Bi s 1.

Hp cht cha nhm chc

1. Mt anehit no X mch h, khng phn nhnh, c cng thc thc nghim l (C2H3O)n. Cng thc cu to thu gn ca
X l :
A. OHC-CHO. B. OHC-CH2-CHO. C. OHC-(CH2)2-CHO. D. OHC-(CH2)3-CHO.
2. Cht X c cng thc phn t C4H8O2 khi tc dng vi dung dch NaOH sinh ra cht Y c cng thc C4H7O2Na. X
thuc loi cht no sau y?
A. Axit. B. Anehit. C. Este. D. Ancol.
3. Mt este c cng thc phn t l C3H6O2, c phn ng trng gng vi dung dch Ag2O trong NH3. Cng thc cu
to ca este l cng thc no?
A. HCOOC2H5. B. HCOOC3H7. C. CH3COOCH3. D. C2H5COOCH3.
4. Cho cc cht sau: C2H5OH, CH3COOH, C6H5OH, C2H5ONa, CH3COONa, C6H5ONa. Trong cc cht , s cp cht
phn ng c vi nhau l
A. 2. B. 3. C. 4. D. 5.
5. Axit fomic c th tc dng vi tt c cc cht trong dy no sau y?
A. Mg, Cu, dung dch NH3, NaHCO3. B. Mg, Ag, CH3OH/H2SO4 c nng.
C. Mg, dung dch NH3, dung dch NaCl. D. Mg, dung dch NH3, NaHCO3.
6. Ch dng mt ho cht no di y phn bit hai bnh mt nhn cha kh C2H2 v HCHO?
A. dung dch Ag2O/NH3. B. dung dch NaOH. C. dung dch Br2. D. Cu(OH)2.
7. C ba cht lng khng m ng trong 3 l mt nhn l ru etylic, phenol, axit fomic. nhn bit 3 cht lng trn c
th dng cc thuc th no di y?
A. Qu tm v dung dch brom. B. Dung dch NaHCO3 v Na.
C. Qu tm v dung dch NaHCO3. D. Cu(OH)2 v Na.
8. Cho s sau: X Y Z T G (axit acrylic).
Cc cht X v Z c th l nhng cht c ghi dy no sau y?
A. C3H8 v CH3-CH2-CH2-OH. B. C2H6 v CH2=CH-CHO.
C. C3H6 v CH2=CH-CHO. D. C3H6 v CH2=CH-CH2-OH.
9. Cho glixerol (glixerin) tc dng vi hn hp 3 axit bo gm: C17H35COOH, C17H33COOH v C17H31COOH th c th
to ra ti a bao nhiu este 3 ln este?
A. 9. B. 15. C. 12. D. 18.
10. Hy sp xp cc axit sau: (1) CH2Cl COOH, (2) CH3COOH, (3) CHCl2 COOH, (4) CH2Br COOH, (5) CCl3
COOH theo th t tng dn tnh axit:
A. (2) < (4) < (1) < (5) < (3). B. (2) < (1) < (4) < (3) < (5).
C. (2) < (4) < (1) < (3) < (5). D. (5) < (3) < (1) < (4) < (2).
11. Este X c cng thc phn t C5H10O2. X phng ha E thu c 1 ancol khng b oxi ha bi CuO. Tn ca X:
A. isopropyl axetat. B. tert-butyl fomiat. C. isobutyl fomiat. D. propyl axetat.
12. Mt este c CTPT l C4H6O2, khi thu phn trong mi trng axit thu c axetanhit, cng thc cu to thu gn
ca este l:
A. CH3COO-CH=CH2. B. HCOO-C(CH3)=CH2.
C. HCOO-CH=CH-CH3. D. CH2=CH-COO-CH3.
13. Hp cht hu c C4H7O2Cl khi thu phn trong mi trng kim c cc sn phm trong c hai cht c kh
nng tham gia phn ng trng gng. Cng thc cu to ca cht hu c l:
A. HCOO-CH2-CHCl-CH3. B. CH3-COO-CH2-CH2Cl.
C. HCOOCHCl-CH2-CH3. D. HCOOC(CH3)Cl-CH3.
14. Xt cc axit c cng thc cho sau:
1) CH3-CHCl-CHCl-COOH 2) CH2Cl -CH2-CHCl-COOH
3) CHCl2-CH2-CH2-COOH 4) CH3 -CH2-CCl2-COOH
Th t tng dn tnh axit l:
A. (1), (2), (3), (4). B. (2), (3), (4), (1). C. (3), (2), (1), (4). D. (4), (2), (1), (3).
15. Cht hu c (A) cha C, H, O. Bit rng (A) tc dng c vi dung dch NaOH, c cn c cht rn (B) v hn
hp hi (C), t (C) chng ct c (D), (D) tham gia phn ng trng gng cho sn phm (E), (E) tc dng vi NaOH
li thu c (B). Cng thc cu to ca (A) l:
A. HCOOCH2-CH=CH2. B. HCOOCH=CH-CH3. C. HCOOC(CH3)=CH2. D. CH3COOCH=CH2.

+Cl2, t
o
+H2O, OH

+CuO, t
o
+Ag2O, NH3
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16. Khi thu phn cc cht CH3COOCH=CH2, CH3CH2COOCH3, HCOOCH3 trong dung dch NaOH th cht cho hn hp
c mui v ru l:
A. CH3COO-CH=CH2 B. CH3COO-CH=CH2, CH3CH2COOCH3, HCOOCH3
C. HCOOCH3 D. CH3CH2COOCH3, HCOOCH3
17. Xt cc phn ng:
(1) CH3COOH + CaCO3 (3) C17H35COONa + H2SO4
(2) CH3COOH + NaCl (4) C17H35COONa + Ca(HCO3)2
Phn ng no khng xy ra c:
A. (1) v (2) B. (3) v (4) C. (2) D. (2) v (4)
18. Dy gm cc cht c sp xp theo chiu tng dn ca tnh axit l
A. C2H5OH < C6H5OH< CH2= CHCOOH < HCOOH < CH3COOH .
B. C2H5OH < C6H5OH< CH3COOH < HCOOH < CH2= CHCOOH .
C. C2H5OH < C6H5OH< HCOOH < CH3 COOH < CH2=CHCOOH .
D. CH3COOH < C6H5OH<C2H5OH < CH2= CHCOOH < HCOOH .
19. T Glixerol (Glixerin) s phng trnh phn ng ti thiu iu ch Axit acrilic (CH2=CH-COOH) l
A. 2 phng trnh. B. 3 phng trnh. C. 4 phng trnh D. 5 phng trnh
20. Cho s : C2H2 X Y CH3COOH. Trong cc cht: C2H6, C2H4, CH3CHO,
CH3COOCH=CH2, s cht ph hp vi cht X trong s trn l
A. 4. B. 3. C. 2. D. 1.
21. Cho cc cht CH3-CHO, CH2=CH-COOH, CH3 -CO-CH3, CH2=CH-CH2-OH. S cht lm mt mu nu ca dung
dch nc brom l
A. 1 B. 2 C. 3 D. 4
22. Cho cc cht : anhit axetic, axit fomic, ru etylic, dimetyl ete v cc nhit si : 100,7
0
C ; 21
0
C ; - 23
0
C ;
78,3
0
C. Dy no sau y xp nhit si ng vi mi cht ?
A. Anhit axetic: 21
0
C ; Axit fomic: 100,7
0
C ; Ru etylic: 78,3
0
C ; imetyl ete: - 23
0
C
B. Anhit axetic: - 23
0
C ; Axit fomic: 100,7
0
C ; Ru etylic: 78,3
0
C ; imetyl ete: 21
0
C
C. Anhit axetic: 78,3
0
C ; Axit fomic: - 23
0
C ; Ru etylic: 21
0
C ; imetyl ete: 100,7
0
C
D. Anhit axetic: 100,7
0
C ; Axit fomic: 21
0
C ; Ru etylic: - 23
0
C ; imetyl ete: 78,3
0
C
23. Cc este c cng thc C4H6O2 c to ra t axit v ru tng ng l :
A.CH2=CH-COO-CH3;CH3COO-CH=CH2;H-COO-CH2-CH=CH2;H-COO-CH=CH-CH3;H-COO-C(CH3)=CH2
B. CH2=CH-COO-CH3 ; CH3COO-CH=CH2 ; H-COO-CH2-CH=CH2
C. CH2=CH-COO-CH3 ; H-COO-CH2-CH=CH2
D. CH2=CH-COO-CH3 ; CH3COO-CH=CH2 ; H-COO-CH2-CH= CH2 ; H-COO-CH=CH-CH3
24. Hirocacbon X phn ng trc tip to ra mt s sn phm theo s :

CH3 CH = O
|
CH3-CH3 X CH3 CHBr2
+
CH2 =CH Cl
X l hirocacbon no sau y ?
