TRNG THPT CHUYN NGUYN HU

THI TH AI HOC LN TH HAI NM HOC 2011 - 2012 MN: HOA - KHI A, B

Thi gian lm bi: 90 pht; ( co 5 trang, gm 60 cu trc nghim) H, tn th sinh:.......................................................................... M thi 208 S bo danh:............................................................................... - Thi sinh khng c s dung tai liu; - Giam thi khng giai thich thi.
I. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40). Cu 1: Xenluloz tc dng vi anhirit axetic iu kin thch hp to ra 9,84 gam hp cht X v 4,8 gam CH3COOH. Cng thc ca X c dng l: A. [C6H7O2(OCOCH3)2OH]n B. [C6H7O2(OCOCH3)3]n C. [C6H7O2(OCOCH3)(OH)2]n D. [C6H7O2(OCOCH3)3]n hoc [C6H7O2(OCOCH3)2OH]n Cu 2: Cho cc phn ng: CH3-CHCl-CH3 Cl2 + 2KOH KCl + KClO + H2O CH3-CH=CH2 + HCl t oc 2MgO + 4NO + O 2Na O + 2H O 4NaOH + O 2Mg(NO )
2 2 2

CuSO4 + Cu + H2O Trong cc phn ng trn c bao nhiu phn ng l oxh-kh ni phn t, bao nhiu phn ng t oxh kh: A. 3 3 B. 3 4 C. 2 4 D. 4 3 Cu 3: X mch h c CTPT C8H14 tc dng vi HBr cho 3 sn phm monobrom. S ng phn cu to tha mn l: A. 6 B. 4 C. 9 D. 15 Cu 4: Cho 15 gam glyxin tc dng va vi 8,9 gam alanin thu c m gam hn hp tripeptit mch h. Gi tr ca m l A. 22,10 gam B. 23,9 gam C. 20,3 gam D. 18,5 gam Cu 5: Kh hon ton 7,1 gam hn hp X gm 2 anehit n chc A, B bng H 2 thu c hn hp Y. Nu cho Y tc dng ht vi Na d thu c 1,68 lt H2 (ktc). Nu cho 7,1 gam hn hp X tc dng vi dung dch AgNO3/NH3 d thu c 43,2 gam Ag. CTCT ca 2 anhit l : A. CH3-CHO ; CH2=CH-CH2-CHO B. HCHO ; CH2=CH-CHO C. HCHO ; CH3-CH2-CHO D. CH3-CHO ; CH2=CH-CHO Cu 6: T Canxi cacbua c th iu ch anilin theo s phn ng :
C CaC2 hs=280% C2 H2 C ,600 75% 6 H6 C hs = H O
0

