Nguyn Hong Bo Hn 12HS

S GD-T BC NINH

TRNG THPT CHUYN BN

THI NH K LN I, NM 2010-2011

( thi c 04 trang)

THI TH I HC
Mn thi: HO HC, khi A,B lp 12
Thi gian lm bi: 90 pht
M thi 122

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit s khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; F = 19; Na = 23; Mg = 24; Al = 27; Si = 28; P = 31; S = 32; Cl = 35,5; K = 39;
Ca = 40; Cr = 52; Fe = 56; Ni = 58; Cu = 64; Zn = 65; Ag = 108; Ba = 137
(Th sinh khng c s dng BNG TUN HON CC NGUYN T HA HC)
Cu 1: Cho CO phan ng vi CuO mt thi gian tao hn hp khi A va hn hp rn B . Cho A phan ng
vi mt dung dich cha 0,025mol Ca(OH)2 tao 2(g) kt tua . Ly cht rn B phan ng vi dung dich HNO3
c, nong d tao V(lit) khi (ktc) mau nu o. Gia tri cua V la:
A. 1,344 lt hoc 0,672 lt
B. 1,120 lt hoc 0,672 lt
C. 1,344 lt hoc 0,896 lt.
D. 1,120 lt hoc 0,896 lt
Cu 2: Cho phn ng sau Fe3O4 + HNO3 Fe(NO3)3 + NO2 + NO + H2O
Nu t l s mol gia NO v NO2 l 1 : 2 th h s cn bng ca HNO3 trong phng trnh ho hc l
A. 30
B. 48
C. 38
D. 66
Cu 3: Cho cn bng sau: 3A(k) 2B(k) + D(r). Khi tng nhit ca phn ng, t khi hi ca hn hp kh
so vi H2 tng ln. Khng nh no sau y ng?
A. Phn ng thun l thu nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng nghch.
B. Phn ng thun l to nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng thun.
C. Phn ng thun l thu nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng thun.
D. Phn ng thun l to nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng nghch.
Cu 4: Cho cng thc cht A l C3H5Br3. Khi A tc dng vi dung dch NaOH d to ra mt hp cht tp
chc ca ancol bc 1 v anehit. Cng thc cu to ca A l
A. CH3-CHBr-CHBr2.
B. CH2Br-CH2-CHBr2.
C. CH2Br-CHBr-CH2Br.
D. CH3-CBr2-CH2Br.
Cu 5: Trn u 6,102 gam hn hp Al, Fe3O4 v CuO (cc cht c cng s mol) ri tin hnh phn ng
nhit nhm thu c hn hp X. Cho X tc dng vi dung dch HNO3 d c V ml ( ktc) hn hp kh
NO2 v NO theo t l mol tng ng l 1:1. Gi tr ca V l
A. 806,4
B. 604,8
C. 403,2
D. 645,12
Cu 6: Hp cht thm X, c cng thc phn t C8H8O2 va c kh nng tc dng vi Na, va c kh nng
tc dng vi NaOH v lm qu tm chuyn mu hng. S ng phn cu to ca X l
A. 4.
B. 5.
C. 6.
D. 3.
Cu 7: Phn ng no sau y sai?
A. 3Na[Al(OH)4] + AlCl3 4Al(OH)3 + 3NaCl
B. 3Na2CO3 + 2FeCl3 + 3H2O 2Fe(OH)3 + 6NaCl + 3CO2
C. Ag2S + 10HNO3 2AgNO3 + H2SO4 + 8NO2 + 4H2O
D. C2H5ONa + H2O C2H5OH + NaOH
Cu 8: Hy la chn cc ho cht cn thit trong phng th nghim iu ch kh sunfur?
A. Na2SO3 v dung dch H2SO4 c
B. CaSO3 v dung dch H2SO4 c
C. CaSO4 v dung dch H2SO4 long
D. CaSO4 v dung dch H2SO4 c
Cu 9: Cacbon phn ng vi tt c cc cht trong dy no sau y ?
A. Fe2O3, Al2O3, CO2,HNO3
B. CO, Al2O3, HNO3 (c), H2SO4 (c)
C. Fe2O3, CO2, H2, HNO3 (c)
D. CO, Al2O3, K2O, Ca
Cu 10: Cho 15 gam fomon 37,5% tc dng vi lng d AgNO3/NH3 thy xut hin m gam kt ta . Gi
tr ca m l
A. 108,0.
B. 81,0.
C. 42,8
D. 40,5
Cu 11: Cht A c cng thc phn t C11H20O4. A tc dng vi NaOH to ra mui ca axit hu c B mch
thng v 2 ancol l etanol v propan-2-ol. Cng thc cu to ca A l
A. C2H5OOC[CH2]4OOCCH2-CH2-CH3.
B. C2H5OOC[CH2]4COOCH2-CH2-CH3.
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C. C2H5OOC[CH2]4COOCH(CH3)2.
D. C2H5OOC[CH2]4OOCCH(CH3)2.
Cu 12: Trng thi lai ha ca cc nguyn t cacbon trong cc phn t: CO2; C2H6; C2H2 v C2H4 ln lt
l
A. sp; sp3; sp; sp2.
B. sp2; sp3; sp; sp2.
C. sp; sp2; sp; sp3.
D. sp; sp3; sp2; sp.
Cu 13: Pht biu no di y khng ng?
A. Nguyn t c cu thnh t cc ht c bn l proton, ntron v electron.
B. V nguyn t c cu thnh bi cc ht electron.
C. Ht nhn nguyn t c cu thnh t cc ht proton v ntron.
D. Vi mi nguyn t, khi lng nguyn t bng s khi.
Cu 14: Trong 1 kg go cha 81% tinh bt, c s mt xch C6H10O5- l
A. 12,044.1024.
B. 6,020.1024.
C. 16,20.1024.
D. 3,012.1024.
Cu 15: Dng thuc th no sau y phn bit bn cht rn: NaCl, CaCO3, Na2CO3 v BaSO4
A. Nc
B. Qu tm
C. Nhit phn
D. Nc v CO2

