TRNG I HC CNG NGHIP TP.

HCM KHOA CNG NGH HA HC

TIU LUN MN: PHN TCH CNG NGHIP

I CNG V XI MNG V THNH PHN. QU TRNH SN XUT XI MNG. XC NH HM LNG MT KHI NUNG, HM LNG SIO2 TRONG XI MNG.

GVGD : Th.S Trn Nguyn An Sa SVTH : Phm L V MSSV : 09072791 Lp : DHPT5

1.i cng v Thnh phn.

1.1.i cng. 1.2.Thnh phn.

2.Qu trnh sn xut xi mng. 3.Xc nh hm lng mt khi nung. 4.Xc nh hm lng SiO2 5.Ti liu tham kho.

1.i cng v Thnh phn. 1.1. i cng. a)Gii thiu chung v xi mng b)Phn loi xi mng 1.2. Thnh phn. a)Thnh phn ha hc. b)Thnh phn khong.

1.1 i cng.
a) Gii thiu chung v xi mng.
L mt cht kt dnh trong nc. C kh nng ng rn trong mi trng khng kh v nc. Thnh phn ch yu ca xi mng pooclng l CaO kt hp vi 3 oxit chnh SiO2, Al2O3, Fe2O3 . To thnh 4 khong chnh: Alit C3S (3CaO.SiO2), Belit C2S (2CaO.SiO2), Celit C3A (3CaO.Al2O3), AluminoFelit C4AF (4CaO.Al2O3.Fe2O3). c sn xut bng cch nung hn hp phi liu c nghin mn to clinker, sau clinker c trn vi ph gia v mt lng nh thch cao (< 3.5) em nghin to xi mng.

Da vo khong.
Da vo thnh phn khong C3S v C2S: C3S -Xi mng poolang alit khi: >4 C2S C3S -Xi mng pooclang thng: >14 C2S C3S -Xi mng poolang belit: <1 C2S Da vo thnh phn khong C3A v C4AF: C3A -Xi mng alumin: > 1,5 C4AF C3A -Xi mng pooclang thng: = 0,4-1,5 C4AF C3A -Xi mng xlit: < 0,4 C4AF

1. 1 i cng. b) Phn loi

Da vo mc ch s dng ca cng trnh: xi mng poolang hn hp xi mng trng, xi mng mu Xi mng pooclng puzolan Xi mng pooclng bn sunfat Xi mng pooclng t ta nhit Xi mng pooclng x ht l cao Xi mng aluminat Xi mng n

1.2. Thnh phn

a.Thnh phn ha hc.
Hm lng CaO 62% - 69% Tham gia thnh phn To tt c khong chnh ca clinke. Tham gia to cc nhm khong silicat ( khong kh nng chy) ca clinke xi mng poolang Tham gia to khong nng chy (aluminat canxi v alumoferit canxi) nh hng Nhiu CaO ng rn nhanh, mc cao, km bn trong mi trng xm thc. Nhiu SiO2 ng rn chm, mc cao, bn trong mi trng xm thc.

SiO2

17% - 26%

Al2O3 4% - 10%

Nhiu Al2O3 ng rn nhanh, ta nhiu nhit, bn trong mi trng xm thc, tng nht pha lng clinke.

a.Thnh phn ha hc
Hm lng Tham gia thnh phn nh hng Nhiu Fe2O3, gim mc xi mng, tng bn trong mi trng xm thc, gim nht pha lng clinke, gim nhit nung clinke. Fe2O3 0,1 - 5% Ch yu tham gia to khong nng chy alumoferit canxi

R2O (gm Na2O v K2O) SO3

0,1 5%

nhit cao bay hi mt Nhiu R2O, gim mc xi phn, mt phn tham gia mng, khng n nh th tch, to khong cha kim. gy loang mu (nu dng lm va trt, n mn ct thp). nhit cao sinh kh SO2 bay ra mt phn, mt phn tham gia to khong cha SO3 , lm gim hm lng mt s khong chnh. Nhiu SO3, gim mc xi mng, to cc hp cht c nhit nng chy thp gy hi cho h thng l,

0 1%

b. Thnh phn khong.