NH4NO2 2H2S + SO2

t oc

3 2

N2 + 2H2O 3S + 2H2O

CaOCl 2 + H2SO4 Cu2O + H2SO4

CaSO4 + Cl2 + H 2O

HNO / H SO 3 2 4 hs 60% =

HCl C6 5 NO2 Fe hs 80% 6H 3Cl H + =C 5NH

NaOH hs 95%

T 1 tn Canxi cacbua cha 80% CaC2 c th iu ch c bao nhiu kg anilin theo s trn ? A. 130,28 kg B. 162,85 kg C. 106,02 kg D. 101,78 kg Cu 7: C cc dung dch sau: (1): K2Cr2O7 + H2SO4; (2): H2SO4c; (3): Na2S; (4): HCl; (5): KBr; (6): Fe(NO3)2. Trn ln lt cc dung dch vi nhau tng cp mt th c bao nhiu cp c phn ng xy ra, trong bao nhiu cp xy ra phn ng oxh- kh: A. 11 8 B. 10-8 C. 11 7 D. 8 7 Cu 8: So snh nng ca cc dung dch sau c cng pH: (1). Natri axetat (2). Natri cacbonat (3). Kali aluminat (4). Kali fomiat A. (2) < (3) < (1) < (4) B. (3) < (2) < (1) < (4) C. (2) < (1) < (4) < (3) D. (3) < (4) < (1) < (2) Cu 9: Hp th 6,72 lt SO2 (ktc) vo 200 ml dung dch KOH 1M; NaOH 0,85M; BaCl2 0,45M sau cho tip 300ml dung dch Ba(OH)2 0,1M thu c m gam kt ta, gi tr ca m l: A. 28,21 gam B. 19,53 gam C. 26,04 gam D. 13,02 gam Cu 10: Cn ly bao nhiu lt dung dch H2SO4 98% (D= 1,84g/ml) sn sut 1 tn supephotphat kp 80%. bit hiu sut mi phn ng l 80%. A. 0,5806 m3 B. 0,8052 m3 C. 0,4645 m3 D. 0,2378 m3
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Cu 11: Cho hn hp gm etanol v phenol tc dng vi Na d thu c 1,68 lt kh (ktc). Nu cho hn hp trn tc dng vi dung dch brom va thu c 9,93 gam kt ta trng. Tnh % khi lng ca phenol trong hn hp: A. 50% B. 66,19% C. 33,81% D. 70,99% Cu 12: C bao nhiu pht biu sai trong cc cu sau y: 1. Trong cng mt chu k bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim. 2. Trong cng mt nhm A, nguyn t ca nguyn t kim loi c in tch ht nhn ln hn so vi nguyn t ca nguyn t phi kim. 3. Nguyn t ca hu ht tt c cc nguyn t kim loi u c s electron lp v ngoi cng 3. 4. Nguyn t cc nhm IA, IIA, IIIA u l nhng nguyn t kim loi v chng c s electron ngoi cng ln lt l 1e, 2e, 3e. A. 1 B. 2 C. 4 D. 3 Cu 13: Mt ancol 2 chc, phn t khng c nguyn t C bc 3. un nh m gam hi ancol trn vi bt CuO (d) n khi phn ng xy hon ton thy khi lng cht rn trong bnh gim 2,24gam ng thi thu c hn hp kh v hi ( ktc) c t khi hi so vi H2 l 18. m c gi tr l: A. 12,88 gam B. 5,32 gam C. 7,84 gam D. 1,54 gam + 3+ Cu 14: Trong mt cc nc c cha 0,01 mol Na ; 0,01 mol Al ; 0,015 mol Ca2+; 0,01 mol Mg2+; 0,045 mol HCO3-; 0,045 mol Cl-. lm mm nc cng u dng cc cch: A. un nng, Na2CO3, Na3PO4 B. un nng, Na3PO4, Ca(OH)2. C. Na3PO4, Na2CO3, HCl. D. Na2CO3, Na3PO4, NaOH Cu 15: Dy no sau y gm tt c cc cht c lin kt cho nhn (vit theo quy tc bt t): A. HNO3, H2SO3, P2O5,CO, Na2SO4 B. Ba(NO3)2, NH4Cl, CO2, H3PO4, H2SO3 C. H2CO3, H2SO4, N2O5, NH3, K2S D. Na2CO3, CH3COONH4, SO2, HNO3, H2SO4 Cu 16: Dung dch X cha a mol NaAlO2; a mol NaOH khi thm vo dung dch X b mol hoc 2b mol HCl th lng kt ta u nh nhau . T s b/a c gi tr l: A. 1 B. 1,5 C. 0,625 D. 1,6 Cu 17: Cht X: C2H7NO2 A tc dng vi dung dch HCl v dung dch NaOH. X thuc loi hp cht: A. Aminoaxit v mui amoni B. Aminoaxit C. Mui amoni D. Aminoaxit v este ca aminoaxit 2+ Cu 18: Cho cc kim loi v ion sau: Cr, Fe , Mn, Mn2+, Fe3+ (cho ZCr = 24, ZMn= 25, ZFe = 26 ). Nguyn t v ion c cng s electron c thn l: A. Mn, Mn2+ v Fe3+ B. Cr v Fe2+ C. Cr v Mn D. Mn2+, Cr, Fe3+ Cu 19: Cho cc cht sau: sec-butyl clorua, neo-pentyl clorua, benzyl clorua, 3-clobut-1-en, 4-clo-2-metylpent-1-en, p-clotoluen. S cht b thy phn khi un vi nc, b thy phn khi un vi dung dch NaOH, b thy phn khi un vi dung dch NaOH c, nhit v p sut cao ln lt l: A. 1 5 1 B. 1 4 6 C. 2 5 6 D. 2 3 1 Cu 20: m gam phi st ngoi khng kh, sau 1 thi gian Fe b oxi ho thnh hn hp X gm 4 cht rn c khi lng 27,2 gam. Ho tan va ht X trong 300 ml dung dch HCl nng a mol/l thy thot ra 3,36 lt H 2 (ktc) v dung dch Y. Cho tip dung dch HNO3 ti d vo dung dch Y c dung dch Z cha hn hp FeCl 3 , Fe(NO3)3 , HNO3 d v c 2,24 lt NO duy nht thot ra (ktc). Gi tr ca m v a ln lt l: A. 16,8 gam v 2M B. 16,8 gam v 3M C. 22,4 gam v 2M D. 22,4 gam v 3M Cu 21: Tn gi theo danh php thay th ca hp cht cho di y l:
CH3 CH3-C - CH-CH CH3 OH CH3

