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CHNG III : AMIN - AMINOAXIT - PEPTIT PROTEIN
-------------------------------------------------------------------------------------------------------------------------------------------------AMIN
A. KIN THC K THA
- Tn gi cc gc hiocacbon, cc axit hu c.
- Tnh cht ha hc ca NH3, phenol.
- Tnh cht ha hc ca axit cacboxylic.
- Xc nh cng thc phn t theo t l mol nguyn t C: H: N:O.
B. KIN THC C BN TRNG TM
I.
AMIN.
1. Khi nim: Amin l nhng hp cht hu c c c khi thay th mt hoc nhiu nguyn t hidro trong phn t NH3
bng mt hoc nhiu gc hidrocacbon.
Th d: CH3NH2 (1) ; C2H5NH2 (2) CH3 NH CH3 (3) CH3 N CH3 (4) ; CH2=CH-CH2-NH2 (5) C6H5NH2 (6)
CH3
2. Phn loi
Amin c phn loi theo 2 cch thng dng:
a ) Theo c im cu to ca gc hidrocacbon.
- Amin thm: Nhm NH2 gn vo nhn benzen. VD: C6H5NH2;...
- amin bo: Nhm NH2 gn vo C mang lin kt n. VD: CH3NH2; C2H5NH2; C3H7NH2;....
b ) Theo bc ca amin
- amin bc 1: CH3NH2 ; C2H5NH2
- amin bc 2: CH3 NH CH3
- amin bc 3: CH3 N CH3
3. Danh php
CH3
- Cch gi tn theo danh php gc-chc: Tn gc hidrocacbon + amin.
VD: CH3NH2 metylamin
C2H5NH2 etylamin
(CH3)2CH-NH2 Isopropylamin
- Tn thng thng: Ch p dng cho mt s amin nh: C6H5NH2 Anilin
4. ng phn: Amin c cc loi ng phn:
- ng phn v mch cacbon. - ng phn v v tr nhm chc.
- ng phn v bc ca amin.
VD: - Amin C2H7N c 2 ng phn, trong c 1 ng phn bc 1 v 1 ng phn bc 2
- Amin C3H9N c 4 ng phn, trong c 2 ng phn bc 1, 1 ng phn bc 2 v 1 p bc 3
5. L tnh: Cc amin no u dy (metyl,etyl) l nhng cht kh c mi khai kh chu , d tan trong nc. Cc amin ng
ng cao hn l nhng cht lng hoc rn, tan trong nc gim dn theo chiu tng ca khi lng phn t.
6. Ha tnh:
a) Tnh baz: Amin c tnh baz yu

[RNH3]+ + OH-;
RNH2 + H2O

CH3NH2 + HCl [CH3NH3]+ClMetylamin

Metylamoni clorua

* Tc dng vi qu hoc phenolphtalein

Qu tm
Phenolphtalein

Metylamin

Anilin

Xanh
Hng

Khng i mu
Khng i mu

* So snh tnh baz: CH3-NH2 >NH3 > C6H5NH2

b) Phn ng th nhn thm ca anilin: Phn ng vi nc brom
NH2
NH2
Br
Br
+ 3Br2

+ 3HBr

Br
Hoc gn:
C6H5NH2+ 3Br2
Theo phng trnh: 93g
Theo :
?g

(trng)

C6H2NH2(Br3) (trng) + 3HBr

330g
?g
theo qui tc tam xut

2011 2012 TRNG THPT NAM SCH II

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7. iu ch: Anilin v cc amin thm thng c iu ch bng cch kh nitro benzen (hoc dn xut nitro tng ng)
bi hidro mi sinh (Fe + HCl)
C6H5NO2 + 6H
Theo phng trnh:
Theo :

HCl Fe

t0

123g
?g

C6H5NH2 + 2 H2O
93g
?g

theo qui tc tam xut

II. AMINO AXIT

1. nh ngha: Aminoaxit l loi HCHC tp chc m phn t cha ng thi nhm amino (NH2) v nhm cacboxyl
(COOH).
VD: H2N CH2 COOH Axit aminoaxetic(cn gi l glixin)
CH3 CH[NH2] COOH Axit -aminopropionic(cn gi l Alanin)
2. Cu to phn t: Nhm COOH v nhm NH2 trong amino axit tng tc vi nhau to ra ion lng cc, ion ny nm
cn bng vi dng phn t.
3. L tnh: Cc aminoaxit l cc cht rn khng mu, v hi ngt, nhit nng chy cao, d tan trong nc.
4. Ha tnh:
a)
Tnh cht axit baz ca dd amino axit
- Amino axit tc dng vi axit v c mnh to mui
HOOC CH2 NH2 + HCl HOOC CH2 NH3Cl
- Amino axit tc dng vi baz mnh to mui v nc
NH2 CH2 COOH + NaOH NH2 CH2 COONa + H2O
=> amino axit c tnh lng tnh: va tc dng vi axit, va tc dng vi baz.
b)
Phn ng este ha nhm COOH
NH2 CH2 COOH + C2H5OH
c)

