GV: Nguyn Vn Th-0977722500

Trng THPT Chuyn Hong Vn Th

AMIN-AMINOAXIT-PROTIT
Cu 1. (cao ng 2009). Thy phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100000vC th s mt xch alanin c trong X l: A. 453 B. 382 C. 328 D. 479 Cu 2. (H KA 2009. Thuc th c dng phn bit Gly Ala Gly v Gly Ala l: A. dd HCl B. Cu(OH)2/OHC. dd NaCl D. dd NaOH Cu 3. (H KA 2009 C 3 dd: amoni hidrocacbonat, natri aluminat, natri phenolat v 3 cht lng: etanol, benzen, anilin ng trong 6 ng nghim ring bit. Nu ch dng mt thuc th duy nht l dd HCl th nhn bit c ti a bao nhiu ng nghim ? A. 4 B. 5 C. 3 D. 6 Cu 4. (H KA 2009 Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l: A. 5 B. 8 C. 7 D. 4 Cu 5. (H KA 2009. Cho 1 mol amino axit X phn ng hon ton vi dd HCl (d), thu c m1 gam mui Y. Cng mol amino axit X phn ng vi dd NaOH d, thu c m2 gam mui Z. Bit m2 m1 = 7,5. CTPT ca X l: A. C4H10O2N2 B. C4H8O4N2 C. C5H9O4N D. C5H11O2N Cu 6. (H KA 2009. Hp cht X mch h c CTPT l C4H9NO2. Cho 10,3 gam X phn ng va vi dd NaOH sinh ra mt cht khi Y v mt dd Z. Kh Y nng hn khng kh, lm giy qu m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dd Z thu c m gam mui khan. Gi tr ca m l: A. 10,8 B. 8,2 C. 9,4 D. 9,6 Cu 7. (H KA 2009) Dy gm cc cht v thuc u c th gy nghin cho ngi l: A. cocain, seduxen, cafein B. heroin, seduxen, erythromixin C. penixilin, paradol, cocain D. ampixilin, erythromixin, cafein Cu 8. (H KB 2009) Cho 0,02 mol amino axit X tc dng va vi 200 ml dd HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dd NaOH 4%. Cng thc ca X l: A. H2NC2H3(COOH)2 B. H2NC3H5(COOH)2 C. (H2N)2C3H5COOH D. H2NC3H6COOH Cu 9. (H KB 2009.) Cho 2 hp cht X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dd NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z, T ln lt l: A. CH3OH v NH3 B. CH3OH v CH3NH2 C. CH3NH2 v NH3 D. C2H5OH v N2 Cu 10. (H KB 2009.) S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 3 B. 1 C. 2 D. 4 Cu 11. (H KA 2008.) Pht biu khng ng l: A. Trong dd H2NCH2COOH cn tn ti dng ion lng cc H3N+CH2COO-. B. Amino axit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. C. Amino axit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. D. Hp cht H2N-CH2-COOH3N-CH3 l este ca glixin. Cu 12. (H KB 2008.) un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dd HCl d, sau khi phn ng kt thc thu c cc cht l: A. H2NCH2CH2COOH, H2NCH2COOH B. H3N+CH2CH2COOHCl-, H3N+CH2COOHCl+ + C. H3N CH2(CH3)COOHCl , H3N CH2COOHCl D. H2NCH2(CH3)COOH, H2NCH2COOH Cu 13. (H KB 2008) Cho 8,9 gam mt hp cht hu c X c cng phn t C3 H7O2N phn ng vi 100ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7gam cht rn. Cng thc cu to thu gn ca X l : A. HCOOH3NCH = CH2 B. H2NCH2CH2 COOH C. CH2 = CHCOONH4 D. H2NCH2COOCH3 Cu 14. (H KB 2008) Cht phn ng vi dung dch FeCl3 cho kt ta l : A. CH3 NH2 B. CH3COOH C. CH3OH D. CH3COOH Cu 15. (H KB 2008) Cho cht hu c X c cng thc phn t : C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t ( theo vC) ca Y l . A. 85 B. 68 C. 45 D. 46 1

