S GIO DC V O TO LONG AN

TRNG THPT CHUYN LONG AN

THI TH I HC LN 1 - 2012
MN HA HC
Thi gian lm bi: 90 pht;
(60 cu trc nghim)
M thi
138

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit khi lng nguyn t (theo vC hay u) ca cc nguyn t:H=1; C=12; N=14; O=16;; Na=23; Mg=24;
Al=27; P=31; S=32; Cl=35,5; K=39; Ca=40; Cr=52; Fe=56;Cu=64; Zn=65; Mn = 55;Br=80; Ag=108;
Sn=118,7; I=127; Ba=137
PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu
1 : Hp cht Q (cha C, H, O) c iu ch theo s :
+ Cl2 (1:1)
+ NaOH
+ KOH / ROH
ddBr2
+ CuO ,t 0
X
T
Propen
Y
Z
Q
2 HBr
500 0 C
Nu ly ton b lng hp cht Q (c iu ch t 0,2 mol propen) cho tc dng vi dung
dch AgNO3/NH3 d th lng kt ta thu c l bao nhiu?
A. 75,4 gam
B. 60,4 gam
C. 43,2 gam
D. 82 gam
Cu Mt mu cht bo c ch s axit bng 7, ch s x phng ha l 191,8. X phng ha 1 tn
2 : mu cht bo ni trn (hiu sut bng a%) thu c 885,195 kg mui natri ca axit bo. Bit
5% khi lng cht bo ny khng phi l triaxyl glixerol hoc axit bo. Ga tr ca a l
A. 95.
B. 89,79.
C. 90.
D. 99,72.
Cu Tin hnh cc th nghim sau:
3 : (a) Cho dung dch Ba(OH)2 vo dung dch NaHCO3.
(b) Cho dung dch Al2(SO4)3 ti d vo dung dch NaAlO2 (hoc dung dch Na[Al(OH)4].
(c) Sc kh CH3NH2 ti d vo dung dch FeCl3.
(d) Sc kh propilen vo dung dch KMnO4.
(e) Sc kh CO2 vo dung dch Na2SiO3.
(g) Sc kh H2S vo dung dch SO2.
(h) Sc kh NH3 ti d vo dung dch AgNO3.
Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta?
D
B. 6
5
A. 7
C. 8
.
Cu So snh nng ca cc dung dch sau c cng pH:
4 : (1). Natri axetat
(2). Natri cacbonat
(3). Kali aluminat
(4). Kali fomiat
A. (2) < (3) < (1) < (4)
B. (3) < (4) < (1) < (2)
C. (2) < (1) < (4) < (3)
D. (3) < (2) < (1) < (4)
Cu Ha tan hon ton 25 gam mt cacbonat kim loi bng dung dch HCl 7,3% (va ) thu
5 : c dung dch mui 10,511%. Khi lm lnh dung dch ny thy thot ra 26,28 gam mui rn
A v nng phn trm ca mui trong dung dch cn li l 6,07% . Mui A c cng thc l
MgCl2.3H2
A. MgCl2.6H2O
B. CaCl2.6H2O
C. CaCl2.3H2O
D.
O
Cu Cho cc phn ng:
6 : CH -CH=CH + HCl
CH3-CHCl-CH3
Cl + 2KOH
KCl + KClO + H O
3

2Na2O2 + 2H2O
NH4NO2
2H2S + SO2

t oc

4NaOH + O2

2Mg(NO3)2

t oc

2MgO + 4NO2 + O2

N2 + 2H2O

CaOCl 2 + H2SO4

CaSO4 + Cl2 + H2O

3S + 2H2O

Cu2O + H2SO4

CuSO4 + Cu + H2O

Trong cc phn ng trn c bao nhiu phn ng l oxh-kh ni phn t, bao nhiu phn
ng t oxh kh
A. 3 4
B. 3 3
C. 2 4
D. 4 3
Cu C bao nhiu gam KClO3 tch ra khi dung dch khi lm lnh 350 gam dung dch KClO3 bo

7:
A.
Cu
8:

A.
Cu
9:
A.
Cu
10 :
A.
Cu
11 :
A.
C.
Cu
12 :
A.
Cu
13 :

A.
Cu
14 :

A.
C.
Cu
15 :
A.
Cu
16 :
A.

ha 80oC xung 20oC. Bit tan ca KClO3 80oC v 20oC ln lt l 40 gam/100 gam
nc v 8 gam/100 gam nc.
170 gam.
B. 95 gam.
C. 80 gam.
D. 115 gam.
Ha tan hon ton 30 gam hn hp X gm Na, K v Ba vo dung dch HCl d thu c dung
dch Y. C cn dung dch Y thu c 54,85 gam hn hp cht rn khan. Ha tan hon ton 45
gam hn hp X vo nc thu c dung dch Z. Cho t t n ht dung dch Z vo 0,4 lt
dung dch ZnCl2 1M n phn ng hon ton thu c kt ta c khi lng l
25,9875
39,6 gam.
B. 27,225 gam.
C. 34,65 gam.
D.
gam.
Cn ly bao nhiu lt dung dch H2SO4 98% (D= 1,84g/ml) sn sut 1 tn supephotphat kp
80%. bit hiu sut mi phn ng l 80%.
0,4645 m3
B. 0,5806 m3
C. 0,2378 m3
D. 0,8052 m3
Trong s cc cht: Al, H2O, CH3COONa, Na2HPO3, NaH2PO3, Na2HPO4, NaHS, Al2(SO4)3,
NaHSO4, CH3COONH4, Al(OH)3, ZnO, CrO, HOOC-COONa, HOOCCH2NH3Cl,CH2(OH)COOCH3 s cht lng tnh l
D
7
B. 10
9
C. 8
.
Xenluloz tc dng vi anhirit axetic iu kin thch hp to ra 9,84 gam hp cht X v
4,8 gam CH3COOH. Cng thc ca X c dng l:
[C6H7O2(OCOCH3)2OH]n
B. [C6H7O2(OCOCH3)3]n hoc
[C6H7O2(OCOCH3)2OH]n
[C6H7O2(OCOCH3)(OH)2]n
D. [C6H7O2(OCOCH3)3]n
Cho 27,25 gam hn hp X gm Mg, Al, Fe, Cu tc dng vi O2 thu c m gam hn hp cht
rn Y. Cho ton b Y tc dng vi dung dch H2SO4 c, nng, thu c dung dch Z (cha 5
mui, vi tng khi lng mui l 96,85 gam) v 10,64 lt (ktc) kh SO2 duy nht. Ga tr
ca m l
38,85.
B. 31,25.
C. 34,85.
D. 20,45.
m gam phi st ngoi khng kh, sau 1 thi gian Fe b oxi ho thnh hn hp X gm 4
cht rn c khi lng 27,2 gam. Ho tan va ht X trong 300 ml dung dch HCl nng a
mol/l thy thot ra 3,36 lt H2 (ktc) v dung dch Y. Cho tip dung dch HNO3 ti d vo
dung dch Y c dung dch Z cha hn hp FeCl3 , Fe(NO3)3 , HNO3 d v c 2,24 lt NO
duy nht thot ra (ktc). Gi tr ca m v a ln lt l:
22,4 gam
22,4 gam v 3M
B. 16,8 gam v 3M
C. 16,8 gam v 2M
D.
v 2M
Tin hnh cc th nghim sau:
1) Cho anehit axetic tc dng vi HCN thu c cht hu c X. Thy phn X trong mi
trng axit v c long thu c cht hu c Y.
2) Cho etyl bromua tc dng vi Mg trong dung mi ete:
-Ly sn phm thu c cho tc dng vi CO2 thu c cht Z. Cho Z tc dng vi dung
dch HCl thu c cht hu c T.
- Nu ly sn phm thu c cho tc dng vi nc thu c cht hu c Q.
Cc cht Y,T,Q ln lt l:
Axit propionic, etyl clorua, etan.
B. Axit lactic, axit propionic, ancol etylic.
Axit lactic, axit propionic, etan.
D. Axit propionic, etyl clorua, ancol
etylic.
t chy hon ton m gam cao su isopren c lu ha bng khng kh va (cha 20%
O2 v 80% N2), lm lnh hn hp sau phn ng ngng t ht hi nc th thu c
1709,12 lt hn hp kh (ktc). Lng kh ny lm ny tc dng va ht vi dung dch cha
0,1 mol Br2 , m c gi tr l
141,2 gam
B. 159,6 gam
C. 141,1 gam
D. 159,5 gam
X c cng thc C4H14O3N2. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y
gm 2 kh iu kin thng v u c kh nng lm xanh qu tm m. S CTCT ph hp
ca X l
5
B. 4
C. 2
D. 3