Thng thng, trong clinke, thnh phn phn trm theo khi lng ca cc khong vt thay i nh sau : Alit: 3CaO.SiO2 (C3S) chim 60-65% Belit: 2CaO.SiO2 (C2S) chim 20-25% Celit: 3Cao.Al2O3 (C3A) chim 4-12% Alumino-Ferit: 4CaO.Al2O3.Fe2O3 (C4AF) chim 1-5%(7-14%)

2. Qu trnh sn xut xi mng.

a.

b.

Nguyn liu sn xut xi mng. Cc giai on sn xut xi mng. Giai on 1: Chun b nguyn liu. Giai on 2: Phi hp nguyn liu. Giai on 3: Nung to clinke. Giai on 4: Nghin clinke vi cc ph gia khc.

Ch tiu CN CN l ng 1. Nguyn l lm vic -Lm vic gin on -Phi liu c cp vo theo tng m, i t trn xung -Qu trnh to khong din ra theo chiu cao ca l v trong tng vin phi liu 2. Phi liu - vi, t st, ph gia, x pirit -Thm ph gia khong ha photphorit- dng vin, m 14%, trn ln vo nhau

CN l quay t -Lm vic lin tc -Phi liu c np t u cao ca l, o trn u theo vng quay ca l -qu trnh to khong c din ra theo chiu di l -Cng sut ln( c th t 3000-5800 tn clinke/ ngy) -Tng t cng ngh l ng -Phi liu dng bn, m 40%, phi liu khng trn ln than

CN l quay kh -Lm vic lin tc -Tng t l quay t - Tng t l quay t - Tng t l quay t

-Tng t cng ngh l ng -Phi liu a vo dng bt mn, m 1-2%, v khng trn ln vi nhau

Ch tiu CN l ng CN 3. Nhin -Ch dung nhin liu liu rn(than) -Tiu tn nhiu nhin liu trn 1 n v sn phm ln 4.Qu trnh nung 5.Nhit v cht lng 6. Mc gy nhim

CN l quay t

CN l quay kh

- C th dng than hoc du, kh -Tiu tn nhin liu trn 1 n v sn phm l ln nht

-Tng t l quay t -Tiu tn nhin liu trn 1 n v sn phm l nh nht -S dng l quay -L quay kh c h thng trao i nhit, thp xyclon Tng t l quay t -Cht lng tt v n nh

-S dng l ng -S dng l quay -Phi tri qua giai on sy gim -Tng t l ng m t 40% xung 2% -Nhit l rt kh t ti -Nhit nung 1450C 1450C -Cht lng khng tt v n nh -Cht lng sn phm tt v n nh -Lng kh thi gy nhim ln -c bit cng ngh ny thi ra 1 lng HF- cn cng ngh x l hin i v chi ph cao

-Lng kh thi gy -Lng kh thi nhim l ln nht gy do s dng rt nhiu nhim la nh nht nhin liu

S sn xut ximng pooclngt bng phng php t 1. t st, vi t m v; 2. Chun b phi liu; 3. nh lng; 4. L quay; 5. Truyn nhin liu; 6. Chuyn Clinke; 7. Kho Clinke;

Sn phm trong cc giai on trong l nung to clinke.

Giai on 1: CaCO3, Al2O3.2SiO2.2H2O, Fe2O3 Giai on 2: CaCO3, Al2O3.2SiO2, Fe2O3 Giai on 3: CaO, Al2O3.2SiO2, Fe2O3 Giai on 4: CaO, Al2O3, SiO2, Fe2O3 Giai on 5: CaO + Al2O3 -> 3CaO.Al2O3 (Celit) CaO + SiO2 -> 2CaO.SiO2 (Belit) 2CaO.SiO2nc + CaO -> 3CaO.SiO2 (Alit)

t st 1

t st 2

vi

qung st

Thch cao

Kho cha t st p nh t st sy kh t st

my p
kho trn u SILO vi nguyn liu my nghin SILO trn u l nung thit b lm ngui

my p

my p

SILO t st 1

SILO t st 2

SILO qung st

SILO thch cao

ph gia

SILO clinke
my nghin xi mng SILO xi mng ng bao xut xi mng ri

3. Xc nh hm lng mt khi nung (MKN). ( theo TCVN 141 :2008)

Nguyn tc: mu th c nung Nung 10000C 500C n khi lng khng i. T s suy gim khi lng tnh ra hm lng mt khi nung.

