thi th i hc, cao ng

Mn thi: Ho hc
Thi gian lm bi: 90 pht (Khng k thi gian pht )
H, tn th sinh:..........................................................................
M thi:
S bo danh:...............................................................................
( thi chnh thc c 05
trang)
Bit nguyn t khi ca cc nguyn t: H = 1; O = 16; C = 12; S = 32; N = 14; Na = 23; Ca = 40;
Mg = 24; Fe = 56; Zn = 65; Cu = 64; He = 4; P = 31; K = 39.
A. PHN CHUNG CHO TT C TH SINH ( 40 cu, t cu 1 n cu 40)
Cu 1: un nng a gam este X n chc trong dung dch NaOH d to ancol Y v 16,4 gam mui natri ca
axit cacboxylic. Lng ancol Y lm bay hi c th tch bng 4,48 lt ktc. un nng Y vi H 2SO4 c
nhit thch hp to ra sn phm hu c Z c

M Z 37
= . CTCT ca X l
M y 23

A. HCOOCH2 -CH3 .

B. HCOOCH2 -CH2 -CH3 .

C. C2H5COOCH2 -CH3 .

D. CH3COOCH2-CH3 .

Cu 2: Cho cc polime sau: PE (1), PVC (2), cao su buna (3), poli isopren (4), amiloz (5), amilopectin (6),
xenluloz (7), cao su lu ho (8). Cc polime c cu trc mch h, khng phn nhnh l
A. 1,2,4,6,8.
B. 1,2,3,4,6,7.
C. 1,3,4,5,8.
D. 1,2,3,4,5,7.
Cu 3: Cht hu c X cha C, H, O khi thu phn trong mi trng axit thu c 2 cht hu c. t chy
hon ton 2 cht hu c trn thu c 2 th tch CO 2 bng nhau (o cng iu kin t0, p). T khi hi ca X
so vi CO2 bng 2. CT ca X l
A. HCOOC3H7 .
B. C2H5COOCH3 .
C. CH3COOC2H5 .
D. HCOOCH3 .
Cu 4: Khi t chy polime X ch thu c kh CO2 v hi nc vi t l mol tng ng l 1:1. X l
A. poli propilen.
B. cao su bu na.
C. poli stiren.
D. tinh bt.
Cu 5: Nit c ho tr cao nht trong hp cht l
A. 4.
B. 5.
C. 3.
D. 6.
Cu 6: Oxi ho 4 gam mt ancol n chc c 5,6 gam hn hp gm anhit, ancol d v nc. Ancol
cho l
A. ancol cha no.
B. CH3OH.
C. C2H5OH.
D. C3H7OH.
Cu 7: Thuc th dng thm phn bit 4 dung dch: Na2SO4,Na2CO3,BaCl 2,KNO3 l
A. qu tm.
B. AgNO3.
C. H2SO4.
D. NaOH.
Cu 8: X phng ho hon ton 8,8 gam este bng dung dch NaOH thu c mui X v ancol Y. Nung ton
b X vi oxi d thu c 5,3 gam Na2CO3, kh CO2 v hi nc. Chng ct ly ancol Y khan ri cho tc dng
ht vi Na thu c 6,8 gam mui. CTPT ca este l
A. CH3COOCH3 .
B. CH3COOC2H5 .
C. HCOOCH3 .
D. CH3COOC2H3 .
Cu 9: t chy hon ton a gam este X cn 4,48 lt O 2 ktc. Sn phm chy cho i qua dung dch NaOH d
thy khi lng dung dch tng 12,4 gam. Mt khc phn tch a gam X thy tng khi lng ca C v H l 2,8
gam. X l
A. C2H4O2 .
B. C4H6O2.
C. C4H8O2.
D. C3H6O2.
Cu 10: Cho cc cht: NH3 (1), C6H5NH2 (2), (C6H5)2NH (3), (CH3)3N (4), (CH3)2NH (5), CH3NH2 (6), NaOH
(7). Dy cht c th t tnh baz gim dn l
A. 7 > 4 > 5 > 6 > 1 > 2 > 3.
B. 7 > 4 > 6 > 5 > 1 > 2 > 3.
C. 7 > 1 > 2 > 4 > 5 > 6 > 3.
D. 7 > 5 > 6 > 4 > 1 > 2 > 3.
Cu 11: Thu phn peptit H2N-CH2 -CO-HN-CH(CH3 )-CO-NH-CH(COOH)-(CH2 )2 -COOH thu c
sn phm l
A. khng xc nh c.
B. alanin, glixin.
C. axit glutamic, alanin, glixin.
D. axit glutamic, alanin.
Cu 12: Cho cc dung dch ring bit cha cc cht: anilin (1), metylamin (2), glixin (3), axitglutamic (4), axit
2,6- iaminohexanoic (5), H2NCH2COONa (6). Cc dung dch lm qu tm ho xanh l
A. 1, 2.
B. 2, 3, 6.
C. 2, 5.
D. 2, 5, 6.
Trang 1/5 - M thi 060

Cu 13: Mt este X c cng thc RCOOR, (R, c 6 nguyn t C), c t khi hi so vi oxi nh hn 4,5. Khi
x phng ho X bng dung dch NaOH thu c 2 mui c t l khi lng l 1,4146. CTCT ca X l
A. C3H7COOC6H5 .
B. HCOOC6H5 .
C. C2H5COOC6H5 .
D. CH3COOC6H5 .
Cu 14: Ho tan hn hp 2 mui KNO3, NaCl vo nc c dung dch X. C cn cn thn X c cht rn
Y c cha s loi tinh th l
A. 5.
B. 4.
C. 3.
D. 2.
Cu 15: Ch c php dng cc cht:
O2N(CH2 )6 NO2 , Br(CH2 )6 Br, Fe, ddHCl, ddNaOH,O2 ,Cuviu kin phn ng c .iu ch
nilon -6,6 cn s phn ng ti thiu l
A. 4.
B. 5.
C. 7.
D. 6.
Cu 16: Trn 2 th tch bng nhau ca C3H8 v O2 ri bt tia la in t chy hon ton. Sau khi lm lnh
(tch nc ngng t) ri a v nhit ban u. Th tch hn hp kh sau (Vs) so vi th tch hn hp kh ban
u (V) l
A. Vs > V.
B. Vs : V = 7 : 10.
C. Vs = V .
D. Vs = 0,5 V.
Cu 17: t chy 0,39 gam cht hu c X hoc Y u thu c 1,32 gam CO2 v 0,27 gam H2O, dX Y =3.
Cng thc phn t ca X v Y ln lt l
A. C8H8 v C2H2.
B. C2H2 v C6H6.
C. C6H6 v C2H2.
D. C4H4 v C2H2.
Cu 18: Ho tan hon ton 20,9 gam hn hp gm Mg, Zn, Fe, Cu trong dung dch H 2SO4 c, nng d thu
c 10,08 lt kh SO2 ktc l sn phm kh duy nht. S gam mui trong dung dch sau phn ng l
A. 32,4.
B. khng xc nh c.
C. 46,4.
D. 64,1.
Cu 19: C5H8O2 l este mch h. Khi x phng ho th s ng phn cho ra 1 anhit v s ng phn cho ra 1
mui ca axit khng no ln lt l
A. 4, 4.
B. 4, 3.
C. 2, 3.
D. 3, 2.
Cu 20: X l cht hu c cha C, H, O c th cho phn ng trng gng v phn ng vi dung dch NaOH.
t chy ht a mol X thu c tng cng 3a mol CO2 v H2O. X l
A. CHO-CH2-COOH.
B. HOOC-COOH .
C. HCOOCH3.
D. CHO COOH .
Cu 21: Thuc th duy nht phn bit 3 dung dch MgCl2, Na2CO3, Na2SiO3 l
A. dung dch NaOH.
B. dung dch HCl.
C. dung dch KNO3.
D. dung dch KCl.
Cu 22: Cho bt Zn vo dung dch hn hp Cu(NO3)2, Mg(NO3)2 , kt thc phn ng c cht rn X cha 2
kim loi v dung dch Y. Cho dung dch NaOH d vo Y thu c
A. Mg(OH)2.
B. Mg(OH)2, Cu(OH)2.
C. Mg(OH)2, Zn(OH)2.
D. Zn(OH)2.
Cu 23: Cho cc cht sau: C2H5OH,C6H6 ,C6H5NH2 ,C6H5ONa . Chn mt thuc th nhn bit cc
cht l
A. dung dch NaOH.
B. dung dch BaCl2.
C. dung dch HCl.
D. dung dch Ca(OH)2.
Cu 24: Este X c CTPT C4H6O2. Khi x phng ho thu c 2 sn phm c kh nng trng bc. CTCT ca X
l
A. HCOOCH=CH-CH3 .
B. CH2 =CH-COOCH3 .
C. CH3COOCH=CH2 .

