Trng THPT Hu lc 2

THI TH I HC LN 2 (2010 - 2011)

MN HO HC (Thi gian lm bi: 90 pht) (Dng chung cho tt c th sinh khi A v B) M 123

thi gm 6 trang
Cho khi lng nguyn t ca cc nguyn t theo vC: C=12, O=16, H=1, Al=27, Mg=24, N=14, Fe=56, Cu=64, S=32, Ag=108, Na=23, K=39, Ba=137, Ca=40, Zn=65, Br=80, Cl=35,5 Cr=52

PHN CHUNG CHO TT C TH SINH (t cu 1n cu 40)

Cu 1: Chn cu pht biu ng Flo l cht oxihoa mnh hn clo v 1. Flo c m in cao hn clo 2. Lin kt F-F km bn hn lin kt Cl-Cl 3. Flo c bn knh nguyn t nh hn clo A. 1, 3 B. 2, 3 C. 1, 2 D. 1, 2, 3 Cu 2 Ha tan hon ton a gam hn hp X gm Fe v Fe2O3 trong dung dch HCl thu c 2,24 lt kh H2 (kc) v dung dch B. Cho dung dch B tc dng vi dung dch NaOH d, lc kt ta nung trong khng kh n khi lng khng i thu c 24 gam cht rn. Gi tr ca a l A. 17,6 C. 20<a<21,6 B. 17,6<a<21,6 D. 21,6 Cu 3: Khi cho Cu vo dung dch FeCl3; H2S vo dung dch CuSO4; HI vo dung dch FeCl3; dung dch AgNO3 vo dung dch FeCl3 ; dd HCl vo dd Fe(NO3)2. S cp cht phn ng c vi nhau l A. 5 B. 3 C. 4 D. 2 Cu 4: Hn hp X gm axetilen, propilen v metan. t chy hon ton 11 gam hn hp X thu c 12,6 gam nc. Mt khc 5,6 lt hn hp X(kc) phn ng va vi dung dch cha 50 gam brom. Thnh phn % th tch ca cc cht trong hn hp X ln lt l A. 37,5%; 37,5%; 25,0% C. 37,5%; 25,0%; 37,5% B. 25,0%; 50,0%; 25,0% D. 50,0%; 25,0%; 25,0% Cu 5: Pht biu sai l A. Mantoz l ng phn ca saccaroz. B. Hp cht saccaroz thuc loi isaccarit, phn t ny c cu to bi 2 gc glucoz. C. Phn t saccaroz c nhiu nhm hydroxyl nhng khng c nhm chc anehit. D.Xenluloz l hp cht cao phn t thin nhin, mch khng phn nhnh do cc mt xch -glucoz to nn. Cu 6: Qu trnh sn xut amoniac trong cng nghip da trn phn ng thun nghch sau N2 (k) + 3 H2 (k) = 2NH3(k) ; H= -92 kJ. Khi phn ng t ti trng thi cn bng, nhng thay i no di y lm cho cn bng chuyn dch theo chiu thun: (1) tng nhit (2) tng p sut (3) gim p sut (4) thm cht xc tc (5) gim nhit (6) ly NH3 ra khi h. A. 1, 2, 4, 5 B. 3, 5, 6 C. 2, 5, 6 D. 2, 4, 5, 6 Cu 7: Cht X c CTPT dng CxHyO2.Cho 0,1 mol X tc dung vi Na d ,thy thot ra 0,2 gam hiro. 0,2 mol cht X tc dng va vi 200 ml dd NaOH 1M. Nu t chy 0,15 mol cht X th thu c lng CO2 nh hn 52,8 gam. S cng thc cu to ca X ph hp l A. 2 B. 3 C. 4 D. 5 Cu 8: Dd A c cha x mol HCl, dd B c cha y mol Na2CO3.Cho t t dd A vo dd B, sau khi phn ng xy ra hon ton thu c 5,6 lt CO2 ( ktc). Nu cho t t dd B vo dd A, sau khi phn ng xy ra hon ton thu c 6,72 lt CO2 ( ktc). y c gi tr l A. 0,25 B. 0,3 C. 0,55 D. 0,35 Cu 9: Cho hi nc i qua than nng c hn hp kh A gm CO2, CO, H2. Ton b lng kh A va kh ht 48 gam Fe2O3 thnh Fe v thu c 10,8 gam nc. Phn trm th tch CO2 trong hn hp kh A l A. 13,235%. B. 28,571%. C. 14,286%. D. 16,135%. 