A. 1, 3, 3-trimetyl-1-phenylbutan-2-ol C. 1-neobutan-2-metyl-2phenyletanol

B. 2,2-imetyl-4-phenylpentan-3-ol D. 2, 2, 4-trimetyl-4-phenylbutan-3-ol

2 2 + Cu 22: Cho cn bng ha hc sau: Cr2 O7 + H 2O 2CrO4 + 2 H . Trong cc trng hp sau: (1) thm OH- vo h; (2) pha long; (3) thm BaCl2; (4) thm Na2CO3; (5) thm NH4Cl; (6) thm NaCl. S trng hp khi tc ng vo h lm cho dung dch chuyn sang mu vng l: A. 3 B. 5 C. 4 D. 6 Cu 23: Cho cc polime sau: t nilon-6,6; poli(vinyl ancol); t capron; teflon; nha novolac; t lapsan, t nitron, cao su buna-S Trong s polime trng hp l:

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A. 6 B. 3 C. 5 D. 4 Cu 24: C cc kim loi ring bit sau: Na, Ca, Al, Fe, Cu. Ch dng thm nc c th phn bit c bao nhiu kim loi trong s cc kim loi trn bng bng phng php ho hc ? A. 5 B. 3 C. 0 D. 2 Cu 25: Cht X c cng thc C4H6O4 c tnh cht sau : Tc dng NaOH to ra mui Y. t Y ch thu c CO2 v Na2CO3. Cng thc cu to X l : A. HOOC-CH2CH2COOH B. CH2=C(COOH)2 C. CH3OOC-COOCH3 D. HCOOCH2COOCH3 Cu 26: t chy hon ton 2,01 gam hn hp gm axit acrylic, vinyl axetat, metyl metacrylat. Ton b sn phm chy cho qua bnh 1 ng H2SO4 c thy khi lng bnh 1 tng m gam, bnh 2 ng Ca(OH)2 d thu c 9 gam kt ta. m c gi tr l: Cu 27: Ha tan hon ton hn hp X gm 0,002 mol FeS 2 v 0,003 mol FeS vo lng H2SO4 c nng d thu c kh X. Hp th X bng lng va Vml dung dch KMnO4 0,05M. V c gi tr l: A. 188 ml B. 228 ml C. 172 ml D. 280ml Cu 28: Mt cht bo c ch s axit bng 7, ch s x phng ha bng 196. un nng 100gam cht bo vi dung dch NaOH va c bao nhiu gam glyxerol (ch s axit l s mg KOH dng trung ha ht lng axit t do c trong 1 gam cht bo, ch s x phng ha l s mg KOH dng x phng ha ht lng triglixerit v lng axit t do c trong 1 gam cht bo): A. 11,5 gam B. 11,04 gam C. 9,38 gam D. 10,35 gam Cu 29: Cho dy gm cc cht Na, Mg; Ag, O3, Cl2, HCl, Cu(OH)2, Mg(HCO3)2, CuO, NaCl, C2H5-OH, C6H5-OH, C6H5-NH2, CH3ONa, CH3COONa, s cht tc dng c vi axit propionic l: A. 8 B. 7 C. 9 D. 10 Cu 30: Cc A ng 0,3 mol Na2CO3 v 0,2 mol NaHCO3. Cc B ng 0,4 mol HCl. rt t t cc A vo cc B . S mol CO2 thot ra l gi tr no? A. 0,3 B. 0,1 C. 0,25 D. 0,4 Cu 31: Cho 17,6 gam Cht X cng thc C4H8O2 tc dng hon ton vi 100 ml dung dch cha NaOH 1,5M v KOH 1,0M. Sau phn ng c cn thu 20 gam cht rn. Cng thc X l A. C2H5COOCH3 B. C3H7COOH C. CH3COO-C2H5 D. HCOO-C3H7 Cu 32: in phn mt dung dch cha FeCl3 , NaCl , HCl , CuCl2 vi in cc tr, mng ngn xp. Cho qu tm vo dung dch sau in phn thy qu tm khng i mu, chng t dng in phn thi im va ht: A. HCl B. FeCl3 C. CuCl2 D. FeCl2 Cu 33: Nung nng hn hp gm 0,4 mol N2 v 1,6 mol H2 trong bnh kn (c xc tc) ri a v nhit t0C thy p sut trong bnh lc ny l P1. Sau cho mt lng d H2SO4 c vo bnh (nhit lc ny trong bnh l t0C) n khi p sut n nh th thy p sut trong bnh lc ny l P2 (P1 = 1,75P2). Hiu sut tng hp NH3 l: A. 75%. B. 50%. C. 60%. D. 65,25%. Cu 34: Cho s chuyn ho sau: CH3COONa NaOH A 1500,lamlanhnhanh B ddHgSO4 D C 0 0 +ddHCl + C2 H 2 , xt + ddBr2 ,t ,t ddAgNO3 E F G H + ddNaOH I . / NH3 G va I c th l : A. C2H5COOCH=CH2 , C2H5COONa B. CH2 = CH-COOCH=CH2 , CH3COONa. C. CH2=CH-COOH , CH3COONa. D. CH3COOCH=CH2 , CH2(OH)CHO Cu 35: Hn hp kh no sau y c th cng tn ti nhit thng: (1): Cl2, NH3; (2): SO2, O2 ; (3): F2, HCl; (4): N2, Cl2 ; (5): H2S, O2. A. 2, 5 B. 1, 2 C. 2, 4 D. 1, 3 Cu 36: Cho 3,92 gam mt este n chc X tc dng va vi 100ml KOH 0,4M thu c 6,16 gam mui Y. Axit ha Y thu c cht Z. Z c cng thc phn t l: A. C5H8O3 B. C6H12O2 C. C5H6O2 D. C6H12O3 Cu 37: Ha tan 7,92g hn hp Na, Mg, Al va trong 500ml dung dch HNO3 1,65M thu c V lt N2O l sn phm kh duy nht. Tm V, khi lng mui thu c: A. 1,848 lt 48,84g B. 3,08 lt 42,02g C. 2,05lt 53,38g D. 3,696 lt 28,38g Cu 38: Cho 18,32 gam axit picric vo mt bnh ng bng gang c dung tch khng i 560cm 3 (khng c khng kh), ri gy n 19110C . p sut trong bnh ti nhit l P atm, bit rng sn phm n l hn hp CO, CO2, N2, H2 v p sut thc t nh hn p sut l thuyt 8%. P c gi tr l
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0

