BI TP HO NNG CAO LP 11 CHNG I: S IN LY

1. Cho 100ml dung dch Ba(OH)2 10-4M vo 100ml dung dch HCl 10-4M. Tnh pH ca dung dch sau phn ng?

2. Trn 100ml dung dch Ca(OH)2 10-3M vi 100ml dung dch HCl 10-3M .Tnh nng mol/l ca cc ion sau phn ng.?

3. Trn 300ml dung dch H2SO4 10-3M vi 200ml dung dch Ba(OH)2 c dung dch A. a) Tnh nng mol/l ca cc ion sau phn ng? b) Tnh khi lng kt tu thu c? c) Tnh pH ca dung dch A?

4. Cho 100ml dung dch H2SO4 5.10-4M vo100ml dung dch HCl 10-3M thu c dung dch A: a) Tnh pH ca dung dch A? b) Tnh VNaOH 2M cn trung ho dung dch A?

5. Trn 100ml dung dch Ca(OH)2 5.10-5M. Vi 100ml dung dch NaOH 10-2M. Thu c dung dch B: a) Tnh pH dung dch B? b) Tnh VHCl 0.5M trung ho dung dch B?

6. Trn 200ml dung dch A gm HCl 10-2M v H2SO4 5.10-3M vi 300ml dung dch NaOH 10-2M. Tnh pH ca dung dch sau phn ng?

7. trung ho 250ml dung dch cha ng thi HCl 0.5M v H2SO4 cn 250ml Ba(OH)2 0.08M v NaOH 0.54M : a) Tnh nng mol/l ca dung dch H2SO4?

b) Tnh khi lng kt ta thu c? c) Sau khi trung ho nu c cn dung dch th c bao nhiu gam mui khang?

8. Tnh pH ca cc dung dch: Dung dch H2SO4 2.10-3M v dung dch HCl 2.10-3M c L=90%

9. Dung dch HCl c pH = 3 cn pha long bao nhiu ln c dung dch c pH =4?

10. Dung dch NaOH c pH=9,phi pha thm hay ly bt nc ra c dung dch c pH=11?

11. Phi ly dung dch axit c pH=5 v baz c pH= 9 theo t l th tch no c dung dch c pH=8?

12. Chia 0.0198g Zn(OH)2 lm hai phn bng nhau:

a) Cho p1 tc dng vi 100ml dung dch H2SO4 2.103

b) Cho p2 tc dng vi 100ml dung dch NaOH 3.103

Tnh pH ca cc dung dch sau phn ng?

13. Cho 100ml ZnCl2 10-2M vo 100ml dung dch NaOH 5.10-2M. Tnh nng mol/l ca cc ion v pH ca dung dch sau phn ng?

14. Cho 150cm3 dung dch NaOH 7.10-2M vo 100cm3 dung dch Al2(OH)3 10-2M.Tnh nng mol/l v pH ca dung dch sau phn ng?

15. Trung ho 300ml dung dch X gm KOH v NaOH x pH =2 bng dung dch HCl c pH = 3. Thu c dung dch A.C cn A c 0.1915 mui khang . Tnh VHCl cn dng v nng mol/l ca KOH v NaOH trong dung dch ban u?

16. Trung ha 200ml dung dch H2SO4 c pH=2 bng dung dch bazo ca kim loi M c pH=12 c dung dch A. a) Tnh th tch bazo cn dng? b) C cn A thu c 0.142g mui khang. Tm cng thc ca phn t ca mui?

17. Dung dch A c pH=12. Trong 500ml dung dch A cha 0.342 gam hn hp mui sunfat v hridroxit ca kim loi kim M. Cho 500ml dung dch A tc dng va vi dung dch Ba(OH)2 thu c 0.233g kt ta. a) Xc nh M b) Tnh nng mol/l ca mui sunfat kim loi kim trong dung dch ban u?

18. Dung dch X c pH=2 cha H2SO4 v mui sunfat ca mt kim loi M. kt ta hon ton ion kim loi trong 500ml dung dch X cn 250ml dung dch NaOH c pH=13. Nung kt ta thu c trong khng kh n khi lng khng thay i, thu c 0.4g cht rn. Tm CTCT ca mui sunfat v CM mui trong dung dch X?

19. Hn hp X gm hai lim loi thuc nhm IIA v hai chu k lin tip, c tng khi lng m=31.7g. Ha tan X vo nc thnh 250ml dung dch. Sau cho B vo dung dch AgNO3 d th thu c 86.1g kt ta. a) Tm hai kim loi. b) Tm CM ca mi mui trong dung dch B?

20. Ha tan 39g hn hp X gm CaCO3, MgCO3, Na2CO3 bng dung dch HCl d thu c 9.856 lt CO2 o 27.3oC, 1atm v dung dch Y.

a) C cn dung dch Y thu c bao nhiu gam mui rn? b) Cho dung dch Y tc dng vi dung dch NaOH d, thu c kt ta Z. Nung Z n khi lng khng i, c 1g cht rn. Tnh phn trm cc mui trong hn hp X?

21. Cho 250ml dung dch A cha HCl, MgCl2, AlCl. Khi cho 250ml dung dch NaOH 0.8M tc dng vi 250ml dung dch A th th thu c kt ta ln nht. Nu thm tip 31.25ml dung dch NaOH trn vo hn hp th thu c kt ta khng i c m=2.9g. Tnh CM cc cht trong dung dch A v pH ca dung dch A?

22. Ha tan ht 4.6g hn hp hai mui cacbonat ca kim loi nhm IIA, thuc hai chu k lin tip bng dung dch HCl d. Thu c 1.12l CO2(ktc). a) Xc nh hai kim loi.

b) Tnh khi lng to thnh trong dung dch? c) Tnh phn trm khi lng hai mui trong hn hp ban u?