Cu
17 :
A.
Cu
18 :

A.
Cu
19 :
A.
Cu
20 :
A.
Cu
21 :
A.
B.
C.
D.
Cu
22 :

A.
Cu
23 :
A.
B.
C.
D.
Cu
24 :

Cho cc kim loi v ion sau: Cr, Fe2+, Mn, Mn2+, Fe3+ (cho ZCr = 24, ZMn= 25, ZFe = 26 ).
Nguyn t v ion c cng s electron c thn l:
Mn, Mn2+ v Fe3+
B. Cr v Fe2+
C. Mn2+, Cr, Fe3+
D. Cr v Mn
Khi cho 200 ml dung dch X gm AlCl3 a mol/l v NaCl b mol/l (a : b = 4 : 3) tc dng vi
325 ml dung dch KOH 2M, sau khi cc phn ng kt thc thu c 11,7 gam kt ta. Nu
cho 80 ml dung dch X tc dng vi dung dch AgNO3 d th thu c kt ta c khi lng
l
107,625
45,92 gam.
B. 43,05 gam.
C. 50,225 gam.
D.
gam.
Nung nng hn hp gm 0,4 mol N2 v 1,6 mol H2 trong bnh kn (c xc tc) ri a v nhit
t0C thy p sut trong bnh lc ny l P1. Sau cho mt lng d H2SO4 c vo bnh
(nhit lc ny trong bnh l t0C) n khi p sut n nh th thy p sut trong bnh lc ny
l P2 (P1 = 1,75P2). Hiu sut tng hp NH3 l:
75%.
B. 65,25%.
C. 60%.
D. 50%.
Cho hn hp kh X gm 3 hirocacbon X1, X2, X3 thuc 3 dy ng ng v hn hp kh Y
gm O2, O3 (t khi Y i vi hiro bng 19). Trn X vi Y theo t l th tch
VX : VY = 1,5 : 3,2 ri t chy hn hp thu c, sau phn ng ch c CO2 v hi nc vi t
l th tch tng ng l 1,3 : 1,2. T khi ca hn hp X so v H2 l
14.
B. 10.
C. 12.
D. 16.
Cho cc cht: natri hiroxit (1), imetylamin (2), etylamin (3),natri etylat (4),p-metylanilin
(5), amoniac (6), anilin (7), p-nitroanilin (8), natri metylat (9) , metylamin (10). Th t gim
dn lc baz l
(1), (4), (9), (2), (3), (10), (6), (5), (8), (7).
(4), (9), (1), (2), (3), (10), (5), (6), (7), (8).
(4), (9), (1), (2), (3), (10), (6), (5), (7), (8).
(9), (4), (1), (2), (3), (10), (6), (5), (7), (8).
Khi cho cht rn X tc dng vi H2SO4 c ung nng sinh ra cht kh Y khng mu. Kh Y
tan rt nhiu trong nc, to ra dung dch axit mnh.Nu cho dung dch Y m c tc dng
vi MnO2 th sinh ra kh Z mu vng nht, mi hc.Khi cho mt mu Na tc dng vi kh Z
trong bnh, li thy xut hin cht rn X ban u. X, Y,Z ln lt l cc cht sau:
NaCl, HCl,
Na2S, H2S, S
B. NaI, HI, I2
C. NaBr, HBr, Br2
D.
Cl2
Cho 2 ming Zn c cng khi lng v cng kch thc vo cc (1) dng dung dch HCl d
v cc (2) ng dung dch HCl d c thm mt t CuCl2. (Hai dung dch HCl c cng nng
mol/l). Hy cho bit kt lun no sau y khng ng?
Kh cc (1) thot ra chm hn cc (2).
cc (1) xy ra s n mn ha hc, cc (2) c xy ra s n mn in ha.
Lng kh cc (1) thot ra t hn cc (2).
Km cc (2) tan nhanh hn cc (1).
Hn hp X gm Hidro, propen, propanal, ancol alylic (CH2=CH-CH2OH). t 1 mol hn hp
X thu c 40,32 lt CO2 (ktc). un X vi bt Ni mt thi gian thu c hn hp Y c dY
X

