KHOA CNG NGH HA HC

TIU LUN MN PHN TCH CNG NGHIP

PHN LOI, THNH PHN, TNH CHT KIM LOI XC NH HM LNG ST TRONG HP KIM NG
GVHD : Ths. TRN NGUYN AN SA SVTH : Nguyn Th Trc

MSSV : 09084641 LP : DHPT5

NI DUNG

Gii thiu v kim loi hp kim

Phng php xc nh hm lng st trong hp kim ng

Gii thiu v kim loi hp kim

Phn loi kim loi
Thnh phn, tnh cht tng loi kim loi Gii thiu s lc v hp kim: Tnh cht Phn loi

Phn loi kim loi

Kim loi

Kim loi en

Kim loi mu

Kim loi nh

Kim loi nng

Kim loi kh nng chy

Kim loi qu

Kim loi phn tn

Kim loi t him

Kim loi en
Gm st v cc hp kim ca st, chim 95% cc kim loi dng trong k trong k thut. Thnh phn chnh: Fe (95.7 99.8%), C (0.2 4.3%).

Ngoi ra cn c cc nguyn t khc: Si, P, S, Mn

Vt liu kim loi en: gang v thp ( gm st v cacbon)

Kim looi mu
Thnh phn : Kim loi nh: nhm,titan,magie. D: 1,7- 4,5 g/cm3 kim loi nng: ng, ch, niken, km, thic. D: 4,5- 11,3 g/cm3 Kim loi qu: vng, bc, nhm platin.

Hp kim

Hp kim

Hp kim n gin

Hp kim phc tp

Xc nh hm lng Fe trong hp kim ng bng phng php so mu

Phm vi p dng

Quy

Nguyn tc Tm tc quy trnh Cng thc tnh

trnh
phn

tch

Phm vi p dng
p dng TCVN 5917- 1995. Tiu chun ny quy nh phng php quang ph 1, 10 phenanthroline xc nh hm lng st trong hp kim ng. Phng php ny p dng xc nh hm lng st n 0,4 % vi cc hp kim ng

Nguyn tc
Chit st t phn mu th dng phc cht st (III) clo bng metyl isobutyl xeton, tin hnh php o quang ph phc cht st (III) phenantraline bc sng tng ng vi hp th cc i = 510 nm.

Quy trnh
Phn hy mu

Xy dng ng chun
Hm lng st

Phn hy mu

Cn 5g mu (chnh xc 0,001g) 40ml HCl

40ml H2O2 Lm ngui

un si 2 pht Lm ngui
Dung dch

Ha tan

Phn hy mu
Da vo hm lng Fe
0,03 0,4%

< 0,004%

0,003-0,04%

Cho ton b dung dch vo phu chit 250 ml

Pha long dung dch n 250ml bng HCl 1:1, ly 25 ml cho vo phu chit

Pha long dung

dch n 500ml
bng nc,ly 5ml cho vo phu chit

+ 20ml HCl 1:1

Phn hy mu
20ml metyl isobutyl cetol Lc 15s chit 5ml phenanthroline o A Tch 2 pha, ly pha hu c

Lc k nh mc ti 50 vch yn 30p

Lc 20s 2ln
50

10ml acid ascobic 1 ln

Dd khng cn mu ng

Xy dng ng chun
20ml axit ascobic 5ml phenanthroline

Lc k
50ml 50ml 50ml

lng 1 phut
50ml

0-20ml dd B
( Tng ng

02.10-4 g Fe )

o quang
50ml

www.themegallery.com

Xy dng ng chun

Bnh nh mc 50 ml DD B (ml) Acid ascobic phenanthroline

1 0

2 2

3 4 5 ml

4 6 20 ml

5 8

6 10

nh mc bng nc ct (50ml) ri o quang 510 nm

Xy dng ng chun
o mt quang ca dung dch cha trong tng bnh. Dung dch so snh l dung dch trong bnh 1 khng c cht cn xc nh T hm lng st c trong mi bnh v gi tr mt quang tng ng => xy dng ng chun. Da vo ng chun v mt quang o c ca mu

=> hm lng st trong mu

Cng thc tnh ton

Hm lng st (Fe) tnh bn phn trm xc nh theo phng php th theo cng thc: Hm lng nh hn 0,004% : Fe = m. 0,00002 Hm lng t 0,003 n 0,04% : Fe = m.0,0002 Hm lng t 0,03 n 0,4% : m.0,002 Trong : m l khi lng st c trong phn dung dch mu ly

xc nh (g)

Ti liu tham kho

[1]. TCVN 5917:1995, Hp kim ng xc nh hm lng st phng php quang ph 1.10 phenanthroline. [2].Gio trnh phn tch cng nghip, TT cng ngh ha hc- trng
i Hc Cng Nghip Tp.HCM, 9 2009.

Thank You!

L/O/G/O