AMIN AMINOAXIT

Posted on 02/06/2010 by BI TP HA HC

Cu 1: Cho cc cht sau: C6H5NH2 (X), (CH3)2NH (Y), CH3NH2 (Z), C2H5NH2 (T), Th t tng dn tnh baz ca cc cht ni trn l A. Y < Z < X < T. C. T < Y < Z < X. B. X < Z < T < Y. D. T < X < Y < Z.

Cu 2: t chy hon ton hn hp 2 amin n chc no bc 1. Trong sn phm chy thy t l mol CO2 v H2O tng ng l 1: 2. Cng thc ca 2 amin l A. C3H7NH2 v C4H9NH2. C. CH3NH2 v C2H5NH2. B. C2H5NH2 v C3H7NH2. D. C4H9NH2 v C5H11NH2.

Cu 3 (A-2007): Cho hn hp X gm 2 cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp kh Z (ktc) gm 2 kh (u lm xanh giy qu m). T khi hi ca Z so vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 8,9 gam. 15,7 gam. B. 14,3 gam. C. 16,5 gam. D.

Cu 4:Cng thc tng qut ca amin l CxHyNz. A. y cha so snh c vi 2x + 2 v c th chn hoc l do cn ph thuc vo z. B. y 2x + 2 v c th chn hoc l v do cn ph thuc vo z. C. y 2x + 2 v y lun lun chn, khng ph thuc vo z. D. y 2x + 2 v y lun lun chn, khng ph thuc vo z. Cu 5: Cho cc loi hp cht sau: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Cc loi cht va tc dng vi dung dch NaOH, va tc dng vi dung dch HCl l A. X, Y, Z, T. B. X, Y, Z. C. X, Y, T. D. Y, Z, T.

Cu 6: S lng ng phn ng vi cng thc phn t C4H11N l A. 5. B. 6. C. 7. D. 8.

Cu 7: Cho cc cht sau: NH3 (X) ; (C6H5)2NH (Y); C6H5NH2 (Z); CH3NH2 (T); C6H5NHCH3 (M). Th t gim dn tnh baz ca cc cht trn l A. T > X > M > Z > Y. C. M > X > Y > Z > T. B. T > X > Z > M > Y. D. X > M > T > Y > Z.

Cu 8: X l mt a- aminoaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 17,8 gam X tc dng vi dung dch HCl d thu c 25,1 gam mui. Tn gi ca X l A. axit amino axetic. C. axit a- amino butiric. B. axit a- amino propionic. D. axit a- amino glutaric.

Cu 9: Cho cc cht: anilin (X), amoniac (Y) v metylamin (Z). Th t tng dn nhit si ca cc cht l A. Y < Z < X. B. Y < X < Z. C. X < Y < Z. D. Z < Y < X.

Cu 10: Cho 4 cht ng phn: n-propylamin (X); trimetylamin (Y); etylmetylamin (Z) v iso-propylamin (T). Th t gim dn tnh baz ca 4 ng phn trn l A. Y > Z > X > T. C. Y > Z > T > X. B. Z > Y > T > X. D. Z > Y > X > T.

Cu 11: A l hp cht hu c cha C, H, N; trong nit chim 15,054% v khi lng. A tc dng vi HCl to ra mui c dng RNH3Cl. Cng thc ca A l A. CH3-C6H4-NH2. C. C6H5-CH2-NH2. B. C6H5-NH2. D. C2H5-C6H4-NH2.

Cu 12: S lng ng phn amin cha vng bezen ng vi cng thc phn t C7H9N l A. 3. B. 4. C. 5. D. 6.

Cu 13: t chy ht 6,72 lt hn hp kh (ktc) X gm 2 amin n chc bc mt A v B l ng ng k tip. Cho hn hp kh v hi sau khi t chy ln lt qua bnh 1 ng H2SO4 c, bnh 2 ng KOH d thy khi lng bnh 2 tng 21,12 gam. Tn gi ca 2 amin l

A. metylamin v etylamin. C. n-propylamin v n-butylamin.

B. etylamin v n-propylamin. D. iso-propylamin v iso-butylamin.

Cu 14: S lng ng phn aminoaxit ng vi cng thc H2N-C3H6-COOH l A. 4. B. 5. C. 6. D. 7.