A.
Cu
25 :
A.
Cu
26 :
A.
C.

= 1,25. Nu ly 0,1 mol hn hp Y th tc dng va vi V lt dung dch Br2 0,2M. Gi tr

ca V l?
0,1 lt
B. 0,3 lit
C. 0,2lt
D. 0,25lit
Cc A ng 0,3 mol Na2CO3 v 0,2 mol NaHCO3. Cc B ng 0,4 mol HCl. rt t t cc
A vo cc B . S mol CO2 thot ra l gi tr no?
0,25
B. 0,1
C. 0,4
D. 0,3
Cho 2,56 gam ng phn ng hon ton vi 25,2 gam dung dch HNO3 60% thu c dung
dch A. Bit rng nu thm 210ml dung dch KOH 1M vo A ri c cn v nung sn phm thu
c ti khi lng khng i th c 20,76 gam cht rn. Nng % ca mui Cu(NO3)2
v HNO3 cn d trong dung dch A l
25,44% v 36,55%
B. 67,34% v 25,45%
36,44% v 23,44%
D. 28,66% v 28,81%

Cu Trong s cc cht: clobenzen, toluen, nitrobenzen, anilin, phenol, axit benzoic, benzanehit,
27 : naphtalen, p-xilen, cumen, p-crezol,s cht tham gia phn ng th nhn thm d hn so vi
benzen l
D
B. 9
6
A. 8
C. 7
.
Cu t a mol X l trieste ca glixerol v axit n chc, mch h thu c b mol CO2 v c mol
28 : H2O, bit b-c=4a. Hiro ha m gam X cn 6,72 lt H2 (ktc) thu c 39 gam X. Nu un m
gam X vi dung dch cha 0,7mol NaOH n phn ng sau y c cn dung dch sau phn
ng th thu c bao nhiu gam cht rn?
A. 61,48 gam
B. 57,2 gam
C. 53,2 gam
D. 52,6 gam
Cu Hirocacbon X c cng thc phn t C8H10 khng lm mt mu dd brom. Khi un nng X
29 : trong dd thuc tm to thnh hp cht C8H4K2O4 (Y). X c kh nng to ra 4 dn xut
monobrom. Tn ca X l
A. 1,4-imetylbenzen.
B. 1,3-imetylbenzen.
C. 1,2-imetylbenzen.
D. etylbenzen.
Cu X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amino axit no mch
30 : h, c mt nhm -COOH v mt nhm -NH2. t chy hon ton 0,1 mol X bng O2 va
thu c sn phm gm CO2, H2O, N2, c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y
cho tc dng hon ton vi NaOH (ly d 20% so vi lng cn thit), sau phn ng c cn
dung dch th thu c bao nhiu gam cht rn?
A. 87,3 gam
B. 9,99 gam
C. 107,1 gam
D. 94,5 gam
Cu Cho 6,00 gam mu cht cha Fe3O4, Fe2O3 v cc tp cht tr. Ha tan mu vo lng d
31 : dung dch KI trong mi trng axit (kh tt c st thnh Fe2+) to ra dung dch A. Pha long
dung dch A n th tch 50ml. Lng I2 c trong 10ml dung dch A phn ng va vi
2
5,50 ml dung dch Na2S2O3 1,00M (sinh ra S4 O6 ). Ly 25 ml mu dung dch A khc, chit
tch I2, lng Fe2+ trong dung dch cn li phn ng va vi 3,20 ml dung dch KMnO4
1,00M trong dung dch H2SO4 . Thnh phn % theo khi lng Fe3O4 trong hn hp l
A. 20,3%
B. 24,67%
C. 17,4%
D. 14,56%
Cu Cho s phn ng:
Cl 2 , xt:Fe
KCN
P2O5
H 2O / H +
32 :
C6H6 +
X +
Y +
T.
Z
Trong : X, Y, Z, T l cc hp cht hu c. Vy T l
anhirit
A. axit benzoic.
B. axit salixylic.
C. Diphenylete
D.
benzoic.
Cu Thc hin phn ng vi ti xt (hiu sut bng 100%) i vi 32,2 gam hn hp X gm 2
33 : mui natri ca 2 axit cacboxylic thu c 6,72 lt (ktc) hn hp kh Y. Nung Y vi mt t
xc tc Ni n khi phn ng xy ra hon ton thu c 4,48 lt (ktc) hn hp kh Z c kh
nng lm mt mu nc brom. Hai mui trong X l
A. (COONa)2 v C2H2(COONa)2.
B. HCOONa v (COONa)2.
C. (COONa)2 v C2H3COONa.
D. HCOONa v C2H3COONa.
Cu Cho cn bng ha hc sau: Cr2 O72 + H 2O 2CrO42 + 2 H + . Trong cc trng hp sau: (1)
34 : thm OH- vo h; (2) NaAlO2 ; (3) thm BaCl2; (4) thm Na2CO3; (5) thm NH4Cl; (6) thm
NaCl. S trng hp khi tc ng vo h lm cho dung dch chuyn sang mu vng l
D
B. 5
6
A. 4
C. 3
.
Cu Trong cc th nghim sau:
35 : (a) Cho kh O3 tc dng vi dung dch KI.
(b) Nhit phn amoni nitrit.
(c) Cho NaClO tc dng vi dung dch HCl c.
(d) Cho kh H2S tc dng vi dung dch FeCl3.
(e) Cho kh NH3 tc dng vi kh Cl2.
(g) Cho dung dch H2O2 tc dng vi dung dch cha KMnO4 v H2SO4 (long).
(h) Sc kh O2 vo dung dch HBr.
(i) Cho NaI tc dng vi dung dch axit H2SO4 c, nng.