2+ 2+ Cu 10 : Dung dch X c cha: Ca 0,1 mol; Mg 0,3 mol; Cl 0,4 mol; HCO3 y mol. C cn dung dch X thu c cht rn Y. Nung Y trong khng kh n khi lng khng i thu c m gam cht rn. Gi tr m l A. 25,4 gam. B. 31,8 gam C. 28,6 gam D. 26,8 gam 1

Cu 11: Trong cc cp kim loi sau: (1) Mg, Fe (2) Fe, Cu (3) Fe, Ag; cp kim loi khi tc dng vi dung dch HNO3 c th to ra dung dch cha ti a 3 mui (khng k trng hp to NH4NO3) l. A. (1) B.(1) v (2) C. (2) v (3) D. (1) v (2) v (3) Cu 12: T 100kg go cha 81% tinh bt c th iu ch c bao nhiu lt ankol nguyn cht (d =0,8g/ml). Bit hiu sut ca c qu trnh l 75%. A. 57,5 lt B. 43,125 lt C. 42,24 lt D. 41,421 lt Cu 13: Cht hu c (A) cha C, H, O. Bit rng (A) tc dng c vi dung dch NaOH, c cn c cht rn (B) v hn hp hi (C), t (C) chng ct c (D), (D) tham gia phn ng trng gng cho sn phm (E), (E) tc dng vi NaOH li thu c (B). Cng thc cu to ca (A) l A. HCOOCH2-CH=CH2 B. HCOOCH=CH-CH3 C. HCOOC(CH3)=CH2 D. CH3COOCH=CH2 Cu 14: Dy no sau y c sp xp theo chiu tng tnh baz A. C2H5ONa, NaOH, NH3, C6H5NH2, CH3C6H4NH2, CH3NH2 B. C6H5NH2,CH3C6H4NH2, NH3,CH3NH2, C2H5ONa, NaOH. C. NH3, C6H5NH2, CH3C6H4NH2, CH3NH2, C2H5ONa, NaOH D. C6H5NH2,CH3C6H4NH2, NH3,CH3NH2, NaOH, C2H5ONa. Cu 15: C cc dung dch sau b mt nhn : CH3COOH , HCOOH , CH2=CHCOOH , CH3CHO , CH3CH2OH . Ho cht dng nhn bit cc cht l A . Br2 , AgNO3 ( dd NH3 ) , Na . C . Qu tm , Br2 , dd AgNO3 / NH3 . B . Cu(OH)2 , Br2 , dd KMnO4 D . Na , dd KMnO4 , Ag2O ( dd NH3 ). Cu 16: Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long d thu c 1,344 lit kh NO sn phm kh duy nht(kc) v dung dich X. Dung dch X c th ha tan ti a 12,88 gam Fe. S mol HNO3 trong dung dch u l A. 1,04 B. 0,64 C. 0,94 D. 0,88 Cu 17: Cho m gam Al vo 400 ml dung dch Fe(NO3)3 0,75M v Cu(NO3)2 0,6M sau phn ng thu c dung dch X v 23,76 gam hn hp 2 kim loi. Gi tr ca m l A. 9,72 gam B. 10,8 gam C. 10,26 gam D. 11,34 gam Cu 18: Trn u ancol etylic, axit axetic vo nc c 4 gam dung dch A. em ton b dung dch A tc dng va vi Na c m gam cht rn v 2,24 lt kh H2 (kc). Gi tr m l A. 3.54 gam B. 8,4 gam C. 3,14 gam D. 10,08 gam Cu 19: Mt hn hp X gm 2,24 lit C3H4 v 4,48 lt hidrocacbon Y. t chy hon ton X thu c 20,16 lit CO2 v 14,4 gam H2O ( cc V o kc). Cng thc phn t ca Y l A. C2H6 B. C4H8 C. C3H6 D. C3H8 Cu 20: Hai cht hu c A, B c cng thc CH5NO2 v C2H7NO2. Hn hp X gm A v B cho tc dng vi NaOH d to ra 2,72 gam mt