A. 207,365 B. 211,836 C. 223,635 D. 201,000 Cu 39: Cho a gam Fe3O4 tc dng va vi 1 lng dung dch HNO3 sao phn ng thu c dung dch X. Cho HCl d vo dung dch X th dung dch thu c ha tan c ti a 17,28g Cu. Tnh a: A. 4,176g B. 3,712g C. 4,64g D. 41,76g Cu 40: loi b kh clo gy c trong phng th nghim ngi ta s dng cht no sau y: A. Ca(OH)2 B. NH3 C. AgNO3 D. H2 II. PHN T CHN ( th sinh c chn 1 trong 2 phn A hoc B): A: Theo chng trnh chun (10 cu, t cu 41 n cu 50): Cu 41: Cho s phn ng sau: S H2S X l: X + H 2O A. Na2S2O3. B. CaS. C. Al2S3. D. Na2S. Cu 42: t chy hon ton hn hp gm FeS2 v Ag2S vi s mol bng nhau thu c 3,696 lt SO2 (ktc) v cht rn B . Cho B tc dng vi dung dch H2SO4 long d, sau phn ng hon ton thy cn li m gam cht rn khng tan. Gi tr ca m l: A. 13,64 B. 17,16 C. 11,88 D. 8,91 Cu 43: un nng V lt hi andehit mch h X vi 3 V lt H2 ( xc tc Ni ) n phn ng xy ra hon ton c hn hp Y c th tch 2V lt ( kh o cng iu kin ). Ngng t Y c cht Z, cho Z tc dng Na sinh mol H 2 bng mol Z. X l anehit no : A. No n chc B. No hai chc C. Khng no, cha 1 lin kt i n chc D. Khng no, cha 1 lin kt i hai chc Cu 44: Chia 23,6 gam hn hp gm HCHO v cht hu c X l ng ng ca HCHO thnh 2 phn bng nhau. Phn 1, cho tc dng vi H2 d (t0C, xc tc), sau phn ng thu c 12,4 gam hn hp ancol. Phn 2, cho tc dng vi dung dch AgNO3/NH3 d thu c108 gam bc . Cng thc phn t ca X l: A. CH3CHO B. C2H3CHO C. (CHO)2 D. C2H5CHO Cu 45: Thuc th duy nht nhn ra cc dung dch axit ring bit sau : NaCl, NaNO3, Na2S, Na3PO4 l: A. Na B. Fe(NO3)2 C. AgNO3 D. Fe(NO3)3 Cu 46: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l: A. Ala, Gly. B. Gly, Val. C. Gly, Gly. D. Ala, Val. Cu 47: Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a (mol/l) thu c dung dch c pH = 12. Gi tr ca a l : A. 0,21. B. 0,11. C. 0,22. D. 0,12. Cu 48: Cho m gam Al vo 500ml dung dch Cu(NO3)2 0,2M, AgNO3 0,1M. Sau khi phn ng xy ra hon ton thu c cht rn nng (m+7,71) gam. Gi tr ca m l : A. 1,53 B. 4,02 C. 5,29 D. 1,89 Cu 49: Hirocacbon X c cng thc phn t C8H10 khng lm mt mu dd brom. Khi un nng X trong dd thuc tm to thnh hp cht C8H4K2O4 (Y). X c kh nng to ra 4 dn xut monobrom. Tn ca X l: A. 1,3-imetylbenzen. B. etylbenzen. C. 1,4-imetylbenzen. D. 1,2-imetylbenzen. Cu 50: phn bit phenol, anilin, benzen, stiren ngi ta s dng cc thuc