You are on page 1of 2

12-28. A 0.6407-g sample containing chloride and iodide ions gave a silver halide precipitate weighing 0.4430 g.

This precipitate was then strongly heated in a stream of Cl2 gas to convert the AgI to AgCl; on completion of this treatment, the precipitate weighed 0.3181 g. Calculate the percentage of chloride and iodide in the sample. (Ans: 4.72% Cl- , 27.05% I-) 12-29. The phosphorus in a 0.1969-g sample was precipitated as the slightly soluble (NH4)3PO4 . 12MoO3. This precipitate was filtered, washed, and then redissolved in acid. Treatment of the resulting solution with an excess of Pb2+ resulted in the formation of 0.2554 g of PbMoO4. Express the results of this analysis in terms of percent P2O5. 12-30 How many grams of CO2 are evolved fro a 1.500-g sample that is 38.0% MgCO3 and 42.0% K2CO3 by mass? (Ans: 0.498) 13-10. A solution of HClO4 was standardized by dissolving 0.4125 g of primary-standard-grade HgO in a solution of KBr: HgO(s) + 4Br-+ H2O > + 2 OH-

The liberated OH- consumed 46.51 mL of the acid. Calculate the molarity of the HClO4. (Ans: 8.190 x 10-2M) 13-12. A 0.4000-g sample that assayed 96.4% Na2SO4 required 41.25 mL of a barium chloride solution. Reaction: Ba2+ + > BaSO4(s) Calculate the analytical molarity of BaCl2 in the solution. (Ans: 0.06581 M) 13-13. A 0.3125-g sample of primary standard Na2CO3 was treated with 40.00 mL of dilute perchloric acid. The solution was boiled to remove CO2, following which the excess HClO4 was back titrated with 10.12 mL of dilute NaOH. IN a separate experiment, it was established that 27.43 mL of HClO4 netralized the NaOH in a 25.00-mL portion. Calculate the molarities of the HClO4 and NaOH. (Ans: 0.1799 M HClO4; 0.1974 M NaOH) 13-15. Titration of the I2 produced from 0.1045 g of primary standard KIO3 required 30.72 mL of sodium thiosulfate. + 5I- + 6H+ > 3I2 + 3H2O I2 + 2S2 > 2I- +

Calculate the concentration of Na2S2O3. (Ans: 0.09537 M) 13-18. The arsenic in a 1.010-g sample of a pesticide was converted to H3AsO4 by suitable treatment. The acid was then neutralized, and exactly 40.00 mL of 0.06222 M AgNO3 was added to precipitate the arsenic quantitatively as Ag3AsO4. The excess Ag+ in the filtrate and in the washings from the precipitate was titrated with 10.76 mL of 0.1000 M KSCN; the reaction was Ag+ + SCN- > AgSCN (s) Calculate the percent As2O3 in the sample. (Ans: 4.61% As2O3)

13-23. A 20-tablet sample of soluble saccharin was treated with 20.00 mL of 0.088181 M AgNO3. The reaction is

+ Ag+

>

Na+

After removal of the solid, titration of the filtrate and washings required 2.81 mL of 0.04124 M KSCN. Calculate the average number of milligrams of saccharin (205.17 g/mol) in each tablet. (Ans: 15.60 mg saccharin/tablet) 16-8. c. How would you prepare 2.00 L of 0.200 M HCl from a reagent that has a density of 1.0579 g/mL and is 11.50% HCl (w/w)? (Dilute about 120 mL of reagent to 2.0 L) 16-20. A 25.0 aliquot of vinegar was diluted to 250 mL in a volumetric flask. Titration of 50.0-mL aliquots of the diluted solution required an average of 34.88 mL of 0.09600 m NaOH. Express the acidity of the vinegar in terms of percentage (w/v) of acetic acid.

You might also like