Cu 58: Hn hp C6H6 v Cl2 c t l mol 1 : 1,5. Trong iu kin c xc tc bt Fe, to, hiu sut 100%.

Sau phn
ng thu c cht g ? bao nhiu mol ?
A.1 mol C6H5Cl ; 1 mol HCl ; 1 mol C6H4Cl2.
B. 1,5 mol C6H5Cl ; 1,5 mol HCl ; 0,5mol C6H4Cl2.
C. 1 mol C6H5Cl ; 1,5 mol HCl ; 0,5 mol C6H4Cl2.
D. 0,5 mol C6H5Cl ; 1,5 mol HCl ; 0,5 mol C6H4Cl2.
Cu 59: Cho 100 ml bezen (d = 0,879 g/ml) tac dung vi mt lng va u brom long (xuc tac bt st, un nong)
thu c 80 ml brombenzen (d = 1,495 g/ml). Hiu sut brom hoa at la
A. 67,6%. B. 73,49%. C. 85,3%. D. 65,35%
Cu 60: Cho benzen vo 1 l ng Cl2 d ri a ra nh sng. Sau khi phn ng xy ra hon ton thu c 5,82 kg
cht sn phm. Tn ca sn phm v khi lng benzen tham gia phn ng l:
A. clobenzen; 1,56 kg. B. hexacloxiclohexan; 1,65 kg.
C. hexacloran; 1,56 kg. D. hexaclobenzen; 6,15 kg.
Cu 62: A la hirocacbon co %C (theo khi lng) la 92,3%. A tac dung vi dung dich brom d cho san phm co
%C (theo khi lng) la 36,36%. Bit MA < 120. Vy A co cng thc phn t la
A. C2H2. B. C4H4. C. C6H6. D. C8H8.
Cu 63: Tin hanh trung hp 10,4 gam stiren c hn hp X gm polistiren va stiren (d). Cho X tac dung vi 200
ml dung dich Br2 0,15M, sau o cho dung KI d vao thy xut hin 1,27 gam iot. Hiu sut trung hp stiren l
A. 60%. B. 75%. C. 80%. D. 83,33%.
Cu 64: hiro ho etylbenzen ta c stiren; trng hp stiren ta c polistiren vi hiu sut chung 80%. Khi
lng etylbenzen cn dng sn xut 10,4 tn polisitren l:
A.13,52 tn. B. 10,6 tn. C. 13,25 tn. D. 8,48 tn.
Cu 65: a. t chy hon ton m gam A (CxHy), thu c m gam H2O. Cng thc nguyn ca A l:
A. (CH)n. B. (C2H3)n. C. (C3H4)n. D. (C4H7)n.
b.t chy hon ton 1,3 gam A (CxHy) to ra 0,9 gam H2O. Cng thc nguyn ca A l:
A. (CH)n. B. (C2H3)n. C. (C3H4)n. D. (C4H7)n.
Cu 66:t chy hon ton hirocacbon X cho CO2 v H2O theo t l mol 1,75 : 1 v th tch. Cho bay hi hon
ton 5,06 gam X thu c mt th tch hi ng bng th tch ca 1,76 gam oxi trong cng iu kin. Nhn xt no
sau y l ng i vi X ?
A. X khng lm mt mu dung dch Br2 nhng lm mt mu dung dch KMnO4 un nng.
B. X tc dng vi dung dch Br2 to kt ta trng.
C. X c th trng hp thnh PS.
D. X tan tt trong nc.
Cu 67: t chy hon ton m gam hirocacbon A, thu c m gam H2O. Cng thc phn t ca A (150 < MA <
170) l:
Cu 71: t chy hon ton hi A (CxHy) thu c 8 lt CO2 v cn dng 10,5 lt oxi. Cng thc phn t ca A l:
A. C7H8. B. C8H10. C. C10H14. D. C9H12.
Cu 73: 1,3 gam cht hu c A chy hon ton thu c 4,4 gam CO2 v 0,9 gam H2O. T khi hi ca A i vi
oxi l d tha mn iu kin 3<d<3,5. Cng thc phn t ca A l:
A. C2H2. B. C8H8. C. C4H4. D. C6H6.
Cu 74: t chay hoan toan mt th tich hi hp cht hu c A cn 10 th tich oxi (o cung iu kin nhit v
p sut), san phm thu c chi gm CO2 va H2O vi mCO2 : mH2O = 44 : 9. Bit MA < 150. A co cng thc
phn t la
A. C4H6O. B. C8H8O. C. C8H8. D. C2H2.
Cu 79: t 0,13 gam mi cht A v B u cng thu c 0,01 mol CO2 v 0,09 gam H2O. T khi hi ca A so
vi B l 3; t khi hi ca B so vi H2 l 13. Cng thc ca A v B ln lt l:
A. C2H2 v C6H6. B. C6H6 v C2H2.
C. C2H2 v C4H4. D. C6H6 v C8H8.
Cu 80: A, B, C la ba cht hu c co %C, %H (theo khi lng) ln lt la 92,3% va 7,7%, ti l khi lng mol
tng ng la 1: 2 : 3. T A co th iu ch B hoc C bng mt phan ng. C khng lam mt mau nc brom. t 0,1
mol B ri dn toan b san phm chay qua binh ng dung dich nc vi trong d.
a. Khi lng binh tng hoc giam bao nhiu gam ?
A. Tng 21,2 gam. B. Tng 40 gam.
C. Giam 18,8 gam. D. Giam 21,2 gam.
b. Khi lng dung dch tng hoc giam bao nhiu gam ?