Cu 16: Cho cc ion:HSO 4 , NO 3 , C6H5O-, -OCO-CH2-NH 3 , CH3NH 3 , Cu2+, Ba2+, Al(OH) 4 , HCO 3 .
Tng s ion c vai tr axit v tng s ion c vai tr lng tnh l
A. 3 v 2
B. 2 v 1
C. 1v 2
D. 2 v 2
Cu 17: Chia 4,58g hn hp gm ba kim loi Zn, Mg, Al thnh hai phn bng nhau:
- Phn 1 tan hon ton trong dung dch HCl gii phng 1,456l H 2 (ktc) v to ra m(g) hn hp mui
clorua .
- Phn 2 b oxi ha hon ton thu c m(g) hn hp ba oxit.
Gi tr ca m v m ln lt l:
A. 6,905 v 4,37
B. 6,905 v 3,33
C. 7,035 v 3,33
D. 7,035 v 4,37
2+
Cu 18: chun mt dung dch Fe axit ho phi dng 50 ml dung dch K2Cr2O7 0,02M. chun
cng lng dung dch Fe2+ trn bng dung dch KMnO4 th th tch dung dch KMnO4 0,02M cn dng
l
A. 25 ml
B. 60 ml
C. 120 ml
D. 30 ml
Cu 19: Hp cht A to bi ion M2+ v ion X 22 . Tng s ht c bn to nn hp cht A l 241 trong ,
tng s ht mang in nhiu hn ht khng mang in l 47. Tng s ht mang in ca ion M2+ nhiu hn
ca ion X 22 l 76 ht. V tr ca M trong bng tun hon l
A. 20, chu k 4, nhm IIA
B. 12, chu k 3, nhm IIA
C. 56, chu k 6, nhm IIA
D. 38, chu k 5, nhm IIA
22+
+
Cu 20: Cho cc ion sau: Cl ; S ; Ca ; K . Th t tng dn bn knh ca cc ion trn l
A. Ca2+; K+; S2-; ClB. Cl-; S2-; Ca2+; K+.
C. S2-; Cl-; K+; Ca2+
D. .Ca2+; K+; Cl-; S2-.
Cu 21: Khi thu phn 0,01 mol este E to bi axit hu c n chc X v ancol Y th dng ng 1,68 gam
KOH, cn khi thu phn 6,35 gam E th cn 3,0 gam NaOH v thu c 7,05 gam mui. Cng thc phn t
ca este l
A. C14H18O6.
B. C9H12O6.
C. C12H20O6.
D. C12H14O6.
Cu 22: t chy hon ton 2,76 gam hn hp X gm CxHyCOOH; CxHyCOOCH3 v CH3OH thu c
2,688 lt CO2 ( ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam hn hp X phn ng va vi 30 ml
dung dch NaOH 1M, thu c 0,96 gam CH3OH. Cng thc ca CxHyCOOH l
A. C2H3COOH.
B. CH3COOH.
C. C3H5COOH.
D. C2H5COOH.
Cu 23: S ng phn ng vi cng thc phn t C3H5Br bng
A. 2.
B. 4.
C. 3.
D. 5.
Cu 24: Khi trn nhng th tch bng nhau ca dung dch A c pH = 13 v dung dch B c pH = 2 th thu
c dung dch c pH bng
A. 12,95
B. 12,65
C. 1,05
D. 1,35
Cu 25: Hn hp Z gm hai este X, Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy
ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O2 ( ktc), thu c 5,6 lt kh
CO2 ( ktc) v 4,5 gam H2O. Cng thc este X v gi tr m tng ng l
A. (HCOO)2C2H4 v 6,6.
B. HCOOC2H5 v 9,5
C. HCOOCH3 v 6,7.
D. CH3COOCH3 v 6,7.
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Cu 26: Cho 10,8 gam hn hp A gm Mg v Fe tc dng vi 500 ml dung dch AgNO3 0,8M, sau khi
phn ng xy ra hon ton thu c dung dch B v 46 gam cht rn D . Thnh phn % khi lng ca mt
kim loi trong hn hp A l
A. 51,85%
B. 22,32%
C. 77,78%
D. 25,93%
Cu 27: X l dung dch H2SO4 0,02M, Y l dung dch NaOH 0,035M. Khi trn ln dung dch X vi dung