HCl

NH2 CH2 COOC2H5 + H2O

Phn ng trng ngng

VD: nH NH [CH2]5CO OH (- NH[CH2]5CO-)n + nH2O
III. PEPTIT
1. Khi nim:
- Lin kt ca nhm CO vi nhm NH gia 2 n v -aminoaxit c gi l lin kt peptit
V d: H2N-CH2-CO-NH-CH-COOH
CH3
Lin kt peptit
- Peptit l nhng hp cht cha t 2 n 50 gc -aminoaxit lin kt vi nhau bng lin kt peptit
2. Phn loi: (gm 2 loi)
- Oligopeptit: c t 2 n 10 gc -aminoaxit
- Polipeptit: c t 11 n 50 gc -aminoaxit
3. Cu to: Phn t peptit hp thnh t cc phn t -aminoaxit l.kt vi nhau bng l.kt peptit theo 1 trt t nht nh.
V d: H2N-CH(R1)-CO-NH(R2)-CH-CO-NH-CH(R3)-CONH-CH(Rn)-COOH
u N
lin kt peptit
u C
4. Danh php: c tn aminoaxit t u N n u C
H2NCH2CO-NHCH2COOH GlyxylGlyxin(Gly-Gly)
H2NCH2CO-NHCH(CH3)COOH Glyxylalanin(Gly-Ala)
5.
ng phn:
Vi n aminaxit khc nhau c n ! peptit ng phn cha cc gc aminoaxit khc nhau.
VD: - Ala v Gly to 2 ipeptit cha c Ala v Gly
- Ala, Gly v Val to 6 tripeptit cha c Ala, Gly v Val.
6. Tnh cht ho hc
a. Phn ng mu biure:
Peptit + Cu(OH)2 phc mu tm
Ch : i peptit khng c phn ng ny
b. phn ng thu phn: to ra cc -aminoaxit
2011 2012 TRNG THPT NAM SCH II