A. Tng 21,2 gam. B. tng 40 gam.

C. giam 18,8 gam. D. giam 21,2 gam.
giai gjup minh vs nha
Cu 58, c ch cha cht ch.
p n D (bo ton nguyn t, bo ton s mol)
Cu 59: A
m brombenzen/m benzen x M benzen/M brombenzen = 0.676
Cu 60: C
Clo d, c nh sng C6H6 + 3Cl2 ---> C6H6Cl6 (Loi A, D)
m benzen = m C6H6Cl6 x M benzen / M C6H6Cl6 = 1,56 (chn C)
Cu 62:
M sn phm = 12x x 100/36,36 = 33x => x chia ht cho 2 (ci ny ni cho c thi ch p n ton s chia ht cho 2
=.=")
M A = 13x
pi x M brom = 33x - 13x = 20x = 160 x pi (pi l s lin kt pi y)
=> x= 8 x pi
=>stiren
(Ci v dng M tnh ny mi hc lm nn lp lun cha cht lm, mi ngi gp thm nh! )
P/S: phn sau mai nh! (nu cha ai lm :P)
Cu 63: C
n stren = 0,1 mol
n I2 = 1,27/254 = 0,005 mol
=> n Br2 d = 0,005 mol
=> n Br2 phn ng (cng vi stiren)= 0,2x0,15-0,005 = 0,025mol
=> n stiren d = 0,025
=> Hiu sut = (0,1-0,025)/0,1= 75%
Cu 64: C
m polistiren = m stiren
m etylbenzen cn dng = m stiren cn dng x M etylbenzen / M stiren
=> m etylbenzen cn dng = (10,4x100/80) x 106 / 104 = 13,25 tn
Cu 65: B
CxHy -----> y/2 H20
m A = m H2O (cho s mol ca A l 1 th ta c)
=> 12x + y = 9y
=> 3x=2y
=>x/y = 2/3
Cu 66: A
nC : nH = nCO2 : (nH2Ox2) = 7 : 8
=> X: (C7H8)n => M X = 92n
M X = 5,06 : (1,76 : 32) = 92
=> n = 1
X : C7H8
p n B mi thy v ny ln u, p n C th khng thoi CTPT ca X, p n D th sai chc (do X l
hidrocacbon) nn mnh dng loi tr ra c cu A
autumns_gust
Cu 67:
Lm ging nh cu 65 ta s c CTPT: (C2H3)n => M = 27n
150 < 27n < 170 => n=6

