THI TH I HC 2012-2013 MN HA HC H, tn th sinh:......................................................S bo danh:......................................

Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; As = 75 ; Br = 80; Rb = 85,5; Ag = 108; Ba = 137.
Cu 1: Cho dung dch NaOH 20% tc dng va vi dung dch FeCl2 10%. un nng trong khng kh cc phn ng xy ra hon ton. Nng % ca mui to thnh trong dung dch l A. 7,45% B. 7,49% C. 8,45% D. 6,32% Cu 2: X v Y u l hp cht ion cu to thnh t cc ion c cu hnh electron ging kh him Argon. Tng s ht proton, ntron, electron trong phn t X v Y ln lt l 108 v 164. X v Y ln lt l A. KCl hoc CaS v K2S B. CaS, K2S hoc CaCl2 C. CaS, CaCl2 D. CaCl2, K2S Cu 3: Nung nng a gam Fe(NO3)2 trong mt bnh kn khng c oxi, c cht rn X v cht kh Y. Dn Y vo mt cc nc c dung dch X. Cho ton b X vo Z, sau phn ng thy cn li b gam cht rn khng tan. Quan h gia a v b l A. a = b B. a = 4,5b C. a = 2,5b D. a = 3,5b Cu 4: Mt hn hp kh A sinh ra t thp tng hp NH3 gm NH3, N2, H2 cho vo bnh ri bt tia la in mt thi gian sau thy th tch hn hp tng 25%. Dn tip hn hp qua bnh ng CuO nung nng, ri qua tip ng ng CaCl2 khan thy th tch gim 75% so vi trc khi thc hin cc th nghim. Gi thit NH 3 b nhit phn hon ton. Hiu sut ca phn ng to ra NH3 trong thp tng hp l A. 20% B. 40% C. 25% D. 30% Cu 5: Cho m gam hn hp X gm Al4C3 v CaC2 vo nc d thu c dung dch A; a gam kt ta B v kh hn hp kh C. Lc b kt ta. t chy hon ton kh C ri dn sn phm chy vo dung dch A thu c thm a gam kt ta na. Hi trong hn hp X, Al4C3 v CaC2 c trn vi t l mol th no A. 1: 1 B. 1:2 C. 1:3 D. 2:1 Cu 6: Ho tan hon ton 0,775 gam n cht A trong 50 ml dung dch HNO3 c c mt hn hp gm hai kh (tn ti trong iu kin thch hp) c khi lng l 5,75 gam, c t khi hi ca hn hp so vi hiro l 115/3 v mt dung dch gm 2 axit c oxi vi hm lng oxi ln nht. trung ho hai axit ny cn dng va ht 0,1 mol NaOH. Nng mol/lit ca dung dch HNO3 dng l A. 4 M B. 5 M C. 2 M D. 2,5M Cu 7: So snh tnh baz ca cc cht sau: (1). Natri axetat (2) Natri phelonat (3). Natri etylat (4) Natri hiroxit A. (1) < (2) < (3) < (4) B. (2) < (1) < (3) < (4) C. (1) < (2) < (4) < (3) D. (2) < (1) < (4) < (3) Cu 8: Ha tan hon ton 4,8 gam kim loi M vo dung dch axit HNO3, thu c dung dch A. Chia A thnh 2 phn bng nhau. - Kt tinh phn 1 iu kin thch hp thu c 25,6 gam mt mui X duy nht. - Cho phn 2 tc dng vi NaOH d c kt ta B. Nung B n khi lng khng i thu c 4,0 gam cht rn. Kim loi M v thnh phn % theo khi lng ca n trong mui X l A. Mg v 9,375 % B. Cu v 16,216% C. Cu v 8,759% D. Mg v 16,216% Cu 9: un si bn dung dch, mi dung dch cha 1 mol mi cht sau: Ba(HCO3)2, Ca(HCO3)2, NaHCO3, NH4HCO3. Khi phn ng xy ra hon ton, trng hp no khi lng dung dch gim nhiu nht (Gi s nc bay hi khng ng k): A. NH4HCO3 B. Ba(HCO3)2 C. Ca(HCO3)2 D. NaHCO3 Cu 10: Cho cc cht sau CO, CO2, SO2, NO, NO2, Cl2, SiO2, Cl2O. Ln lt dn chng qua dung dch Ba(OH)2 th xy ra bao nhiu phn ng v bao nhiu phn ng oxi ho kh? A. 4 phn ng v 2 phn ng oxi ha kh B. 6 phn ng v 2 phn ng oxi ha kh C. 6 phn ng v 3 phn ng oxi ha kh D. 5 phn ng v 2 phn ng oxi ho kh Cu 11: Cho 17,04 gam hn hp rn A gm Ca, MgO, Na2O tc dng ht vi 720 ml dung dch HCl 1M (va ) thu c dung dch A. Khi lng mui NaCl c trong dung dich A l A. 14,04g. B. 15,21g. C. 4,68g. D. 8,775g. Cu 12: Hn hp X gm Na, Ca, Na2O, CaO. Ha tan ht 51,3 gam hn hp X thu c 5,6 lt H2(ktc) v dung dch kim Y trong c 28 gam NaOH. Hp th 17,92 lt kh SO2 (ktc) vo dung dch Y thu c m gam kt ta. Gi tr ca m l A. 60 gam B. 54 gam C. 72 gam D. 48 gam Cu 13: Cho cc nguyn t c m in nh sau: Nguyn t O Cl Mg C H Al N m in 3,44 3,16 1,31 2,55 2,20 1,61 3,04 Trang 1/8 CHUN