dch Y ta thu c dung dch Z c th tch bng tng th tch hai dung dch mang trn v c pH = 2. T l
th tch gia dung dch Y v dung dch X l
A. 2:1
B. 1:2
C. 3:2
D. 2:3
Cu 28: trung ho hn hp gm axit axetic, ancol propylic v p-crezol cn 150 ml dung dch NaOH
2M. Ho tan hon ton 28,8 gam hn hp trn trong hexan ri cho Na d vo th thu c 4,48 lt H2 (
ktc). Lng p-crezol hn hp bng
A. 0,1 mol.
B. 0,2 mol.
C. 0,3 mol
D. 0,4 mol
Cu 29: Hn hp X gm NaBr v NaI. Cho hn hp X tan trong nc thu c dung dch
A. Nu cho brom d vo dung dch A, sau phn ng hon ton, c cn thy khi lng mui khan thu
c gim 7,05 gam. Nu sc kh clo d vo dung dch A, phn ng hon ton, c cn dung dch thy khi
lng mui khan gim 22,625 gam. Thnh phn % khi lng ca mt cht trong hn hp X l
A. 47,8%
B. 64,3%
C. 35,9%
D. 39,1%
Cu 30: Tinh th NaCl kt tinh theo kiu mng lp phng tm mt. S ion clo tip gip vi mi ion natri l
A. 4.
B. 12.
C. 8.
D. 6.
Cu 31: t chy hon ton 200 ml hp cht hu c X (cha C, H, O) vi 1200 ml kh O 2 (ly d). Sau
phn ng th tch cn 1700 ml, sau khi i qua H2SO4 c cn 900 ml v sau khi qua KOH cn 300 ml. Xc
nh cng thc phn t ca X, bit cc kh c o cng iu kin.
A. C4H8O2.
B. C4H8O.
C. C3H6O2.
D. C3H8O.
Cu 32: Nung hn hp gm 11,2g Fe; 6,4g Cu v 26g Zn vi mt lng d lu hunh n hon ton. Sn
phm ca phn ng tc dng vi dung dich HCl d thu c kh A . Tnh th tch dung dch CuSO 4 10% (d
= 1,1g/ml) ti thiu cn dng hp th ht kh A?
A. 750,25lm
B. 872,73ml
C. 1018,18ml
D. 525,25ml
Cu 33: Cho isopren phn ng vi Br2 theo t l 1:1. S sn phn thuc loi dn xut ibrom thu c
(khng xt ng phn hnh hc) l
A. 3.
B. 4.
C. 2.
D. 1.
Cu 34: C bao nhiu ng phn l dn xut ca benzen c cng thc phn t C7H6O2?
A. 4.
B. 5.
C. 2.
D. 3.
Cu 35: Cho m gam Cu tc dng vi 100ml dung dch hn hp HNO3 0,9M v H2SO4 0,2M thu c 0,672
lt kh NO ktc l sn phm duy nht v dung dch X c pH = x. Gi tr ca m v x l
A. 2,88 v 1,5.
B. 1,92 v 1,5.
C. 1,92 v 1,0
D. 2,88 v 1,0
Cu 36: Pht biu no di y khng ng?
A. M ng vt ch yu cu thnh t cc este ca cc axit bo no, tn ti th rn.
B. Du thc vt ch yu cu thnh t cc este ca cc axit bo khng no, tn ti th lng.
C. Hiro ho du thc vt lng s to thnh cc m ng vt rn.
D. Cht bo nh hn nc v khng tan trong nc
Cu 37: Polime no di dy c cu to khng iu ho?
H
H
H
H
Cl Cl
Cl Cl
-H2C - C - CH2 - C - CH2 - C - CH2-C-H2C - C - C - CH2 - CH2 - C - C- CH2CH3
CH3
CH3
CH3
CH3CH3
CH3CH3
A.
B.
H
H
H
H
H
-H2C - C - CH2 - C - C H2 - C -H2C - C = C - CH2 - CH2 - C = C- CH2OOCCH3 OOCCH3 OOCCH3
Cl
Cl
C.
D.
Cu 38: C 6 ng nghim, mi ng nghim cha mt trong cc dung dch sau: glixerol; glucoz; lng trng
trng; axit fomic; natri hiroxit; axit axetic . phn bit 6 dung dch ny c th dng mt loi thuc th l
A. Qi tm.
B. CuSO4.
C. AgNO3/NH3.
D. Br2.
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Cu 39: t chy hon ton 0,336 lt kh ( ktc) mt ankaien lin hp X. Sn phm chy c hp th
hon ton vo 40 ml dung dch Ba(OH)2 1,5M thu c 8,865 gam kt ta . Cng thc phn t ca X l
A. C3H4 hoc C5H8
B. C4H6.
C. C3H4.
D. C5H8.
Cu 40: Khi trng ngng 7,5 gam axit amino axetic vi hiu sut 80%, ngoi amino axit cn d, thu c
m gam polime v 1,44 gam H2O. Gi tr ca m l
A. 5,56.
B. 6,00.
C. 4,25.
D. 4,56.
Cu 41: Thm t t 300ml dung dch HCl 1M vo 200ml dung dch hn hp gm Na2CO3 1M v NaHCO3
0,5M c dung dch A v gii phng V lt kh CO2 ktc . Cho thm nc vi vo dung dch A ti d thu
c m gam kt ta trng. Gi tr ca m v V l
A. 15gam v 3,36lt
B. 10gam v 3,36lt
C. 10gam v 2,24lt
D. 15gam v 2,24lt
Cu 42: So snh tnh baz ca cc cht sau: (a) C6H5NH2; (b) CH3-NH2; (c) CH3-C6H4-NH2; (d) O2N-C6H4NH2
A. a> b > c > d
B. a > b > d > c
C. b > c > a > d
D. b > c > d > a
Cu 43: ng vi cng thc phn t C3H6O c bao nhiu hp cht mch h bn khi tc dng vi H 2 (Ni, t0)
sinh ra ancol?
A. 4.
B. 1.
C. 2.
D. 3.
H2N-CH-CO-NH-CH2-CO-NH-CH-COOH
Cu 44: Tn gi cho peptit
CH3
CH3
A. alanylglyxylalanyl. B. glixylalanylglyxin.
C. glixylalanylglyxin. D. alanylglixylalanin.
Cu 45: Cho cc cht: tinh bt, benzen, cht bo, protein. S cht khi t chy ht trong khng kh to ra
hn hp chy gm CO2, H2O, N2 l
A. 4.
B. 5.
C. 6.
D. 3.
Cu 46: un nng 132,35 gam axit axetic vi 200 gam ancol isoamylic ((CH3)2CH-CH2CH2-OH) c H2SO4
lm xc tc thu c isoamyl axetat (du chui). Tnh lng du chui thu c, bit hiu sut phn ng
t 68%.
A. 97,5 gam.
B. 195,0 gam.
C. 292,5 gam.
D. 159,0 gam
Cu 47: Trong s cc cht l propan, etyl clorua, axeton, v etyl axetat, th cht tan tt nht trong nc l
A. propan.
B. etyl clorua
C. etyl axetat
D. axeton
Cu 48: Hn hp X gm CO v NO c t khi hi so vi H2 l 14,5. V(l) hn hp X tc dng va vi
1,6g O2 c hn hp Y. Cho Y sc vo 200 ml dung dch NaOH 2M c 200ml dung dch A . S cht
tan trong dung dch A v nng ca mt cht trong dung dch A l
A. 4 v 0,20M
B. 4 v 0,25M
C. 3 v 0,25M
D. 3 v 0,20M
Cu 49: Nhng cu sau y, cu no sai ?
A. Cc nguyn t lin kt vi nhau thnh phn t chuyn sang trng thi c nng lng thp hn.
B. Phn t NH4NO3 cha cc lin kt ion, lin kt cng ho tr.
C. Trong nhm A, cc nguyn t c xp theo chiu s hiu nguyn t tng dn.
D. Nguyn t ca cc nguyn t cng chu k c s electron bng nhau.
Cu 50: Hin tng ca th nghim no di y c m t khng ng?
A. Cho Br2 vo dung dich phenol xut hin kt ta mu trng.
B. Cho qu tm vo dung dch phenol, qu chuyn mu .
C. Cho phenol vo dung dch NaOH, ban u phn lp, sau to dung dch ng nht.
D. Thi kh CO2 qua dung dch natri phenolat xut hin vn c mu trng.
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