Trng i Hc Cng Nghip Tp.

H Ch Minh
Khoa Cng Ngh Ha Hc

Tiu lun mn hc Phn Tch Cng Nghip

Ti: Phn Tch Hp Kim ng

GVGD: Ths Trn Nguyn An Sa SVTH: L Th Thu Thy Lp: DHPT5 MSSV: 09121471
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Ni Dung
1 2 3 4

Gii Thiu Chung V Hp Kim ng Cc Ch Tiu Phn Tch Quy Trnh Phn Tch Ti liu tham kho

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Gii thiu chung v hp kim ng

ng thanh l hp kim ca ng vi nhng kim loi mu khc tr Zn. ng thau l hp kim ca ng vi Zn. Click to edit Master subtitle style Ta xt ch yu ng thau v ng thau a nguyn.

Hp kim ng c bit c nhng tnh cht c l c bit dng trong cc thit b o, thit b in..
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Cc Ch Tiu Phn Tch

Ch tiu1 Xc nh Hm Lng ng Bng Phng Php in Phn (Theo TCVN 5915 1995 ISO 1554 1976). Ch tiu 2 Xc nh Hm Lng Photpho Bng Phng Php Quang Ph Molipddovanaadat (Theo TCVN 5924 1995 ISO 4741 1984). Ch tiu 3 Xc nh Hm Lng Niken (Hm Lng Thp) (Theo TCVN 5916 1995 ISO 1810 1976).

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Quy Trnh Phn Tch Hm Lng ng

v

Phm vi p dng:

Phng php in phn xc nh hm lng ng ca hp kim ng c v gia cng p lc lm t hp kim ng km, ng nhm v ng niken km.
v

Nguyn l:

Xc nh hm lng ng bng in phn trong dung dch HNO2 floboric cha phn mu th.

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Quy Trnh Phn Tch Hm Lng ng

15ml H3BO3 2ml HCl 30ml HNO3

Cn 2,5g mu
y np

Dung dch 1
ngui thm 50ml H2O Ra np v thnh cc Nung 1h 90oC

Dung dch 2
Cho dung dch NH3

Kt ta

+ HNO3 d

Dung dch 3

nh mc 300ml

Dung dch mang in phn

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Nhng cc in cc(catot platin kiu Winkler v anot xon c lm bng dy hp kim platin) vo trong dung dch trn v y cc li. Ta in phn trong iu kin khng khuy vi mt dng l 0,6A/dm2 Khi ta thy dung dch bt u gim mu, th phi gim mt dng xung khong 0,3A/dm2 v ra np, thnh cc v cc in cc. Tip tc in phn khi ng ngng kt hon ton.

Quy Trnh Phn Tch Hm Lng ng

Khi ht ng, khng rt in, ta nhanh chng thay cc ng dung dch bng cc khc c cha 350ml nuc ct, in phn tip khong 15ph.

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Cng Thc Tnh Ton

Trong : m0: khi lng mu (g) m1: khi lng ng ngng t (g)

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Quy Trnh Phn Tch Hm Lng Phtpho

v

Phm vi p dng:

Phng php ny p dng xc nh hm lng photpho t 0,0005 0,5% trong cc loi ng v hp kim ng.
v

Nguyn l:

Ha tan mu th vi HNO3 v kh cc nguyn t gy nh hng bng cch cho bc hi vi HBr, HF, HClO4. Phn hy phootpho khng tan bng cch cho nng chy vi Na2CO3

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Quy Trnh Phn Tch Hm Lng Photpho

Cn 1g mu 10ml HNO3 0,5ml HCl 10ml HClO4 Cc PTFE
Thm 50ml H2O 10ml amoni molipdat I 15ml isobutal Lc k trong 30s

+ 10ml H2O + 10ml HBr

Vi ml HNO3 + 30ml H2O un si 10ph

Lp li qu trnh 2 ln vi 5ml isobutanol

Loi b nc ly pha hu c nh mc vi metanol 50ml 5/14/12

+ 15ml SnCl2 Lc k trong 30s

Gp 3 ln chit Ra 2 ln vi 5ml H2O

Quy Trnh Phn Tch Hm Lng Phtpho

o ngay bng quang ph k vi cuvet 1cm, ti 623nm. S dng hn hp 1 + 1 ca isobutanol v metanol lm dung mi so snh. Lm mu trng vi tt c cc bc nh trn.

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Xy Dng ng Chun

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Cng Thc Tnh Ton

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Quy Trnh Phn Tch Hm Lng Niken

v

Phm vi p dng:

Phng php quang ph Dimethylglyoxime xc nh hm lng Niken trong hp kim ng. Phng php ny p dng xc nh hm lng Niken n 2,55% trong mi loi hp kim ng.
v

Nguyn l:

Chit Niken trong phn mu th dng phc Dimethylglyoxime mu vng bng clorofom v tin hnh o quang bc sng khong 405nm.

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Quy Trnh Phn Tch Hm Lng Niken

20ml HCl 10ml H2O2 un si 1ph ngui dd 500ml Ht 25ml dd nh mc 5ml HONH3Cl + 50ml dd phc Cuvet 2cm Chnh pH= 6,5 -7,2 3ml dimethylglioxime Lc k dd trong 60s 20ml clorofom Lc k trong 40s

1g mu

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Quy Trnh Phn Tch Hm Lng Niken

Lm tng t nh trn i vi mu trng, nhng khng cho phn mu th. Chun b 1 cuvet cha clorofom nh sau:

clorofom Na2SO4 khan

Cuvet 2cm

Ta tin hnh o quang vi dung dich th v dung dich mu trng ti bc sng l 405nm, iu chnh my quang ph v hp thu bng 0 ng vi clorofom.
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Xy Dng ng Chun

Ht 100ml dung dich Ni chun cho vo bnh nh mc 500ml, nh mc ti vch. Chun b 6 bnh nh mc 500ml, ht ln lt 0, 5, 10, 20, 30, 50ml dung dch trn, thm 1g ng khng cha Ni, tin hnh ha tan nh phn mu trn. Ht 25ml dung dch trn cho vo phu chit 250ml, thm 5ml hydroxylammonium clorit v 50ml dung dch phc, tip tc tin hnh nh phn mu. Tin hnh o quang v xy dng ng chun.

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Cng Thc Tnh Ton

Vi: m1 l khi lng mu (g). m0 l khi lng Ni c trong phn mu th hiu chnh theo mu trng (mg).

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Lu
v

Nu d on hm lng Ni khong 0,5%, cn 1g mu. Nu hm lng Ni khong 0,5 2,5% , cn 0,4g mu v cho thm 0,6g ng tinh khit khng cha Ni. Nu hm lng Ni d on qu thp, c kt qu chnh xc cn s dng cuvet dy 4cm hoc o bc sng 365nm.

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Ti Liu Tham Kho

1.

TCVN 5924 1995 ISO 4741 1984. TCVN 5915 1995 ISO 1554 1976. TCVN 5916 1995 ISO 1810 1976. Phn tch kim loi, Khoa Cng Ngh Ha Hc Chuyn Nghnh Ha Phn Tch, Chng 2 t trang 43 54.

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