Phan Vn Ninh, Ng Duy Cng1, Bi Tin Dng1

LP SN PH T T HP NHA PHENOL - NHA EPOXY - DU V HT O (PED)

i hc Khoa hc T nhin

Summary The mixture of phenolic resin, epoxy resin and cashew nut shell oil (PED mixture) was being used afilm former of paint coating. The coating with satifaction phyiscal properties was formed from the composition = 50 - 55% : 20 - 25 : 25- 30% with temperature stove is 20 2 minutes are sutable of hard these paint coatings. Coatings based on this composition are able to protection metal material, applicating in diluted acid and moderated alkali conditions. M U Nha phenol, nha epoxy c dng nhiu trong vt liu cao phn t, dng truyn thng nha ny khng th lm cht to mng c lp cho lp ph sn. Nhiu mt hng sn phenolic, sn epoxy trn th trng u xut pht t nha phenol v nha epoxy bin tnh. Nhiu cng trnh nghin cu tng tc ho hc ca nha phenol, epoxy vi du v ht o (DVH) [1] . Hay dng cho cacdanol trong DVH tng hp nha phenol, dng trong cht do [2] , lm cht to mang cho sn [3] ... Bi bo ny gii thiu mt t hp l thnh phn trn, c kh nng s dng trc tip lm cht to mng, hnh thnh lp ph sn tnh nng cao. Vt liu sn mi c th trin khai ng dng trong thc t. THC NGHIM 1. Ho cht - Nha epo xy ED-16, ch s epoxy 14,5 v phn t lng trung bnh 550. - Nha phenol dng resol t iu ch c: T l moi F : P ban u: 1 ,5 - 2,0. Thi gian keo ho 150oC: 3,2 pht. - Du v ht o: Tinh ch t du o th p nhit bng chng ct p sut thp (theo cng ngh Vin KTQSPK). 2. Phng php nghin cu - Kh nng to mng ca t hp. Hn hp nha c thnh phn thay i c ho tan nng trong h dung mi (xylen+butanol). Dung dch nha c n nh nht v hm lng phn kh. Mng sn c to thnh trn cc tm mu (Knh, thp, thp l trng thic) theo tiu chun. Mng cn c ph trn thp 12mm khong nhit nghin cu (100 - 160oC) - Xc nh bn ca mng sn. Tnh cht c l ca mng c o trn cc( dng c chuyn dng ( cng, bn, bn va p, bm dnh) theo TCVN - 93. Tnh bn ho cht c theo di qua thi gian ngm mu mng trn thp hnh tr trong cc mi tng tng ng. KT LUN V THO LUN 1 Kho st thnh phn phi liu

a) nh hng ca t l nha epoxy

Trong dy th nghim ny nha phenol v DVH c gi t l khng i 2/1 theo khi lng, t l nha epoxy thay i. Mng c sy 125oC n kh M3. T kt qu bng 1 cho thy t l nha epoxy tng th cng ca mng sn tng, nhng cc tnh cht c l khc u gim. Trong nhng iu kin ny, hm lng epoxy thch hp nm trong khong 22 - 25 %.

Bng 1 : nh hng ca t l epoxy n tnh cht mng sn.

S TT 1 T l epoxy, % 10 cng, G 250 bn un, mm 1

bn va p Kg.cm 50

bm, % 100

2 3 4 5

20 22 25 30

350 400 400 450

1 1 2 3

50 45 45 45

100 98 96 90

b) nh hng ca nha phenol

Nha phenol l hp phn ch yu c kho st trong khong rng 30 -70% theo khi lng, y t l epoxy v DVH c ly cng t l.

Hnh 1 : S ph thuc cng ca mng sn vo t l nha phenol Kt qu thc nghim ch ra l nha phenol tng cng lm tng nhanh cng mng. Nu vt qu 55% cng tng khng ng k m tnh cht c l khc li gim i r rt. Phi liu cha 50 - 55% nha phenol t tnh cht u vit.

c) nh hng ca du v ht iu Bng 2. nh hng ca l DVHD n tnh cht mng

S TT 1 2 3 4 5 T l DVHD, % 10 25 27 30 40 cng, G 450 450 400 300 150

bn un, mm 3 2 1 1 1

bn va p Kg.cm 40 45 45 50 50

bm, % 90 95 99 100 100

DVH trong phi liu c thay i t 20 - 40% trong khi t l E : P gi khng i v bng 1 : 2. Tri vi nhng hp phn nha du o lm gim cng ca mng. Khi DVH t t l 30% tr ln mng sn kh do dai, bn un, bn va p v bm dnh t tr s cc i ca thang o. C th chn lng du o 25-30% iu chnh tnh cht c l cho mng. Nh vy trong nhng iu kin kho st hn hp PED, to c mng vi tnh bn c l kh nht c thnh phn trong bng sau: P : E : D = 50-55 : 20-25 : 25-30 (phn trm trng lng). 2. Kho st qu trnh to mng sn Nhiu yu t nh hng n qu trnh to mng v tnh cht ca mng: thnh phn cht kt dnh, h dung mi c dng to mng trc tip, ch nhit - thi gian cho qu trnh hnh thnh mng sn...

