OXI - LU HUYNH Nng cao

I. T khi
Bi 1: T khi hi ca hn hp gm ozon v oxi i vi hidro l 22,4. Xc nh % v th tch ca mi cht trong hn hp. Bai 2: Co mt hn hp khi gm oxi va ozon. Hn hp khi nay co ti khi i vi khi hidro bng 18. a. Tinh % ( theo th tich) mi khi trong hn hp. hn hp). a. Tinh % ( theo th tich) mi khi trong hn hp b. Tinh % ( theo khi lng mi khi trong

Bai 3: 5,6 lit hn hp (Z) gm O2 va Cl2 ktc. Ti khi cua (Z) i vi khi H2 la 29. b. Tinh s mol mi khi trong hn hp. Bai 4: Hn hp (A) gm co O2 va O3, ti khi cua (A) i vi H2 la 19,2. a. Mt mol hn hp (A) co th t chay hoan toan bao nhiu mol khi CO b. Tinh mol hn hp (A) cn dung t chay ht 1 mol hn hp (B) gm H2 va CO, bit ti khi cua B so vi H2 la 3,6. Bai 5: t chay hoan toan m gam Cacbon trong V lit khi oxi ktc, thu c hn hp khi (A) co ti khi so vi H2 la 15. a. Tinh % ( theo th tich ) mi khi trong hn hp (A). b. Tinh m va V. Bit rng khi dn hn hp khi (A) vao binh ng dung dich Ca(OH)2 ( d) thy co 6 gam kt tua . Bai 6: t chay hoan toan m gam cacbon trong V lit khi oxi ktc, thu c hn hp khi (A) co ti khi so vi oxi la 1,25. a. Tinh % ( theo th tich ) mi khi trong hn hp (A). b. Tinh m va V. Bit rng khi dn hn hp khi (A) vao binh ng dung dich Ca(OH)2 ( d) thy co 6 gam kt tua. Bi 7. Ha tan hon 14,4 gam hn hp Fe v FeS bng 200 ml dung dch HCl va thu c hn hp kh X c t khi so vi H2 l 9. Tnh % Fe v khi lng v nng mol ca HCl dng ? Bi 8. Hn hp X gm Fe v S. Nung nng 20g X phn ng xy ra hon ton thu c hn hp Y. Ha tan hon Y bng dung dch HCl d thu c hn hp kh Z c t khi so vi H2 l 6,333. Tnh %Fe v khi lng ? Bi 9. Hn hp X gm Al v S. Nung nng 10,2g X phn ng xy ra hon ton thu c hn hp Y. Ha tan hon Y bng dung dch HCl d thu c hn hp kh Z c t khi so vi H2 l 9. Tnh %Al v khi lng ?

II. Tng gim th tch v hiu sut.

Bai 1: Co hn hp khi oxi va ozon. Sau mt thi gian, ozon bi phn huy ht, ta c mt cht khi duy nht co th tch tng 2% a. Hay giai thich s gia tng th tich cua hn hp. b. Xac inh % ( theo th tich) cua mi khi trong hn hp u. Bai 2: un nong 3 lit SO2 vi 2 lit khi O2 xuc tac V2O5 sau khi phan ng hoan toan thu c hn hp khi (A). Tinh % ( theo th tich) mi khi trong hn hp (A), bit cac khi o cung iu kin nhit ap sut. Bai 3: un nong 6 lit SO2 vi 4 lit khi O2 xuc tac V2O5 sau khi phan ng mt thi gian thu c hn hp khi (B) co th tich la 9 lit , bit cac khi o cung iu kin nhit ap sut. a. Tinh % ( theo th tich) mi khi trong hn hp (B). b. Tinh hiu sut phan ng Bi 4. un nong 0,3 mol SO2 vi 0,2 mol khi O2 (xuc tac V2O5 ) sau khi phan ng mt thi gian thu c hn hp khi (X) co th tich la 8,96 lit ( ktc ). a. Tinh % ( theo th tich) mi khi trong hn hp (X). b. Tinh hiu sut phan ng Bi 5. 13,44 lt kh X ( SO2 v O2 ) c t khi so vi H2 l 24. un nng X vi V2O5 sau mt thi gian thu c hn hp Y c th tch l 11,2 lt ( ktc ). 1

a. Tinh % ( theo th tich) mi khi trong hn hp X v Y.

b. Tinh hiu sut phan ng

Bi 6. Hn hp kh X ( SO2 v O2 ) c t khi so vi He l 12. un nng X vi V2O5 sau mt thi gian thu c hn hp Y c khi lng l 14,4 gam. a. Tinh % ( theo th tich) mi khi trong hn hp X ? b. Tinh hiu sut phan ng Bi 7. Hn hp kh X ( SO2 v O2 ) c t khi so vi H2 l 22,4. un nng X vi V2O5 sau mt thi gian thu c hn hp Y c t khi so vi H2 l 27,185. a. Gii thch ti sao t khi so vi H2 li tng sau phn ng ? b. Tinh hiu sut phan ng Bi 8. Hn hp kh X ( SO2 v O2 ) c t khi so vi H2 l 25,6. un nng X vi V2O5 sau mt thi gian thu c hn hp Y c t khi so vi H2 l 32. a. Gii thch ti sao t khi so vi H2 li tng sau phn ng ? b. Tinh hiu sut phan ng Bi 9. Hn hp A gm SO2 v khng kh c t l mol l 1: 5. Nung nng hn hp A vi xc tc V 2O5 th thu c hn hp kh B, t khi ca hn hp A so vi B l 0,93 (Bit khng kh c 20% O2 v 80% N2). Hiu sut ca phn ng trn ?

III. Bo ton khi lng v bo ton electron

Bai 1: Chia 10 gam hn hp gm hai kim loai A, B co hoa tri khng i thanh hai phn bng nhau. Phn 1 t chay hoan toan cn V lit khi O2 kct, thu c 5,32 gam hn hp hai oxit. Phn con lai hoa tan hoan toan trong dung dich HCl ( d) thy co V lit khi H2 thoat ra ktc va m gam mui clorua. Tinh cac gia tri: V, V, m? Bai 2: Hn hp khi (A) gm khi Cl2 va O2. A phan ng va ht vi mt hn hp gm 4,8 gam Mg va 8,1 gam Al tao ra 37,05 gam hn hp cac mui clorua va oxit cua hai kim loai. Xac inh % ( theo th tich ) cua mi khi trong hn hp (A). Bi 3. Ha tan 32 gam X ( Fe, Mg, Al, Zn ) bng dung dch HCl d thu c 2,24 lt H 2 (ktc). Mt khc 32 gam X tc dng vi H2SO4 c nng d thu c 3,36 lt SO2 ( ktc ). Tnh %Fe v khi lng ? Bi 4. Ha tan m gam hai kim loi A v B c ha tr khng i bng dung dch HCl d thu c 5,6 lt H 2 ( ktc ). Mt khc ha m hn hp bng H2SO4 c d thu c V lt SO2 ( ktc ). Tnh V ? Bi 5: 6,72 gam phoi bo st ngoi khng kh, sau mt thi gian thu c 7,68 gam hn hp A gm Fe, FeO, Fe3O4, Fe2O3. Ha tan hon ton hn hp A trong dung dch H2SO4 c nng d thu c V lt kh SO2(ktc). Tnh V v s mol H2SO4 tham gia phn ng. Bi 6: m gam Fe ngoi khng kh, sau mt thi gian bin thnh hn hp X c khi lng 12 gam gm FeO, Fe2O3, Fe3O4 v Fe. Ha tan ht X vo dung dch H2SO4 c thu c 3,36 lt kh SO2 o ktc. Tnh m v s mol H2SO4 p/ng ? Bi 7: m gam Fe ngoi khng kh, sau mt thi gian c 7,2 gam hn hp X gm FeO, Fe2O3, Fe3O4 v Fe. Ha tan ht X vo dung dch H2SO4 c thu c V lt kh SO2 ( ktc). Tnh m v V bit s mol H2SO4 p l 0,2 mol. Bi 9. Cho 12,8 gam hn hp A gm Fe, FeO, Fe3O4, Fe2O3 tc dng hon ton vi dung dch H2SO4 c nng thu c 2

4,48 lt kh SO2 ( ktc ) v dung dch X. Tnh khi lng mui c trong X ? Bi 10. Cho 23,2 gam hn hp X gm Fe, FeO, Fe3O4, Fe2O3 tc dng hon ton vi dung dch H2SO4 c nng thu c 1,12 lt kh SO2 ( ktc ) v dung dch Y. Tnh khi lng mui c trong Y ? Bi 11: Cho 10,24 gam hn hp A gm Fe, FeO, Fe3O4, Fe2O3 tc dng hon ton vi dung dch H2SO4 c nng thy c 0,27 mol H2SO4 tham gia phn ng, sau phn ng thu c dung dch B. Cho dung dch B tc dng vi dung dch NaOH d, lc kt ta v nung n khi lng khng i thu c m gam cht rn. Xc nh gi tr ca m. IV. Hn hp HCl v H2SO4 phn ng vi baz tan. Bi 1. Tnh th tch dung dch A ( NaOH 1M v Ca(OH)2 0,5M ) trung ha 100 ml dung dch KOH 1M. Bi 2. Tnh th tch dung dch A ( NaOH 1M v Ca(OH) 2 1M ) trung ha 200 ml dung dch B ( HCl 1M v HNO31M) Bi 3. Tnh th tch dung dch A (NaOH 1M v Ba(OH) 2 0,5M ) trung ha 200 ml dung dch B (HCl 1M v H2SO4 0,5M) Bi 4. Tnh th tch dung dch A( KOH 0,5M v Ca(OH)2 0,5M ) trung ha 200 ml dung dch B ( HCl 1M v H2SO4 1M)

V. Xc nh cht da vo bo ton E.
Cu 1. Ha tan 4,64 gam mt oxit st trong dung dch H2SO4 c nng d thu c 0,224 lt SO2. Xc nh oxit st ? Cu 2. Ha tan 3,6 gam mt oxit st trong dung dch H2SO4 c nng d thu c 0,224 lt SO2. Xc nh oxit st ? Cu 3. Ha tan 16 gam mt oxit st trong dung dch H 2SO4 c nng d thu c 40 gam mui khan. Xc nh oxit st ? Cu 4. Ha tan 2,4 gam Mg bng dung dch H2SO4 c nng d thu c 0,56 lt kh X. Xc nh X ? Cu 5. Ha tan 2,4 gam Mg bng dung dch H2SO4 c nng d thu c 2,24 lt kh X. Xc nh X ? Cu 6. Ha tan hon ton mt oxit FexOy bng H2SO4 c, nng thu c 2,24 lt SO2 ktc, phn dung dch cha 120g mt mui st duy nht. Xc nh cng thc ca oxit st