mui duy nht v bay ra mt hn hp kh c M = 27,5. Hn hp X c khi lng A. 1,47 gam B. 2,94 gam C. 4,42 gam D. 3,32 gam Cu 21: ng trng hp butadien vi stiren c cao su buna-S. t chy hon ton mt lng cao su trn nCO2 16 = thy . T l trung bnh gia s mt xch butaien v s mt xch stiren trong cao su trn l n H 2O 9 A. 1/1 B. 3/2 C. 2/3 D. 1/2 Cu 22: Cho 0,2 mol CO2 hp th ht vo dung dch cha 0,6 mol NaOH c dung dch A. Dung dch A cho tc dng vi dung dch FeCl3 d. Lng kt ta thu c l A. 16,05 gam B. 14.3 gam C. 18,19 gam D. 21,4 gam Cu 23: Dy ch cha nhng animo axit c s nhm chc amino v s nhm cacboxyl bng nhau l A. Gly, ala, glu, tyr C. Gly, val, lys, ala B. Gly, val, tyr, ala D. Gly, ala, glu, lys Cu 24: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng thu c hn hp Y c t khi so vi He l 5. Hiu sut phn ng hydrohoa l A. 40% B. 50% C. 25% D. 20% 2

Cu 25: un nng a mol Cht hu c X c CTPT: ClCH2COOC6H3ClOH (cha nhn benzen) vi dung dch NaOH long d. S mol NaOH phn ng l A. 5a B. 3a C. 4a D. 6a Cu 26: Ha tan ht m gam Ba vo 200 gam dung dch Al2(SO4)3 17,1% . Sau khi phn ng hon ton thu c dung dch X, kt ta Y v 7,84 lt kh bay ra(kc). Nng phn trm ca dung dch X l A. 7,49% B. 7,16% C. 7,88% D. 7,52% Cu 27: Cho 2,24 gam Cu vo 100 ml dung dch gm KNO3 0,26 M v H2SO4 long 0,4M c dung dch A,. Cho dung dch gm KOH v Ba(OH)2 d vo dung dch A khi lng kt ta thu c l A. 12,75 gam B. 12,26 gam C. 9,32 gam D. 15,43 gam Cu 28: Cho dung dch c a mol H3PO4 vo dung dch c b mol NaOH thu c dung dch A gm hai cht tan c s mol bng nhau. Gi tr ln nht ca a/b l A. 2,5 B. 1 C. 1,5 D. 2 Cu 29: Hn hp X gm axit Y n chc v axit Z hai chc cng s nguyn t cacbon. Chia X thnh hai phn bng nhau. Phn 1 tc dng ht vi Na sinh ra 4,48 lt kh(kc). t chy hon ton phn 2 sinh ra 26,4 gam CO2. Cng thc cu to thu gn v % v khi lng ca Z trong X l A. CH2(COOH)2 ; 70,87% C. CH2(COOH)2: 54,88% B. (COOH)2 ; 60% D. (COOH)2 : 42,86% Cu 30 Th hnh l A. Cc dng nguyn t khc nhau ca cng mt nguyn t B. Cc dng tinh th khc nhau ca cng mt nguyn t C. Cc dng n cht khc nhau ca cng mt nguyn t D.Cc dng hp cht khc nhau ca cng mt nguyn t Cu 31: Cho cc phn ng sau: A+BC+D C + E Nha phenol fomanehit E + O2 H IJ+K JL L + Cl2 M + B M+NC+D Natri + F N + K Cc cht A, I, M c th l: A. C2H5ONa; C2H6Cl v C2H5Cl C. C6H5ONa; CH4 v C6H5Cl B. C6H5OH; C3H8 v C3H7Cl D. C2H5ONa; C3H8 v C2H5Cl Cu 32: T khi hi ca 2 andehit no, n chc i vi oxi < 2 . t chy hon ton m gam hn hp hai andehit trn thu c 7,04 gam CO2 Khi cho m gam hn hp trn phn ng vi AgNO3/ NH3 d thu c 12,96 gam Ag . Cng