ANCOL PHENOL

Cu 1. Sn phm chnh ca phn ng tch nc ca 2-metylpentan-3-ol l:

A. 4-metylpent-2-en.
B. 4-metylpent-3-en.
C. 2-metylpent-3-en.
D. 2-metylpent-2-en.
Cu 2. X c cng thc phn t l C4H10O. X tch nc cho 3 anken ng phn. X l:
A. Butan-2-ol.
B. Ancol isobutylic.
C. Ancol butylic.
D. metylpropan-1-ol.
Cu 3. S cht ng phn c cng cng thc phn t C4H10O tha mn tnh cht: tch nc thu c anken, khi
oxi ha c xc tc thu c sn phm c kh nng tham gia phn ng trng bc l:
A. 2.
B. 3.
C. 4.
D. 1.
Cu 4. un nng ancol X vi H2SO4 c 170oC, ch thu c 1 anken duy nht. Cng thc cu to ca X l:
A. CH3-CH(CH3)CH2-OH.
B. CH3-CH(OH)-CH2-CH3.
C. CH3-CH2-CHOH-CH(CH3)2.
D. C6H5-CH2-CH2-OH.
Cu 5. Cht no sau y khi b oxi ha ( c xc tc) to ra anehit:
A. CH3CHOHCH3.
B. (CH3)3COH.
C. CH3CH2OCH3.
D. CH3CH2CH2OH.
Cu 6. Cho dy chuyn ha sau:
Y l sn phm chnh ca phn ng, cng thc cu to ca X, Y ln lt l:
A. CH3-CH2-CH2-CH2OH; CH3-CH=CH-CH3.
B. CH3-CH(CH3)-CH2OH; CH3-CH=CH-CH3.
C. CH3-CHOH-CH2-CH3; CH3-CH=CH-CH3.
D. CH3-CHOH-CH2-CH3; CH2=CH-CH2-CH3.
Cu 7. Ancol no di y thuc dy ng ng c cng thc chung CnH2nO:
A. CH3CH2OH.
B. CH2=CH-CH2OH.
C. C6H5CH2OH.
D. CH2OH-CH2OH.
Cu 8. phn bit: etylbenzen, xiclopropaan, o-crosol v phenol ngi ta c th dng thuc th:
A. dd Br2 d v dd HNO3.
B. dd KMnO4 v Na.
C. dd Br2 d v Na.
D. dd Br2 v Cu(OH)2.
Cu 9. phn bit cc cht: NH4HCO3, C6H5ONa, C3H7OH, C6H6 c th dng thuc th:
A. dd Br2.
B. dd NaOH.
C. dd HCl.
D. Nc.
Cu 10. C 4 l mt nhn ng: etilen glycol, phenol, stieren, etanol. nhn bit 4 l trn c th dng:
A. dd NaOH v Na.
B. Na v Cu(OH)2.
C. dd Br2 v Cu(OH)2.
D. dd Br2 v Na.
Cu 11. Cng thc tng qut ca ancol no, mch h, n chc, bc I l:
A. R-CH2OH.
B. CnH2n+1OH.
C. CnH2n+1CH2OH.
D. CnH2n+2O.
Cu 12 t chy ancol X, thu c s mol H2O ln hn s mol CO2. X l ancol:
A. No, mch h.
B. No, n chc, mch h.
C. Khng no, mch h.
D. No, a chc.
Cu 13. Ancol no sau y c sai tn:
A. 2-metylhexan-1-ol
CH3-CH2-CH2-CH2-CH(CH3)-CH2-OH.
B. 4,4-imetylpentan-2-ol
CH3-C(CH3)2-CH(OH)-CH3.
C. 3-etylbutan-2-ol
CH3-CH(C2H5)-CH(OH)-CH3.
D. 3-metylpentan-2-ol
CH3-CH2-CH(CH3)-CH(OH)-CH3.
Cu 14. Cho cc hp cht sau: HO-CH2-CH2OH (1); HO-CH2-CHOH-CH2OH (2); HO-CH2-CH2-CH2OH (3);
HO-CH2-CHOH-CH3 (4); HO-CH2-CH2-CHOH-CH2OH (5);
HO-CH2-CH2-CHOH-CH2-CH2OH (6).
Cht to c vi Cu(OH)2 phc mu xanh l:
A. (1), (2), (3), (4).
B. (1), (2), (4), (5), (6).
C. (1), (2), (5), (4).
D. (1), (2), (4).
Cu 15. Dy cc cht u phn ng c vi C2H5OH l:
A. K, HBr, dd Br2, HCOOH, CuO, O2.
B. K, NaOH, dd Br2, CuO, O2, C2H5OH.
C. Na, HBr, CH3COOH, CuO, O2, CH3OH.
D. Na, HCl, CuO, O2, C2H5OH, dd Br2.
Cu 16. X c cng thc phn t C4H10O. X tch nc cho 2 anken ng phn. X l:
A. Butan-2-ol.
B. Ancol isobutylic.
C. Ancol butylic.
D. metylpropan-1-ol.
Cu 17. A, B c cng cng thc phn t C3H8O. A tc dng vi Na, khi b oxi ha khng hon ton thu c sn
phm tham gia phn ng trng bc. B khng tc dng vi Na. A, B ln lt l:
A. Propan-2-ol v etyl metyl ete.
B. Propan-1-ol v etyl metyl ete.
C. Propan-2-ol v ietyl ete.
D. Propan-1-ol v ietyl ete.
Cu 18. Mt ancol no, mch h c cng thc thc nghim (C2H5O)n. Vy CTPT ca ancol l:
A. C6H15O3.
B. C4H10O2.
C. C4H10O.
D. C6H14O2.
Cu 19. Cht no sau y khng nn dng lm khan ancol:
A. H2SO4 c.
B. CaO mi nung.
C. CuSO4 khan.
D. P2O5 rn.
o
Cu 20. un nng mt ancol A vi H2SO4 m c 170 C ch thu c mt olefin duy nht. Cng thc tng
qut ca ancol A l:

A. CnH2n+1CH2OH.
B. CnH2n+1OH.
C. CnH2nO.
D. CnH2n-1CH2OH.
Cu 21. Trong s cc phng php iu ch ancol etylic sau y, phng php no ch dng trong phng th
nghim:
A. un nng anken vi nc c xc tc thch hp.
B. un nng dn xut halogen vi dung dch kim.
C. Ln men glucozo c xc tc.
D. Hidro ha anehit.
Cu 22. C bao nhiu ng phn c cng cng thc phn t l C5H10 khi cng nc cho sn phm l ancol bc 3:
A. 6.
B. 2.
C. 4.
D. 3.
Cu 23. C cc cht hu c: C2H5Cl; C2H5OH; n-C4H9OH; CH3OCH3. Cht tan tt nht trong nc l:
A. C2H5Cl.
B. C2H5OH.
C. CH3OCH3.
D. n-C4H9OH.
Cu 24. X l mt dn xut ca benzen, khng phn ng vi dung dch NaOH, c cng thc phn t C 7H8O. S
ng phn ph hp ca X l:
A. 2.
B. 3.
C. 4.
D. 5.
Cu 25 Cht hu c X c cng thc phn t C6H6O2. Bit X l hp cht thm v c tc dng vi KOH theo t l
mol 1:2. S ng phn cu to ca X l:
A. 1.
B. 2.
C. 3.
D. 4.
Cu 26. Trong s cc dn xut ca benzene c cng thc phn t C8H10O. C bao nhiu ng phn (X) tha mn:
(X) + NaOH Khng phn ng.
A. 1.
B. 2.
C. 3.
Cu 27. Cho dy chuyn ha: A1 A2 A3 n-C3H7OH.

