B GIO DC V O TO

CHNH THC

( thi c 06 trang)

THI TUYN SINH I HC NM 2010

Mn: HO HC; Khi A
Thi gian lm bi: 90 pht, khng k thi gian pht
M thi 419

H, tn th sinh: ..........................................................................
S bo danh: ............................................................................

Cho bit nguyn t khi (theo vC) ca cc nguyn t:

H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5;
K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr = 88; Ag = 108;
Sn = 119; Cs = 133; Ba = 137; Pb = 207.
I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c
cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu
t chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng
M vi H2SO4 c thc hin phn ng este ho (hiu sut l 80%) th s gam este thu c l
A. 18,24.
B. 34,20.
C. 22,80.
D. 27,36.
Cu 2: Ho tan hon ton m gam ZnSO4 vo nc c dung dch X. Nu cho 110 ml dung dch
KOH 2M vo X th thu c 3a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th
thu c 2a gam kt ta. Gi tr ca m l
A. 32,20.
B. 17,71.
C. 24,15.
D. 16,10.
Cu 3: Axeton c iu ch bng cch oxi ho cumen nh oxi, sau thu phn trong dung dch
H2SO4 long. thu c 145 gam axeton th lng cumen cn dng (gi s hiu sut qu trnh iu
ch t 75%) l
A. 400 gam.
B. 600 gam.
C. 300 gam.
D. 500 gam.
Cu 4: Hn hp kh no sau y khng tn ti nhit thng?
A. H2S v N2.
B. H2 v F2.
C. CO v O2.
D. Cl2 v O2.
Cu 5: Cho 4 dung dch: H2SO4 long, AgNO3, CuSO4, AgF. Cht khng tc dng c vi c 4
dung dch trn l
C. NaNO3.
D. BaCl2.
A. KOH.
B. NH3.
Cu 6: Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng phn cu to nht l
A. C3H8.
B. C3H8O.
C. C3H9N.
D. C3H7Cl.
Cu 7: Cho 19,3 gam hn hp bt gm Zn v Cu c t l mol tng ng l 1 : 2 vo dung dch cha
0,2 mol Fe2(SO4)3. Sau khi cc phn ng xy ra hon ton, thu c m gam kim loi. Gi tr ca m l
A. 12,00.
B. 12,80.
C. 6,40.
D. 16,53.
Cu 8: Pht biu ng l:
A. Axit nucleic l polieste ca axit photphoric v glucoz.
B. Khi thy phn n cng cc protein n gin s cho hn hp cc -aminoaxit.
C. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m.
D. Enzim amilaza xc tc cho phn ng thy phn xenluloz thnh mantoz.
Cu 9: Pht biu no sau y ng?
A. Cc kim loi: natri, bari, beri u tc dng vi nc nhit thng.
B. Theo chiu tng dn ca in tch ht nhn, cc kim loi kim th (t beri n bari) c nhit
nng chy gim dn.
C. Kim loi xesi c dng ch to t bo quang in.
D. Kim loi magie c kiu mng tinh th lp phng tm din.
Cu 10: C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3
aminoaxit: glyxin, alanin v phenylalanin?
A. 4.
B. 6.
C. 9.
D. 3.
Trang 1/6 - M thi 419

26
55
Cu 11: Nhn nh no sau y ng khi ni v 3 nguyn t: 26
13 X, 26 Y, 12 Z?
A. X v Z c cng s khi.
B. X, Y thuc cng mt nguyn t ho hc.
C. X v Y c cng s ntron.
D. X, Z l 2 ng v ca cng mt nguyn t ho hc.
Cu 12: un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc
Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn
ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi H2
l 10,08. Gi tr ca m l
A. 0,328.
B. 0,205.
C. 0,620.
D. 0,585.

Cu 13: Dung dch X c cha: 0,07 mol Na+; 0,02 mol SO 24 v x mol OH . Dung dch Y c cha
ClO 4 , NO 3 v y mol H+; tng s mol ClO 4 v NO 3 l 0,04. Trn X v Y c 100 ml dung dch Z.
Dung dch Z c pH (b qua s in li ca H2O) l
A. 2.
B. 12.
C. 13.
D. 1.
Cu 14: Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam CuO.
Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3, thu c 23,76
gam Ag. Hai ancol l:
A. C2H5OH, C3H7CH2OH.
B. CH3OH, C2H5OH.
C. C2H5OH, C2H5CH2OH.
D. CH3OH, C2H5CH2OH.
Cu 15: C cc pht biu sau:
(1) Lu hunh, photpho u bc chy khi tip xc vi CrO3.
(2) Ion Fe3+ c cu hnh electron vit gn l [Ar]3d5.
(3) Bt nhm t bc chy khi tip xc vi kh clo.
(4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O.
Cc pht biu ng l:
A. (1), (3), (4).
B. (1), (2), (4).
C. (1), (2), (3).
D. (2), (3), (4).
Cu 16: t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy ng ng, thu c
3,808 lt kh CO2 (ktc) v 5,4 gam H2O. Gi tr ca m l
A. 5,42.
B. 7,42.
C. 5,72.
D. 4,72.
Cu 17: Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%,
thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l
A. C2H5COOH v C3H7COOH.
B. HCOOH v C2H5COOH.
D. CH3COOH v C2H5COOH.
C. HCOOH v CH3COOH.
Cu 18: Trong s cc pht biu sau v phenol (C6H5OH):
(1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl.
(2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm.
(3) Phenol dng sn xut keo dn, cht dit nm mc.
(4) Phenol tham gia phn ng th brom v th nitro d hn benzen.
Cc pht biu ng l:
A. (1), (3), (4).
B. (1), (2), (3).
C. (2), (3), (4).
D. (1), (2), (4).
Cu 19: Cho cn bng: 2SO2 (k) + O2 (k) 2SO3 (k). Khi tng nhit th t khi ca hn hp kh
so vi H2 gim i. Pht biu ng khi ni v cn bng ny l:
A. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
B. Phn ng thun to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
C. Phn ng thun thu nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
D. Phn ng nghch to nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
Cu 20: Cc nguyn t t Li n F, theo chiu tng ca in tch ht nhn th
A. bn knh nguyn t gim, m in tng.
B. bn knh nguyn t v m in u tng.
C. bn knh nguyn t v m in u gim.
D. bn knh nguyn t tng, m in gim.
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Cu 21: Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n mn in ho xy ra

khi nhng hp kim Zn-Cu vo dung dch HCl c c im l:
A. Phn ng cc dng u l s oxi ho Cl.
B. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi.
C. u sinh ra Cu cc m.
D. Phn ng xy ra lun km theo s pht sinh dng in.
Cu 22: Thc hin cc th nghim sau:
(I) Sc kh SO2 vo dung dch KMnO4.
(II) Sc kh SO2 vo dung dch H2S.
(III) Sc hn hp kh NO2 v O2 vo nc.
(IV) Cho MnO2 vo dung dch HCl c, nng.
(V) Cho Fe2O3 vo dung dch H2SO4 c, nng.
(VI) Cho SiO2 vo dung dch HF.
S th nghim c phn ng oxi ho - kh xy ra l
A. 6.
B. 4.
C. 3.
D. 5.
Cu 23: Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l
A. 4.
B. 1.
C. 2.
D. 3.
Cu 24: Hn hp kh X gm N2 v H2 c t khi so vi He bng 1,8. un nng X mt thi gian trong
bnh kn (c bt Fe lm xc tc), thu c hn hp kh Y c t khi so vi He bng 2. Hiu sut ca
phn ng tng hp NH3 l
A. 50%.
B. 40%.
C. 25%.
D. 36%.
Cu 25: Mt phn t saccaroz c
A. mt gc -glucoz v mt gc -fructoz. B. mt gc -glucoz v mt gc -fructoz.
C. hai gc -glucoz.
D. mt gc -glucoz v mt gc -fructoz.
Cu 26: Cho x mol Fe tan hon ton trong dung dch cha y mol H2SO4 (t l x : y = 2 : 5), thu c
mt sn phm kh duy nht v dung dch ch cha mui sunfat. S mol electron do lng Fe trn
nhng khi b ho tan l
A. y.
B. 2y.
C. 3x.
D. 2x.
Cu 27: Cho 7,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th Y tc dng ht
vi lng d dung dch HCl long, thu c 5,6 lt kh (ktc). Kim loi X, Y l
A. liti v beri.
B. natri v magie.
C. kali v canxi.
D. kali v bari.
Cu 28: Ho tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v
2,688 lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4, t l mol tng ng l 4 : 1. Trung ho dung
dch X bi dung dch Y, tng khi lng cc mui c to ra l
A. 14,62 gam.
B. 18,46 gam.
C. 13,70 gam.
D. 12,78 gam.
Cu 29: Nung nng tng cp cht sau trong bnh kn: (1) Fe + S (r), (2) Fe2O3 + CO (k), (3) Au + O2 (k),
(4) Cu + Cu(NO3)2 (r), (5) Cu + KNO3 (r), (6) Al + NaCl (r). Cc trng hp xy ra phn ng oxi ho kim
loi l:
A. (2), (5), (6).
B. (1), (4), (5).
C. (2), (3), (4).
D. (1), (3), (6).
Cu 30: Cho m gam NaOH vo 2 lt dung dch NaHCO3 nng a mol/l, thu c 2 lt dung dch X.
Ly 1 lt dung dch X tc dng vi dung dch BaCl2 (d) thu c 11,82 gam kt ta. Mt khc, cho 1
lt dung dch X vo dung dch CaCl2 (d) ri un nng, sau khi kt thc cc phn ng thu c 7,0
gam kt ta. Gi tr ca a, m tng ng l
A. 0,08 v 4,8.
B. 0,04 v 4,8.
C. 0,07 v 3,2.
D. 0,14 v 2,4.
Cu 31: Cho s chuyn ho:
+ H d (Ni, to )

+ NaOH d, t Y
+ HCl Z.
2
Triolein
X
Tn ca Z l
A. axit stearic.
B. axit panmitic.
C. axit oleic.

D. axit linoleic.

Trang 3/6 - M thi 419

Cu 32: Cho s chuyn ho:

dung dch Br

NaOH

CuO,t o

O ,xt

CH OH,t o ,xt

3
2
C 3 H 6 2
X Y
Z
T
E (Este a chc).

Tn gi ca Y l
A. propan-2-ol.
B. glixerol.
C. propan-1,3-iol.
D. propan-1,2-iol.
+
2+
Cu 33: Cho dung dch X gm: 0,007 mol Na ; 0,003 mol Ca ; 0,006 mol Cl; 0,006 mol HCO3 v
0,001 mol NO3. loi b ht Ca2+ trong X cn mt lng va dung dch cha a gam Ca(OH)2.
Gi tr ca a l
A. 0,444.
B. 0,222.
C. 0,180.
D. 0,120.
Cu 34: Cho cc cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht tc dng c vi
dung dch NaOH long nhit thng l
A. 4.
B. 3.
C. 5.
D. 6.
Cu 35: Pht biu khng ng l:
A. Tt c cc nguyn t halogen u c cc s oxi ho: -1, +1, +3, +5 v +7 trong cc hp cht.
B. Trong cng nghip, photpho c sn xut bng cch nung hn hp qung photphorit, ct v
than cc 1200oC trong l in.
C. Kim cng, than ch, fuleren l cc dng th hnh ca cacbon.
D. Hiro sunfua b oxi ho bi nc clo nhit thng.
Cu 36: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l
A. 2-etylpent-2-en.
B. 3-etylpent-2-en.
C. 3-etylpent-3-en.
D. 3-etylpent-1-en.
Cu 37: Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t tng
hp l
A. 3.
B. 2.
C. 4.
D. 5.
Cu 38: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu
c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin).
Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y
thu c 12,88 gam cht rn khan. Gi tr ca m l
A. 8,88.
B. 10,56.
C. 6,66.
D. 7,20.
Cu 39: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c
dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH
phn ng l
A. 0,65.
B. 0,70.
C. 0,55.
D. 0,50.
Cu 40: Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon
ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc.
Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o
cng iu kin). Cng thc phn t ca hai hirocacbon l
A. CH4 v C2H6.
B. C2H6 v C3H8.
C. C3H6 v C4H8.
D. C2H4 v C3H6.
_________________________________________________________________________________
II. PHN RING [10 cu]
Th sinh ch c lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung
dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam
so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l
B. C3H6.
C. C3H4.
D. C2H6.
A. C3H8.
Cu 42: Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi kim
loi kim c tng khi lng l 15,8 gam. Tn ca axit trn l
A. axit butanoic.
B. axit propanoic.
C. axit metanoic.
D. axit etanoic.
Cu 43: Cc cht va tc dng c vi dung dch HCl va tc dng c vi dung dch AgNO3 l:
A. Zn, Cu, Fe.
B. CuO, Al, Mg.
C. Zn, Ni, Sn.
D. MgO, Na, Ba.
Trang 4/6 - M thi 419