=> C12H18
Cu 71: B
t l mol = t l V
nC = nCO2 = 8
nH = 2x nH2O = 2x 2x(10,5-8) = 10
Cu 73: B
A. C2H2. B. C8H8. C. C4H4. D. C6H6.
nC=nCO2=0,1 mol
nH= 2x nH2O=0,1 mol
=> CTPT: (CH)n => M=13n
3x32 < 13n < 3,5x32
=> n =8
huyhoang94
11-04-2011, 17:50
Cu 74: t chay hoan toan mt th tich hi hp cht hu c A cn 10 th tich oxi (o cung iu kin nhit v
p sut), san phm thu c chi gm CO2 va H2O vi mCO2 : mH2O = 44 : 9. Bit MA < 150. A co cng thc
phn t la
gi cng thc chung ca HC l CxHy
CxHyOz+(x+Y/4-Z/2)O2=>xCO2+Y/2H2O
gt=>44x:9y=44:19 <=>x=y
mmt th tich hi hp cht hu c A cn 10 th tich oxi nn trong hp cht c oxi ,ng p n coi c p n B l
tm
death15
Cu 80: dng s % bi cho gii c CTDGN : (CH)_n
\Rightarrow 3 cht : C_2H_2,C_4H_4,C_6H_6
Cht B : C_4H_4 \Rightarrow 4CO_2 + 2H_2O
\Rightarrow khi lng bnh tng : 4.0,1.44 + 2.0,1.18 = 21,2 g -> Chn A
b.
CO_2 + Ca(OH)_2 \Rightarrow CaCO_3 + H_2O
Ta c : m_{Ca(OH)_2} l m dung dch lc u
m dung dch lc sau : m_{H_2O} (lng nc thm vo) + m_{H_2O}
\Rightarrow gim 18,8 g -> chn C
huyhoang94
11-04-2011, 18:22
Cu 79: t 0,13 gam mi cht A v B u cng thu c 0,01 mol CO2 v 0,09 gam H2O. T khi hi ca A so
vi B l 3; t khi hi ca B so vi H2 l 13. Cng thc ca A v B ln lt
qt=>MB=26(u)=>Ma=78(u)
v mc+mh=0,13=>o oxi
v Ma=>12x+y=78<=>y=78=12x
m y<=2x+2=>x>=5.4=>ch c x=6 ,y=6 l tm =>C6H6 (A)
TT i vi Mb ta c x=y=2 =>C2H2(B)
=>n B
autumns_gust
11-04-2011, 22:31
Cu 74: t chy hon ton mt th tch hi hp cht hu c A cn 10 th tch oxi (o cng iu kin nhit v
p sut), sn phm thu c ch gm CO2 v H2O vi mCO2 : mH2O = 44 : 9. Bit MA < 150. A c cng thc
phn t l
gi cng thc chung ca HC l CxHy

CxHyOz+(x+Y/4-Z/2)O2=>xCO2+Y/2H2O
gt=>44x:9y=44:19 <=>x=y
mmt th tch hi hp cht hu c A cn 10 th tch oxi nn trong hp cht c oxi ,ng p n coi c p n B l
tm
Mnh c cht thc mc, bn c th gii thch r hn v sao t thng tin cn 10 th tch oxi th c th kt lun A c
oxi khng?
Mnh th sao khi tm c t l x v y mnh lm tip th ny.
CxHxOz + (x+x/4-z/2) O2 -----> x CO2 + x/2 H2O
...... 1 .............. 10
=> (x+x/4 - z/2)=10 <=> 5x - 2z = 40
Do Hp cht ch c C,H (c th c hoc khng c O) nn x chia ht cho 2, mnh ch xt cc gi tr chn (nu nh
lm kiu t lun, cn trc nghim th tt nhin xt x=8 trc, nu c th chn, khng th chn cu D).
x=2 => z=15
x=4 => z=10
x=6 => z=5
x=8 => z=0
Ng p n th chn cu C.
ndquan1994
13-04-2011, 20:46
63: C
n stren = 0,1 mol
n I2 = 1,27/254 = 0,005 mol
=> n Br2 d = 0,005 mol
=> n Br2 phn ng (cng vi stiren)= 0,2x0,15-0,005 = 0,025mol
=> n stiren d = 0,025
=> Hiu sut = (0,1-0,025)/0,1= 75%
64: C
m polistiren = m stiren
m etylbenzen cn dng = m stiren cn dng x M etylbenzen / M stiren
=> m etylbenzen cn dng = (10,4x100/80) x 106 / 104 = 13,25 tn