D. 4.

Bit A2, A3 u l sn phm chnh ca cc phn ng. Cng thc cu to ca A1, A2, A3 ln lt l:
A. CHC-CH3; CH3-CH2-CH3; CH2=CH-CH3.
B. CH3-CH2-CH3; CH2=CH-CH3; CH2=CH-CH2Cl.
C. CH2=CH-CH3; CH2=CH-CH2Cl; CH2=CH-CH2OH.
D. CH2=CH-CH3; CHC-CH3; CH3-CH2-CHO.
Cu 28. Cho dy chuyn ha sau: C3H8 A B CH3-CH(OH)-CH3.
Bit B l sn phm chnh ca phn ng. Cng thc cu to ca A, B ln lt l:
A. CH2=CH-CH3; CH3-CH2-CH2Cl.
B. C2H2; CH2=CH-CH3.
C. (CH3COO)2Ca; CH3-CO-CH3.
D. CH2=CH-CH3; CH3-CHCl-CH3.
Cu 29. Cht hu c A c cng thc phn t l C3H8O2. A c cc tnh cht: Tc dng vi Na gii phng hidro.
Ha tan c Cu(OH)2 to dung dch c mu xanh thm. A c cng thc cu to l:
A. CH3-CH2-CH(OH)2.
B. CH2OH-CH2-CH2OH.
C. CH3-CHOH-CH2OH.
D. CH3-CH2-COOH.
Cu 30. Cho dy chuyn ha sau: C3H8 X Y Z glixerin.
X, Y, Z u l sn phm chnh ca cc phn ng. Cng thc cu to ca X, Y, Z ln lt l:
A. CH2=CH-CH3; CH3-CH2-CH2Cl; CH2Cl-CHCl-CH2OH.
B. CHC-CH3; CH3-CO-CH3; CH3-CHOH-CH3.
C. CH2=CH-CH3; CH3-CH2-CH2Cl; CH2Cl-CHOH-CH2Cl.
D. C2H2; CH2=CH-CH3; CH2Cl-CHCl-CH2Cl.
Cu 31. Ch dng cc cht no di y phn bit 2 ancol ng phn c cng CTPT l C3H7OH?
A. Na v H2SO4 c.
B. Na v CuO.
C. CuO v dung dch AgNO3/NH3.
D. Na v dung dch AgNO3/NH3.
Cu 32. Ch dng ho cht no sau y phn bit hai ng phn khc chc c CTPT l C3H8O?
A. Al.
B. Cu(OH)2.
C. CuO.
D. dd AgNO3/NH3.
Cau 33. Sn phm chnh khi tch nc t ancol 3-metyl butan-2-ol l:

A. 2-metyl but-1-en

B. 2-metyl-but-2-en

C. 3-metyl but-1-en

D. 3-metyl-but-2-en

Cu 34. Ancol no, a chc X c cng thc n gin nht l C2H5O. X c CTPT l
A. C4H10O2.
B. C6H15O3.
C. C2H5O.
D. C8H20O4.
0
Cu 35. Khi un nng CH3CH2CH(OH)CH3 (butan-2-ol ) vi H2SO4 c, 170 C th thu c sn phm chnh l
A. but-1-en.
B. but-2-en.
C. ietyl ete.
D. butanal.
Cu 36. Cho cc ancol sau: CH3-CH2-CH2-OH (1); (CH3)2CH-OH (2);
CH3-CH(OH)-CH2-OH (3); CH3-CH(OH)-C(CH3)3 (4). Dy gm cc ancol khi tch nc ch cho mt olefin duy
nht l
A. (1), (2).
B. (1), (2), (3).
C. (1), (2), (4). D. (2), (3).
Cu 37. Khi cho etanol i qua hn hp oxit ZnO v MgO 4500C th thu c sn phm chnh c cng thc l
A. C2H5OC2H5.
B. CH2=CH-CH=CH2.
C. CH2=CH-CH2-CH3.
D. CH2=CH2.

Cu 32 Cht hu c X mch h, c cng thc phn t C4H8O. X tc dng c vi Na gii phng hidro; X lm
mt mu dung dch brom; tn ca X bt u bng ch trans. Cng thc cu to ca X l:
A. CH3-CH=CH-CH2OH.
B. CH2=CH-CH2-CH2OH.
C. CH3-CH(CH3)-CH2OH.
D. CH3-CH2-CH=CHOH.
Cu 33. iu ch C2H4 ngi ta un nng C2H5OH vi axit H2SO4 c 170oC. Hiu sut ca phn ng t
60%. Khi lng ring ca etylic bng 0,8 gam/ml. thu c 13,44 lt ( ktc) C2H4 th th thch ancol 95o cn
l:
A. 57,5 ml.
B. 60,53 ml.
C. 36,32 ml.
D. 34,50 ml.
Cu 34. Cho 1,24 gam hn hp 2 ancol n chc tc dng va vi Na, thy thot ra 336 ml kh H2 ( ktc) v m
gam mui natri. m c gi tr bng:
A. 1,93 gam.
B. 2,93 gam.
C. 1,90 gam.
D. 1,47 gam.
Cu 35. X, Y l 2 ancol no n chc, mch h k tip nhau trong dy ng ng. Cho hn hp gm 1,6 gam X v
2,8 gam Y tc dng ht vi Na thu c 1,12 lt H2 ktc. X, Y c cng thc phn t ln lt l:
A. CH3OH , C2H5OH.
B. C2H5OH , C3H7OH.
C. C3H7OH, C4H9OH.
D. C4H9OH, C5H11OH.
Cu 36. Hn hp X gm 2 ancol no, n chc, mch h. Chia mt lng X thnh 2 phn bng nhau. t chy
hon ton phn 1 thu c 0,2 mol CO2. Tch nc hon ton phn 2, thu c hn hp Y ch gm 2 anken. t
chy hon ton hn hp Y thu c m gam nc. m c gi tr bng:
A. 1,8 gam.
B. 3,6 gam.
C. 2,7 gam.
D. 8,8 gam.
Cu 37 t chy hon ton mt ancol n chc A thu c 8,8 gam CO2 v 7,2 gam H2O. Cng thc phn t ca
A l: A. C2H5OH.
B. C3H5OH.
C. C3H7OH.
D. CH3OH.
Cu 38 Trong sn xut, iu ch ru vang, ngi ta ln men glucozo c trong nc qu nho. Phn ng ln
men glucozo iu ch ancol etylic t hiu sut 90%. Bit ancol etylic nguyn cht c khi lng ring 0,80
g/ml. Khi lng glucozo cn iu ch 100 lt ru vang 9,2o l:
A. 14,40 kg.
B. 16,00 kg.
C. 1,600 kg.
D. 1,440 kg.
Cu 39 Mt ancol n chc A tc dng vi HBr cho hp cht B cha 58,40% Br v khi lng. Mt khc nu un
nng A vi H2SO4 c 170oC thu c hn hp 3 anken. Cng thc cu to ca A l:
A. CH3-CHOH-CH2-CH3.
B. CH3-CH2-CH2-CH2OH.
C. CH3-CHOH-CH3.
D. CH3-CH(CH3)-CH2OH.
Cu 40. t chy hon ton mt lng hn hp hai ancol n chc ( X, Y) k tip nhau trong dy ng ng thu
c 4,48 lt CO2 ( ktc) v 4,95 gam H2O. Bit rng khi oxi ha hon ton X, Y thu c sn phm u c kh
nng tham gia phn ng trng bc. Cng thc cu to ca X, Y l:
A. C2H5OH, C3H7OH. B. C2H5OH, i-C3H7OH.
C. C3H7OH, C4H9OH.
D. CH3OH, C2H5OH.
Cu 41. iu ch C2H4 ngi ta un nng C2H5OH vi axit H2SO4 c 170oC. Hiu sut ca phn ng t
60%. Khi lng ring ca etylic bng 0,8 gam/ml. thu c 13,44 lt ( ktc) C2H4 th th thch ancol 95o cn
l:
A. 57,5 ml.
B. 60,53 ml.
C. 36,32 ml.
D. 34,50 ml.
Cu 42 Hp cht B cha C, H, O c cng thc phn t trng vi cng thc n gin. Khi phn tch a gam B, thy
tng khi lng C v H trong l 0,46 gam. t chy hon ton a gam B cn 0,896 lt oxi ( ktc). Cho ton
b sn phm chy qua bnh ng dung dch NaOH d, thy khi lng bnh tng 1,9 gam. B c cng thc phn t
l:
A. C2H6O.
B. C6H6O2.
C. C7H8O2.
D. C4H8O2.
Cu 43. Ti mt nh my ancol, ngi ta dng khoai ty cha 20% tinh bt sn xut ancol etylic. Cn phi
dng bao nhiu tn khoai ty thu c 1 tn ancol, bit s hao ht trong sn xut l 15%.
A. 10,358 tn.
B. 2,0716 tn.
C. 1,7609 tn.
D. 7,484 tn.
Cu 44. C 4 cht sau: (X) C6H5OH ; (Y) C6H5-CH2OH ; (Z) C6H5-CH =CH2 ; (T) CH2= CH-CH2-OH.