A. C4H10 B. C2H4 C. C2H6 D. C2H2
25.
X + CH3COOH
tac xuc
X1
X1

+ OH O H ,
2
Y1 + Y2
Y2+ H2SO4 CH3COOH + ?
Y2+ Ag2O Ag + ?
Vy X l :
A. CH3OH B. C2H5OH C. CH CH D. CH2 = CH2




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Bi s 2. Hp cht cha nhm chc
26. Hai este A, B l dn xut ca benzen c cng thc phn t C9H8O2 ; A v B u cng hp vi brom theo t l mol l
1 : 1. A tc dng vi xt cho mt mui v mt andehit, B tc dng vi xt d cho 2 mui v nc, cc mui c khi
lng phn t ln hn khi lng phn t ca natri axetat. Cng thc cu to ca A v B c th l :
A. HOOC C6H4 CH = CH2 v CH2 = CH COO- C6H5.
B. C6H5 COO CH = CH2 v C6H5 CH = CH COOH
C. HCOO C6H4 CH = CH2 v HCOO CH =CH -C6H5
D. C6H5 COO CH = CH2 v CH2 = CH COO C6H5
27. Cho cc phn ng sau :
(X) + NaOH d
o
t
(Y) + (Z) + 2NaCl + H2O (Y) + NaOH
o
t
CH3OH + Na2CO3
( Z) + HCl HCOOH + NaCl
Cho bit (X) khng c phn ng trng gng, s mol ca (X), (Y), (Z) bng nhau. X, Y v Z c th l
A. Cl- CH2 COO CHCl OH; HO-CH2 COONa v HCOONa
B. Cl- CH2 COO CHCl OH; CH3 COONa v HCOONa
C. CH3COO CH2 OH; NaOOC CH2 COONa v CH3COONa
D. Cl- CH2 OOC CH2 OH ; HO-CH2 OOCCH3; CH3COONa
28. Xc nh cng thc cu to cc cht A2, A3, A4 theo s bin ho nh sau
C4H8O2 A2 A3 A4 C2H6.
A. C2H5OH; CH3COOH v CH3COONa B. C3H7OH ; C2H5COOH v C2H5COONa
C. C4H9OH; C3H7COOH v C3H7COONa D. C B v C ng
29. tch CH3CHO ra khi hn hp gm CH3CHO, CH3COOH, C2H5OH ngi ta c th dng cc ho cht no sau
y:
A. NaHSO3 v HCl B. AgNO3 trong NH3 C. NaOH v HCl D. AgNO3 /NH3 v HCl
30. Este to bi ru no n chc v axit khng no n chc (c 1 lin kt i C = C) c CTTQ l
A. CnH2n 2O2 ( n > 2). B. CnH2n 2O2 ( n > 4). C. CnH2n 2O2 ( n > 3). D. CnH2nO2 ( n > 4).
31. Trong cc cht hu c c thnh phn C, H, O, trong phn t cha hai nguyn t cacbon, cht c lc axit ln nht l
A. HOCH2COOH B. HOOC COOH C. CH3COOH. D. HOCH2CH2OH.
32. C s sau :
X1
X CH3CHO.
X2
Cc k hiu X , X1 , X2 tng ng vi cc cht
A. CH CH ; CH2 = CHCl ; CH3 CHCl2 B. CH CH ; CH2 = CCl2 ; CH2 = CH2
C. CH CH ; C2H6 ; CH2 = CHOOC CH3 D. CH CH ; CH2 = CHOOC H ; CH2 = CH C CH
33. Cho s : X Y CH3COOH. Vi X l cht hu c c C, H hoc c c O hoc halogen vi s nguyn t cacbon
s
2 ; Y l cht hu c. C bao nhiu cch thc hin s trn ?