thc phn t ca hai andehit v thnh phn % khi lng ca chng l A. CH3CHO: 27,5% ; CH3CH2CHO : 72,5% B. HCHO 20,5% ; CH3CHO : 79,5% C. CH3CHO: 60,27% ; CH3CH2CHO : 39,73% D. HCHO: 12,82% ; CH3CH2CHO : 87,18% Cu 33: Trong hin tng n mn in ha xy ra A. s oxi ha cc m B. s kh cc m C. . s oxi ha cc dng D. s oxi ha kh u cc dng Cu 34: Cho Ba vo dung dch gm AlCl3, KCl, K2SO4, NH4Cl, CrCl3 s phn ng ha hc ti a xy ra l A. 6 B. 7 C. 8 D. 9 Cu 35: Nguyn tc luyn thp t gang l: A. Dng O2 oxi ho cc tp cht Si, P, S, Mn, trong gang thu c thp. B. Dng cht kh CO kh oxit st thnh st nhit cao. C. Dng CaO hoc CaCO3 kh tp cht Si, P, S, Mn, trong gang thu c thp. D. Tng thm hm lng cacbon trong gang thu c thp. Cu 36: t chy hon ton 1 mol ancol X thu c 6,72 lit CO2 (kc) v 7,2 gam H2O th tch oxi cn t chy bng 1,5 ln th tch CO2 thu c. X l A. C3H6(OH)2 B. C3H5(OH)3 C. CH2(CH2OH)2 D. C3H7OH Cu 37: Hn hp X gm 2 este c khi lng bng nhau cng dy ng ng phn t hn km nhau 4 nguyn t hidro. Hiu s mol ca 2 este trong 5,28 gam X l 0,014. Khi cho 5,28 gam X tc dng ht vi 100ml dung dch NaOH 1M sau phn ng hon ton c cn dung dch thu c 1ancol duy nht v m gam cht rn. Gi tr m l A. 5.452 gam B. 5,872 gam C, 6,942 gam D. 6,912 gam 3

Cu 38: Trong cc dd sau: Na2SO4,CuSO4, NaCl, AgNO3, KNO3, BaCl2 , s dd m trong qu trnh in phn c pH khng thay i l A. 2 B. 3 C. 4 D. 5 o Cu 39: Cho 3 cht hu c c cng cng thc phn t C3H8O tc dng vi CuO d (t ) thu c hn hp sn phm. Cho hn hp sn phm tc dng vi AgNO3/NH3 d thu c 21,6 gam Ag. Nu un hn hp trn vi H2SO4 c 1400C thi c 34,5 gam hn hp ete v 4,5 gam H2O. Thnh phn % khi lng ancol bc 2 c trong hn hp l A. 30,77% B. 15,38% C. 61,54% D. 46,15% Cu 40 : Khi lm lnh 400 ml dd ng sunfat 25% (d = 1,2 g/ml) th c 50g CuSO4.5H2O Kt tinh li. Lc b mui kt tinh ri cho 11,2 lt kh H2S (ktc) i qua nc lc. Khi lng kt ta to thnh v CuSO4 cn li trong dd l A. 48 v 8 B. 24 v 4 C. 32 v 8 D. 48 v16 PHN RING: Hc sinh chn mt trong 2 phn sau Phn I. Theo chng trnh chun ( t cu 41 n cu 50) Cu 41: Cho 2 ming Zn c cng khi lng vo cc (1) dng dung dch HCl d v cc 2 ng dung dch HCl d c thm mt t CuCl2. (Hai dung dch HCl c cng nng mol/l). Hy cho bit kt lun no sau y khng ng? A. kh cc (1) thot ra nhiu hn cc (2). B. kh cc (1) thot ra chm hn cc (2). C. kh cc (1) thot ra t hn cc (2) D. cc (1) n mn ha hc v cc (2) n mn in ha Cu 42: Cho hn hp gm khng kh d v hi ca 24 gam metanol i qua bt Cu nung nng (xt) sn phm thu c c th to ra 40ml fomalin 36% (d=1,1g/ml). Hiu xut ca qu trnh trn l A. 80,4% B. 70,4% C. 65,5% D. 76,6% Cu 43: Cho