D. HCOOCH2 -CH=CH2 .

Cu 25: T kh NH3 c th iu ch c phn m NH4NO3 trong cng nghip cn s phn ng ti thiu l

A. 5.
B. 7.
C. 4.
D. 3.
Cu 26: t chy hon ton 1 mol cht hu c X cha thu c 2 mol CO2, 11,2 lt N2 ktc v 63 gam H2O.
T khi hi ca X so vi He = 19,25. Bit X d phn ng vi dung dch HCl v NaOH.
X c CTCT l
A. HCOONH3CH3(1).
B. (1) hoc (3).
C. CH3CH2COONH4(2).
D. CH3COONH4(3).
Cu 27: Bn l mt nhn cha : Ancol etylic, ancol anlylic, i etylete, etan1,2-iol. Trnh t cc cht trong
dy no sau y s nhn bit c cc cht trn?
A. khng xc nh c.
B. nc Br2, Na, dd AgNO3/NH3.
C. Na, Cu(OH)2, nc Br2.
D. Cu(OH)2, nc Br2, dd AgNO3/NH3.
Trang 2/5 - M thi 060

Cu 28: Thu phn hon ton 62,5 gam dung dch sacaroz 17,1% trong mi trng axit(va ), thu c
dung dch X(hiu sut phn ng t 100%). Cho X tc dng vi dung dch AgNO3/NH3( d), un nng thu
c 6,75 gam Ag. Hiu sut phn ng trng bc l
A. 100%.
B. 75%.
C. 50%.
D. 90%.
Cu 29: Trong k thut in t, cht c dng lm t bo quang in l
A. silic tinh khit.
B. thch anh.
C. than ch.
D. kim cng.
Cu 30: Cho 0,1 mol mt -amino axit X tc dng va vi dung dch 0,1 mol NaOH thu c 16,8 gam
mui. Mt khc 0,1 mol X tc dng va vi 200 ml dung dch HCl 1M. CTCT ca X l
A. H2N-(CH2 )2 -CH(NH2 )-COOH .
B. H2N-(CH2 )4 -CH(NH2 )-COOH .
C. HOOC-(CH2 )3-CH(NH2 )-COOH .

D. H2N-(CH2 )3 -CH(NH2 )-CH2 -COOH.

Cu 31: Dung dch X cha 2 axit HCl v H2SO4 c pH = 2. trung ho hon ton 0,59 gam hn hp Y gm
2 amin no, n chc mch h, bc 1 ( c s nguyn t C 4) phi dng ht 1 lt dung dch X. CTPT ca 2
amin l
A. C2H5NH2 vCH3NH2 .
B. C2H5NH2 vC3H7NH2 .
C. C2H5NH2 vC4H9NH2 .

D. C3H7NH2 vC4H9NH2 .

Cu 32: Cho phn ng este ho: CH3COOH +C2H5OH CH3COOC2H5 +H2O .

Bit nng ban u [CH3COOH] = [C2H5OH] = 1M, hng s cn bng = 4. Nng ca este v axit lc
cn bng ln lt l
A. 0,75M v 0,25M.

B. 0,85M v 0,15M.

C. 0,8M v 0,2M.

D.

2
1
M v M .
3
3

Cu 33: thu c Cu t hn hp bt Fe, Cu sao cho khi lng khng i ta cho hn hp tc dng vi
A. dung dch FeCl3 d.
B. dung dch NaOH
C. dung dch CuCl2 d.
D. dung dch HCl.
Cu 34: X c CTPT l C4H4O tho mn iu kin sau:
1)X tc dng vi AgNO3/NH3 cho 2 kt ta, c 1 cht hu c v 1 cht v c.
2)X lm mt mu dung dch KMnO4.
X l
A. CH - C = O .
CH - CH2

B. HC C-CH2 -CHO .

C. HC C-O-CH=CH2 .
D. H2C=C=CH-CHO .
Cu 35: Trn 600 ml dung dch HCl 1M vi 400 ml dung dch NaOH x M c 1 lt dung dch c
pH = 1. Gi tr ca x l
A. 1.
B. 0,75.
C. 0,25.
D. 1,25.
Cu 36: in phn hon ton dung dch hn hp gm a (mol) Cu(NO 3)2 v b (mol) KCl (bit b<2a), vi in
cc tr, mng ngn xp. Dung dch thu c c pH l
A. > 7.
B. < 7.
C. 7.
D. = 7.
Cu 37: Ho tan hon ton m gam hn hp bt X gm Al, Al2O3 trong dung dch HNO3 long c dung dch
Y cha 33,45 gam mui. Cng lng X nh trn khi ho tan trong dung dch HNO 3 (long, d), kt thc phn
ng thu c V lt kh NO duy nht ( ktc) v dung dch Z cha 32,7 gam mui. Gi tr ca V l
A. 0,56.
B. 2,24.
C. khng xc nh c.
D. 0,28.
Cu 38: Ho tan hon ton 28,4 gam P2O5 cn 300 ml dung dch NaOH a M thu c 52,4 gam hn hp mui
axit. Gi tr ca a l
A. 2.
B. 0,5.
C. 1,5.
D. 1.
Cu 39: Cho V lt kh CO2 ktc hp th ht trong 200ml dung dch NaOH 1M thu c 13,7 gam mui . V
c gi tr l
A. 2,688.
B. 4,032.
C. 3,36.
D. 2,24.
Cu 40: t chy hon ton 4,3 gam cht hu c Y ch cha 1 nhm chc. Dn ton b sn phm chy hp
th vo dung dch Ca(OH)2 d, thu c 20 gam kt ta. Khi lng dung dch cn li gim 8,5 gam so vi
trc phn ng, bit MY < 100. Cng thc ca Y l
A. C4H10O2 .
B. C3H6O2 .
C. C4H6O2 .
D. C4H8O2 .
B. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn 1 hoc phn 2)
Trang 3/5 - M thi 060

Phn 1: Theo chng trnh chun (10 cu, t cu 41 n cu 50)

Cu 41: Cho s chuyn ho sau: CH4 X Y C2H5OH. X cha 3 nguyn t C,H,O; Y l
A. Eten.
B. Cloetan.
C. Glucoz.
D. Axit axetic.
Cu 42: Xenluloz tc dung vi dung dch hn hp HNO3 c, H2SO4 c, un nng thu c sn phm X
cha 14,14% nit v khi lng. CTCT ca X v khi lng dung dch HNO3 63% dng chuyn 405 gam
xenluloz thnh X l
A. [C6H7O2 (ONO2 )3]n,750g.
B. [C6H7O2 (ONO2 )(OH)2 ]n ,635g.
C. [C6H7O3(ONO2 )3]n,475g.