A. 4 B. 5 C. 6 D. 7
35. X c cng thc phn t l C7H8O2. Cho a mol X tc dng vi Na d thu c a mol H2. Cho a/2 mol X tc dng vi
a mol NaOH th va ng. Cng thc cu to ca X c th l:
A. HO-C6H4-CH2OH. B. HO-C6H3(CH3)OH. C. HO-C6H3(CH2OH)2. D. (HO)2C6H2(CH2OH)2.
36. t chy hon ton mt ete n chc thu c H2O v CO2 theo t l s mol 4 : 3. Ete ny c th iu ch t ru
no di y bng mt phn ng ho hc?
A. CH3OH v CH3CH2CH2OH. B. CH3OH v CH3CH(CH3)OH.
C. CH3OH v CH3CH2OH. D. C2H5OH v CH3CH2CH2OH.
37. t chy 14,6 gam mt axit cacboxylic no, a chc mch h, khng phn nhnh thu c 0,6 mol CO2 v 0,5 mol
H2O. Cng thc cu to thu gn ca axit l:
A. HOOC-CH2-COOH. B. HOOC-CH2-CH2-COOH. C. HOOC-(CH2)3-COOH. D. HOOC-(CH2)4-COOH.
38. Cho 15,0 gam mt axit cacboxylic no, n chc X tc dng vi 150 ml dung dch NaOH 2M, sau phn ng, c cn
dung dch thu c 22,5 gam cht rn khan. Cng thc cu to thu gn ca X l:
A. CH3COOH. B. C2H5COOH. C. C3H7COOH. D. HCOOH.
39. Chia 0,6 mol hn hp hai axit hu c no thnh 2 phn bng nhau. Phn 1 t chy hon ton thu c 11,2 lt kh
CO2 (ktc). trung ho hon ton phn 2 cn 250 ml dung dch NaOH 2M. Cng thc cu to thu gn ca hai axit:



1:1
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A. CH3-COOH, CH2=CH-COOH. B. H-COOH, HOOC-COOH.
C. CH3-COOH, HOOC-COOH. D. H-COOH, CH3-CH2-COOH.
40. Ln men a gam glucoz vi hiu sut 90%, lng CO2 sinh ra hp th ht vo dung dch nc vi trong thu c
10 gam kt ta v khi lng dung dch gim i 3,4 gam. Tnh a?
A. 13,5 gam. B. 20,0 gam. C. 15,0 gam. D. 30,0 gam.
41. Oxi ho 4,0 gam ru n chc X bng O2 (xc tc, t
o
) thu c 5,6 gam hn hp Y gm anehit, ru d v
nc. Tn ca X v hiu sut phn ng l
A. metanol; 75%. B. Etanol; 75%. C. propanol-1; 80%. D. metanol; 80%.
42. Oxi ho 3,75 gam mt anehit n chc X bng oxi (xc tc) c 5,35 gam hn hp gm axit, anehit d. Tn ca
X v hiu sut ca phn ng l:
A. anehit fomic; 75%. B. anehit axetic; 75%. C. anehit propionic; 80%. D. anehit fomic; 80%.
43. Cho hn hp 2 anhit l ng ng k tip tc dng ht vi H2 d (Ni/t
0
) thu c hn hp Y gm 2 ancol n
chc. t chy hon ton hn hp Y thu c 11 gam CO2 v 6,3 gam H2O. Cng thc phn t ca 2 anhit trn l:
A. C3H6O v C4H6O. B. H2CO v C2H4O. C. C2H4O v C3H6O. D. C2H4O v C3H4O.
44. 0,1 mol axit hu c X tc dng vi mt lng va 200 ml dung dch KOH 1M. Mt khc, t chy hon ton ; 0,1
mol axit hu c X trn th thu c 4,48 lt kh CO2 (ktc). Cng thc cu to thu gn ca X l:
A. HOOCCH2COOH. B. CH3COOH. C. HOOC-COOH. D. HCOOH.
45. Tnh khi lng este metylmetacrylat thu c khi nung nng 215 gam axit metacrylic vi 100 gam ru metylic.
Gi thit phn ng ha este t hiu sut 60%.
