Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc

TNG HP HO HC HU C
Cu 1: Dy gm tt c cc cht u phn ng c vi HCOOH l A. AgNO3 /dung dch NH3, CH3NH2, C2H5OH, KOH, Na2CO3. B. NH3, K, Cu, NaOH, O2, H2. C. Na2O, NaCl, Fe, CH3OH, C2H5Cl. D. CH3NH2, C2H5OH, KOH, NaCl. Cu 2: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C 2H4O2 ln lt tc dng vi Na, NaOH, Cu(OH)2. S phn ng xy ra l A. 2. B. 3. C. 4. D. 5. Cu 3: Cho cc hp cht sau: phenol, anehit axetic, dung dch Na 2SO4, dung dch brom, dung dch NaOH, dung dch NaCl. Nu cho phn ng tng i mt th s phn ng xy ra l A. 1. B. 2. C. 3. D. 4. Cu 4: Cho cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenol, p-crezol, phenylamoni clorua, ancol benzylic. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 3. B. 4. C. 5. D. 6. Cu 5: Hp cht C3H6O tc dng vi Na, H2 v trng hp c. C3H6O c th l A. metyl vinyl ete. C. propanal. B. ancol anlylic. D. axeton.

Cu 6: Dy gm cc cht u tc dng vi dung dch AgNO3 trong NH3 l A. axit fomic, axetilen, propen. C. anehit axetic, but-1-in, etilen. Cu 7: Cho dy chuyn ho sau:
2 C6H5CH3 X Y Z o o as

B. metyl fomat, vinylaxetilen, propin. D. anehit axetic, axetilen, but-2-in.

CuO t

Cl (1 : 1)

NaOH t

Cht Z c cng thc l A. C6H5CH2OH. B. C6H5CHO. C. HOC6H4CH3. D. C6H5COCH3. Cu 8: Cho s chuyn ho sau:
2 2 2 CH4 X Y Z T M

1500o C

H O

Cng thc cu to ca M l A. CH3COOC2H5. C. CH3COOCH=CH2. Cu 9: Cho s chuyn ho sau: B. CH3COOCH3. D. CH2=CHCOOCH3.

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc

NaOH H2SO4 NaOH HCl Br2 But-1-en X1 X2 X3 X4 X5 o o o t 170 C t

Cng thc cu to ca X5 l A. CH3CH(OH)CH2CH3. C. CH3CH(OH)CH(OH)CH3. B. CH3CH2CH(OH)CH2OH. D. CH3CH2CH2CH2OH.

(1) Cu 10: Cho s phn ng: C2H4 C2H4Br2 (X) ( 2) C2H6O2 (Y) (3) ( 4) ( 5) ( 6) C2H2O2 C2H2O4 C4H6O4 (Z) C5H8O4

Cng thc cu to thu gn ca X, Y, Z ln lt l A. Br-CH2-CH2-Br, HO-CH2-CH2-OH, CH3OOC-COOCH3. B. CH3-CHBr2, CH3-CH(OH)2, CH3OOC-COOCH3. C. Br-CH2-CH2-Br, HO-CH2-CH2-OH, C2H5OOC-COOH. D. C A, C u ng. Cu 11: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. xiclohexan. B. xiclopropan. C. stiren. D. etilen. Cu 12: Sp xp cc cht sau y theo chiu tng dn nhit si: CH 3COOH (A), CH3COOCH3 (B), C2H5COOH (C), HCOOCH3 (D), C3H7OH (E). Th t ng l: A. D < B < E < A < C. C. D < B < E < C < A. B. B < D < E < A < C. D. B < D < C < E < A.