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IV- PROTEIN
1- Khi nim v phn loi:
- Protein l nhng polipeptit cao phn t c pt khi t vi chc nghn n vi triu.
- Protein gm 2 loi:
+ Protein n gin: c to thnh t cc gc -aminoaxit
+ protein phc tp: c to thnh t protein n gin cng vi thnh phn phi protein nh axit nucleic, lipit,
cacbohidrat,
2. Tnh cht ha hc ca protein:
a/ P thy phn: Protein polipeptit cc - aminoaxit
b/ phn ng mu:
+ P vi Cu(OH)2 (p biure): Protein + Cu(OH)2 phc mu tm
+ P vi HNO3 c: Protein + HNO3c kt ta mu vng
V. Khi nim v enzim v axit nucleic
- Enzim l nhng cht hu ht c bn cht protein, c kh nng xc tc cho cc qu trnh ha hc,
c bit trong c th sinh vt
- Xc tc enzim c 2 c im:
+ C tnh chn lc cao
+ Lm tng tc p 109 1011 ln so vi xc tc ha hc.
- Axit nucleic l polieste ca axit photphoric v pentoz.
BI TP VN DNG: AMIN - AMINOAXIT - PEPTIT PROTEIN
Cu 1 S ng phn amin c cng thc phn t C2H7N l ?
A. 4.
B. 3.
C. 2.
D. 5.
...................................................................................................................................................................................................
Cu 2 S ng phn amin c cng thc phn t C3H9N l ?
A. 4.
B. 3.
C. 2.
D. 5.
...................................................................................................................................................................................................
Cu 3 S ng phn amin c cng thc phn t C4H11N l ?
A. 5.
B. 7.
C. 6.
D. 8.
...................................................................................................................................................................................................
Cu 4 S ng phn amin bc mt ng vi cng thc phn t C3H9N l ?
A. 4.
B. 3.
C. 2.
D. 5.
...................................................................................................................................................................................................
Cu 5 S ng phn amin bc mt ng vi cng thc phn t C4H11N l ?
A. 4.
B. 3.
C. 2.
D. 5.
...................................................................................................................................................................................................
Cu 6 C bao nhiu amin cha vng benzen c cng cng thc phn t C7H9N ?
A. 3 amin.
B. 5 amin.
C. 6 amin.
D. 7 amin.
...................................................................................................................................................................................................
Cu 7 Anilin c cng thc l ?
A. CH3COOH.
B. C6H5OH.
C. C6H5NH2.
D. CH3OH.
Cu 8 Trong cc cht sau, cht no l amin bc 2 ?
A. H2N-[CH2]6NH2
B. CH3CH(CH3)NH2
C. CH3NHCH3
D. C6H5NH2
Cu 9 C bao nhiu amin bc hai c cng cng thc phn t C5H13N ?
A. 4 amin.
B. 5 amin.
C. 6 amin.
D. 7 amin.
...................................................................................................................................................................................................
Cu 10 Trong cc tn gi di y, tn no ph hp vi cht CH3CH(CH3)NH2 ?
A. Metyletylamin.
B. Etylmetylamin.
C. Isopropanamin.
D. Isopropylamin.
Cu 11 Trong cc tn gi di y, cht no c lc baz mnh nht ?
A. NH3
B. C6H5CH2NH2
C. C6H5NH2
D. (CH3)2NH
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Cu 12 Trong cc tn gi di y, cht no c lc baz yu nht ?
A. C6H5NH2
B. C6H5CH2NH2
C. (C6H5)2NH
D. NH3
Cu 13 Cht no l amin bc II ?
A. Phenylamin.
B. Benzylamin.
C. Anilin.
D. Phenylmetylamin.
...................................................................................................................................................................................................
Cu 14 Trong cc cht di y, cht no c tnh baz mnh nht ?
A. C6H5NH2.
B. (C6H5)2NH
C. p-CH3-C6H4-NH2.
D. C6H5-CH2-NH2
Cu 15 Cht khng c kh nng lm xanh nc qu tm l ?
A. Anilin
B. Natri hiroxit.
C. Natri axetat.
D. Amoniac.
Cu 16 Cht khng phn ng vi dung dch NaOH l ?
A. C6H5NH3Cl.
B. C6H5CH2OH.
C. p-CH3C6H4OH.
D. C6H5OH.
Cu 17 tch ring tng cht t hn hp benzen, anilin, phenol ta ch cn dng cc ho cht ( dng c,iu kin th
nghim y ) l ?
A. dung dch NaOH, dung dch HCl, kh CO2.
B. dung dch Br2, dung dch HCl, kh CO2.
C. dung dch Br2, dung dch NaOH, kh CO2.
D. dung dch NaOH, dung dch NaCl, kh CO2.
...................................................................................................................................................................................................
Cu 18 Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l ?
A. anilin, metyl amin, amoniac.
B. amoni clorua, metyl amin, natri hiroxit.
C. anilin, amoniac, natri hiroxit.
D. metyl amin, amoniac, natri axetat.
Cu 19 Kt ta xut hin khi nh dung dch brom vo ?
A. ancol etylic.
B. benzen.
C. anilin.
D. axit axetic.
Cu 20 Cht lm giy qu tm m chuyn thnh mu xanh l ?
A. C2H5OH.
B. CH3NH2.
C. C6H5NH2.
D. NaCl.
Cu 21 Anilin ( C6H5NH2 ) phn ng vi dung dch ?
A. NaOH.
B. HCl.
C. Na2CO3.
D. NaCl.
Cu 22 C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng
trnl ?
A. dung dch phenolphtalein.
B. nc brom.
C. dung dch NaOH.
D. giy qu tm.
Cu 23 Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi ?
A. dung dch NaCl.
B. dung dch HCl.
