TRNG H CNG NGHIP TP H CH MINH KHOA CNG NGH HA HC ------

Tiu lun mn : PHN TCH CNG NGHIP

ti : Xc nh thnh phn SO3 v clorua trong ximng

GVGD : Th.s Trn Nguyn An Sa SVTH : Thiu Quang Minh MSSV : 09108781 Lp : DHPT5

NI DUNG

1 2 3 4 5

TNG QUAN V XIMNG PHM VI P DNG NGUYN TC QUY TRNH THC HIN TNH TON KT QU

TNG QUAN V XIMNG

1.1. nh ngha Xi mng l cht kt dnh thy lc c to thnh bng cch nghin mn clinker, thch cao thin nhin v ph gia. Khi tip xc vi nc th xy ra cc phn ng thy ha v to thnh mt dng h gi l h xi mng. Tip , do s hnh thnh ca cc sn phm thy ha, h xi mng bt u qu trnh ninh kt sau l qu trnh ha cng cui cng nhn c mt dng vt liu c cng v n nh nht nh.

TNG QUAN V XIMNG

1.2. Phn loi Trn quan im ho hc ngi ta phn chia nh sau : Xi mng

Nhm xi mng Silc

Nhm xi mng Alumin

Nhm xi mng khc

TNG QUAN V XIMNG

Xi mng Portland : Xi mng Portland thuc nhm xi mng Silic l loi vt liu c s dng ph bin nht trn ton th gii, n

l thnh phn c bn ca b tng, va, h. C thnh phn

ch yu l clinker Portland chim t l 95 - 97% v thch cao chim t l 3-5%. Ngoi ra ngi ta c th thm cc

cht ph khc vo thnh phn ca xi mng Portland (x

l cao, tro than, pouzzolan t nhin, v.v.).

TNG QUAN V XIMNG

Xi mng Alumin : Xi mng Alumin thuc nhm xi mng Alumin Mi trng nhit cao. C thnh phn ch yu l

clinker, thch cao, ngoi ra cn c th thm cc cht ph

khc vo thnh phn ca xi mng Alumin. Xi mng alumin c s dng ch yu cho b tng chu la v

mt s loi va, b tng c chng trong xy dng (ng

rn nhanh, cng cao, bn ho).

PHM VI P DNG

TCVN 141: 2008 xi mng Portland phng php phn tch ha hc

TCVN 7947 : 2008 xi mng Alumin phng php phn tch ha hc p dng: cho cc loi xi mng Portland, clanhke xi mng

Portland
Khng p dng: cho clanhke v xi mng Portland cha bari

NGUYN TC

3.1. Xc nh thnh phn SO3 trong xi mng Portland v xi mng Alumin Xc nh thnh phn SO3 bng cch cho kt ta sunfat di dng bari sunfat. Ri t bari sunfat thu c tnh ra khi lng ca anhydric sunfuric thng qua h s chuyn i t BaSO4 sang SO3 3.2. Xc nh thnh phn Clorua trong xi mng Portland Xc nh thnh phn Clorua bng cch cho kt ta clorua bng bc nitrat, ri sau chun lng bc nitrat d bng amoni sunfoxyanua

QUY TRNH THC HIN

4.1 Xc nh thnh phn SO3 4.1.1. Chun b dung dch

Cn khong 1g xi mng 5 ml HCl

45 ml H2O

Ha tan trong cc 100ml

Dm cho tan ht mu un si nh un 30 pht

Lc bng giy lc khng tro chy trung bnh

Lc
Nc si

Ra

Nc lc

QUY TRNH THC HIN

4.1.2. Quy trnh

Ly dung dch nc lc un si dd BaCl2 10%

un si dd nc lc

Cho dd BaCl2 vo dd nc lc

Khuy u

un nh trong 5 pht

yn kt ta t 4 n 8 gi Lc bng giy lc khng tro chy chm Lc kt ta

5 ln bng dd HCl 5% un nng

Nc si Ra kt ta v giy lc Nung kt ta v giy lc T 8000C 8500C

60 pht

Thu c khi lng m2

QUY TRNH THC HIN

4.2. Xc nh thnh phn Clorua

Cn khong 1g mu
Thm 50ml nc ct 20ml dd HNO3 Ha tan trong bnh tam gic 500ml 200 ml nc Lm ngui v pha long

5ml dd AgNO3

2 3 ml NH4Fe(SO4)2
Thc hin phn ng Bng dd NH4SCN Chun lng AgNO3 d Thu c th tch V

TNH TON KT QU

5.1. Xc nh thnh phn SO3 Hm lng anhydric sunfuric SO3 tnh bng phn trm theo cng thc:

trong m1 l khi lng chn c kt ta , tnh bng gam m2 l khi lng chn khng c kt ta, tnh bng gam m l khi lng mu tng ng vi th tch mu ly xc nh anhydric sunfuric, tnh bng gam 0.0343 l h s chuyn i t BaSO4 sang SO2

TNH TON KT QU

5.2. Xc nh thnh phn clorua Hm lng clorua tnh bng phn trm theo cng thc :

Trong : V0 l th tch dd tiu chun NH4SCN tiu th khi mu trng, tnh bng mililit V l th tch dd tiu chun NH4SCN tiu th khi mu th, tnh bng mililit 0.003546 l khi lng Cl- tng ng vi 1 ml dd NH4SCN 0.1 N. tnh bng gam m l khi lng mu ly phn tch , tnh bng gam

TI LIU THAM KHO

TCVN 141: 2008 xi mng Portland phng php phn tch ha hc TCVN 7947 : 2008 xi mng Alumin phng php phn tch ha hc Gio trnh Phn Tch Cng Nghip, Khoa Cng Ngh Ha hc, HCN TP HCM vi.wikipedia.org

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