Cu 44: Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO3
trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit hu c.
Gi tr ca m l
A. 9,5.
B. 10,9.
C. 14,3.
D. 10,2.
Cu 45: Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na2CO3
0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l
A. 0,015.
B. 0,020.
C. 0,010.
D. 0,030.
Cu 46: in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi
catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c
anot l
A. kh Cl2 v O2.
B. ch c kh Cl2.
C. kh Cl2 v H2.
D. kh H2 v O2.
Cu 47: Cht c dng ty trng giy v bt giy trong cng nghip l
A. CO2.
B. N2O.
C. SO2.
D. NO2.
Cu 48: T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu
sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X.
trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l
A. 20%.
B. 10%.
C. 80%.
D. 90%.
Cu 49: Trong phn ng: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O
S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr
ca k l
A. 4/7.
B. 3/7.
C. 1/7.
D. 3/14.
Cu 50: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng
phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol
H2O v y mol N2. Cc gi tr x, y tng ng l
A. 8 v 1,5.
B. 7 v 1,5.
C. 7 v 1,0.
D. 8 v 1,0.
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Cho 0,448 lt kh NH3 (ktc) i qua ng s ng 16 gam CuO nung nng, thu c cht rn
X (gi s phn ng xy ra hon ton). Phn trm khi lng ca Cu trong X l
A. 14,12%.
B. 87,63%.
C. 85,88%.
D. 12,37%.
Cu 52: Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi
lng d dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c
8,98 gam mui khan. Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3
oxit th th tch kh O2 (ktc) phn ng l
A. 0,672 lt.
B. 2,016 lt.
C. 1,344 lt.
D. 1,008 lt.
Cu 53: Xt cn bng: N2O4 (k) 2NO2 (k) 25oC. Khi chuyn dch sang mt trng thi cn bng
mi nu nng ca N2O4 tng ln 9 ln th nng ca NO2
A. gim 3 ln.
B. tng 9 ln.
C. tng 4,5 ln.
D. tng 3 ln.
Cu 54: in phn (in cc tr) dung dch X cha 0,2 mol CuSO4 v 0,12 mol NaCl bng dng
in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l
A. 1,344 lt.
B. 1,792 lt.
C. 2,912 lt.
D. 2,240 lt.
Cu 55: Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong
dy ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H2 (ktc). Nu un nng hn hp X (c
H2SO4 c lm xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn
hp este (gi thit phn ng este ho t hiu sut 100%). Hai axit trong hn hp X l
A. C3H7COOH v C4H9COOH.
B. C2H5COOH v C3H7COOH.
C. HCOOH v CH3COOH.
D. CH3COOH v C2H5COOH.
Cu 56: Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol
mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y
l
A. CH3-CH2-CH2-OH.
B. CH3-CH(OH)-CH3.
C. CH3-CH2-CH2-CH2-OH.
D. CH3-CH2-CH(OH)-CH3.
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Cu 57: Hiro ho cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn thay th l

A. metyl isopropyl xeton.
B. 2-metylbutan-3-on.
C. 3-metylbutan-2-ol.
D. 3-metylbutan-2-on.
Cu 58: t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp
gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc
dng vi axit nitr nhit thng, gii phng kh nit. Cht X l
A. CH3-CH2-CH2-NH2.
B. CH3-CH2-NH-CH3.
C. CH2=CH-NH-CH3.
D. CH2=CH-CH2-NH2.
Cu 59: Trong cc polime sau: (1) poli(metyl metacrylat); (2) polistiren; (3) nilon-7; (4) poli(etylenterephtalat); (5) nilon-6,6; (6) poli(vinyl axetat), cc polime l sn phm ca phn ng trng ngng
l:
A. (1), (3), (6).
B. (1), (2), (3).
C. (1), (3), (5).
D. (3), (4), (5).
Cu 60: Trong s cc ngun nng lng: (1) thy in, (2) gi, (3) mt tri, (4) ho thch; nhng
ngun nng lng sch l:
A. (1), (2), (4).
B. (1), (2), (3).
C. (1), (3), (4).
D. (2), (3), (4).
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HT ----------

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