Sp xp theo s gim dn phn cc ca cc phn t sau: HCl, MgCl2, CO2, NH3, Al2O3. A. Al2O3 > MgCl2 > HCl > CO2 > NH3 B. MgCl2 > Al2O3 > HCl > CO2 > NH3 C. MgCl2 > Al2O3 > HCl > NH3 > CO2 D. Al2O3 > MgCl2 > HCl > NH3 > CO2 Cu 14: Cho cc cht: AgNO3, Cu(NO3)2, MgCO3, Ba(HCO3)2, NH4HCO3, NH4NO3 v Fe(NO3)2. Nu nung cc cht trn n khi lng khng i trong cc bnh kn khng c khng kh, ri cho nc vo cc bnh, s bnh c th to li cht ban u sau cc th nghim l A. 3. B. 4. C. 6. D. 5. Cu 15: Hn hp X gm Fe3O4, Cu v ZnO trong cc cht ly cng s mol. Ho tan X bng dung dch HCl d, sau khi cc phn ng kt thc thu c dung dch Y. Cho t t n d dung dch NaOH vo dung dch Y thu c kt ta Z. Thnh phn cc cht trong Z l A. Fe(OH)2 v Cu(OH)2 B. Zn(OH)2 v Fe(OH)2 C. Cu(H)2 v Fe(OH)3 D. Fe(OH)2 v Fe(OH)3 Cu 16: in phn mt dung dch cha FeCl3 , NaCl , HCl , CuCl2 vi in cc tr, mng ngn xp. Cho qu tm vo dung dch sau in phn thy qu tm khng i mu, chng t dng in phn thi im va ht: A. HCl B. CuCl2 C. FeCl3 D. FeCl2 Cu 17: Cho dung dch X cha 0,1 mol FeCl2, 0,2 mol FeSO4. Th tch dung dch KMnO4 0,8M trong H2SO4 long va oxi ha ht cc cht trong X l: A. 0,075 lt. B. 0,125 lt. C. 0,3 lt. D. 0,03 lt. Cu 18: C cc dung dch sau: (1): K2Cr2O7 + H2SO4; (2): H2SO4c; (3): Na2S; (4): HCl; (5): KBr; (6): Fe(NO3)2. Trn ln lt cc dung dch vi nhau tng cp mt th c bao nhiu cp c phn ng xy ra, trong bao nhiu cp xy ra phn ng oxh- kh: A. 10-8 B. 11 8 C. 8 7 D. 11 7 Cu 19: C cc nhn xt sau: (1) Cu hnh electron dng tng qut ca kim loi nhm IA c dng [KH]ns 1, ca phi kim Halogen nhm VIIA c dng [KH]ns2np5 (2) Mi trng dung dch trung tnh lm qu tm khng i mu, dung dch baz lm qu tm ha xanh, dung dch axit lm qu tm ha (3) Khi phn ng vi dung dch baz: axit 1 nc ch to 1 loi mui; axit 2 nc c th to 2 loi mui, axit 3 nc c th to ng thi 3 loi mui trong sn phm thu c. (4) H3PO3 l axit 3 nc nhng khi phn ng vi dd kim sn phm c th ch c 2 loi mui. Nhng nhn xt sai l A. (3), (4) B. (1), (3) C. (1), (2), (3) D. (2),(4) Cu 20: Thy phn hon ton 1 mol PCl3 cn bao nhiu mol NaOH trung ha dung dch thu c? A. 6 mol B. 5 mol C. 4 mol D. 3 mol Cu 21: Cho cc kim loi v cc dd: Al, Cu, FeSO4, HNO3 long, HCl, AgNO3. S lng phn ng xy ra gia tng cp cht l: A. 7 B. 8 C. 9 D. 10 Cu 22: Cho 18,6g hn hp Fe v Zn vo 500ml dd HCl x(M). Sau phn ng hon ton c cn c 34,575g cht rn. Nu cho hn hp trn tc dng vi 800ml dd HCl x(M) c cn thu oc 39,9g cht rn. Gi tr ca x v khi lng ca Fe trong hn hp l A. x = 0,9 v 5,6 gam B. x = 0,9 v 8,4 gam C. x = 0,45 v 5,6 gam D. x = 0,45 v 8,4 gam Cu 23: X mch h c CTPT C8H14 tc dng vi HBr cho 3 sn phm monobrom. S ng phn cu to tha mn l: A. 6 B. 4 C. 9 D. 15 Cu 24: Cho 3,584 lt (ktc) hn hp gm mt ankan (X), mt anken (Y), mt ankin (Z). Ly hn hp cho tc dng vi dung dch AgNO3 d trong amoniac thy th tch hn hp gim 12,5% v thu c 1,47 gam kt ta. Cho hn hp cn li i qua dung dch brom d thy khi lng bnh brom tng 2,22 gam v c 13,6 gam brom phn ng. t chy hon ton lng kh i ra khi bnh brom ri hp th ton b sn phm chy vo dung dch Ba(OH)2 d th thu c 2,955 gam kt ta. Cc cht X, Y, Z ln lt l: A. CH4, C2H4, C2H2. B. C3H8, C2H4, C3H4. C. C3H8, C2H4, C2H2. D. CH4, C2H4, C3H4. Cu 25: X mch h c cng thc CxHy. Mt bnh c dung tch khng i cha hn hp kh X v O2 d 150o C v c p sut 2 atm. Bt tia la in t chy X sau a bnh v 150oC, p sut trong bnh vn l 2 atm. Ngi ta trn 9,6 gam X vi 0,6 gam hiro ri cho qua bnh ng Ni nung nng (h= 100%) th thu c hn hp Y. Khi lng mol trung bnh ca Y l A. 52,5. B. 46,5. C. 48,5. D. 42,5. Cu 26: Cho cc cht sau: sec-butyl clorua, neo-pentyl clorua, benzyl clorua, 3-clobut-1-en, 4-clo-2-metylpent-1en, p-clotoluen. S cht b thy phn khi un vi nc, b thy phn khi un vi dung dch NaOH, b thy phn khi un vi dung dch NaOH c, nhit v p sut cao ln lt l: A. 1 5 1 B. 2 5 6 C. 1 4 6 D. 2 3 1