a) nh hng qu trnh to mng sn

Cc mu PED c t l hn hp nha khc nhau, c to mng v ng rn vi thi gian 20 2 (pht) khong 100 - 150oC. Tng nhit sy cng tng nhanh nhng tnh cht c l khc gim xung. nhng mu t l du o 25% thy s thay i ny cng r rt. Vi mu (a) nhit sy thch hp l 120oC 5oC.

Hnh 2: S ph thuc nhng tnh cht c hc ca mng sn vo nhit sy

Cc ng a, b v c trn hnh tng ng vi mu c t l phi liu: P : E : D = a : 11 : 5 : 4; b : 10 : 6 : 4; c : 10 : 5 : 5 b) nh hng ca thi gian sy Bng 3. nh hng ca thi gian sy n tnh cht mng sn
S TT 1 2 3 4 5 Thi gian, pht 14 17 20 24 30 cng, G 100 200 300 400 450 bn un, mm 50 50 15 45 40

Sy l cng on cui cng ca quy trnh sn ph hon thin sn phm PED- 11 : 5 : 4 c to mng v sy ng rn 120 - 5oC trong khong 10 - 30 pht. bn va p Kg.cm 1 1 1 2 3

bm, % 100 100 100 96 92

Ko thi gian sy qu 24 pht cng ca mng sn tng ln nhng nhiu tnh cht c l khc ca mng sn gim i ng k (c bit l bn un). Mng sn 'loi ny c th duy tr thi gian sy 20 2 pht. 3. bn ho hc ca mng sn Vic th bn ho hc nhm xc nh kh nng ng dng ca mng sn mi. y cc mu a, b v c c to mng ln thp hnh tr. Cc mu c ngm trong mi trng ho cht v theo di thi gian mng cha bin i.

Bng 4. bn ho hc ca mng sn
Mi trng H2SO4 Mu 10 a 31

Nng , % 15 25 20 20 25 9 30 5 35 2

b c a NaOH b c

30 35 -

20 29 > 60 > 60 > 60

13 23 45 48 43

7 11 31 35 28

3 7 23 27 20

0,5 4 10 11 7

T kt qu bng 4 cho thy: Cc s liu chu c ca mi trng kim lu hn trong mi trng xt. Trong NaOH 15% cc mu ngm 60 ngy cha thay i. Trong H2SO4 15% nhng mu ny ch chu c 20 - 30 ngy. Trong dy cc mu th bn axit a, b v c xp x nhau. Trong mi trng kim, mu b c thi gian chu ng di hn c th hon thin lp ph v s dng to mng bo v kim loi trong mi trng axit long v trong mi trng kim c nng trung bnh (mu c). KT LUN 1 . C th s dng trc tip hn hp 3 thnh phn: nha penol, nha epoxy v du v ht o lm cht kt dnh, pha ch c nhng vt liu sn n nh. 2. Trong nhng iu kin th nghim kho st hn hp nha PED to c mng vi tnh bn c l kh nht c thnh phn: P : E : D : 50 - 55% : 20 - 25% : 25 - 30% 3. kho st qu trnh ng rn cc mu mng trn kim loi. Ch ng rn lp ph dy 20- 40 micromet nh sau: nhit 120 5oC, thi gian 20 2 pht. 4. Lp ph trn kim loi c bn c hc cao v bn ho cht tng i tt c th lm vic trong mi trng axit long v trong kim ti nng 20%. TI LIUTHAM KHO 1. Mai Vn Thanh, Phng H, L Minh Nam. Mng ph trn c s cacdanol - ful.fural - fomandehyt epoxy. Tp ch Ho hc, T 27, s 1, trang 3-6 (1989) 2. Mai vn Thanh, V Tn Cnh v cng s. Vt liu mi trn c s cacdanol - fulfural - fomandehyt. Tp ch Ho hc , T.26, s 4, trang 1 1 - 1 3 ( 1 998) 3. V Phin, L Thanh Long, v cng s. Tp ch ho hc, T.22, s 4, trang 10 - 14 (1984); T.23, s 1, trang 10 - 13 (1985).