn trm khi lng l 4 : 6. Ho tan m gam hn hp X bng dung
dch HNO3 thu c 0,448 lt kh NO (sn phm kh duy nht, o ktc) dung dch Y v 0,65m gam kim loi
khng tan. Khi lng mui khan trong dung dch X l
A. 5,4 gam.
B. 6,4 gam.
C. 11,2 gam.
D. 8,6 gam.

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