th l: A. dung dch brom, qu tm B. dung dch NaOH, dung dch brom C. qu tm, dung dch brom D. dung dch HCl, dung dch KmnO4 B: Theo chng trnh nng cao (10 cu, t cu 51 n cu 60): Cu 51: Trong cu mui ca pin in ha Zn-Cu c s di chuyn ca: A. Cc nguyn t Zn B. Cc nguyn t Cu C. Cc ion D. Cc electron Cu 52: Hn hp X cha glixerol v mt ancol no, n chc mch h Y. Cho 20,3 gam X tc dng vi Na d thu c 5,04 lt H2 (ktc). Mt khc 8,12 gam X ho tan va ht 1,96 gam Cu(OH)2. Cng thc phn t ca Y v thnh phn phn trm khi lng ca Y trong hn hp l: A. C5H12O v 65,94% B. C3H8O v 77,34% C. C4H10O v 54,68% D. C2H6O v 81,87% Cu 53: Cho a gam hn hp bt gm Ni v Cu vo dung dch AgNO 3 (d). Sau khi kt thc phn ng thu c 54 gam cht rn. Mt khc cng cho a gam hn hp 2 kim loi trn vo dung dch CuSO4 (d), sau khi kt thc phn ng thu c cht rn c khi lng (a + 0,5) gam. Gi tr ca a l:
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A. 42,5 gam B. 15,5 gam C. 33,7 gam D. 53,5 gam Cu 54: Kh hon ton m gam Fe2O3 cn 5,376 lt CO (ktc). Mt khc cho m gam Fe2O3 tc dng va vi dung dch HI 0,3M thu c dung dch X. Nng ion I- c trong dung dch X l: A. 0,05M B. 0,3M C. 0,2M D. 0,1M Cu 55: X c cng thc phn t C4H7ClO2 X tc dng NaOH cho mui X1 + ancol etylenglicol + NaCl cng thc X l : A. Cl-CH2-COO-CH2 -CH3 B. CH3- CHCl- COO -CH3 C. CH3-COO-CHCl-CH3 D. CH3 -COO-CH2-CH2Cl Cu 56: Cp ancol v amin c cng bc l: A. C6H5NHCH3 v C6H5CH(OH)CH3 B. (CH3)2CHOH v (CH3)2CH-NH2 C. (CH3)3COH v (CH3)3CNH2 D. (C6H5)2NH v C6H5CH2OH Cu 57: Thuc gim au Paracetamol c cha lin kt amit trong phn t v c to thnh bng cch cho axit axetic tc dng vi p- amino phenol. Cng thc ca thuc l:
CH3 - C - N CH3 - C - N OH

O H

A.

O H

B.
NH2 CH3 - C - N O H

OH

CH3 - C - O -

OH O C. D. Cu 58: Nguyn liu iu ch axeton trong cng nghip l: A. isopropylbenzen B. propan-2-ol C. propan-1- ol D. propin Cu 59: Hn hp kh X gm 0,1mol vinylaxetilen v 0,4 mol H2. Nung nng hn hp X (c xc tc Ni) mt thi gian, thu c hn hp Y c t khi so vi hiro bng 10. Nu dn hn hp Y qua dung dch Brom th khi lng Brom tham gia phn ng l: A. 0 gam B. 24 gam C. 8 gam D. 16 gam 0 0 Cu 60: Cho sut in ng ca cc pin in ha: E (Fe-Cu) = 0,78V E (Cu-Ag) = 0,46V . Sut in ng ca pin Fe - Ag l: A. 0,34V B. 0,44V C. 0,8V D. 1,24V
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