Trang 2/8 CHUN

Cu 27: t chy hon ton 0,08 mol hn hp 2 ancol bc mt, sau phn ng thu c 6,16 gam CO 2. Nu oxi ho 0,08 mol hn hp 2 ancol trn bng oxi, xc tc Cu, un nng (gi s hiu sut 100%). Sau cho sn phm tc dng vi dung dch AgNO3/NH3 d, thu c m gam Ag. Gi tr ca m l A. m = 34,56 gam B. 17,28 gam < m 34,56 gam C. m = 17,28 gam D. 21,6 gam m < 34,56 gam Cu 28: Cho V lt (ktc) hn hp kh gm 2 olefin lin tip nhau trong cng dy ng ng hp nc (xc tc H+) thu c 12,9 gam hn hp X gm 3 ancol. un nng X trong H 2SO4 c 1400C thu c 10,65 gam hn hp Y gm 6 ete khan. Gi s hiu sut cc phn ng l 100%. Cng thc phn t ca 2 olefin v gi tr ca V l A. C2H4, C3H6, 5,60 lt B. C4H8, C5H10, 5,6 lt C. C2H4, C3H6, 4,48 lt D. C3H6, C4H8, 4,48 lt Cu 29: X, Y l cc hp cht hu c ng chc cha cc nguyn t C, H, O. Khi tc dng vi AgNO3 trong NH3 th 1 mol X hoc Y to ra 4 mol Ag. Cn khi t chy X, Y th t l s mol O2 tham gia t chy, CO2v H2O to thnh nh sau: - i vi X: n O2 : n CO2 n H 2O =1: 1: 1 - i vi Y: n O2 : n CO2 n H 2O =1,5: 2: 1 Cng thc phn t v cng thc cu to ca X, Y l: A. CH3CHOv HCHO B. HCHOv C2H5CHO C. HCOOH v HCHO D. HCHO v (CHO)2 Cu 30: Mt ancol 2 chc, phn t khng c nguyn t C bc 3. un nh m gam hi ancol trn vi bt CuO (d) n khi phn ng xy hon ton thy khi lng cht rn trong bnh gim 2,24gam ng thi thu c hn hp kh v hi ( ktc) c t khi hi so vi H2 l 18. m c gi tr l: A. 12,88 gam B. 7,84 gam C. 5,32 gam D. 1,54 gam Cu 31: Cho dy gm cc cht Na, Mg; Ag, O3, Cl2, HCl, Cu(OH)2, Mg(HCO3)2, CuO, NaCl, C2H5-OH, C6H5OH, C6H5-NH2, CH3ONa, CH3COONa, s cht tc dng c vi axit propionic l: A. 8 B. 10 C. 7 D. 9 Cu 32: Cho s chuyn ha: A Bit A, B l 2 ancol ng ng k tip tha mn iu kin d X B; B = 1,4375 . Vy X l A A. CH3COOC2H5 B. C2H5COOCH3 C. C2H5COOC2H5 D. CH3COOCH3 Cu 33: Mt loi lipit cha 50,0 % triolein, 30,0 % tripanmitin v 20,0 % tristearin. X phng ha m gam lipit trn thu c 138 gam glixerol. Vy gi tr ca m l A. 1302,5 gam. B. 1292,7 gam C. 1225,0 gam. D. 1305,2 gam Cu 34: Cho 3,92 gam mt este n chc X tc dng va vi 100ml KOH 0,4M thu c 6,16 gam mui Y. Axit ha Y thu c cht Z. Z c cng thc phn t l: A. C5H6O2 B. C5H8O3 C. C6H12O2 D. C6H12O3 Cu 35: t chy 0,27 gam cht hu c X thu c 0,22 gam CO2; 0,18 gam H2O v 56 ml N2 (ktc). Bit t khi hi ca X so vi oxi l 3,375. Khi cho X tc dng vi dung dch NaOH d ri c cn thu c mt cht hu c Y n chc v hn hp cht v c. X l: A. Mui ca amin. B. Amino este. C. Mui amni. D. Amino axit. Cu 36: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit GlyGly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l: A. Gly, Gly. B. Ala, Val. C. Ala, Gly. D. Gly, Val. Cu 37: Hn hp M gm mt peptit X v mt peptit Y (chng cu to t 1 loi aminoaxit, tng s nhm CO NH trong 2 phn t l 5) vi t l s mol nX:nY=1:3..Khi thy phn hon ton m gam M thu c 81 gam glixin v 42,72 gam alanin. m c gi tr l A. 104,28 gam B. 109,5 gam C. 116,28 gam D. 110,28 gam Cu 38: Hn hp kh X gm etylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l A. CH4 v C2H6. B. C2H4 v C3H6. C. C2H6 v C3H8. D. C3H6 v C4H8. Cu 39: Phn ng tng hp glucoz trong cy xanh cn c cung cp nng lng , 6CO2 + 6H2O asclorofin C6H12O6 + 6O2 H = 2813kJ. Trong mt pht, mi cm2 l xanh nhn c khong nng lng 2,09 J nng lng Mt tri, nhng ch 10% c s dng vo phn ng tng hp glucoz. Vi mt ngy nng (t 6 gi n 17 gi), din tch l xanh l 1m2 th khi lng glucoz tng hp c l A. 80,70g. B. 93,20g. C. 88,27g. D. 78,78g.