C. nc Br2.
D. dung dch NaOH.
Cu 24 Dung dch metylamin trong nc lm ?
A. qu tm khng i mu.
B. qu tm ha xanh.
C. phenolphtalein ho xanh.
D. phenolphtalein khng i mu.
Cu 25 Cht c tnh baz l ?
A. CH3NH2.
B. CH3COOH.
C. CH3CHO.
D. C6H5OH.
Cu 26 Cho 500 gam benzen phn ng vi HNO3 (c) c mt H2SO4 c, sn phm thu c em kh thnh anilin. Nu
hiu sut chung ca qu trnh l 78% th khi lng anilin thu c l ?
A. 456 gam.
B. 564 gam.
C. 465 gam.
D. 546 gam.
...................................................................................................................................................................................................
Cu 27 Cho 9,3 gam anilin (C6H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l ?
A. 11,95 gam.
B. 12,95 gam.
C. 12,59 gam.
D. 11,85 gam.
...................................................................................................................................................................................................
Cu 28 Cho 5,9 gam etylamin (C3H7NH2) tc dng va vi axit HCl. Khi lng mui (C3H7NH3Cl) thu c l ?
A. 8,15 gam.
B. 9,65 gam.
C. 8,10 gam.
D. 9,55 gam.
...................................................................................................................................................................................................
Cu 29 Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l ?
A. 7,65 gam.
B. 8,15 gam.
C. 8,10 gam.
D. 0,85 gam.
...................................................................................................................................................................................................
Cu 30 Cho anilin tc dng va vi dung dch HCl thu c 38,85 gam mui. Khi lng anilin phn ng l ?
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A. 18,6g
B. 9,3g
C. 37,2g
D. 27,9g.
...................................................................................................................................................................................................
Cu 31 Trung ha 11,8 gam mt amin n chc cn 200 ml dung dch HCl 1M. Cng thc phn t ca X l
A. C2H5N
B. CH5N
C. C3H9N
D. C3H7N
...................................................................................................................................................................................................
Cu 32 Cho lng d anilin phn ng hon ton vi dung dch cha 0,05 mol H2SO4 long. Khi lng mui thu
cbng bao nhiu gam ?
A. 7,1g.
B. 14,2g.
C. 19,1g.
D. 28,4g.
...................................................................................................................................................................................................
Cu 33 trung ha 20 gam dung dch ca mt amin n chc X nng 22,5% cn dng 100ml dung dch HCl 1M.
Cng thc phn t ca X l ?
A. C2H7N
B. CH5N
C. C3H5N
D. C3H7N
...................................................................................................................................................................................................
Cu 34 Cho 10 gam amin n chc ( X ) phn ng hon ton vi HCl ( d ), thu c 15 gam mui khan. S ng phn
cu to ca X l ?
A. 8.
B. 7.
C. 5.
D. 4.
...................................................................................................................................................................................................
Cu 35 t chy hon ton 0,2 mol metylamin (CH3NH2), sinh ra V lt kh N2 ( ktc). Gi tr ca V l ?
A. 4,48.
B. 1,12.
C. 2,24.
D. 3,36.
...................................................................................................................................................................................................
Cu 36 t chy hon ton m gam metylamin (CH3NH2), sinh ra 2,24 lt kh N2 ( ktc). Gi tr ca m l ?
A. 3,1 gam.
B. 6,2 gam.
C. 5,4 gam.
D. 2,6 gam.
...................................................................................................................................................................................................
Cu 37 Th tch nc brom 3% (d = 1,3g/ml) cn dng iu ch 4,4 gam kt ta 2,4,6 - tribrom anilin l
A. 164,1ml.
B. 49,23ml.
C 146,1ml.
D. 16,41ml.
...................................................................................................................................................................................................
Cu 38 t chy hon ton amin no n chc X, thu c 16,8 lt CO2 ; 2,8 lt N2 (ktc) v 20,25 g H2O. Cng thc phn
t ca X l ?
A. C4H9N.
B. C3H7N.
C. C2H7N.
D. C3H9N.
...................................................................................................................................................................................................
Cu 39 Mt amin n chc c cha 31,111%N v khi lng. Cng thc phn t v s ng phn ca amin tng ng l
A. CH5N; 1 ng phn. B. C2H7N; 2 ng phn. C. C3H9N; 4 ng phn. D. C4H11N; 8 ng phn.
...................................................................................................................................................................................................
Cu 40 Cho 11,25 gam C2H5NH2 tc dng vi 200 ml dung dch HCl x(M). Sau khi phn ng xong thu c dung dch
