CU HI N TP CHNG HIROCACBON THM - ANCOL PHENOL

1/. V sao ancol c nhit si cao hn cc hirocacbon khc c cng s nghuyn t C? 2/. Trong cc cht sau: ancol, phenol, ete . Cht no c nhit si cao nht? v sao? 3/.Cho cc cht sau: C6H5OH, CH3CH2OH, C6H5CH2OH, CH2=CH-OH, CH2=CH-CH2-OH, ..cht no thuc loi ancol, phenol, ch r ancol loi no? 4/. Phn bit ancol etylic v glixerol bng phng php ho hc? 5/. Vit cng thc cu to v gi tn cc ancol ng phn C4H9OH 6/. Vit CTCT cc ancol c tn gi sau: ancol etylic, ancol n-propylic, etanol, propan-1-ol. 7/. Gi tn cc ancol sau theo danh php thay th. a. CH3-CH(OH)-CH2-CH3; CH3-CH2-CH2-CH2OH; CH3-C(CH3)2-CH2-CH(OH)-CH3b. 3-metylbutan1-ol, 2-metylbutan-2-ol, pentan-1-ol, 2-metylpropan-2-ol. 8/. Hon thnh cc PTHH ca cc phn ng sau: a. CH3OH + Na b. C3H5(OH)3 + Na c. ROH + HCl H SO ,140 C d. C2H5OH
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H SO ,170 C e. C2H5OH f. C6H5OH + Na g. C6H5OH + KOH h. C6H5OH + Br2 H SO (c), t i. C6H5OH + HNO3 (c) 9/. Hon thnh cc chui phn ng sau: a/.Metan axetilen etilen etanol anehit axetic b. Benzen brombenzen natri phenolat 10/Nhn bit cc cht sau bng phng php ha hc: a. Phenol, etanol, glixerol, nc. b. Propan-1,2-iol; propan-1,3-iol. 11/.t chy hon ton 5,5 gam hn hp X gm hai ancol CH3OH v C2H5OH thu c 4,48 lt kh CO2 (ktc) v m gam nc. a. Tnh % khi lng mi ancol trong hn hp u. b. Tnh gi tr m. 12/. t chy hon ton 0.1 mol mt ancol no, n chc X cn V lt O2 (ktc) thu c 6.72 lt kh CO2 (ktc) v gam nc. a. Xc nh cng thc phn t ca X. b. Tnh gi tr m. 13/. t chy hon ton mt ancol n chc X thu c 4,4 gam CO2 v 3,6 gam H2O. Xc nh cng thc phn t ca X. 14/.Cho 3,7 gam mt ancol no, n chc, mch h tc dng vi Na d thy c 0,56 lt kh thot ra ( ktc). Xc nh cng thc phn t ca X. 3/. Cho 14 gam hn hp A gm phenol v etanol tc dng vi Na d thu c 2,24 lt kh H2 (ktc). a. Vit PTHH ca cc phn ng xy ra. b. Tnh % mi cht trong hn hp A.
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15/.Cho 0,1 mol ru X phn ng ht vi Na d thu c 2,24 lt kh H2(ktc). S nhm chc -OH ca ru X l bao nhiu? 16/. Vit phng trnh chng minh nh hng qua li gia nhm OH v vng benzen ca phenol 17/. V sao ancol tan c trong nc cn ankan, anken, ankin th khng tan. 18/.T CH4 v cc ha cht v c cn thit khc, hy vit cc PTHH iu ch: Cao su buna, benzen, PE v PVC. 19/. Vit phng trnh chng minh phenol c tnh axit yu v yu hn axit cacbonic. 20/. Nhn bit cc cht sau bng phng php ha hc. c. Benzen, hex-1-en v toluen d. Benzen, stiren v propin 21/. Cho m g phenol tc dng va vi 200ml dd Br2 x M, sau phn ng thu c 33,1g kt ta trng. Xc nh m v x. 22/. So sng kh nng th vo vng ca cc cht sau: benzen v toluen. 23/. Dn 3,36 lt hn hp A gm propin v etilen i vo mt lng d dung dch AgNO3 trong NH3 thy cn 0,84 lt kh thot ra v c m gam kt ta. Cc th tch kh c o iu kin tiu chun. a. Tnh % theo th tch etilen trong A. b. Tnh m 24/. Hon thnh chui phn ng sau: CH4 C2H2 C6H6 C6H5Br 25/. Vit phng trnh, cho bit hin tng xy ra (nu c): a) Propin tc dng vi lng d dd Br2 b) etilen tc dng vi HBr c) Toluen + Cl2 c chiu sng d) Benzen + Br2 c xc tc bt Fe. e) Toluen + H2 xc tc Ni, t0.