23.Mt dung dch c cha 2 ion Fe+ (0.1 mol): Al3+ ( 0.2 mol); v hai ion l Cl- (x mol); SO4-2 (y mol). Tnh x, y, bit rng khi c cn dung dch thu c 46.9g cht rn khan.

24.Hy xc nh khi lng cc mui trong dung dch A cha cc ion Na+, NH4+, SO42- ,CO32-. Bit rng khi chos A tc dng vi dung dch Ba(OH)2 d v un nng thu c 0.34g kh c th lm qu tm ha xanh v 4.3g kt ta ; khi cho A tc dng vi dung dch H2SO4 d th thu c 0.224l kh( ktc).

25.Cho 100ml dung dch NaOH vo 25ml dung dch AlCl3 va . Thu c lng kt ta cc i bng 1.872g.

a)Tnh CM ca mi dung dch? b)Nu thm V dung dch NaOH trn vo 25ml dung dch AlCl3 trn , sn phm thu c lng kt ta bng 9/10 lng kt ta cc i. Tnh V NaOH dng?

26.Dung dch A cha ZnSO4, dung dch B cha NaOH. Nu thm 200ml dung dch A vo 200ml dung dch B th thu c 7.425g kt ta. Nu thm 200ml dung dch A vo 300ml dung dch B th thu c 8.6625g kt ta. Tnh [A] v [B] ?(S [A] = 0.75M, [B] = 0.5M)

27. trung ha ht 100ml dung dch gm HCl v H2SO4 cn dng 40ml dung dch KOH 0.5M. Mt khc nu ly 100ml dung dch axit trn em trung ha trung ha mt lng NaOH va , ri c c cn dung dch thu c 13.2g mui khang. a) Tnh CM ca mi axit ban u?

b) Tnh nng mol/l ca ion H+ trong dung dch axit trn?

28.Cho 15.28g hn hp A gm Cu v Fe vo 1.1l dung dch Fe2(SO4)3 0.2M . Phn ng kt thc thu c dung dch X v 1.92g cht rn B. Cho B vo dung dch H2SO4 th khng thy kh thot ra. a) Tnh phn trm Cu, Fe trong A? b) Dung dch X phn ng vi 200ml dung dch KmnO4 trong H2SO4. Tnh nng mol/l dung dch KMnO4?

29.Nh t t dung dch NaOH 2M vo 100ml dung dch Y cha cc ion Zn2+, Fe3+ v SO42+ cho n khi kt ta ht ion kim loi th thy dung dch NaOH 2M dng l 350ml. Tip tc thm 200ml dung dch NaOH 2M vo h trn th mt cht kt ta va tan ht. Tnh nng mol/l ca cc ion trong dung dch Y?

30.Trn 3 dung dch H2SO4 0.1M, HNO3 0.2M, HCl 0.3M vi nhng th tch bng nhau thu c dung dch A. Ly 300ml dung dch A cho tc dung vi dung dch B gm NaOH 0.2M v KOH 0.29M. Tnh VB cn dng sau khi tc dung vi 300ml dung dch A c dung dch c pH = 2.

31.X l dung dch H2SO4 0.02M; Y l dung dch NaOH 0.035M. Hi phi trn hai dung dch trn theo th tch no c dung dch c pH= 2. Cho bit th tch dung dch sau khi trn khng thay i.

32.Hn hp A gm SO2 v khong kh c t l s mol 1: 5. Nung nng hn hp vi xc tc V2O5 th thu c hn hp kh B. T khi hi ca A so vi B l 0.93. a)Tnh hiu sut phn ng trn. Cho bit khng kh c 20% O2 v 80% N2.

b)Bit phn ng trn l phn ng thun - nghch. Hi cn bng chuyn dch theo chiu no khi: -Tng nhit phn ng. -Thm V2O5 vo phn ng.

33.Ly 100ml dung dch A cha HCl 2M v HNO3 1.5M cho tc dng vi 400ml dung dch B cha NaOH 0.05M v KOH nng a mol/l c dung dch trung tnh. Tnh a v nng mol/l cc ion trong dung dch C?

34.Cho 100ml dung dch A cha Na2SO4 0.1M v Na2CO3 0.1M tc dng va vi 100ml dung dch B cha Ba(OH)2 0.05M v Pb(NO)3 a mol/l to kt ta. Tnh a v khi lng kt ta to thnh?

35.Ha tan 7.2g hn hp hai mui sunfat ca hai kim loi ha tr II v III vo nc c dung dch X. Thm vo X mt lng BaCl2 va kt ta hon ton

mui BaSO4 thu c 11.65g BaSO4. C cn dung dch sau khi lc b kt ta thu c bao nhiu gam hn hp mui clorua?

36.Trn dung dch A cha NaOH v dung dch B cha Ba(OH)2 vi th tch bng nhau c dung dch C. Trung ha 100ml dung dch C cn 35ml dung dch H2SO4 2M ng thi thu c 9.32g kt ta. a) Tnh nng mol/l ca dung dch A v B? b) Cn trn bao nhiu ml dung dch B vi 20ml dung dch A c dung dch c th ha tan ht 1.08 Al.

37.Ha tan 54.7g hn hp A gm 3 mui BaCl2, KCl, MgCl2 vo 600ml dung dch AgNO3. sau phn ng thu c dung dch Dung dch v kt ta B. Lc b B ri cho 22.4g bt st vo D; khi phn ng kt thc thu c dung dch E v cht rn F. Ha tan F trong dung dch HCl d thu c 4.48l H2(ktc). Cho NaOH d

vo dung dch E c kt ta, nung kt ta n khi lng khng i c 36.4g cht rn. a) Vit phng trnh phn ng v tnh B, F? b)Tnh % khi lng cc cht trong A?