Khi cho 4 cht trn tc dng vi Na, dd NaOH, dd nc brom, th pht biu no sau y l ng:
A. (X), (Y), (Z), (T) u tc dng vi Na
B. (X), (Z), (T) u tc dng vi nc brom
C. (X), (Y) tc dng vi NaOH.
D. (Z), (T) tc dng c c Na v nc brom
Cu 45. t chy hon ton 1,08 gam hp cht hu c X thu c 0,72 gam nc. Dn ton b lng kh
CO2 thu c vo dung dch Ca(OH)2 0,02M thy to thnh 3 gam kt ta. Lc b ta, un dung dch
nc lc ta thu c 2 gam kt ta na. Bit trong phn t X ch cha mt nguyn t oxi.
a) Vy CTPT ca X l:
A. C2H6O
B. C6H6O
C. C6H5O
D. C7H8O
b) Th tch dung dch Ca(OH)2 0,02M l:
A. 2,24 lt
B. 1,5 lt
C. 2,5 lt
D. 2,55 lt

Cu 46. Cho 31 gam hn hp 2 phenol A, B lin tip trong cng dy ng ng ca phenol n chc tc
dng va vi 0,5 lt dung dch NaOH 0,6M. Xc nh CTPT ca 2 phenol v % khi lng hn hp.
A. C6H5OH 30,32% v CH3-C6H4OH 69,68%
B. CH3-C6H4OH 30,32% v C2H5-C6H4OH 69,68%
C. C6H5OH 69,68% v CH3-C6H4OH 30,32%
D. CH3-C6H4OH 69,68% v C2H5-C6H4OH 30,32%
Cu 47. Ha tan hon ton 16 gam ancol etylic vo nc c 250 ml dung dch , cho bit khi lng
ring ca ancol etylic nguyn cht l 0,8 g/ml. Dung dch ancol c l:
A. 80
B. 5,120
C. 6,40
D. 120
Cu 48: Cht X c CTPT C7H8O2
- Khi cho 0,62g X tc dng ht vi Na thu c V lt hiro- ktc
- Khi cho 0,62g X tc dng va ht vi dung dch NaOH 0,1M th s mol NaOH cn dng bng s
mol hiro thot ra trn v cng bng s mol X tham gia phn ng
a. Tm CTCT c th c ca X?
b. Tnh V v th tch NaOH dng
Cu 49: Mt hn hp X gm phenol v 2 ancol no n chc (s ngt cacbon trong hai ancol gp i
nhau). Chia 15,7 gam hn hp X thnh hai phn bng nhau:
- phn 1: cho phn ng vi Na d thu c 2,218 lit H2 (27oC v 740mmHg).
- phn 2: phn ng va vi 50ml ddNaOH 0,5M.
Xc nh CTPT ca hai ancol trong hh X ?
A. CH3OH v C2H5OH
B.C2H5OH v C4H9OH
C. C3H7OH v C6H13OH
D.C2H5OH v C4H7OH
Cu 50: Mt ancol no a chc X mch h c n nguyn t cacbon v m nhm hiroxyl trong phn t. Cho
7,6g X phn ng vi Na (d) thu c 2,24 lt kh bay ra ( ktc). Biu thc lin h gia n v m l :
A. 7m + 1 = 11n.
B. 7m = 11n + 1.
C. 7n + 1 = 11m.
D. 7n = 11m +
1.
Cu 51:t chy hon ton hn hp X gm 2 ancol n chc no k nhau trong dy ng ng th thy t
l s mol CO2 v s mol H2O sinh ra ln lt l 9: 13. Phn trm s mol ca mi ancol trong hn hp X
(theo th t ancol c s cacbon nh, ancol c s cacbon ln) l:
A. 40% , 60%
B. 75% , 25%
C. 25% , 75%
D. p s khc.