Cu 13: Cho cc cht: CH2=CH-CH=CH2 ; CH3-CH2-CH=C(CH3)2 ; CH3-CH=CH2 ; CH3CH=CH-CH=CH2 ; CH3-CH=CH-COOH. S cht c ng phn hnh hc l A. 4. B. 3. C. 2. D. 1. Cu 14: Cho glixerol tc dng vi hn hp ba axit bo th to ti a bao nhiu sn phm trieste ? A. 18. B. 9. C. 15. D. 12. Cu 15: Pht biu ng l A. Tnh axit ca phenol yu hn ca ancol. B. Cao su thin nhin l sn phm trng hp ca isopren. C. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp. D. Tnh baz ca anilin mnh hn ca amoniac. Cu 16: Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa. Nhng dung dch c pH > 7 l A. Na2CO3, C6H5ONa, CH3COONa. C. KCl, C6H5ONa, CH3COONa. B. Na2CO3, NH4Cl, KCl. D. NH4Cl, CH3COONa, NaHSO4.

Cu 17: Dy gm 4 dung dch cc cht u lm giy qu tm chuyn sang mu l

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc A. nhm sunfat, axit acrylic, phenylamoni clorua, axit glutamic. B. axit nitric, axit axetic, natri phenolat, amoni clorua. C. phenol, amoni clorua, axit glutamic, axit fomic. D. axit clohiric, amoni clorua, anilin, natri fomat. Cu 18: Cho cc phn ng sau: a) FeO + HNO3 (c nng) c) Al2O3 + HNO3 (c nng)
Ni, t e) CH3CHO + H2
o

b) FeS + H2SO4 (c nng) d) Cu + dung dch FeCl3 f) glucoz + AgNO3 /dd NH3 h) glixerol + Cu(OH)2

g) C2H4 + Br2

Dy gm cc phn ng u thuc loi phn ng oxi ho - kh l A. a, b, d, e, f, h. C. a, b, c, d, e, h. Cu 19: Pht biu khng ng l A. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c phenol. C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin. D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu c natri phenolat. Cu 20: Cho cc hp cht hu c: (1) ankan ; (2) ancol no, n chc, mch h ; (3) xicloankan ; (4) ete no, n chc, mch h ; (5) anken ; (6) ancol khng no (c mt lin kt i C=C), mch h ; (7) ankin ; (8) anehit no, n chc, mch h ; (9) axit no, n chc, mch h ; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l A. (1), (3), (5), (6), (8). B. (3), (4), (6), (7), (10). B. a, b, d, e, f, g. D. a, b, c, d, e, g.

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc C. (3), (5), (6), (8), (9). Cu 21: Cho s phn ng: C2H2 D. (2), (3), (5), (7), (9). X Y

CH4 Cng thc ca X, Y v Z ln lt l A. C2H6, C2H5Cl, C2H4. B. CH3CHO, C2H5OH, CH3COOH. C. C2H4, C2H5OH, CH3COOH. D. C2H5OH, CH3COOH, CH3COOC2H5. Cu 22: Cho dy chuyn ho sau:

+X

+Y

B
+Y

E D
+X

Bit E c cng thc phn t l C2H6O v F l polime. Tn gi cc cht A, C, D, E ln lt l A. metan, buta-1,3-ien, anehit axetic, etanol. B. etan, etilen, axit axetic, imetyl ete. C. metan, eten, axetanehit, ancol etylic. D. propan, axetilen, axit axetic, imetyl ete. Cu 23: Cho dy chuyn ho sau: Phenol Phenyl axetat Y (hp cht thm) o
t

+ NaOH (d)

Hai cht X, Y trong s trn ln lt l A. axit axetic, phenol. C. anhirit axetic, natri phenolat. B. anhirit axetic, phenol. D. axit axetic, natri phenolat.

Cu 24: X c cng thc phn t C4H6O2Cl2. Khi cho X phn ng hon ton vi dung dch NaOH thu c etylen glicol, HOCH2COONa v NaCl. Cng thc cu to ca X l A. CH2Cl-COO-CHCl-CH3. C. CHCl2-COO-CH2-CH3. B. CH2Cl-COO-CH2-CH2Cl. D. HOCH2-CO-CHCl-CH2Cl.