c cha 22,2 gam cht tan. Gi tr ca x l ?
A. 1,3M
B. 1,25M
C. 1,36M
D. 1,5M
...................................................................................................................................................................................................
Cu 41 t chy hon ton mt amin no, n chc, mch h thu c t l khi lng ca CO2 so vi nc l 44 : 27.
Cng thc phn t ca amin l ?
A. C3H7N
B. C3H9N
C. C4H9N
D. C4H11N
...................................................................................................................................................................................................
Cu 42 Cho m gam Anilin tc dng ht vi dung dch Br2 thu c 9,9 gam kt ta. Gi tr m dng l ?
A. 0,93 gam
B. 2,79 gam
C. 1,86 gam
D. 3,72 gam
...................................................................................................................................................................................................
Cu 43 Ba cht lng: C2H5OH, CH3COOH, CH3NH2 ng trong ba l ring bit. Thuc th dng phn bit ba cht
trn l ?
A. qu tm.
B. kim loi Na.
C. dung dch Br2.
D. dung dch NaOH.
Cu 44 Dy gm cc cht c xp theo chiu tnh baz gim dn t tri sang phi l ?
A. CH3NH2, NH3, C6H5NH2.
B. CH3NH2, C6H5NH2, NH3.
C. C6H5NH2, NH3, CH3NH2.
D. NH3, CH3NH2, C6H5NH2.
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Cu 45 Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c
vi NaOH ( trong dung dch ) l ?
A. 3.
B. 2.
C. 1.
D. 4.
Cu 46 in t thch hp vo ch trng trong cu sau: S kt ta protein bng nhit c gi l......................protein.
A. S trng ngng
B. S ngng t
C. S phn hy
D. S ng t.
Cu 47 Bc ca amin ph thuc vo:
A. Bc ca nguyn t cacbon mang nhm -NH2.
B. Ha tr ca nit
C. S nguyn t H trong NH3 c thay bng gc hidrocacbon.
D. S nhm NH2
Cu 48 Vi cc cht amoniac(1), metylamin(2), etylamin(3), anilin(4). Tnh baz tng dn theo trnh t:
A. (4) < (1) <(2) < (3)
B. (4) < (1) < (3) < (2)
C. (3) < (2) < (1) <(4)
D. (3) < (2) < (4) < (1)
Cu 49 Cp ancol v amin no sau y cng bc ?
A: (CH3)2CHOH v (CH3)2CHNH2.
B: (CH3)3COH v (CH3)3CNH2.
C: C6H5NHCH3 v C6H5CH(OH)CH3.
D: (C6H5)2NH v C6H5CH2OH.
...................................................................................................................................................................................................
Cu 50 Cho 9,3 gam anilin (C6H5NH2) phn ng va vi 200 ml dung dch HCl nng x mol/lit. Gi tr ca x l :
A 0,5 mol/lit.
B 0,25 mol/lit.
C 0,2 mol/lit.
D 0,1 mol/lit.
...................................................................................................................................................................................................
Cu 51 Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi HCl. Khi lng mui (C2H5NH3Cl) thu c l :
A 8,10 gam
B 7,65 gam
C 0,85 gam
D 8,15 gam
...................................................................................................................................................................................................
Cu 52 Mt amin n chc trong phn t c cha15,05% N. Amin ny c cng thc phn t l:
A C6H7N
B C2H5N
C C4H9N
D CH5N
...................................................................................................................................................................................................
Cu 53 Trong cc cht di y cht no c lc baz mnh nht ?
A (CH3)2NH
B NH3
C C6H5-CH2-NH2
D C6H5-NH2
Cu 54 t chy hon ton mt amin khng no n chc trong phn t c mt lin kt i gc hircacbon thu c
s mol H2O : s mol CO2 = 9:8. CTPT ca amin l:
A C4H9N
B C2H5N
C C4H11N
D C3H7N
...................................................................................................................................................................................................
Cu 55 Mt amin n chc trong phn t c cha 77,42% Cacbon. Amin ny c cng thc phn t l:
A C6H7N
B C2H5N
C C4H9N
D CH5N
...................................................................................................................................................................................................
Cu 56 Hy sp xp cc cht sau y theo trt t tng dn tnh baz :
NH3, CH3NH2, C6H5NH2; (CH3)2NH v (C6H5)2NH
A CH3NH2 < (CH3)2NH < C6H5NH2 < (C6H5)2NH< NH3
B (C6H5)2NH < C6H5NH2 <NH3 < CH3NH2 < (CH3)2NH
C (C6H5)2NH < NH3 < C6H5NH2 < (CH3)2NH < CH3NH
D (CH3)2NH>CH3NH2 >NH3>C6H5NH2 > (C6H5)2NH
Cu 57 Nhm c cha dung dch ( hoc cht ) u lm giy qu tm chuyn sang mu xanh l :
A NaOH, NaCl
B CH3NH2, NaOH
C Amoniac, phenol
D NH3, Anilin
Cu 58 Pht biu no sau y l sai:
A Anilin c iu ch trc tip t nitrobenzen.
B Anilin c tnh baz yu hn amoniac.
C Anilin l mt baz c kh nng lm qu tm ha xanh.
D Anilin cho c kt ta trng vi nc brom.
Cu 59 Cho vi git anilin vo nc, sau thm dung dch HCl (d) vo, ri li nh tip dung dch NaOH vo, s xy
ra hin tng :
A. Lc u dung dch b vn c, sau trong sut v cui cng b vn c li.
B. Lc u dung dch trong sut, sau b vn c v cui cng tr li trong sut.
C. Dung dch trong sut.
D. Dung dch b vn c hon ton
Cu 60 phn bit anilin v etylamin ng trong 2 l ring bit, ta dng thuc th no
A. Dung dch Br2
B. Dung dch HCl
C.Dung dch NaOH
D. Dung dch AgNO3
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AMINOAXIT PEPTIT PROTEIN

Cu 1 Amino axit l hp cht hu c trong phn t ?
A. cha nhm cacboxyl v nhm amino.
B. ch cha nhm amino.
C. ch cha nhm cacboxyl.
D. ch cha nit hoc cacbon.
Cu 2 C4H9O2N c my ng phn amino axit c nhm amino v tr ?
A. 4.
B. 3.
C. 2.
D. 5.
..............................................................................................................................................................................................
Cu 3 C bao nhiu amino axit c cng cng thc phn t C4H9O2N ?
A. 3 cht.
B. 4 cht.
C. 5 cht.
D. 6 cht.
..............................................................................................................................................................................................
Cu 4 C bao nhiu amino axit c cng cng thc phn t C3H7O2N ?
A. 3 cht.
B. 4 cht.
C. 2 cht.
D. 1 cht.
Cu 5 Trong cc tn gi di y, tn no khng ph hp vi cht CH3CH(NH2)COOH ?
A. Axit 2-aminopropanoic.
B. Axit-aminopropionic.
C. Anilin.
D. Alanin.
Cu 6 Trong cc tn gi di y, tn no khng ph hp vi cht CH3-CH(CH3)-CH(NH2)-COOH ?
A. Axit 3-metyl-2-aminobutanoic.
B. Valin.
C. Axit 2-amino-3-metylbutanoic.
D. Axit -aminoisovaleric.
Cu 7 Trong cc cht di y, cht no l glixin ?
A. H2N-CH2-COOH
B. CH3CH(NH2)COOH
C. HOOC-CH2CH(NH2)COOH
D. H2NCH2-CH2COOH
Cu 8 Dung dch ca cht no sau y khng lm i mu qu tm ?
A. Glixin (CH2NH2-COOH)
B. Lizin (H2NCH2-[CH2]3CH(NH2)-COOH)
C. Axit glutamic (HOOCCH2CHNH2COOH)
D. Natriphenolat (C6H5ONa)
..............................................................................................................................................................................................
Cu 9 Cht X va tc dng c vi axit, va tc dng c vi baz. Cht X l ?
A. CH3COOH.
B. H2NCH2COOH.
C. CH3CHO.
D. CH3NH2.
..............................................................................................................................................................................................
Cu 10 Cht no sau y va tc dng c vi H2NCH2COOH, va tc dng c vi CH3NH2 ?
A. NaCl.
B. HCl.
C. CH3OH.
D. NaOH.
..............................................................................................................................................................................................
Cu 11 Cht rn khng mu, d tan trong nc, kt tinh iu kin thng l ?
A. C6H5NH2.
B. C2H5OH.
C. H2NCH2COOH.
D. CH3NH2.
Cu 12 Cht tham gia phn ng trng ngng l ?
A. C2H5OH.
B. CH2 = CHCOOH. C. H2NCH2COOH.
D. CH3COOH.
Cu 13 Cho dy cc cht: C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2, C6H5OH. S cht
trong dy tc dng c vi dung dch HCl l ?
A. 4.
B. 2.
C. 3.
D. 5.
Cu 14 chng minh aminoaxit l hp cht lng tnh ta c th dng phn ng ca cht ny ln lt vi ?
A. dung dch KOH v dung dch HCl.
B. dung dch NaOH v dung dch NH3.
C. dung dch HCl v dung dch Na2SO4 .
D. dung dch KOH v CuO.
Cu 15 Cht phn ng c vi cc dung dch: NaOH, HCl l ?
A. C2H6.
B. H2N-CH2-COOH.
C. CH3COOH.
D. C2H5OH.
..............................................................................................................................................................................................
Cu 16 Axit aminoaxetic (H2NCH2COOH) tc dng c vi dung dch ?
A. NaNO3.
B. NaCl.
C. NaOH.
D. Na2SO4.
..............................................................................................................................................................................................
Cu 17 Dung dch ca cht no trong cc cht di y khng lm i mu qu tm ?
A. CH3NH2.
B. NH2CH2COOH
C. HOOCCH2CH2CH(NH2)COOH.
D. CH3COONa.
Cu 18 phn bit 3 dung dch H2NCH2COOH, CH3COOH v C2H5NH2 ch cn dng mt thuc th l ?
A. dung dch NaOH. B. dung dch HCl.
C. natri kim loi.
D. qu tm.
Cu 19 C cc dung dch ring bit sau C6H5-NH3Cl, H2N-CH2-CH2-CH(NH2)-COOH, ClH3N-CH2-COOH, HOOCCH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l ?
A. 2.
B. 5.
C. 4.
D. 3.
Cu 20 Glixin khng tc dng vi ?
A. H2SO4 long.
B. CaCO3.
C. C2H5OH.
D. NaCl.
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