Trang 3/8 CHUN

Cu 40: Thy phn hon ton 34,2 gam mantoz. Ly ton b sn phm ca phn ng thy phn cho tc dng vi lng d Cu(OH)2 trong dung dch NaOH nng th thu c a gam kt ta. Cn nu cho ton b sn phm ny tc dng vi dung dch nc brom d th c b gam brom tham gia phn ng. Gi tr ca a v b ln lt l A. 14,4 gam v 16 gam B. 28,8 gam v 16 gam C. 14,4 gam v 32 gam D. 28,8 gam v 32 gam Cu 41: t chy hon ton 1 lng cao su buna-N vi lng khng kh va , thy to 1 hn hp kh nhit trn 127oC m CO2 chim 14,1% v th tch. T l mol gia butaien v vinyl xianua trong polime ny l A. 2/1 B. 2/3 C. D. Cu 42: Hp cht X c cng thc phn t C11H20O4. Bit X tc dng vi NaOH to ra mui ca axit hu c Y mch thng v 2 ancol l etanol v propan 2 ol. Kt lun no sau y khng ng? A. X l ieste. B. T Y c th iu ch c t nilon 6,6. C. Cng thc ca Y l HOOC[CH2]4COOH D. Tn gi ca X l etyl propyl aipat. Cu 43: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. HCOOH v HCOOCH3 B. HCOOH v HCOO C2H5 C. C2H5COOH v C2H5COOCH3 D. CH3COOH v CH3COOC2H5 Cu 44: t chy ht 5,4 gam cht hu c A, ch thu c CO2 v H2O. Cho hp thu ht sn phm chy vo bnh ng nc vi trong d, khi lng bnh tng 19 gam. Trong bnh c 35 gam kt ta. Hi A nh hn hi cumen (isopropylbenzen). Nu A l mt hp cht thm v tc dng c dung dch kim th cng thc phn t tm c ca A c th ng vi bao nhiu cht? A. Hai cht B. Ba cht C. Bn cht D. Nm cht Cu 45: X l mt dn xut ca benzen c cng thc phn t C 7H9NO2. Cho 1 mol X tc dng va vi NaOH, c cn dung dch thu c mt mui khan c khi lng l 144 gam. Cng thc cu to thu gn ca X l A. C6H5COONH4. B. HCOOH3NC6H5. C. HCOOC6H4NO2. D. HCOOC6H4NH2. Cu 46: Cho s sau:
Cl Cl NaOH H 2 O(t , e ol( ) e ol( ) (CH3)2CH-CH2CH2Cl KO H/tant A H B KO H/tant C H D ) E E c cng thc cu to l A. (CH3)2C(OH)-CH2CH3. B. (CH3)2CH-CH(OH)CH3. C. (CH3)2C=CHCH3. D. (CH3)2CH-CH2CH2OH Cu 47: t chy hon ton hn hp A gm 2 ankin X, Y. Hp th ton b sn phm chy vo 4,5 lt dung dch Ca(OH) 2 0,02M thu c kt ta v khi lng dung dch tng 3,78 gam. Cho dung dch Ba(OH)2 va vo dung dch thu thm kt ta. Tng khi lng kt ta 2 ln l 18,85 gam. Bit rng s mol X bng 60% tng s mol ca X v Y c trong hn hp A . Cc phn ng xy ra hon ton. Cng thc ca X, Y ln lt l A. C3H4 v C4H6. B. C2H2 v C4H6. C. C2H2 v C3H4. D. C4H6 v C2H2. Cu 48: Xt cc cht sau: xiclopropan, stiren, cumen, toluen, benzen, phenol, alanin, naphtalen, fructoz, axetanehit, axeton, glyxeryl stearopanmitooleat. S cht lm mt mu dung dch Br2 l: A. 7 B. 4 C. 6 D. 5 Cu 49: Cho hp cht hu c n chc X c cng thc l C 3H10O3N2. Cho m gam X tc dng vi NaOH va thu c 2,55 gam mui v c. Gi tr ca m l: A. 3,705 gam B. 3,66 gam C. 3,795 gam D. 3,84 gam Cu 50: Khi cho 13,8 gam glixerol (X) tc dng vi axit fomic th thu c hp cht hu c (Y) c khi lng bng 1,18 ln khi lng cht (X) ban u. Bit hiu sut ca phn ng l 73,35 %. Vy tng s nguyn t c trong (Y) l: A. 16 B. 14 C. 18 D. 20
0 0 0