A. 150 gam B. 200 gam. C. 125 gam D. 175 gam.
46. t chy hon ton 0,1 mol este X th thu c 8,96 lt kh CO2 (ktc) v 7,2 gam H2O. CTPT ca X l:
A. C4H6O4. B. C3H6O2. C. C4H6O2. D. C4H8O2.
47. Cho hn hp gm khng kh d v hi ca 24gam metanol i qua bt Cu nung nng (xc tc) sn phm thu c
c th to ra 40 ml fomalin 36% c d = 1,1 g/ml. Hiu sut ca qu trnh trn l:
A. 80,4% B. 70,4% C. 65,5% D. 76,6%
48. Cho 0,94 gam hn hp hai anehit n chc, no l ng ng lin tip tc dng ht vi dung dch AgNO3/NH3 thu
c 3,24 gam Ag. Cng thc phn t ca 2 anehit l:
A. CH3CHO v HCHO. B. CH3CHO v C2H5CHO. C. C2H5CHO v C3H7CHO. D. C3H7CHO v C4H9CHO.
49. Cho 0,0125 mol este n chc M vi dung dch KOH d thu c 1,4 gam mui.T khi ca M i vi CO2 bng 2.
M c cng thc cu to l:
A. C2H5COOCH3. B. CH3COOC2H5. C. HCOOC3H7. D. C2H3COOCH3.
50. Oxi ha hon ton hn hp X gm HCHO v CH3CHO bng O2 (xt) thu c hn hp axit tng ng Y. T khi hi
ca Y so vi X bng 145/97. Tnh % s mol ca HCHO ?
A. 16,7% B. 22,7% C. 83,3% D. 50,2%
51. Oxi ho 3,75 gam mt andehit n chc X bng oxi ( xc tc ) c 5,35 gam hn hp gm axit, andehit d. Tn
ca X v hiu sut phn ng l ?
A. Andehit axetic, 75% B. Andehit fomic, 75% C. Andehit propionic; 80% D. Andehit fomic, 80%
52. Cho 10,6 gam hn hp gm axit axetic v axit ng ng tc dng ht vi CaCO3 thy bay ra 2,24 lt kh (ktc). Tm
cng thc phn t ca X ?
A. C3H7COOH B. C2H5COOH C. HCOOH D. C4H9COOH
53. Chia 7,8 gam hn hp ru etylic v mt ng ng ca n thnh hai phn bng nhau . Phn 1 tc dng vi
Na(d) thu 1,12 lt kh ( ktc) . phn 2 tc dng vi 30 gam CH3COOH ( c mt H2SO4 c ) . Tnh tng khi lng este
thu c ? bit hiu sut phn ng este ha l 80%.
A. 8,1 gam B. 8,8 gam C. 6,48 gam D. 7,28 gam
54. Cho 1,0 gam axit axetic vo ng nghim th nht v cho 1,0 gam axit fomic vo ng nghim th hai, sau cho vo
c hai ng nghim trn mt lng d bt CaCO3. Khi phn ng xy ra hon ton th th tch CO2 thu c cng t
0
,P
A. t hai ng nghim bng nhau B. t ng th nht nhiu hn t ng th hai
C. t ng th hai nhiu hn t ng th nht D. t c hai ng u ln hn 22,4 lt (ktc)
55. X phng ho hon ton 9,7 gam hn hp hai este n chc X, Y cn 100 ml dung dch NaOH 1,50 M. Sau phn
ng, c cn dung dch thu c hn hp hai ru ng ng k tip v mt mui duy nht. Cng thc cu to thu gn
ca 2 este l:
A. H-COO-CH3 v H-COO-CH2CH2CH3. B. CH3COO-CH3 v CH3COO-CH2CH3
C. C2H5COO-CH3 v C2H5COO-CH2CH3 D. H-COO-CH3 v H-COO-CH2CH3.
56. Kh ho hon ton m gam hn hp 2 anehit n chc, cn 5,6 lit H2(ktc). Sn phm thu c cho tc dng ht
vi Na c 1,68 lit H2(ktc). Vy 2 anehit l :