hn hp gm cc kim loi M, X vo dung dch cha Cu(NO 3)2 khuy u cho cc phn ng xy ra hon ton thu c kt ta gm 2 kim loi l M, Cu v dung dch cha 2 mui M(NO 3)2 v X(NO3)2. Th t sp xp theo chiu tng dn tnh kh ca cc kim loi l A. X, Cu, M. B. Cu, X, M. C. Cu, M, X. D. M, Cu, X. Cu 44: Cho 50 g hn hp gm Fe3O4, Cu , Mg tc dng vi dung dch HCl d ,sau phn ng c 2,24 lt H 2 (ktc) v cn li 18 g cht rn khng tan. % Fe3O4 trong hn hp ban u l : A. 25,92 B. 52,9 C. 46,4 D. 59,2 Cu 45: t chy hon ton hirocacbon X cho CO2 v H2O theo t l mol 1,75 : 1 v th tch. Cho bay hi hon ton 5,06 g X thu c mt th tch hi ng bng th tch ca 1,76 g oxi trong cng iu kin. Nhn xt no sau y l ng i vi X A. X khng lm mt mu dung dch Br2 nhng lm mt mu dung dch KMnO4 un nng . B. X tc dng vi dung dch Br2 to kt ta trng. C. X c th trng hp thnh PS. D. X tan tt trong nc. Cu 46: Khi bo qun dung dch FeSO4 trong phng th nghim, ngi ta ngm vo dung dch mt inh st sch ? A. Fe kh mui st (III) thnh mui st (II). C. Fe tc dng ht kh2O tan trong dung dch mui. ha B. Fe tc dng vi cc tp cht trong dung dch. D. Fe tc dng vi dung dchS trong khng kh. 2 H Cu 47: Ha tan ht m gam hn hp gm Fe v FeCO3 vo dung dch c a mol HNO3 thu c dung dch A ch c mt cht tan duy nht v 13,44 lt (kc) hn hp kh X gm NO v CO2 . T khi hi ca X so vi H2 l 18,5. Gi tri ca a v gi tr ln nht ca m l A. 1,8 v 60 B. 1,8 v 46 C. 1,4 v 60 D. 1,4 v 51,6 Cu 48: Cho -amino axit mch thng X c cng thc H2NR(COOH)2 phn ng va vi 0,1 mol NaOH to 9,55 gam mui. X l: A. axit 2-aminobutanioic B. axit 2-aminopropanioic C. axit 2-aminopropenioic D. axit 2-aminopentanioic Cu 49: Trong 1 bnh kn dung tch khng i cha mt lng hn hp 2 este ng phn c cng cng thc phn t CnH2nO2 v O2 136,5oC, p sut trong bnh 1at (th tch oxi ly gp i th tch cn cho phn ng chy). t chy hon ton hn hp trong bnh 819oK, p sut trong bnh sau phn ng bng 2,375atm. Cng thc cu to 2 este l 4

A. HCOOC2H5, CH3COOCH3 B. HCOOC3H7, CH3COOCH3 C. HCOOC2H5, CH3COOC2H5 D. CH3COOC3H7, C2H5COOCH3 Cu 50: Cho 1,8 gam mt axit cacboxilic phn ng vi dung dch NaHCO3 d sau phn ng hon ton thu c 0,986 lit kh CO2 (kc). Khi cho 13,5 gam X phn ng vi 400 ml dung dch NaOH 1M c cn dung dch sau phn ng thu c m cht rn. Gi tr m l A. 20,1 gam B. 26.8 gam C. 40,2 gam D. 24,1 gam Phn II. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho hn hp X gm hai hp cht hu c no, n chc A, B tc dng va vi 100 ml dung dch KOH 0,4 M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 5,27 gam. Cng thc ca A, B l A. C2H5COOH v C2H5COOCH3. B. CH3COOH v CH3COOC2H5. C. HCOOH v HCOOC2H5. D. HCOOH v HCOOC3H7. Cu 52: Cho cc dy chuyn ha: + NaOH +HCl +HCl + NaOH Glixin A X Glixin B Y X v Y ln lt l: A. u l ClH3NCH2COONa B. ClH3NCH2COOH v ClH3NCH2COONa C. ClH3NCH2COONa v H2NCH2COONa D. ClH3NCH2COOH v H2NCH2COONa Cu 53: t chy 5,8g cht A ta thu c 2,65g Na2CO3; 2,25g H2O v 12,1g CO2 .Bit rng 1 phn t A ch cha 1 nguyn t Oxi .Cho kh CO2 sc vo dd ca A thu c cht rn B l 1 dn xut ca benzen . trung ha a (g) hn hp gm B v 1 ng ng k tip theo C ca B cn dng 200g dung dch NaOH nng 6a % Cng thc phn t ca A v t l s mol ca B v C trong hn hp l 31 A. C6H5ONa v 1:1 C. CH3C6H4ONa v 1:2 B. C6H5ONa v 1:2 D. CH3C6H4ONa v 1:2 Cu 54: Cho E0(Cu-X) = 0,46 V, E0(Y-Cu) = 1,1 V, E0(Z-Cu) = 0,47 V, Dy cc kim loi c xp theo chiu tng tnh kh l A. Z, Y, Cu, X B. X, Cu, Z,Y C. Y, Z, Cu, X D. X, Cu, Y, Z Cu 55: chuyn hon ton 0,2 mol mui CrCl2 thnh mui Cr(III) bng oxi trong dung dch HCl th cn va s mol O2 , s mol HCl ln lt l A. 0,05 v 0,1 B. 0,05 v 0,2 C. 0,1 v 0,2 D. 0,1 v 0,3 Cu 56: Pht biu no sau y khng ng? A. Trong mi phn t protit, cc aminoaxit c sp xp theo mt th t xc nh B. Phn t c hai nhm - CO-NH- c gi l ipeptit, ba nhm th c gi l tripeptit C. Cc peptit c t 11 n 50 n v amino axit cu thnh c gi l polipeptit D. Lin kt ca nhm CO vi nhm NH gia hai n v - aminoaxit c gi l lin kt peptit Cu 57: un hai ru n chc vi H2SO4 c 1400C c hn hp 3 ete. Ly 0,72(g) mt trong ba ete em t chy hon ton thu c 1,76(g) CO2 v 0,72(g) H2O. Hai ru l ? A. CH3OH v C2H5OH B. CH3OH v C3H5OH C. C2H5OH v C4H9OH D. C2H5OH v C3H7OH Cu 58: m mt lp bc ln b mt mt vt bng ng ngi ta lm th no? A. in phn dung dch mui ng v vt cn m ng vai tr cc m B. in phn dung dch mui ng v vt cn m ng vai tr cc dng C. in phn dung dch mui bc v vt cn m ng vai tr cc m D. in phn dung dch mui bc v vt cn m ng vai tr cc dng Cu 59: Hn hp X gm: Fe2O3, Cr2O3, Al2O3. Cho 20,7 gam X vo dung dch NaOH c (d), sau khi kt thc phn ng thu c 8 gam cht rn. Mt khc kh hon ton 20,7 gam X cn 5,4 gam Al. Khi lng Cr 2O3 trong 20,7 gam X l? A. 11,4 gam. B. 15,2 gam. C. 7,6 gam. D. 2,28 gam. Cu 60: Cho 100ml dung dch Al2(SO4 )3 tc dng vi 100ml dung dch Ba(OH)2 , nng mol ca dung dch Ba (OH)2 bng 3 ln nng mol cu dung dch Al2(SO4 )3 thu c kt ta A. Nung A n khi lng 5

khng i th khi lng cht rn thu c b hn khi lng ca A l 5,4 gam .Nng mol ca Al2(SO4 )3 v Ba(OH)2 trong dung dch ban u ln lt l A. 0,5M v 1,5M C. 0,6M v 1,8M B. 1M v 3M D. 0,4M v 1,2M Th sinh khng c s dng bng tun hon cc nguyn t ho hc ..............................................Ht