Cu 15: Trong dung dch, H2N-CH2-COOH tn ti dng A. phn t trung ho. C. anion. B. cation. D. ion lng cc.

Cu 16: t chy hon ton hn hp 2 amin n chc, no, bc 1, l ng ng k tip thu c t l mol CO2 v H2O tng ng l 1:2. Cng thc ca 2 amin l A. C2H5NH2 v C3H7NH2. C. CH3NH2 v C2H5NH2. B. C4H9NH2 v C3H7NH2. D. C4H9NH2 v C5H11NH2.

Cu 17: X l a-aminoaxit mch thng. Bit rng: 0,01mol X tc dng va vi 80ml dung dch HCl 0,125M thu c 1,835g mui. Mt khc, nu cho 2,94g X tc dng va vi NaOH th thu c 3,82g mui. Tn gi ca X l. A. glyxin. lysin. Cu 18: Cho hn hp 2 aminoaxit no cha 1 chc axit v 1 chc amino tc dng vi 110ml dung dch HCl 2M c dung dch A. tc dng ht vi cc cht trong A cn dng 140ml dung dch KOH 3M. Tng s mol 2 aminoaxit l A. 0,1. B. 0,2. C. 0,3. D. 0.4. B. alanin. C. axit glutamic. D.

Cu 19: a-aminoaxit X c phn trm khi lng ca nit l 15,7303%, ca oxi l 35,9551%. Tn gi ca X l A. glyxin. B. alanin. C. axit glutamic. D. lysin.

Cu 20 (B-2007): Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng vi dung dch NaOH v dung dch HCl l A. Y, Z, T. B. X, Y, T. C. X, Y, Z, T. D. X, Y, Z.

Cu 21: X c cha nhm amino v c cng thc phn t l C3H7O2N. Khi cho X phn ng vi dung dch NaOH, thu c mui C2H4O2NNa. Cng thc cu to ca X l A. H2N-CH(CH3)-COOH. C. H2N-CH2-COOCH3. B. H2N-CH2-CH2-COOH. D. CH3-NH-CH2-COOH.

Cu 22 (A-2007): a-aminoaxit X cha mt nhm NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCH2CH2COOH. C. CH3CH2CH(NH2)COOH. B. H2NCH2COOH. D. CH3CH(NH2)COOH.

Cu 23: Nguyn nhn gy nn tnh baz ca C2H5NH2 l do A. C2H5NH2 to lin kt hiro vi nc nn tan nhiu trong nc. B. gc C2H5- y electron v pha N nn phn t C2H5NH2 phn cc. C. m in ca N ln hn H nn cp electron gia N v H b lch v pha N. D. nguyn t N cn c cp electron t do nn c kh nng nhn proton. Cu 24 (A-2007): t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2 ; 0,56 lt kh N2(cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca X l A. H2N-CH2-COO-C3H7. C. H2N-CH2-COO-CH3. B. H2N-CH2-COO-C2H5. D. H2N-CH2-CH2-COOH.

Cu 25: t chy hon ton mt amin n chc, no, bc 2 thu c CO2 v H2O vi t l mol tng ng l 2:3. Tn gi ca amin l A. etyl metylamin. C. metyl iso-propylamin. B. ietylamin. D. imetylamin.

Cu 26: Cho 0,01 mol mt aminoaxit X tc dng va vi 40ml dung dch NaOH 0,25M. Mt khc, 1,5 gam X tc dng va vi 40ml dung dch KOH 0,5M. Tn gi ca X l A. glyxin. B. alanin. C. axit glutamic. D. lysin.

Cu 27: H2N-[CH2]4-CH(NH2)-COOH c tn gi l A. glyxin. lysin. B. alanin. C. axit glutamic. D.