D. [C6H7O2 (ONO2 )3]n,590g.

Cu 43: Phn bit glucoz v fructoz ta dng thuc th l

A. (2) hoc (3).
B. dung dch AgNO3/NH3 (2).
C. dung dch Br2 (1).
D. Cu(OH)2(3).
Cu 44: Hp cht hu c X ch cha 2 loi nhm chc l amino v cacboxyl. Cho 100 ml dung dch X 0,3 M
phn ng va vi 48 ml dung dch NaOH 1,25M. C cn dung dch sau phn ng thu c 5,31 gam mui
khan. X l
A. C4H9O2N .
B. C3H5O4N .
C. C3H7O2N .
D. C4H7O4 N .
Cu 45: in phn 100 ml dung dch hn hp gm Cu(NO3)2 0,1M v NaCl 0,2M ti khi c 2 in cc cng
c kh thot ra th dng li. Dung dich sau in phn c pH l
A. 6.
B. 5.
C. 7.
D. 8.
Cu 46: Cho Na vo dung dch CuSO4 trong nc xy ra phn ng
A. oxiho-kh.
B. oxi ho-kh v trao i ion.
C. phn ng trao i ion.
D. phn ng ho hp v trao i.
Cu 47: Cho 2,8 lt kh CO2 ktc hp th bng 100ml dung dch NaOH 1M v Ba(OH)2 1M th thu c s
gam kt ta l
A. 14,775.
B. 24,625.
C. 39,4.
D. 19,7.
Cu 48: t chy ht a mol ancol no X thu c 2a mol H2O. X l
A. C3H7OH.
B. C2H4(OH)2.
C. C3H5(OH)3.
D. CH3OH.
Cu 49: Cho 12,32 gam kim loi M tan ht trong dung dch HNO3 thu c 7,392 lt hn hp kh gm NO,
NO2 c t khi so vi H2 bng 19. M l
A. Fe.
B. Mg.
C. Zn.
D. Cu.
Cu 50: Kh NH3 c ln hi nc, c NH3 kh ta cho hn hp i qua
A. P2O5.
B. CaO.
C. H2SO4 c.
D. K.
Phn 2: Theo chng trnh nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Trong phng php thu luyn dng iu ch Ag t qung cha Ag2S, cn dng thm
A. dung dch HCl c v Zn.
B. dung dch H2SO4 c, nng v Zn.
C. dung dch HNO3 c v Zn.
D. dung dch NaCN v Zn.
Cu 52: Cho 0,1 mol cht X c CTPT C2H8O3N tc dng vi dung dch cha 0,2 mol NaOH, un nng thu
c cht kh Y lm xanh giy qu tm t v dung dch Z. C cn Z thu c m gam cht rn khan. Gi tr
ca m l
A. 21,8.
B. 12,5.
C. 5,7.
D. 15.
0
Cu 53: Mt hirocacbon X c CT (CH)n. 1 mol X phn ng vi 4 mol H2 (Ni, t ) hoc 1 mol dung dch Br2. X
l
A. toluen.
B. benzen.
C. 4-phenyl but-1-in.
D. stiren.
Cu 54: Sn phm ca phn ng (C6H5CO)2O+CH3OH ? l
A. C6H5COOH .

B. C6H5CHO .

C. C6H5COOCH3 .

D. C6H5COOCH3 v C6H5COOH .

Cu 55: kh hon ton 23,2 gam mt oxit kim loi, cn dng 8,96 lt kh CO ktc. Kim loi l
A. Fe.
B. Al.
C. Mg.
D. Cr
Cu 56: in phn 1 lt dung dch CuSO4 2M vi cc in cc bng Cu ti khi catt tng 6,4 gam th lc
nng CuSO4 trong dung dch l (th tch dung dch coi nh khng thay i)
A. 1,9M.
B. 2M.
C. 0,5M.
D. 0,3M.
Cu 57: Ho tan hon ton a mol CuFeS2 bng dung dch HNO3 c, nng (d) sinh ra b mol NO2 (sn phm
kh duy nht). Mi lin h ng gia a v b l
A. a = 17b.
B. b = 15a.
C. b = 17a.
D. a = 15b.
Trang 4/5 - M thi 060

Cu 58: Cp pin in ho xy ra phn ng:

2Cr (r)+3Cu2+(dd) 2Cr3++3Cu.

Bit E 0Cu2+ =+0,34V; E 0Cr3+ =-0,74V. E 0ca pin
in ho l
Cu

Cr

A. 1,08 V.
B. 1,25 V.
C. -1,08 V.
D. 0,4 V.
Cu 59: Hirat ho hon ton 1,56 gam mt ankin X thu c anhit Y. Trn Y vi mt anhit n chc Z,
thm nc vo c 0,1 lt dung dch T cha Y v Z vi nng tng cng l 0,8 M. Thm t t dung dch
AgNO3/NH3 (d) vo T th thu c 21,6 gam Ag kt ta. Cng thc cu to v s mol Y v Z ln lt l
A. CH3CHO;0,1mol v HCHO;0,2mol .
B. CH3CHO;0,08mol v HCHO;0,05mol .
C. CH3CHO;0,1mol v C2H5CHO;0,2mol .

D. CH3CHO;0,06mol v HCHO;0,02mol .

Cu 60: Cht X cha C, H, O, trong hiro chim 2,439% v khi lng. t chy X thu c nX =nH2O .
Bit 1 mol X phn ng vi 4 mol [Ag(NH3)2] OH. Cng thc ca X l
A. OHC-C C-CHO . B. HC C-CHO .
C. HCHO.
D. HCOOH.
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Trang 5/5 - M thi 060