----------- HT ----------

P N THI TH I HC 2013

Trang 4/8 CHUN

Cu 1: Cho dung dch NaOH 20% tc dng va vi dung dch FeCl2 10%. un nng trong khng kh cc phn ng xy ra hon ton. Nng % ca mui to thnh trong dung dch l A. 7,45% B. 7,49% C. 8,45% D. 6,32% Cu 2: X v Y u l hp cht ion cu to thnh t cc ion c cu hnh electron ging kh him Argon. Tng s ht proton, ntron, electron trong phn t X v Y ln lt l 108 v 164. X v Y ln lt l A. KCl hoc CaS v K2S B. CaS, K2S hoc CaCl2 C. CaS, CaCl2 D. CaCl2, K2S Cu 3: Nung nng a gam Fe(NO3)2 trong mt bnh kn khng c oxi, c cht rn X v cht kh Y. Dn Y vo mt cc nc c dung dch X. Cho ton b X vo Z, sau phn ng thy cn li b gam cht rn khng tan. Quan h gia a v b l A. a = b B. a = 4,5b C. a = 2,5b D. a = 3,5b Cu 4: Mt hn hp kh A sinh ra t thp tng hp NH3 gm NH3, N2, H2 cho vo bnh ri bt tia la in mt thi gian sau thy th tch hn hp tng 25%. Dn tip hn hp qua bnh ng CuO nung nng, ri qua tip ng ng CaCl2 khan thy th tch gim 75% so vi trc khi thc hin cc th nghim. Gi thit NH 3 b nhit phn hon ton. Hiu sut ca phn ng to ra NH3 trong thp tng hp l A. 20% B. 40% C. 25% D. 30% Cu 5: Cho m gam hn hp X gm Al4C3 v CaC2 vo nc d thu c dung dch A; a gam kt ta B v kh hn hp kh C. Lc b kt ta. t chy hon ton kh C ri dn sn phm chy vo dung dch A thu c thm a gam kt ta na. Hi trong hn hp X, Al4C3 v CaC2 c trn vi t l mol th no A. 1: 1 B. 1:2 C. 1:3 D. 2:1 Cu 6: Ho tan hon ton 0,775 gam n cht A trong 50 ml dung dch HNO3 c c mt hn hp gm hai kh (tn ti trong iu kin thch hp) c khi lng l 5,75 gam, c t khi hi ca hn hp so vi hiro l 115/3 v mt dung dch gm 2 axit c oxi vi hm lng oxi ln nht. trung ho hai axit ny cn dng va ht 0,1 mol NaOH. Nng mol/lit ca dung dch HNO3 dng l A. 4 M B. 5 M C. 2 M D. 2,5M Cu 7: So snh tnh baz ca cc cht sau: (1). Natri axetat (2) Natri phelonat (3). Natri etylat (4) Natri hiroxit A. (1) < (2) < (3) < (4) B. (2) < (1) < (3) < (4) C. (1) < (2) < (4) < (3) D. (2) < (1) < (4) < (3) Cu 8: Ha tan hon ton 4,8 gam kim loi M vo dung dch axit HNO3, thu c dung dch A. Chia A thnh 2 phn bng nhau. - Kt tinh phn 1 iu kin thch hp thu c 25,6 gam mt mui X duy nht. - Cho phn 2 tc dng vi NaOH d c kt ta B. Nung B n khi lng khng i thu c 4,0 gam cht rn. Kim loi M v thnh phn % theo khi lng ca n trong mui X l A. Mg v 9,375 % B. Cu v 16,216% C. Cu v 8,759% D. Mg v 16,216% Cu 9: un si bn dung dch, mi dung dch cha 1 mol mi cht sau: Ba(HCO3)2, Ca(HCO3)2, NaHCO3, NH4HCO3. Khi phn ng xy ra hon ton, trng hp no khi lng dung dch gim nhiu nht (Gi s nc bay hi khng ng k): A. NH4HCO3 B. Ba(HCO3)2 C. Ca(HCO3)2 D. NaHCO3 Cu 10: Cho cc cht sau CO, CO2, SO2, NO, NO2, Cl2, SiO2, Cl2O. Ln lt dn chng qua dung dch Ba(OH)2 th xy ra bao nhiu phn ng v bao nhiu phn ng oxi ho kh? A. 4 phn ng v 2 phn ng oxi ha kh B. 6 phn ng v 2 phn ng oxi ha kh C. 6 phn ng v 3 phn ng oxi ha kh D. 5 phn ng v 2 phn ng oxi ho kh Cu 11: Cho 17,04 gam hn hp rn A gm Ca, MgO, Na2O tc dng ht vi 720 ml dung dch HCl 1M (va ) thu c dung dch A. Khi lng mui NaCl c trong dung dich A l A. 14,04g. B. 15,21g. C. 4,68g. D. 8,775g. Cu 12: Hn hp X gm Na, Ca, Na2O, CaO. Ha tan ht 51,3 gam hn hp X thu c 5,6 lt H2(ktc) v dung dch kim Y trong c 28 gam NaOH. Hp th 17,92 lt kh SO2 (ktc) vo dung dch Y thu c m gam kt ta. Gi tr ca m l A. 60 gam B. 54 gam C. 72 gam D. 48 gam Cu 13: Cho cc nguyn t c m in nh sau: Nguyn t O Cl Mg C H Al N m in 3,44 3,16 1,31 2,55 2,20 1,61 3,04 Sp xp theo s gim dn phn cc ca cc phn t sau: HCl, MgCl2, CO2, NH3, Al2O3. A. Al2O3 > MgCl2 > HCl > CO2 > NH3 B. MgCl2 > Al2O3 > HCl > CO2 > NH3 C. MgCl2 > Al2O3 > HCl > NH3 > CO2 D. Al2O3 > MgCl2 > HCl > NH3 > CO2 Cu 14: Cho cc cht: AgNO3, Cu(NO3)2, MgCO3, Ba(HCO3)2, NH4HCO3, NH4NO3 v Fe(NO3)2. Nu nung cc cht trn n khi lng khng i trong cc bnh kn khng c khng kh, ri cho nc vo cc bnh, s bnh c th to li cht ban u sau cc th nghim l A. 3. B. 4. C. 6. D. 5.