A. hai anehit no. B. hai anehit n chc lin tip trong dy ng ng.
C. hai anehit cha no. D. mt anehit no v mt anehit cha no.
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Bi s 3. Hp cht cha nhm chc
57. Mt hn hp A gm 2 ankanal X , Y c tng s mol l 0,25 mol .Khi cho hn hp A tc dng vi dung dch
AgNO3/NH3 c d, th to ra 86,4 gam kt ta v khi lng dung dch AgNO3 gim 77,5 gam . Bit MX < MY Vy CTPT
ca X l :
A. CH3CHO. B. HCHO. C. C2H5CHO. D. khng xc nh c.
58. Hn hp X gm 2 este A, B l ng phn vi nhau v u c to thnh t axit n chc v ru n chc . Cho
2,2gam hn hp X bay hi O
0
C v 1atm thu c 0,56 lt hi este. Mt khc em thu phn hon ton 26,4 gam hn
hp X bng 100ml dung dch NaOH 20% ( d = 1,2 g/ml) ri em c cn th thu c 33,8 gam cht rn khan. Vy CTPT
este l:
A. C2H4O2. B. C3H6O2. C. C4H8O2 . D. C5H10O2.
59. Khi thu phn hon ton 0,05 mol este ca mt axit a chc vi mt ru n chc, tiu tn ht 5,6 gam KOH . Mt
khc khi thu phn 5,475 gam este th tn ht 4,2 gam KOH v thu c 6,225 gam mui . Vy CTCT ca este l:
A. CH2(COOCH3)2 B. CH2(COOC2H5)2. C. (COOC2H5)2 D. CH(COOCH3)3.
60. Cho 20,15 gam hn hp 2 axit no n chc tc dng va vi dung dch Na2CO3, thu c V(lit) kh CO2 (ktc)
v dung dch, c cn dung dch thu c 28,96 gam mui . Gi tr ca V l:
A. 4,84 lt B. 4,48 lit C. 2,24 lit D. 2,42 lt.
61. Cho 0,92 gam mt hn hp gm C2H2 v CH3CHO tc dng va vi Ag2O trong NH3 thu c 5,64 gam hn
hp rn chng t phn trm khi lng ca C2H2 trong hn hp l
A. 28,26% B. 26,74% C. 74,27% D. 59,05%
62. Chia m gam mt este E thnh hai phn bng nhau: Phn 1 b t chy hon ton thu c 4,48 lt kh CO2 (ktc) v
3,6 gam nc. Phn 2 tc dng vi 100 ml dung dch NaOH 0,5M th thu c 3 gam ru. Gi tr ca m l
A. 8,8 B. 3,6 C. 4,4 D. 7,2
63. Hn hp A gm C2H5OH v C6H5OH, cho A tc dng ht vi Na thu c 0,784 lt kh (ktc), cng cho mt lng A
nh trn tc dng vi dung dch NaOH d th lng NaOH tham gia phn ng l 0,03mol. Chng t s mol ca C2H5OH
v C6H5OH trong A ln lt l:
A. 0,04 v 0,03 B. 0,02 bv 0,03 C. 0,03 v 0,04 D. 0,02 v 0,05
64. Cho mt axit cacboxylic n chc tc dng vi etylenglicol thu c mt este duy nht. Cho 0,2 mol este ny tc
dng va vi dung dch NaOH thu c 16,4 gam mui. Axit l :
A. HCOOH. B. CH3COOH. C. C2H5COOH. D. C2H3COOH.
65. Kh 1,6 gam hn hp hai anehit no bng kh H2 thu c hn hp hai ancol. un hai ancol ny vi H2SO4 c
c hn hp hai anken l ng ng k tip. t chy hai anken ny c 3,52 gam CO2. Bit cc phn ng xy ra
hon ton, cng thc ca hai anehit l
A. HCHO, CH3CHO. B. CH3CHO, C2H5CHO. C. C2H5CHO, C3H7CHO. D. Khng xc nh
66. Hn hp X gm hai axit cacboxylic u no, mch h. Trung ho 0,3 mol X cn 500 ml dung dch NaOH 1M. Khi t
chy hon ton 0,3 mol X thu c 11,2 lt CO2 ( ktc). Cng thc ca hai axit l
A. HCOOH; C2H5COOH. B. CH3COOH; C2H5COOH.
C. HCOOH; (COOH)2. D. CH3COOH; CH2(COOH)2.
67. Khi lng este metylmetacrylat thu c l bao nhiu khi un nng 215 gam axit metacrylic vi 100 gam ancol
metylic, gi thit hiu sut phn ng este ho t 60%.
A. 125 gam B. 175gam C. 150 gam D. 200 gam
68. Ly 0,94gam hn hp hai anhit n chc no k tip nhau trong dy ng ng cho tc dng ht vi dung dch
AgNO3/NH3 thu c 3,24 gam Ag. Cng thc phn t hai anhit ln lt l :
A. C2H5CHO v C3H7CHO B. C3H7CHO v C4H9CHO
C. CH3CHO v HCHO D. CH3CHO v C2H5CHO
69. un 12,00 gam axit axetic vi 13,80 gam ancol etylic (c axit H2SO4 c lm xc tc). n khi phn ng dng li thu
c 11,00 gam este. Hiu sut ca phn ng este ho l :
A. 75,0% B. 62,5% C. 41,67% D. 60,0%
70. 1,76 gam mt este ca axit cacboxylic no, n chc v mt ru no n chc phn ng va ht vi 40ml dung
dch NaOH 0,50M thu c cht A v cht B. t chy hon ton 1,20 gam cht B cho 2,64gam CO2 v 1,44 gam nc.
Cng thc cu to ca este l :
A. CH3COO - CH3 B. CH3CH2COOCH3 C. H-COO-CH2CH2CH3 D. CH3COO - CH2CH2CH3
71. Chia m (g) mt anehit X thnh hai phn bng nhau.
- Phn 1: t chy hon ton thu c 3,36 lt CO2 (ktc) v 2,7 gam H2O.
- Phn 2: Cho tc dng vi AgNO3/ NH3 d thu c Ag kim loi vi t l mol nX : nAg= 1: 4. Anehit X l:
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A. Anehit no n chc B. Anehit no 2 chc. C. Anehit fomic D. Khng xc nh c
72. Thy phn 0,01 mol este ca 1 ru a chc vi 1 axit n chc tiu tn ht 1,2g NaOH. Mt khc khi thy phn
6,35g este th ht 3g NaOH v thu c 7,05g mui. CTCT ca este l:
A. (CH3COO)3C3H5 B. (C2H3COO)3C3H5 C. C3H5(COOCH3)3 D. C3H5 (COOC2H3)3
73. 3,52g este ca axit cacboxylic n chc no v ru n chc tc dng va vi 40ml dung dch NaOH 1M, to ra
mui A v ru B. t chy hon ton 0,6g ru B cho 1,32g CO2 v 0,72g H2O. T khi hi cu ru B so vi H2 bng
30. Oxi ha ru B cho anehit. Cng thc cu to ca este l:
A. CH3CH2COOCH3. B. HCOOCH(CH3)2. C. CH3COOCH2CH3. D. HCOOCH2CH2CH3.
74. t chy hon ton 0,74g hp cht X ta ch thu c nhng th tch bng nhau ca kh CO2 v hi nc trong
c 0,672lit CO2( kc). Cho t khi hi ca X so vi heli bng 18,5. Cho 0,74g X vo 100ml dung dch NaOH 1M(d=
1,0354g/ml). un nng cho phn ng hon ton, sau nng nhit t t cho bc hi n kh, lm lnh cho ton b
phn hi ngng t ht. Sau th nghim ta c cht rn khan Y v cht lng ngng t Z( mZ=100g). Khi lng cht rn
Y l:
A. 4,30g. B. 4,00g. C. 4,28g. D. 3,9g.
75. X phng ho hon ton 20,4 g cht hu c X n chc bng dung dch NaOH thu c mui Y v h/c hu c Z.
Cho Z tc dng vi Na d thu c 2,24 (l) kh H2 (ktc). Nung Y vi NaOH rn cho 1 kh R, d X/O2 = 0,5. Z tc dng vi
CuO nng cho sn phm khng c phn ng trng bc. Tn gi ca X l :
A. etyl axetat B. n-propyl axetat C. n-propyl propinoat D. isopropyl fomiat
76. Cho hn hp X gm axit butanoic, axit 2 - metylpropanoic v vinyl isobutirat tc dng hon ton v va vi 200ml
dung dch NaOH 1,5 M, tng khi lng mui thu c sau phn ng l
A. 11 gam. B. 22 gam. C. 33 gam. D. 55 gam.
77. X phng ha hon ton 13,6 gam mt este X cn va 50ml dung dch NaOH 4M, thu c 19,8 g hai mui ca
natri c s mol bng nhau. Cng thc cu to ca X c th l
A. CH3CH2COOCH2COOCH3. B. CH2 = CH COOCH2COOCH3.
C. C6H5 COOCH3 D. CH3 COO C6H5
78. Cho ancol hai chc X tc dng vi lng d cht rn CuO (nung nng) n phn ng xong thu c 9,36g mt cht
hu c a chc Y, ng thi thy lng cht rn gim 4,16 gam. Cht Y c cng thc cu to l
A. OHC CHO B. OHC CH2CHO C. CH3COCHO D. CH3CO CO CH3
79. t chy hon ton 25ml hi axit hu c n chc X cn va 187,5 ml oxi, sinh ra kh cacbonic v 75 ml hi
nc (th tch o cng nhit v p sut). X khng lm mt mu dung dch KMnO4. Cng thc cu to ca X l
A. CH3CH2COOH. B. CH CC CCH2CH2COOH.
C. C6H5 COOH. D. CH2 = CH CH2 COOH.
80. Hn hp A gm mt axit n chc v andehit c hai chc. t chy hon ton 9,44 gam A cn va 0,54 mol O2
thu c 0,46 mol CO2. S mol hn hp A l:
A. 0,1 mol B. 0,2 mol C. 0,3 mol D. 0,4 mol.
81. Hn hp X gm mt axit no n chc mch h v mt ru ( ancol ) no n chc mch h c phn t khi bng
nhau. Chia m gam X thnh hai phn bng nhau:
- t chy ht phn 1 ri cho sn phm chy hp th qua dung dch Ba(OH)2 c d thu c 7,88 gam kt ta.
- Cho phn 2 tc dng ht vi Na thu c 168 ml H2 (ktc).
Cng thc cu to ca A v B c th l:
A. HCOOH v C2H5OH. B. CH3COOH v C3H7OH. C. C2H5COOH v C4H9OH. D. CH3COOH v C2H5OH.
82. Thy phn hon ton 35,2 gam hn hp X gm 2 este c cng cng thc phn t l C4H8O2 bng 4 lt dung dch
NaOH 0,2 M. Sau phn ng c cn dung dch thu c 53 gam cht rn khan v 2 ru (ancol) ng ng lin tip.
Khi lng mi este trong hn hp l:
A. 22 gam v 13,2 gam. B. 8,8 gam v 26,4 gam. C. 8,2 gam v 27 gam. D. 1,32 gam v 22 gam.
83. Hn hp X gm axit CH3COOH v axit CH2=CH-COOH t l mol 2:1. Ly 12.8 gam hn hp X cho tc dng vi 18
gam C3H7OH c xc tc H2SO4 c thu c m gam hn hp este ( hiu sut cc phn ng este ho u bng 60%).
Gi tr ca m l:
A. 12,72 B. 18,36 C. 19,08 D. 21,2
84. Ly cng s mol cht hu c X cho phn ng vi dung dch NaHCO3 d, hay vi Na d u thu c CO2 v H2 c
s mol bng nhau. V bng s mol X em phn ng. X l:
A. HO-CH2-CH2-COOH. B. HO-CH2-CH(OH)-COOH. C. HOOC-CHOH-COOH. D. HOOC-CH2-COOH.
85. Hn hp X cha 3 cht hu c n chc no c cng 2 cacbon ( 1 ru ( ancol ), 1 axit, 1 andehit) v H2O. Chia X
thnh hai phn u nhau.
- Phn 1: cho tc dng vi Na va to ra 0,4 mol H2 v hn hp Y . Cho Y bay hi cn li 48,8 gam cht rn.
- Phn 2: Cho tc dng vi AgNO3/NH3 d thu c 0,2 mol Ag.
Khi lng ca mi phn l:
A. 58gam. B. 56 gam C. 54 gam. D. 35,6 gam.
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