GV: Nguyn Vn Th-0977722500 Trng THPT Chuyn Hong Vn Th Cu 16. (H KB 2008) Cho dy cc cht : CH4, C2H2, C2H4, C2H5OH, CH2 = CH COOH, C6H5NH2 ( anilin), C6H5OH (phenol), C6H6 ( benzen). S cht trong dy phn ng c vi nc brom l : A. 6 B. 8 C. 7 D. 5 Cu 17. (H KA 2007) Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 ( cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l ( cho H = 1, O = 16 ) . A. C4 H9N B. C3H7N C. C2H7N D. C3H9N Cu 18. (H KA 2007) Cho hn hp X gm hai cht hu c c cng cng thc phn t ( C2H7NO2) tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh ( u lm xanh giy qu m ). T khi hi ca Z i vi H2 bng i vi H2 bng 13,75 c cn dung dch Y thu c khi lng mui khan l ( cho H=1, C=12, N =14, 0 = 16, Na = 23) A. 16,5g B. 14,3g C. 8,9g D. 15,7g Cu 19. (H KA 2007) - aminoaxit X cha mt nhm NH2 . Cho 10,3 gam X tc dng vi axit ( HCl) ( d ), thu c 13,95 gam mui khan. Cng thc cu tothu gn ca X l ( Cho H = 1, C=12, N = 14, O = 16, Cl=35,5) A.H2NCH2COOH B. CH3CH2CH(NH2 )COOH C.H2NCH2CH2COOH D. CH3CH2 (NH2)COOH Cu 20. (H KA 2007.) Nilon 6,6 l mt loi A. t visco B. polieste C. t poliamit D. t axetat Cu 21. (H KA 2007 ) t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 Lt kh N2 ( cc kh o ktc) v 3,15 gam H20. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2NCH2-COONa. CTCT thu gn ca X l A.H2NCH2CH2COOH B. H2NCH2COOCH3 C.H2NCH2CCOOC3H7 D. H2NCH2COOC2H5 Cu 22. (H KB 2007) Cho cc hp cht amino axit (X ) , mui amoni ca axit caboxylic (Y), amin (Z), este ca amino axit (T). Dy gm cc loi cht u tc dng vi dd NaOH v u tc dng vi dd HCl l: A. X, Y, Z, T B. X, Y, T C. X, Y, Z D. Y, Z, T Cu 23: -DH-2010 Hn hp khi X gm imetylamin va hai hirocacbon ng ng lin tip. t chay hoan toan 100 ml hn hp X bng mt lng oxi va u, thu c 550 ml hn hp Y gm khi va hi nc. Nu cho Y i qua dung dich axit sunfuric c (d) thi con lai 250 ml khi (cac th tich khi va hi o cung iu kin). Cng thc phn t cua hai hirocacbon la A. C2H6 va C3H8 B. C3H6 va C4H8 C. CH4 va C2H6 D. C2H4 va C3H6 Cu 23: -DH-10Phat biu ung la A. Khi thuy phn n cung cac protein n gian se cho hn hp cac -aminoaxit B. Khi cho dung dich long trng trng vao Cu(OH)2 thy xut hin phc mau xanh m C. Enzim amilaza xuc tac cho phan ng thuy phn xenluloz thanh mantoz D. Axit nucleic la polieste cua axit photphoric va glucoz Cu 24: DH-10 Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,50. B. 0,65. C. 0,70. D. 0,55. Cu 25: DH-10 Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 8 v 1,0. B. 8 v 1,5. C. 7 v 1,0. D. 7 v 1,5. Cu 26: DH-2010 t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l A. CH2=CH-NH-CH3. B. CH3-CH2-NH-CH3. C. CH3-CH2-CH2-NH2. D. CH2=CH-CH2-NH2. Cu 27: DH-2010 Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. vinylamoni fomat v amoni acrylat. B. amoni acrylat v axit 2-aminopropionic. C. axit 2-aminopropionic v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic. Cu 28: DH-2010 ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm NH2 v mt nhm COOH). t chy hon ton 0,1 mol Y, thu c tng khi 2

GV: Nguyn Vn Th-0977722500 Trng THPT Chuyn Hong Vn Th lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 120. B. 60. C. 30. D. 45. Cu 29: DH-2010 t chay hoan toan 0,1 mol mt amin no, mach h X bng oxi va u thu c 0,5 mol hn hp Y gm khi va hi. Cho 4,6g X tac dung vi dung dich HCl (d), s mol HCl phan ng la A. 0,1 B. 0,4 C. 0,3 D. 0,2 Cu 30: DH-2010 Hn hp X gm alanin va axit glutamic. Cho m gam X tac dung hoan toan vi dung dich NaOH (d), thu c dung dich Y cha (m+30,8) gam mui. Mt khac, nu cho m gam X tac dung hoan toan vi dung dich HCl, thu c dung dich Z cha (m+36,5) gam mui. Gia tri cua m la A. 112,2 B. 165,6 C. 123,8 D. 171,0 Cu 31: DH-2010 Thuy phn hoan toan 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) va 1 mol Phenylalanin (Phe). Thuy phn khng hoan toan X thu c ipeptit Val-Phe va tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X co cng thc la A. Gly-Phe-Gly-Ala-Val B. Gly-Ala-Val-Val-Phe C. Gly-Ala-Val-Phe-Gly D. Val-Phe-Gly-Ala-Gly Cu 32: DH-2010 Trung ha han tan 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. H2NCH2CH2CH2CH2NH2. B. CH3CH2CH2NH2. C. H2NCH2CH2NH2 D. H2NCH2CH2CH2NH2. Cu 33 : DH-2010 Dung dich nao sau y lam quy tim chuyn mau xanh ? A. Glyxin B. Etylamin C. Anilin D. Phenylamoni clorua Cu 34: DH-2010 ng vi cng thc phn t C2H7O2N co bao nhiu cht va phan ng c vi dung dich NaOH va phan ng c vi dung dich HCl ? A. 2 B. 3 C. 1 D. 4 Cu 35 : DH-2010 Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l A. CH3NH2 v C2H5NH2 B. C2H5NH2 v C3H7NH2 Cu 36 : DH-2010 Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau? A. 3 B. 1 C. 2 D. 4 Cu 37: DH-2010 S amin thm bc mt ng vi cng thc phn t C7H9N l A. 2 B. 4 C. 5 D. 3 Cu 38. (H KB 2007) Cho cc cht etyl axetat, anilin, etanol, axit acrylic, phenol, phenolamoni clorua, ancol benzylic, p-crezol. Trong cc cht cht ny, s cht tc dng vi NaOH l : A. 6 B. 4 C. 5 D. 3 Cu 39. (H KB 2007) Mt trong nhng im khc nhau ca protit so vi lipit v glucozo l: A. protit lun l cht hu c no B. Protit lun cha nhm hidroxyl C. protit c khi lng phn t ln hn D. protit lun cha nito Cu 40. (H KB 2007.) Dy gm cc cht u lm qu tm m chuyn mu xanh l: A. anilin, metylamin, amoniac B. amoni clorua, metylamin, natri hidroxit C. anilin, amoniac, natri hidroxit D. metylamin, amoniac, natri axetat Cu 41: S lng ng phn amin cha vong bezen ng vi cng thc phn t C7H9N la A. 3. B. 4. C. 5. D. 6. Cu 42: t chay ht 6,72 lit hn hp khi (ktc) X gm 2 amin n chc bc mt A va B la ng ng k tip. Cho hn hp khi va hi sau khi t chay ln lt qua binh 1 ng H 2SO4 c, binh 2 ng KOH d thy khi lng binh 2 tng 21,12 gam. Tn goi cua 2 amin la A. metylamin va etylamin. B. etylamin va n-propylamin. C. n-propylamin va n-butylamin. D. iso-propylamin va iso-butylamin.