Trang 5/8 CHUN

Cu 15: Hn hp X gm Fe3O4, Cu v ZnO trong cc cht ly cng s mol. Ho tan X bng dung dch HCl d, sau khi cc phn ng kt thc thu c dung dch Y. Cho t t n d dung dch NaOH vo dung dch Y thu c kt ta Z. Thnh phn cc cht trong Z l A. Fe(OH)2 v Cu(OH)2 B. Zn(OH)2 v Fe(OH)2 C. Cu(H)2 v Fe(OH)3 D. Fe(OH)2 v Fe(OH)3 Cu 16: in phn mt dung dch cha FeCl3 , NaCl , HCl , CuCl2 vi in cc tr, mng ngn xp. Cho qu tm vo dung dch sau in phn thy qu tm khng i mu, chng t dng in phn thi im va ht: A. HCl B. CuCl2 C. FeCl3 D. FeCl2 Cu 17: Cho dung dch X cha 0,1 mol FeCl2, 0,2 mol FeSO4. Th tch dung dch KMnO4 0,8M trong H2SO4 long va oxi ha ht cc cht trong X l: A. 0,075 lt. B. 0,125 lt. C. 0,3 lt. D. 0,03 lt. Cu 18: C cc dung dch sau: (1): K2Cr2O7 + H2SO4; (2): H2SO4c; (3): Na2S; (4): HCl; (5): KBr; (6): Fe(NO3)2. Trn ln lt cc dung dch vi nhau tng cp mt th c bao nhiu cp c phn ng xy ra, trong bao nhiu cp xy ra phn ng oxh- kh: A. 10-8 B. 11 8 C. 8 7 D. 11 7 Cu 19: C cc nhn xt sau: (1) Cu hnh electron dng tng qut ca kim loi nhm IA c dng [KH]ns 1, ca phi kim Halogen nhm VIIA c dng [KH]ns2np5 (2) Mi trng dung dch trung tnh lm qu tm khng i mu, dung dch baz lm qu tm ha xanh, dung dch axit lm qu tm ha (3) Khi phn ng vi dung dch baz: axit 1 nc ch to 1 loi mui; axit 2 nc c th to 2 loi mui, axit 3 nc c th to ng thi 3 loi mui trong sn phm thu c. (4) H3PO3 l axit 3 nc nhng khi phn ng vi dd kim sn phm c th ch c 2 loi mui. Nhng nhn xt sai l A. (3), (4) B. (1), (3) C. (1), (2), (3) D. (2),(4) Cu 20: Thy phn hon ton 1 mol PCl3 cn bao nhiu mol NaOH trung ha dung dch thu c? A. 6 mol B. 5 mol C. 4 mol D. 3 mol Cu 21: Cho cc kim loi v cc dd: Al, Cu, FeSO4, HNO3 long, HCl, AgNO3. S lng phn ng xy ra gia tng cp cht l: A. 7 B. 8 C. 9 D. 10 Cu 22: Cho 18,6g hn hp Fe v Zn vo 500ml dd HCl x(M). Sau phn ng hon ton c cn c 34,575g cht rn. Nu cho hn hp trn tc dng vi 800ml dd HCl x(M) c cn thu oc 39,9g cht rn. Gi tr ca x v khi lng ca Fe trong hn hp l A. x = 0,9 v 5,6 gam B. x = 0,9 v 8,4 gam C. x = 0,45 v 5,6 gam D. x = 0,45 v 8,4 gam Cu 23: X mch h c CTPT C8H14 tc dng vi HBr cho 3 sn phm monobrom. S ng phn cu to tha mn l: A. 6 B. 4 C. 9 D. 15 Cu 24: Cho 3,584 lt (ktc) hn hp gm mt ankan (X), mt anken (Y), mt ankin (Z). Ly hn hp cho tc dng vi dung dch AgNO3 d trong amoniac thy th tch hn hp gim 12,5% v thu c 1,47 gam kt ta. Cho hn hp cn li i qua dung dch brom d thy khi lng bnh brom tng 2,22 gam v c 13,6 gam brom phn ng. t chy hon ton lng kh i ra khi bnh brom ri hp th ton b sn phm chy vo dung dch Ba(OH)2 d th thu c 2,955 gam kt ta. Cc cht X, Y, Z ln lt l: A. CH4, C2H4, C2H2. B. C3H8, C2H4, C3H4. C. C3H8, C2H4, C2H2. D. CH4, C2H4, C3H4. Cu 25: X mch h c cng thc CxHy. Mt bnh c dung tch khng i cha hn hp kh X v O2 d 150o C v c p sut 2 atm. Bt tia la in t chy X sau a bnh v 150oC, p sut trong bnh vn l 2 atm. Ngi ta trn 9,6 gam X vi 0,6 gam hiro ri cho qua bnh ng Ni nung nng (h= 100%) th thu c hn hp Y. Khi lng mol trung bnh ca Y l A. 52,5. B. 46,5. C. 48,5. D. 42,5. Cu 26: Cho cc cht sau: sec-butyl clorua, neo-pentyl clorua, benzyl clorua, 3-clobut-1-en, 4-clo-2-metylpent-1en, p-clotoluen. S cht b thy phn khi un vi nc, b thy phn khi un vi dung dch NaOH, b thy phn khi un vi dung dch NaOH c, nhit v p sut cao ln lt l: A. 1 5 1 B. 2 5 6 C. 1 4 6 D. 2 3 1 Cu 27: t chy hon ton 0,08 mol hn hp 2 ancol bc mt, sau phn ng thu c 6,16 gam CO 2. Nu oxi ho 0,08 mol hn hp 2 ancol trn bng oxi, xc tc Cu, un nng (gi s hiu sut 100%). Sau cho sn phm tc dng vi dung dch AgNO3/NH3 d, thu c m gam Ag. Gi tr ca m l A. m = 34,56 gam B. 17,28 gam < m 34,56 gam C. m = 17,28 gam D. 21,6 gam m < 34,56 gam