Cu 21 Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phn ng ht vi dung dch HCl. Sau phn ng, khi lng
mui thu c l ? ( Cho H = 1, C = 12, O = 16, Cl = 35, 5 )
A. 43,00 gam.
B. 44,00 gam.
C. 11,05 gam.
D. 11,15 gam.
..............................................................................................................................................................................................
Cu 22 Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phn ng ht vi dung dch NaOH. Sau phn ng, khi
lng mui thu c l ? ( Cho H = 1, C = 12, O = 16, Na = 23 )
A. 9,9 gam.
B. 9,8 gam.
C. 7,9 gam.
D. 9,7 gam.
..............................................................................................................................................................................................
Cu 23 Cho m gam alanin phn ng ht vi dung dch NaOH. Sau phn ng, khi lng mui thu c 11,1 gam.
Gi tr m dng l ? ( Cho H = 1, C = 12, O = 16, Na = 23 )
A. 9,9 gam.
B. 9,8 gam.
C. 8,9 gam.
D. 7,5 gam.
..............................................................................................................................................................................................
Cu 24 Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi
dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l ?
A. H2NC3H6COOH.
B. H2NCH2COOH.
C. H2NC2H4COOH.
D. H2NC4H8COOH.
..............................................................................................................................................................................................
Cu 25 1 mol - amino axit X tc dng va ht vi 1 mol HCl to ra mui Y c hm lng clo l 28,287% Cng
thc cu to ca X l ?
A. CH3-CH(NH2)COOH
B. H2N-CH2-CH2-COOH C. H2N-CH2-COOH
D. H2N-CH2-CH(NH2 )-COOH
..............................................................................................................................................................................................
Cu 26 Khi trng ngng 13,1 g axit - aminocaproic vi hiu sut 80%, ngoi aminoaxit cn d ngi ta thu c m
gam polime v 1,44 g nc. Gi tr m l ?
A. 10,41
B. 9,04
C. 11,02
D. 8,43
..............................................................................................................................................................................................
Cu 27 Este A c iu ch t ancol metylic v amino axit no B (cha mt nhm amino v mt nhm cacboxyl). T
khi hi ca A so vi oxi l 2,78125. Amino axit B l ?
A. axit amino fomic.
B. axit aminoaxetic.
C. axit glutamic.
D. axit -amino propionic.
..............................................................................................................................................................................................
Cu 28 C 0,01 mol aminoaxit (A) phn ng va vi 40 ml dung dch NaOH 0,25M. Mt khc 1,5 gam aminoaxit
(A) phn ng va vi 80 ml dung dch NaOH 0,25M. Khi lng phn t ca A l ?
A. 150.
B. 75.
C. 105.
D. 89.
..............................................................................................................................................................................................
Cu 29 0,01 mol aminoaxit (A) tc dng va vi 50 ml dung dch HCl 0,2M. C cn dung dch sau phn ng c
1,835 gam mui khan. Khi lng phn t ca A l ?
A. 89.
B. 103.
C. 117.
D. 147.
..............................................................................................................................................................................................
Cu 30 Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu
c 15,06 gam mui. Tn gi ca X l ?
A. axit glutamic.
B. valin.
C. alanin.
D. glixin
..............................................................................................................................................................................................
Cu 31 Este A c iu ch t -amino axit v ancol metylic. T khi hi ca A so vi hidro bng 44,5. Cng thc
cu to ca A l ?
A. CH3CH(NH2)COOCH3.
B. H2N-CH2CH2-COOH
C. H2NCH2COOCH3.
D. H2NCH2CH(NH2)COOCH3.
..............................................................................................................................................................................................
Cu 32 A l mt aminoaxit. Cho bit 1 mol A phn ng va vi 1 mol HCl, hm lng clo trong mui thu c
l 19,346%. Cng thc ca A l ?
A. HOOCCH2CH2CH(NH2)COOH
B. HOOCCH2CH2CH2CH(NH2)COOH
C. CH3CH2CH(NH2)COOH
D. CH3CH(NH2)COOH
..............................................................................................................................................................................................
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