Cu43: t chay hoan toan hn hp 2 amin n chc, no, bc 1, la ng ng k tip thu c ty l mol CO2 va H2O tng ng la 1:2. Cng thc cua 2 amin la 3

GV: Nguyn Vn Th-0977722500 Trng THPT Chuyn Hong Vn Th A. C2H5NH2 va C3H7NH2. B. C4H9NH2 va C3H7NH2. C. CH3NH2 va C2H5NH2. D. C4H9NH2 va C5H11NH2. Cu 44: X la -aminoaxit mach thng. Bit rng: 0,01mol X tac dung va u vi 80ml dung dich HCl 0,125M thu c 1,835g mui. Mt khac, nu cho 2,94g X tac dung va u vi NaOH thi thu c 3,82g mui. Tn goi cua X la. A. glyxin. B. alanin. C. axit glutamic. D. lysin. Cu 45: Cho hn hp 2 aminoaxit no cha 1 chc axit va 1 chc amino tac dung vi 110ml dung dich HCl 2M c dung dich A. tac dung ht vi cac cht trong A cn dung 140ml dung dich KOH 3M. Tng s mol 2 aminoaxit la A. 0,1. B. 0,2. C. 0,3. D. 0.4. Cu 46: -aminoaxit X co phn trm khi lng cua nit la 15,7303%, cua oxi la 35,9551%. Tn goi cua X la A. glyxin. B. alanin. C. axit glutamic. D. lysin. Cu 47: X co cha nhom amino va co cng thc phn t la C3H7O2N. Khi cho X phan ng vi dung dich NaOH, thu c mui C2H4O2NNa. Cng thc cu tao cua X la A. H2N-CH(CH3)-COOH. B. H2N-CH2-CH2-COOH. C. H2N-CH2-COOCH3. D. CH3-NH-CH2-COOH. Cu 48: t chay hoan toan mt amin n chc, no, bc 2 thu c CO 2 va H2O vi ty l mol tng ng la 2:3. Tn goi cua amin o la A. etyl metylamin. B. ietylamin. C. metyl iso-propylamin. D. imetylamin. Cu 49: Cho 0,01 mol mt aminoaxit X tac dung va u vi 40ml dung dich NaOH 0,25M. Mt khac, 1,5 gam X tac dung va u vi 40ml dung dich KOH 0,5M. Tn goi cua X la A. glyxin. B. alanin. C. axit glutamic. D. lysin. Cu 50: Khi ni v peptit v protein, ph no sau y l sai? t biu A. Protein c phn ng mu biure vi Cu(OH)2. B. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit. C. T hy phn hon ton protein n gin thu c cc -amino axit. D. Tt c cc protein u tan trong nc to thnh dung dch keo. Cu 51: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 81,54. B. 66,44. C. 111,74. D. 90,6. Cu 52: Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/10 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l A. 8,15 gam. B. 7,09 gam. C. 7,82 gam. D. 16,30 gam. Cu 53: Ancol v amin no sau y cng bc? A. (CH3)3COH v (CH3)3CNH2. B. (C6H5)2NH v C6H5CH2OH. C. (CH3)2CHOH v (CH3)2CHNH2. D. C6H5NHCH3 v C6H5CH(OH)CH3. Cu 54: Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l A. 3,56. B. 5,34. C. 2,67. D. 4,45.