Trng THPT Nguyn Ch Thanh T Ha Hc A.

L Thuyt:

CNG HK2 NH: 2011-2012

CNG N TP HC K II KHI 11 (2011 2012 )

Chng 5: HIDROCACBON NO: c tn, TCHH v iu ch ca ankan Chng 6. HIDROCACBON KHNG NO - c tn cc hidrocacbon khng no - Tnh cht ha hc v iu ch ca anken, ankadien, ankin. Chng 7. HIDROCACBON THM - c tn cc ng ng ca benzen (n gin) v tnh cht ha hc ca benzen, stiren Chng 8. ANCOL PHENOL - c tn cc ancol no, khng no n chc mch h (n gin) v TCHH ca ancol, phenol. Chng 9. ANDEHIT AXIT CACBOXYLIC - c tn cc andehit n chc, cc axit cacboxylic n chc. - Tnh cht ha hc ca Andehit, axit cacboxylic v cch iu ch chng. B. Bi Tp: cc dng ton sau y:. 1/ Nhn bit: cc dung dch benzen v ng ng, ancol no n chc, a chc, phenol, anehit no n chc, axit cacboxylic. 2/ Chui phn ng: - Mt s chui iu ch polime c bn, iu ch ancol, andehit, axit cacboxylic. 3/ Ton hn hp: - t chy hn hp hidrocac bon khng no. - t chy hn hp ancol no, n chc, mch h - Hn hp ancol no n, phenol tc dng vi Na hoc NaOH - t chy hn hp anhit, axit cacboxylic no n chc, mch h - Ton axit cacboxylic no n chc tc dng vi kim loi, baz. - Ton phn ng este ha, hiu sut.

MT S BI TP THAM KHO
1/ Phn bit cc dd sau: a/ benzen, toluen, stiren, nc b/ etanol, glixerol, phenol, nc c/ Propan-1-ol, propan-2-ol, glixerol d/ Etanal, axit axetic, glixerol, phenol e/ axit fomic, axit axetic, etanol, dd amoniac 2/ Hon thnh chui phn ng: a/ CaC2 C2H2 C2H4 C2H5OH C2H4 C2H4(OH)2 (C2H4(OH)O)2 b/ CH4 C2H2 C2H4 CH2=CHCl PVC c/ CH4 HCHO CH3OH CH3COOH (CH3COO)2Ca d/ CH4 C2H4 C2H5OH CH3CHO CH3COOH CH3COOC2H5 3/ Mt s dng ton: 1/ t chy 3 lt hn hp hai ankan k tip nhau trong dy ng ng dn sn phm ln lt qua bnh (1) ng CaCl2 khan ri bnh (2) ng dung dch KOH. Sau th nghim khi lng bnh (1) tng 6,43g bnh (2) tng 9,82g. Lp CTPT ca hai ankan v tnh % theo th tch ca hai ankan trong hn hp cc th tch kh o kc? 2/ A v B l hai anken k tip nhau trong dy ng ng. Cho 13,44 lt hn hp trn qua mt bnh ng dung dch brom d thy bnh tng thm 28g a/Xc nh CTPT vit CTCT ca hai anken (c th c) b/Cho2 anken trn td vi HCl th thu c ti a 3 sn phm. Xc nh CTCT ca 2 anken v gi tn ca chng 3/ t chy 8,96 lt hn hp X gm hai olfin A v B ng ng k tip th thy khi lng CO2 ln hn khi lng H2O l 39 gam. a/Xc nh CTPT ca A v B b/Tnh % theo th tch hn hp X 4/ Cho 62,4g dd gm phenol, ru etylic c ln nc tc dng vi Na kim loi th thu c 11,2 lt kh (ktc). Mt khc, nu cho lng hn hp ny tc dng vi 200ml dung dch NaOH 2M th va . Tm thnh phn % v khi lng ca hn hp? 5/ Cho 0,87(g) mt anhit no n chc phn ng hon ton vi AgNO3/NH3 sinh ra 3,24(g)Ag a/ Vit CTCT ca anhit b/ Cho 11,6(g) anhit trn phn ng vi H2(Ni xc tc) .Tnh VH2 (kc) phn ng v khi lng sn phm thu c gi s phn ng xy ra hon ton? 6/ trung ha 20ml dung dch ca mt axit hu c no n chc cn dng 30ml dung dch NaOH 0,5M a/Tnh nng mol/l ca dung dch axit b/C cn dung dch trung ha thu c 1,44g mui khan. Xc nh CTPT, CTCT v gi tn axit 7/ Cho 10g hn hp A gm axit fomic v axetic tc dng vi 392,8ml dung dch NaHCO3 0,5M. Sau phn ng phi dng 100ml dung dch HCl 0,36M tc dng ht vi lng NaHCO3 cn tha

Trng THPT Nguyn Ch Thanh T Ha Hc CNG HK2 NH: 2011-2012 a/Vit phn ng xy ra. Tnh % khi lng mi axit trong hn hp b/Cho 10g hn A tc dng vi 23 g ru etylic c H 2SO4 lm xc tc. Tnh lng sn phm hu c thu c nu hiu sut l 90% ?