A.
Cu
36 :
A.
Cu
37 :
A.
Cu
38 :

(k) Cho SiO2 tc dng vi Na2CO3 nng chy.

S th nghim to ra n cht l
5
B. 8
C. 7
D. 6
Cho phn ng: ure + NaBrO N2 + CO2 + NaBr + H2O.
Sau khi cn bng phng trnh ho hc, tng h s nguyn ti gin ca cc cht phn ng l
2.
B. 4.
C. 11.
D. 7.
Cho 5,528 gam hn hp X gm Fe v Cu (nFe : nCu = 18,6) tc dng vi dung dch cha 0,352
mol HNO3 thu c dung dch Y v kh NO (sn phm kh duy nht). Tin hnh in phn
dung dch Y vi in cc tr, cng dng in I = 3,6345 ampe trong thi gian t giy thy
khi lng cactt tng 0,88 gam (gi thit kim loi sinh ra bm ht vo catt).Gi tr ca t l
1252.
B. 2602.
C. 2337.
D. 797.
T Canxi cacbua c th iu ch anilin theo s phn ng :
HO

HNO /H SO

C,600 C
Fe HCl +
NaOH
3
2
4
2
CaC 2
C2H 2

C6H

C
H NO
2

C6 H5 NH

Cl

C6 H5 NH2
6
6 5
3 =
hs=80%
hs
= 75%
=hs 60%
= hs 80%
hs 95%

hs=hiu sut. T 1 tn Canxi cacbua cha 80% CaC2 c th iu ch c bao nhiu kg anilin
theo s trn ?
A. 106,02 kg
B. 130,28 kg
C. 101,78 kg
D. 162,85 kg
Cu Cho dy gm cc cht Na, Mg; Ag, O3, Cl2, HCl, Cu(OH)2, Mg(HCO3)2, CuO, NaCl, C2H539 : OH, C6H5-OH, C6H5-NH2, CH3ONa, CH3COONa. S cht tc dng c vi axit propionic l
D
B. 7
9
A. 10
C. 8
.
0
Cu Cho s chuyn ho sau: CH COONa NaOH
ddHgSO4
C ,lamlanhnhanh
A 1500
D
3