Trang 6/8 CHUN

Cu 28: Cho V lt (ktc) hn hp kh gm 2 olefin lin tip nhau trong cng dy ng ng hp nc (xc tc H+) thu c 12,9 gam hn hp X gm 3 ancol. un nng X trong H 2SO4 c 1400C thu c 10,65 gam hn hp Y gm 6 ete khan. Gi s hiu sut cc phn ng l 100%. Cng thc phn t ca 2 olefin v gi tr ca V l A. C2H4, C3H6, 5,60 lt B. C4H8, C5H10, 5,6 lt C. C2H4, C3H6, 4,48 lt D. C3H6, C4H8, 4,48 lt Cu 29: X, Y l cc hp cht hu c ng chc cha cc nguyn t C, H, O. Khi tc dng vi AgNO3 trong NH3 th 1 mol X hoc Y to ra 4 mol Ag. Cn khi t chy X, Y th t l s mol O2 tham gia t chy, CO2v H2O to thnh nh sau: - i vi X: n O2 : n CO2 n H 2O =1: 1: 1 - i vi Y: n O2 : n CO2 n H 2O =1,5: 2: 1 Cng thc phn t v cng thc cu to ca X, Y l: A. CH3CHOv HCHO B. HCHOv C2H5CHO C. HCOOH v HCHO D. HCHO v (CHO)2 Cu 30: Mt ancol 2 chc, phn t khng c nguyn t C bc 3. un nh m gam hi ancol trn vi bt CuO (d) n khi phn ng xy hon ton thy khi lng cht rn trong bnh gim 2,24gam ng thi thu c hn hp kh v hi ( ktc) c t khi hi so vi H2 l 18. m c gi tr l: A. 12,88 gam B. 7,84 gam C. 5,32 gam D. 1,54 gam Cu 31: Cho dy gm cc cht Na, Mg; Ag, O3, Cl2, HCl, Cu(OH)2, Mg(HCO3)2, CuO, NaCl, C2H5-OH, C6H5OH, C6H5-NH2, CH3ONa, CH3COONa, s cht tc dng c vi axit propionic l: A. 8 B. 10 C. 7 D. 9 Bit A, B l 2 ancol ng ng k tip tha mn iu kin d Cu 32: Cho s chuyn ha: A X B; B = 1,4375 . Vy X l A A. CH3COOC2H5 B. C2H5COOCH3 C. C2H5COOC2H5 D. CH3COOCH3 Cu 33: Mt loi lipit cha 50,0 % triolein, 30,0 % tripanmitin v 20,0 % tristearin. X phng ha m gam lipit trn thu c 138 gam glixerol. Vy gi tr ca m l A. 1302,5 gam. B. 1292,7 gam C. 1225,0 gam. D. 1305,2 gam Cu 34: Cho 3,92 gam mt este n chc X tc dng va vi 100ml KOH 0,4M thu c 6,16 gam mui Y. Axit ha Y thu c cht Z. Z c cng thc phn t l: A. C5H6O2 B. C5H8O3 C. C6H12O2 D. C6H12O3 Cu 35: t chy 0,27 gam cht hu c X thu c 0,22 gam CO2; 0,18 gam H2O v 56 ml N2 (ktc). Bit t khi hi ca X so vi oxi l 3,375. Khi cho X tc dng vi dung dch NaOH d ri c cn thu c mt cht hu c Y n chc v hn hp cht v c. X l: A. Mui ca amin. B. Amino este. C. Mui amni. D. Amino axit. Cu 36: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit GlyGly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l: A. Gly, Gly. B. Ala, Val. C. Ala, Gly. D. Gly, Val. Cu 37: Hn hp M gm mt peptit X v mt peptit Y (chng cu to t 1 loi aminoaxit, tng s nhm CO NH trong 2 phn t l 5) vi t l s mol nX:nY=1:3..Khi thy phn hon ton m gam M thu c 81 gam glixin v 42,72 gam alanin. m c gi tr l A. 104,28 gam B. 109,5 gam C. 116,28 gam D. 110,28 gam Cu 38: Hn hp kh X gm etylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l A. CH4 v C2H6. B. C2H4 v C3H6. C. C2H6 v C3H8. D. C3H6 v C4H8. Cu 39: Phn ng tng hp glucoz trong cy xanh cn c cung cp nng lng , 6CO2 + 6H2O asclorofin C6H12O6 + 6O2 H = 2813kJ. 2 Trong mt pht, mi cm l xanh nhn c khong nng lng 2,09 J nng lng Mt tri, nhng ch 10% c s dng vo phn ng tng hp glucoz. Vi mt ngy nng (t 6 gi n 17 gi), din tch l xanh l 1m2 th khi lng glucoz tng hp c l A. 80,70g. B. 93,20g. C. 88,27g. D. 78,78g. Cu 40: Thy phn hon ton 34,2 gam mantoz. Ly ton b sn phm ca phn ng thy phn cho tc dng vi lng d Cu(OH)2 trong dung dch NaOH nng th thu c a gam kt ta. Cn nu cho ton b sn phm ny tc dng vi dung dch nc brom d th c b gam brom tham gia phn ng. Gi tr ca a v b ln lt l A. 14,4 gam v 16 gam B. 28,8 gam v 16 gam C. 14,4 gam v 32 gam D. 28,8 gam v 32 gam Cu 41: t chy hon ton 1 lng cao su buna-N vi lng khng kh va , thy to 1 hn hp kh nhit trn 127oC m CO2 chim 14,1% v th tch. T l mol gia butaien v vinyl xianua trong polime ny l A. 2/1 B. 2/3 C. D. Trang 7/8 CHUN