Cu 33 Tri peptit l hp cht ?
A. m mi phn t c 3 lin kt peptit.
B. c lin kt peptit m phn t c 3 gc amino axit ging nhau.
C. c lin kt peptit m phn t c 3 gc amino axit khc nhau.
D. c 2 lin kt peptit m phn t c 3 gc -amino axit.
..............................................................................................................................................................................................
Cu 34 C bao nhiu tripeptit m phn t cha 3 gc amino axit khc nhau ?
A. 3 cht.
B. 5 cht.
C. 6 cht.
D. 8 cht.
Cu 35 Trong cc cht di y, cht no l ipeptit ?
A. H2N-CH2-CO-NH-CH2-CH2-COOH.
B. H2N-CH2-CO-NH-CH(CH3)-COOH.
C. H2N-CH2-CO-NH-CH(CH3)-CO-NH-CH2-COOH.
D. H2N-CH(CH3)-CO-NH-CH2-CO-NH-CH(CH3)-COOH
Cu 36 T glyxin (Gly) v alanin (Ala) c th to ra my cht ipeptit ?
A. 1 cht.
B. 2 cht.
C. 3 cht.
D. 4 cht.
Cu 37 S ng phn tripeptit to thnh t 1 phn t glyxin v 2 phn t alanin l ?
A. 2.
B. 3.
C. 5.
D. 4.
Cu 38 S ng phn tripeptit c cha gc ca c glyxin v alanin l ?
A. 6.
B. 3.
C. 5.
D. 4.
Cu 39 Sn phm cui cng ca qu trnh thy phn cc protein n gin nh cht xc tc thch hp l ?
A. -aminoaxit.
B. -aminoaxit.
C. axit cacboxylic.
D. este.
Cu 40 S ng phn ipeptit to thnh t 1 phn t glyxin v 1 phn t alanin l ?
A. 3.
B. 1.
C. 2.
D. 4.
Cu 41 Cho dung dch cha cc cht sau:
(X1) C6H5NH2
(X2)CH3NH2
(X3)H2NCH2COOH;
(X4) HOOCCH2CH2CH(NH2) COOH
(X5) H2NCH2CH2CH2CH2CH (NH2 )COOH.
Dung dch lm qu tm ha xanh l:
A. X1; X2; X5;
B. X2; X3; X4;
C. X2; X5;
D. X1; X5; X4;
Cu 42 C 3 cht hu c : H2N-CH2-COOH; CH3-CH2-COOH v CH3-CH2-CH2-NH2
nhn ra dung dch ca cc hp cht trn, ngi ta ch cn th vi mt cht no trong cc cht sau y
A- NaOH
B- HCl
C- CH3OH/HCl
D- Qu tm
Cu 43 Cho dung dch qu tm vo 2 dd sau : X. H2N-CH2-COOH; Y:HOOC-CH(NH2)-CH2-COOH.
Hin tng xy ra l g?
A. X v Y u khng i mu qu tm.
B. X lm qu chuyn mu xanh, Y lm qu chuyn mu d.
C. X khng i mu qu tm, Y l qu chuyn mu .
D. C hai u lm qu chuyn sang mu .
Cu 44 CTCT ca glyxin l :
A CH3CH(NH2)COOH
B H2NCH2COOH
C H2N(CH2)2COOH
D CH2(OH)CH(OH)CH2(OH)
Cu 45 Cho cc cht: CH3COOH, CH3COOCH3, H2NCH2COOH, CH3CH2NH2. S cht phn ng c vi dung dch
NaOH l :
A 1
B 2
C 4
D 3
Cu 46 Cho qu tm vo 2 dung dch sau:
X: HOOC CH(NH2) CH2 COOH
Y: H2N CH2 COOH.
Hin tng xy ra l:
A X v Y u khng lm i mu qu tm.
B X lm qu tm chuyn mu xanh, Y lm qu tm chuyn mu .
C C 2 u lm qu tm chuyn sang mu .
D X lm qu tm i mu , Y khng lm i mu qu.
Cu 47 Cht khng tc dng vi Cu(OH)2 to sn phm c mu tm l:
A Ala-Gly.
B Ala-Gly-Ala.
C Ala-Gly-Ala -Gly-Ala.
D Gly-Ala -Gly-Ala.
Cu 48 T Ala,Gly, Vla c th to s tri peptit cha c Ala,Gly,Vla l:
A 6
B 12
C 3
D 9.
Cu 49 T Ala,Gly c th to ti a s ipeptit l:
A 5
B 2
C 3
D 4
Cu 50 Cht tc dng vi Cu(OH)2 to sn phm c mu tm l:
A Xenluloz
B peptit
C Tinh bt
D anehit axetic

2011 2012 TRNG THPT NAM SCH II