B
40 :
+ddHCl
+ C2 H 2 , xt
+ ddBr2
ddAgNO3 / NH 3 ,t 0
+ ddNaOH ,t 0

E F G H
I .
G va I c th l
A. CH3COOCH=CH2 , CH2(OH)CHO
B. CH2 = CH-COOCH=CH2 ,
CH3COONa.
C. CH2=CH-COOH , CH3COONa.
D. C2H5COOCH=CH2 , C2H5COONa
PHN RING __ Th sinh ch c lm 1 trong 2 phn: phn I hoc phn II ____
Phn I. Theo chng trnh c bn (10 cu, t cu 41 n cu 50):
Cu Cho hi nc i qua than nng thu c hn hp kh than t X gm CO, H2, v CO2. Cho ton b
41 : kh X i qua ng s ng CuO nung nng d n phn ng hon ton thy khi lng ng s gim
8,0 gam, ng thi to thnh 5,4 gam H2O. Ly ton b kh v hi thot ra khi ng s hp th vo
nc vi trong d c m gam kt ta. Gi tr ca m l
A. 20 gam.
B. 30 gam.
C. 17,5 gam.
D. 25 gam.
Cu Cho s chuyn ha sau
+ SiO2 + C
+ O2
+ Ca
+ HCl
+ K OH
+ K OH
+
K OH
42 : Ca3 (PO4 )2
A

B
C

D
E
F

G
1200 o C
to
t o
Cht C v E ln lt l
PH3 v K2HPO4.
B. PCl5 v KH2PO4.
C. PH3 v KH2PO4.
D. PCl5 v K2HPO4.
Ha tan a gam oleum H2SO4.3SO3 vo 100 gam dung dch H2SO4 10% thu c mt oleum mi c
phn trm khi lng SO3 l 10%. Gi tr ca a l
721,39
B. 672,06
C. 558,00
D. 163,93
Mt loi kh than cha ng thi N2, CO v H2. t chy 4,48 lt (ktc) hn hp kh ny bng lng
O2 va ri dn sn phm chy vo nc vi trong (d) thy tch ra 10 gam kt ta, thu c dung
dch X v c 0,56 lt kh N2 (ktc) thot ra. Khi lng dung dch X thay i so vi khi lng dung
dch nc vi trong ban u l
A. gim 4,25 gam.
B. tng 6 gam.
C. tng 5,75 gam.
D. gim 8,65 gam.
Cu Cho cc ht vi m: F-, Na+, Mg2+, O2-, Ne, Al3+. Dy c sp xp theo chiu tng dn bn knh ht l
45 :
A. Al3+, Mg2+, Na+, Ne, F- , O2-.
B. F-, Na+, Mg2+, O2-, Ne, Al3+
+
23+
2+
C. F , Na , O , Ne, Al , Mg
D. Al3+,Mg2+, Na+, F- , O2-, Ne
Cu Hn hp X gm metanal v etanal. Khi oxi ha (H = 100%) m gam hn hp X thu c hn hp Y
46 : gm hai axit hu c tng ng c d Y/X = x. Gi tr ca x trong khong no sau y ?
A. 1,53 < x < 1,62.
B. 1,62 < x < 1,75.
C. 1,36 < x < 1,53.
D. 1 < x < 1,36.
A.
Cu
43 :
A.
Cu
44 :