MT S CU HI TRC NGHIM
1: Cho ln lt cc cht C2H5Cl, C2H5OH, C6H5OH vo dd NaOH un nng. S cht tham gia phn ng l A. 0. B. 2. C. 3. D. 1. o 2: Thc hin phn ng trime ho C2H2 c xc tc l cacbon hot tnh 600 C iu ch benzen. Nu dng 28 lt C2H2 (ktc) v hiu sut phn ng l 60% th khi lng benzen thu c l bao nhiu? A. 13 gam. B. 19,5 gam. C. 32,5 gam. D. 54,17 gam. 3: Cho cc cht: Propen, propan, propin. Thuc th dng nhn bit cc cht l A. dd AgNO3/NH3, dd Cl2. B. dd AgNO3/NH3, dd Br2. C. dd KMnO4, HBr. D. dd Br2, dd Cl2. 4: Dng phn ng ha hc no chng minh nguyn t hiro trong nhm hiroxyl (-OH) ca phenol linh ng hn nguyn t hiro trong nhm hiroxyl (-OH) ca ancol etylic ? A. C6H5OH + Na. B. C6H5OH + NaOH. C. C6H5OH + Br2. D. A, B u ng. 5: Cho cc cht c cng thc cu to nh sau: HO CH2 CH2 OH (X); HO CH2 CH2 CH2 OH (Y); HO CH2 CH(OH) CH2 OH (Z); CH3 CH2 O CH2 CH3 (R); CH3 CH(OH) CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch c mu xanh lam l: A. X, Y, R, T. B. X, Y, Z, T. C. Z, R, T. D. X, Z, T. 6: Cho cc cht sau: metan, etilen, but-1- in, but -2- in, axetilen, andehit axetic, glixerol, axeton. Trong cc cht trn, c bao nhiu cht tc dng vi dung dch AgNO3/NH3 to thnh kt ta? A. 3. B. 2. C. 1. D. 4. 7: Cho cc cht: phenol, metanol, etanol, imetyl ete. Cht c nhit si cao nht l A. etanol. B. imetyl ete. C. phenol. D. metanol. 8: S ng phn ancol ng vi ctpt C3H8O v C4H10O ln lt bng: A. 2, 5. B. 2, 3. C. 3, 4. D. 2, 4. 9: Trong cc cht sau y cht no c ng phn hnh hc? A. CH3 CH = CH CH3. B. CH2 = CH CH2 CH3. C. CH2 = CH CH3. D. CH3 CH = C(CH3) CH3. 10: nhn bit propanal v axeton ngi ta dng: A. qu tm. B. AgNO3/NH3. C. H2, xt Ni, t0. D. dd Na2CO3. 11: Hiro ho (cng H2, xt Ni, t0) hon ton 4,4g mt anehit no, n chc, mch h X thu c cht Y. Cho ton b lng Y sinh ra tc dng vi Na (d) th thu c 1,12 lt kh (ktc). Cng thc cu to ca X l? A. CH3CH2OH. B. CH3OH. C. CH3CHO. D. HCHO. 12: t chy mt hircacbon A thu c 17,6 gam CO2 v 9,0 gam H2O. Xc nh dy ng ng ca A? A. Ankan. B. Ankin. C. Ankaien. D. Anken. 13: Khi cho glixerol tc dng vi Cu(OH)2. Hin tng xy ra l: A. Cu(OH)2 khng tan v c kt ta gch. B. Cu(OH)2 tan ra to thnh dd c mu xanh lam. C. Cu(OH)2 tan ra to thnh dd c mu lam thm. D. Khng c hin tng g. 14: Cho 5,4 g mt anehit no, n chc, mch h thc hin p trng bc hon ton thu c 16,2 g Ag kt ta. Cng thc ca anehit l A. CH3CHO. B. HCHO. C. C2H5CHO. D. C3H7CHO. 15: Mt ancol no (X) c cng thc l (C2H5O)n. Hi cng thc phn t ca X l g? A. C8H20O4. B. C6H15O3. C. C2H5O. D. C4H10O2. 16: Khi tch nc t ancol 3-metylbutan-2-ol, sn phm chnh thu c l A. 3-metylbut-1-en. B. 2-metylbut-2-en. C. 2-metylbut-3-en. D. 3-metylbut-2-en. 0 17: Khi ln men 0,1 lt ancol etylic 92 vi hiu sut phn ng 80%. Bit khi lng ring ancol etylic bng 0,8 g/ml. Khi lng axit axetic thu c l bao nhiu? A. 96,8 g. B. 76,8 g. C. 7,68 g. D. 30,9 g. 18: Cho 9,2 gam hn hp B gm ancol propylic v mt ancol (A) thuc dy ng ng ca ancol etylic tc dng vi K d thu c 2,24 lt kh (ktc). Cng thc cu to thu gn ng ca ancol A l A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH. 19: Mt anehit (Z) trong oxi chim 37,21% theo khi lng v Z ch cha mt loi nhm chc. C 1 mol (Z) phn ng vi dung dch AgNO3/NH3 un nng to ra 4 mol Ag. Vy cng thc cu to ng ca Z l A. HCHO. B. CH3CHO. C. CHO CH2 CHO. D. CHO C2H4 CHO. 20: Cho 5,4 g mt anehit no, n chc, mch h thc hin p trng bc hon ton thu c 16,2 g Ag kt ta. Cng thc ca anehit l: A. CH3CHO. B. HCHO. C. C2H5CHO. D. C3H7CHO