Cu 42: Hp cht X c cng thc phn t C11H20O4. Bit X tc dng vi NaOH to ra mui ca axit hu c Y mch thng v 2 ancol l etanol v propan 2 ol. Kt lun no sau y khng ng? A. X l ieste. B. T Y c th iu ch c t nilon 6,6. C. Cng thc ca Y l HOOC[CH2]4COOH D. Tn gi ca X l etyl propyl aipat. Cu 43: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. HCOOH v HCOOCH3 B. HCOOH v HCOO C2H5 C. C2H5COOH v C2H5COOCH3 D. CH3COOH v CH3COOC2H5 Cu 44: t chy ht 5,4 gam cht hu c A, ch thu c CO2 v H2O. Cho hp thu ht sn phm chy vo bnh ng nc vi trong d, khi lng bnh tng 19 gam. Trong bnh c 35 gam kt ta. Hi A nh hn hi cumen (isopropylbenzen). Nu A l mt hp cht thm v tc dng c dung dch kim th cng thc phn t tm c ca A c th ng vi bao nhiu cht? A. Hai cht B. Ba cht C. Bn cht D. Nm cht Cu 45: X l mt dn xut ca benzen c cng thc phn t C7H9NO2. Cho 1 mol X tc dng va vi NaOH, c cn dung dch thu c mt mui khan c khi lng l 144 gam. Cng thc cu to thu gn ca X l A. C6H5COONH4. B. HCOOH3NC6H5. C. HCOOC6H4NO2. D. HCOOC6H4NH2. Cu 46: Cho s sau:
Cl Cl NaOH H 2 O(t , e ol( ) e ol( ) (CH3)2CH-CH2CH2Cl KOH/tant A H B KOH/tant C H D ) E E c cng thc cu to l A. (CH3)2C(OH)-CH2CH3. B. (CH3)2CH-CH(OH)CH3. C. (CH3)2C=CHCH3. D. (CH3)2CH-CH2CH2OH Cu 47: t chy hon ton hn hp A gm 2 ankin X, Y. Hp th ton b sn phm chy vo 4,5 lt dung dch Ca(OH)2 0,02M thu c kt ta v khi lng dung dch tng 3,78 gam. Cho dung dch Ba(OH)2 va vo dung dch thu thm kt ta. Tng khi lng kt ta 2 ln l 18,85 gam. Bit rng s mol X bng 60% tng s mol ca X v Y c trong hn hp A . Cc phn ng xy ra hon ton. Cng thc ca X, Y ln lt l A. C3H4 v C4H6. B. C2H2 v C4H6. C. C2H2 v C3H4. D. C4H6 v C2H2. Cu 48: Xt cc cht sau: xiclopropan, stiren, cumen, toluen, benzen, phenol, alanin, naphtalen, fructoz, axetanehit, axeton, glyxeryl stearopanmitooleat. S cht lm mt mu dung dch Br2 l: A. 7 B. 4 C. 6 D. 5 Cu 49: Cho hp cht hu c n chc X c cng thc l C 3H10O3N2. Cho m gam X tc dng vi NaOH va thu c 2,55 gam mui v c. Gi tr ca m l: A. 3,705 gam B. 3,66 gam C. 3,795 gam D. 3,84 gam Cu 50: Khi cho 13,8 gam glixerol (X) tc dng vi axit fomic th thu c hp cht hu c (Y) c khi lng bng 1,18 ln khi lng cht (X) ban u. Bit hiu sut ca phn ng l 73,35 %. Vy tng s nguyn t c trong (Y) l: A. 16 B. 14 C. 18 D. 20
0 0 0

Trang 8/8 CHUN