Cu Hp cht X c vng benzen v c cng thc phn t l C8H10O2. Oxi ha X trong iu kin thch hp
47 : thu c cht Y c cng thc phn t l C8H6O2. Hy cho bit X c bao nhiu cng thc cu to?
D
B. 3
4
A. 5
C. 2
.
Cu T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut
48 : 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X.
trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l
A. 20%.
B. 90%.
C. 80%.
D. 10%.
Cu Thu phn hon 0,15 mol este X ca 1 axit a chc v 1 ancol n chc cn 100 ml dung dch NaOH
49 : 10% ( d = 1,2 g/ ml) thu c ancol Y v 22,2 gam mui. Ly ht Y tc dng vi CuO d, sn phm
sinh ra cho tc dng vi dung dch AgNO3/ NH3 d th thu c 129,6 gam kt ta. Vy X l
A. (COOCH3)2.
B. CH2(COOC2H5)2.
C. (COOC2H5)2
D. CH2(COOCH3)2
3
3
Cu Hn hp Y gm hirocacbon X v N2. t 300cm hn hp Y bi 725 cm O2 d trong mt kh nhin
50 : k, thu c 1100 cm3 hn hp kh v hi. Nu ngng t hi nc th cn li 650 cm3 v sau tip
tc li qua KOH th ch cn 200 cm3. CTPT ca X l
D
B. C4H8.
C3H6.
A. C3H8.
C. C2H6.
.
Phn II. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60):
Cu Cho 3 cht hu c n chc c cng cng thc phn t C3H8O tc dng vi
51 : CuO d(nhit ) thu c hn hp sn phm.Cho hn hp sn phm tc dng
vi AgNO3/NH3 d thu c 21,6 gam Ag . Nu un nng hn hp 3 cht trn vi
H2SO4 c 140 0C th thu c 34,5 gam hn hp 4 ete v 4,5 gam nc.Thnh
phn phn trm khi lng ancol bc 2 c trong hn hp l
A. 46,15%
B. 30,77%
C. 61,53%
D. 15,38%
Cu Cho cc polime sau: t nilon-6,6 (a); poli(ure-fomanehit) (b); t nitron (c); teflon (d);
52 : poli(metyl metacrylat) (e);poli(phenolfomanehit) (f).
Dy gm cc polime c iu ch bng phn ng trng hp l
A. (c), (d), (e).
B. (a), (b), (f).
C. (b), (c), (d).
D. (b), (c), (e).
Cu Ha tan hon ton 65,45 gam hn hp X gm CuCO3, ZnCO3, K2CO3, Na2CO3 trong 500ml dd
53 : hn hp gm HCl 2M v H2SO4 0,5M thu c 13,44 lit kh (ktc) v dung dch Y. Khi lng
mui c trong dung dch Y l
A. 74,55 m 78,3. B. 74,55.
C. 74, 55 m 89, 25. D. 78,3.
Cu Ho tan hon ton m1 gam hn hp 3 kim loi A, B (u c ho tr II), C ( ho tr III) vo dung
54 : dch HCl d thy c V lt kh thot ra ( ktc) v dung dch X. C cn dung dch X th c m2
gam mui khan. Biu thc lin h gia m1, m2, V l:
A. 112m2 = 112m1 + 355V.
B. 112m2 = 112m1 + 71V.
C. m2 = m1+ 35,5V.
D. m2 = m1+ 71V.
Cu Hp cht hu c X c cng thc phn t C4H7O2Cl.Khi thu phn X trong mi
55 : trng kim thu c cc sn phm trong c 2 cht c kh nng tham gia
phn ng trng gng.CTCT ca X l
HCOOCH2CHCl
B
C2H5COOCH2C
D HCOOCHClCH2
CH3COOCH2Cl
A.
C.
CH3
.
H2Cl
. CH3
Cu nh gi s nhim kim loi nng trong nc thi ca mt nh my, ngi ta ly mt t
56 : nc, c c ri thm dung dch Na2S vo thy xut hin kt ta mu . Hin tng trn chng
t nc thi b nhim bi ion
A. Cu2+
B. Fe2+
C. Pb2+
D. Hg2+
Cu S so snh no sau y ng vi chiu tng dn tnh axit ?
57 :
A. p-CH3-C6H4OH < C6H5OH < CH3COOH < p-O2N-C6H4OH
B. p-CH3-C6H4OH < C6H5OH < p-O2N-C6H4OH< CH3COOH

C. C6H5OH < p-CH3-C6H4OH< p-O2N-C6H4OH< CH3COOH

D. C6H5OH < p-CH3-C6H4OH < CH3COOH < p-O2N-C6H4OH
Cu Trong cc cht NaHSO4, NaHCO3, NH4Cl, Na2CO3,CO2, AlCl3, FeCl3 S cht khi tc dng vi dung
58 : dch NaAlO2 thu c Al(OH)3 l :
A. 5

B. 4

C. 1

D. 3

Cu Trn 25 ml dung dch NH3 0,2M vi 15 ml dung dch HCl 0,2M th thu c dung dch X. Gi tr
59 : pH ca X l (Bit hng s phn li baz ca NH3 l Kb= 1,8. 10-5)
A. 4,75
B. 9,1
C. 9,25
D. 4,9
Cu Hn hp X gm K, Al nng 10,5 gam. Ho tan hon ton X trong nc c dung dch Y. Thm
60 : t t dung dch HCl 1M vo Y nhn thy khi thm c 100 ml th bt u c kt ta, v khi
thm c V ml th thu c 3,9 gam kt ta trng keo. Gi tr ca V v phn trm khi lng K
trong X l
A. 150 ml hoc 350 ml v 66,67%
B. 50 ml hoc 250 ml v 74,29%
C. 50 ml hoc 250 ml v 66,67%

D. 150 ml hoc 250 ml v 74,29%