Cch tin hnh

Chn s
Nung 10000C 500C 1h

Cn 10000C 500C

Chn s + 1g mu m1
Nung 10000C 500C 1h 15 pht Nung 10000C 500C

ngui trong bnh ht m

Cn

Cn m2

Tnh ton kt qu
% MKN = Trong :
m1 l khi lng mu v chn trc khi nung (g). m2 l khi lng mu v chn sau khi nung (g). m l khi lng mu ly phn tch (g). Chnh lch gia hai kt qu xc nh song song khng ln hn 0,08%.
1 2

4. Xc nh hm lng SiO2.
(theo TCVN 141: 2008) Nung mu vi hn hp nung chy

Hm lng SiO2 tng

Xc nh hm lng SiO2

Phn hy mu bng HCl v NH4Cl

SiO2 cn li bng phng php so mu

4. Xc nh hm lng SiO2.

Phng php nung mu vi hn hp nung chy Nguyn tc: phn hy mu xi mng bng cch nung vi hn hp nung chy, ha tan khi nng chy bng dung dch axit clo hydric long, c cn dung dch tch nc ca H2SiO3. Nung kt ta 10000=C 500C, dng dung dch HCl tch Si dng SiF4, nung, cn, lng mt i tng ng vi hm lng SiO2.

Cch tin hnh

Bc 1: ha tan mu
1g mu xi mng Nung 900- 9500C + Chn bch kim c sn 4 - 5g mu hh nung chy 30 pht, ngui

Chuyn khi nung chy vo bt s y bt s bng mt 30 ml HCl knh ng h Mu tan ht Dng nc si ra Khuy u thnh bt s v mt knh ng h Dung dch

Cch tin hnh.

Bc 2: chuyn thnh mui
Dung dch Dng a dm C cn trn bp cch ct,(100 -1100C)n kh nh ht mui C ht < 2mm Tip tc c 1- 1h30pht

ngui
15ml HCl , yn 10pht 90-100 ml Khuy u

Dung dch tan ht mui

Cch tin hnh.

Bc 3: Tch SiO3
Dung dch tan ht mui

Lc dung dch cn nng dd HCl 5% nng ra kt ta v thnh bt Lc gn 3 ln, chuyn kt ta vo giy lc Ra bng nc ct si n ht ClThu nc lc V nc ra

Bnh nh mc 500ml Chuyn giy lc c ngui. kt ta SiO2 vo Nung li to trn n chn bch kim, sy khi lng khng i Cn chn v t m1

Cch tin hnh.

Bc 4: thu SiO2
Chn cn m1 Vi git nc Lm bay hi + 0,5 ml H2SO4 (1+1) cht cha trong +10ml HF 40% chn Chn cn 3-4 ml HF. Lm bay hi n ngng bc khi trng Nung chn Pt v cn 10000C 500C

Chn cn

Ly ra, ngui n t0 phng

Cn m2

Nung li t0 trn n khi lng khng i

Cch tnh
%
1 2 SiO2=

100

Trong m1 l khi lng chn bch kim v kt ta trc khi x l bng HF (g). m2 l khi lng chn bch kim v kt ta sau khi x l bng HF (g). m l khi lng mu ly phn tch (g).

5. Ti liu tham kho.

1. 2.

3.

4.
5.

6.

7.

TCVN 141 : 2008 Trn Nguyn An Sa, GIO TRNH PHN TCH CNG NGHIP, trng i hc Cng nghip TP HCM, trung tam cng ngh ha hc, 2009. phanquangthoai@yahoo-upload, Bo co quy trnh sn xut v kim sot cht lng xi mng. Xi_mng_Portland.htm. Nguyn Thnh Long, Nguyn Quang Sng, Trn Vn Vit, Nguyn Vn Hin, CNG NGH SN XUT XI MNG L QUAY KH V CC VN MI TRNG Nguyn Vn Chnh, Trn V Minh Nht, NGHIN CU DNG X TRONG CNG NGHIP SN XUT XI MNG PORTLAN X, khoa k thut xy dng, i hc Bch khoa TP HCM, Mt s ti liu nc ngoi.