Cu 25: C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim ? A. 5. B. 6. C. 3. D. 4. Cu 26: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l A. 1. B. 4. C. 3. D. 2. Cu 27: Hp cht thm ng vi cng thc phn t C8H8O2 c a ng phn khng tc dng vi Na nhng tc dng c vi dung dch NaOH v nc brom ; c b ng phn khng tc dng vi Na nhng tc dng vi dung dch KOH theo t l mol tng ng 1: 2. Tng a + b l A. 7. B. 5. C. 6. D. 8. Cu 28: Cho cc hp cht hu c: C2H2 ; C2H4 ; CH2O ; CH2O2 (mch h) ; C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3 to ra kt ta l A. 3. B. 4. C. 5. D. 2. Cu 29: Hp cht X c cng thc phn t l C4H6O2. X c phn ng trng gng. Hiro ho X thu c cht Y c cng thc phn t l C4H10O2. Y ho tan Cu(OH)2 nhit thng. Tn gi ca Y l A. butan-1,2-iol. C. 2-metylpropan-1,2-iol. B. butan-1,3-iol. D. 2-metylpropan-1,3-iol.

Cu 30: Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na ; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v HCOOC2H5. C. HCOOC2H5 v HOCH2CH2CHO. B. HCOOC2H5 v HOCH2COCH3. D. C2H5COOH v CH3CH(OH)CHO.

Cu 31: Mt ancol c cng thc phn t C5H12O. Oxi ho ancol bng CuO c un nng thu c sn phm c phn ng trng gng. C bao nhiu cng thc cu to tho mn iu kin trn ? A. 3. B. 4. C. 5. D. 6. Cu 32: X l mt hp cht hu c c cng thc phn t l C2H2On (n 2). X tc dng c vi dung dch AgNO3 trong NH3 (d) th gi tr ca n l A. n = 2. C. n = 0 ; n = 1. B. n = 0 ; n = 2. D. n = 0 ; n = 1 ; n = 2.

Cu 33: t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l A. HO-CH2-CH2-CH=CH-CHO. C. HO-CH2-CH=CH-CHO. B. HOOC-CH=CH-COOH. D. HO-CH2-CH2-CH2-CHO.

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc Cu 34: Cho X l hp cht thm ; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HO-C6H4-COOCH3. C. HO-CH2-C6H4-OH. B. CH3-C6H3(OH)2. D. HO-C6H4-COOH.

Cu 35: Cht hu c X c cng thc phn t C4H6O4 tc dng vi dung dch NaOH (un nng) theo phng trnh ho hc: C4H6O4 + 2NaOH 2Z + Y. oxi ho ht a mol Y th cn va 2a mol CuO (un nng), sau phn ng to thnh a mol cht T (bit Y, Z, T l cc hp cht hu c). Phn t khi ca T l A. 44. B. 58. C. 82. D. 118. Cu 36: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HO-CH2-CHO v HO-CH2-CH2-CHO. B. HO-CH2-CH2-CHO v HO-CH2-CH2-CH2-CHO. C. HO-CH(CH3)-CHO v HOOC-CH2-CHO. D. HCOOCH3 v HCOOCH2-CH3. Cu 37: Hn hp X c t khi so vi hiro l 27,8 gm butan, metylxiclopropan, but-2-en, but1-in v buta-1,3-ien. Khi t chy hon ton 8,34 gam X, tng khi lng CO 2 v H2O thu c l A. 36,66 gam. B. 46,92 gam. C. 24,50 gam. D. 35,88 gam. Cu 38: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom ; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=C(CH3)2. C. CH2=CH-CH2-CH3. B. CH2=CH2. D. CH3-CH=CH-CH3.

Cu 39: Hn hp X gm hirocacbon (A) v H2. un nng hn hp ny vi xc tc Ni thu c kh Y duy nht. T khi hi ca Y so vi H2 gp 3 ln t khi hi ca X so vi H2. t chy hon ton mt lng khc ca Y thu c 22,0 gam CO2 v 13,5 gam H2O. Cng thc phn t ca A l A. C2H2. B. C3H4. C. C2H4. D. C3H6. Cu 40: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d dung dch AgNO3 trong NH3 thu c 12

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng