TRNG THPT CHUYN H LONG ------------------

THI TH I HC LN 3 NM HC 2011 - 2012 MN: HA HC Thi gian lm bi: 90 pht (50 cu trc nghim)

H, tn th sinh:.......................................................................... S bo danh:............................................................................... I. PHN CHUNG CHO TT C TH SINH (40 cu , t cu 1 n cu 40) Cu 1 : Hp cht E to t ion Xn+ v Y-. C Xn+, Y- u c cu hnh e l 1s2 2s2 2p6. So snh bn knh ca X, Y, Xn+ v Y- ? A. Xn+ < Y < Y- < X. B. Xn+ < Y < X < YCu 2 :C cc nhn nh sau: a, Cu hnh electron ca ion X2+ l 1s22s22p63s23p63d6. Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc chu k 4, nhm VIIIB. b, Cc ion v nguyn t: Ne , Na+ , F c bn knh tng dn. c, Phn t CO2 co lin kt cng hoa tri, phn t phn cc. d, Dy gm cc nguyn t c sp xp theo chiu tng dn bn knh nguyn t t tri sang phi l K, Mg, Si, N. e, Tnh baz ca dy cc hiroxit: NaOH, Mg(OH)2, Al(OH)3 gim dn. Cho: N (Z = 7), F (Z=9), Ne (Z=10), Na (Z=11), Mg (Z=12), Al (Z=13), K (Z = 19), Si (Z = 14). Nhng nhn nh ng l: A. b, c, e B. a, c, d, e C. a, c, e D. a, e Cu 3:Cn bng ca mt phn ng ho hc t c khi : A. nng phn t ca cc cht tham gia phn ng v sn phm phn ng bng nhau trong cng mt iu kin. B. phn ng dng li. C. nhit ca phn ng thun v nghch bng nhau D. vn tc ca phn ng thun v nghch bng nhau trong cng mt iu kin. Cu 4 :Cho phng trnh phn ng:
t FeS2 + Cu2S + HNO3 Fe2(SO4)3 + CuSO4 + NO + H2O Tng cc h s ca phng trnh vi cc s nguyn ti gin l: A. 100 B. 108 C. 118
2
0

D. 150

Cu 5:Dung dch X cha 0,025 mol CO 3 ; 0,1 mol Na+; 0,3 mol Cl-, cn li l ion NH + . Cho 270 ml dung dch 4 Ba(OH)2 0,2 M vo dung dch X v un nng nh. Hi tng khi lng dung dch X v dung dch Ba(OH) 2 gim bao nhiu gam? Gi s nc bay hi khng ng k. A. 4,215 gam. B. 6,761 gam. C. 5,269 gam. D. 7,015 gam. Cu 6: Dung dch HX ( X: l halogen) c tnh kh tng dn theo th t no sau y? A. HF < HBr < HCl < HI B. HI < HBr < HCl < HF C. HF < HCl < HBr < HI D. HBr < HF < HI < HCl Cu 7: C th iu ch oxi bng cch phn hy KMnO4, KClO3, H2O2. Nu ly cng mt khi lng mi cht trn em phn hy hon ton th th tch oxi thu c t: A. KMnO4 ln nht B. KClO3 l ln nht C. H2O2 ln nht D. H2O2 nh nht Cu 8
a lit H2 O2 Cho s : Photpho (a gam) + du, t X +O dd Y + dd N aOH 0,1M Z dd Cht tan trong dung dich Z gm: A. NaH2PO4 va H3PO4. B. Na3PO4 va NaHPO4. C. Na3PO4 va NaOH. D. Na2HPO4 va NaH2PO4. Cu 9 Mc ni tip hai bnh in phn cha ln lt hai dung dch NaCl(bnh 1) v AgNO3(bnh 2). Sau mt thi gian in phn th thu c catot ca bnh 1 l 2,24lit kh (ktc). Khi lng bc bm trn catot ca bnh 2 v th tch kh thot ra anot bnh 2 l : A. 10,8g; 0,56(l). B. 21,6g; 0,28(l). C. 21,6g; 1,12(l) D. 43,2g; 1,12(l).
0

Cu 10 Phn ng no di y khng ng? Bit gi tr th in cc chun:

Mg 2+
o

Mg

Fe 2+

Fe

Cu 2+

Cu

Fe3+

Fe

2+

Ag +

Ag

E (V) -2,37 -0,44 +0,34 +0,77 +0,80 3+ 2+ 2+ + 3+ A. Mg (d) + 2Fe Mg + 2Fe B. Fe + 3Ag (d) Fe + 3Ag 3+ 2+ C. Fe + 2Fe 3Fe D. Cu + 2Fe3+ Cu2+ + 2Fe2+ Cu 11 X l dung dch AlCl3, Y l dung dch NaOH 2 M. Thm 150 ml dung dch Y vo cc cha 100ml dung dch X, khuy u n phn ng hon ton thy trong cc c 7,8 gam kt ta. Thm tip vo cc 100 ml dung dch Y, khuy u n phn ng hon ton thy trong cc c 10,92 gam kt ta. Nng mol/l ca dung dch X bng A. 2,0 M. B. 3,2 M. C. 1,6 M. D. 1,0 M. Cu 12 Ho tan mt ming Al vo dung dch cha 0,05 mol NaOH ,thy c 0,672 (ktc) H2 bay ln v cn li dung dch A .Cho vo dung dch A dung dch cha 0,065mol HCl th lng kt ta sinh ra l: A. 1,56g B. 2,34g C. 1,17g D. 0,78g Cu 13 Cho a mol CO hp th ht vo dung dch cha b mol NaOH thu c dung dch A . Cho BaCl d vo dung dch A 2 2 m ). T s T = b/a c gi thu c m(g) kt ta. Nu cho Ba(OH) d vo dung dch A thu c m (g) kt ta ( m 2 1 1 tr ng l? A. T 2 B. 0<T<1 C. T>0 D. 1<T<2 Cu 14 C cc pht biu sau: (1) Tt c cc kim loi kim th u tan v hn trong nc (2) Cc kim loi kim c th y cc kim loi yu hn ra khi dung dch mui. (3) Na+, Mg2+, Al3+ c cng cu hnh electron v u c tnh oxi ho yu. (4) Kim loi kim c dng nhiu trong tng hp hu c. (5) Cho dung dch NaOH d vo dung dch AlCl3, sau phn ng thu c dung dch trong sut. Nhng pht biu ng l: A. (3), (4), (5) B. (3), (5) C. (1), (2), (5) D. (1), (3), (4) Cu 15 Cho hn hp gm Al, BaO v Na2CO3 (c cng s mol) vo nc d thu c dung dch X v cht kt ta Y. Cht tan trong dung dch X l: A. Ba(AlO2)2 v Ba(OH)2. B. NaAlO2. C. NaOH v NaAlO2. D. NaOH v Ba(OH)2. Cu 16 Dung dch X gm (KI v mt t h tinh bt ). Cho ln lt tng cht sau: O2, O3, Cl2, H2O2, FeCl3 tc dng vi dung dch X. S cht lm dung dch X chuyn mu xanh tm l : A. 4 B. 5. C. 3. D.2. Cu 17 Sc kh H2S cho ti d vo 100 ml dung dch hn hp gm FeCl3 0,2M v CuCl2 0,2M; phn ng xong thu c a gam kt ta. Gi tr ca a l: A. 3,68 gam. B. 4 gam. C. 2,24 gam. D. 1,92 gam. Cu 18 Trong cc th nghim sau, s th nghim to ra n cht l: (a) Cho kh O3 tc dng vi dung dch KI. (b) Nhit phn amoni nitrit. (c) Cho NaClO tc dng vi dung dch HCl c. (d) Cho kh H2S tc dng vi dung dch FeCl3. (e) Cho kh NH3 d tc dng vi kh Cl2. (g) Cho dung dch H2O2 tc dng vi dung dch cha KMnO4 v H2SO4 (long). (h) Sc kh O2 vo dung dch HBr. (i) Cho NaI tc dng vi dung dch axit H2SO4 c, nng. (k) Cho SiO2 tc dng vi Na2CO3 nng chy. (m) Cho amin bc I tc dng vi hn hp NaNO2 v HCl iu kin thng.

A. 7 B. 8 C.9 D. 6 Cu 19 Thc hin cc th nghim sau: (a) un nng hn hp bt Fe v I2. (b) Cho Fe vo dung dch HCl. (c) Cho Fe(OH)2 d vo dung dch HNO3 long. (d) t dy st trong hi brom. (e) Cho Fe3O4 vo dung dch H2SO4 long, d. S th nghim c to ra mui st (II) l: A. b, c B. b, e C. a, b, d, e D. a, b, e Cu 20 Nhit phn hon ton 44,1 gam hn hp X gm AgNO3 v KNO3 thu c hn hp kh Y. Trn Y vi a mol NO2 ri cho ton b vo nc ch thu c 6 lt dung dch (cha mt cht tan duy nht) c pH = 1. Gi tr ca a l: A. 0,5. B. 0,2. C. 0,3. D. 0,4. Cu 21 Cho t t tng git ca dung dch cha b mol HCl vo dung dch cha a mol Na2CO3 thu c V lt kh CO2. Ngc li, cho t t tng git ca dung dch cha a mol Na2CO3 vo dung dch cha b mol HCl thu c 2V lt kh CO2 (cc th tch kh o cng iu kin). Mi quan h gia a v b l: A. a = 0,75b. B. a = 0,8b. C. a = 0,35b. D. a = 0,5b. Cu 22 Nhm cht kh u c kh nng lm mt mu nc Br2 l: A. etilen, axetilen, cacbon ioxit. B. etilen, axetilen, lu hunh ioxit. C. etilen, etan, lu hunh ioxit. D. etilen, axetilen, etan. Cu 23 Mt hn hp gm ankaien X v O2 ly d (O2 chim 90% th tch) c np y vo mt bnh kn p sut 2 atm. Bt tia la in t chy ht X ri a bnh v nhit ban u cho hi nc ngng t ht th p sut gim 0,5 atm. Cng thc phn t ca X l A. C4H6. B. C5H8. C. C3H4. D. C6H10. Cu 24 t chy hon ton m gam hn hp X gm 2 ancol n chc trong cng dy ng ng thu c 3,52 gam CO 2 v 1,98 gam H2O. Gi tr ca m l: A. 0,83 gam B. 1,245 gam C. 1,66 gam D. 0,161 gam Cu 25 un nng sec-butylbromua vi dung dch NaOH thu c sn phm chnh l: A. Butan-1-ol B. Butan-2-ol C. But-2-en D. But-1-en Cu 26 t chy hon ton 54 gam hn hp X gm axit fomic, axit axetic, axit acrylic, axit oxalic v axit aipic thu c 39,2 lt CO2 (ktc) v m gam H2O. Mt khc, khi cho 54 gam hn hp X phn ng hon ton vi dung dch NaHCO3 d, thu c 21,28 lt CO2 (ktc). Gi tr ca m l: A. 46,8gam. B. 43,2 gam. C. 23,4 gam. D. 21,6 gam. Cu 27 Ch ra pht biu ng : A. Gia hai phn t axit cacboxylic c th c hai lin kt hiro, lin kt hiro ca axit km bn hn ca ancol. B.Gia 2 phn t axit cacboxylic c th c 2 lin kt hiro, lin kt hiro ca axit bn hn ca ancol. C. Gia 2 phn t axit cacboxylic ch c 1 lin kt hiro, lin kt hiro ca axit km bn hn ca ancol. D. Gia 2 phn t axit cacboxylic ch c 1 lin kt hiro, lin kt hiro ca axit bn hn ca ancol. Cu 28 Cho dy cc cht: benzyl axetat, vinyl axetat, metyl fomat, anlyl clorua, phenyl fomat, isopropyl clorua, triolein. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l: A. 4 B. 6 C. 5 D. 3 Cu 29 Cho 15,84 gam este no, n chc, mch h tc dng va vi 30ml dung dch MOH 20% (d=1,2g/ml) vi M l kim loi kim. Sau phn ng hon ton, c cn dung dch thu c cht rn X. t chy hon ton X thu c hn hp kh v hi gm CO2, H2O v 9,54 gam M2CO3. Kim loi M v cng thc cu to ca este ban u l : A. Na v HCOO-C2H5. B. Na v CH3COOC2H5. C. K v HCOO-CH3. D. K v CH3COOCH3. Cu 30

Cho 0.1 mol cht X ( CH6O3N2) tc dng vi dd cha 0.2 mol NaOH un nng thu c cht kh lm xanh giy qu tm m v dd Y. C cn dd Y thu c m gam rn khan. Gi tr ca m l: A. 8,5 gam. B. 12,5 gam. C. 15 gam. D. 21,8 gam. Cu 31 Cht X c cng thc phn th C8H15O4N. X tc dng vi NaOH to Y, C2H6O v CH4O. Y l mui natri ca -amino axit Z mch h khng phn nhnh. S cng thc cu to ca X tha mn yu cu ca l: A. 2 B. 1 C. 3 D. 4 Cu 32 Thy phn hon ton mt tripeptit thu c hn hp gm alanin v glyxin theo t l mol l 2: 1. Hy cho bit c bao nhiu tripeptit tha mn? A. 1 B. 3 C. 2 D. 4 Cu 33 Thy phn hon ton m gam hn hp X gm saccaroz v mantoz thu c dung dch Y. Cho Y tc dng vi lng d dung dch AgNO3 trong NH3 thu c 0,2 mol Ag. Mt khc, thy phn m gam hn hp X mt thi gian (hiu sut thy phn mi cht u l 80%) thu c dung dch Z. Cho Z tc dng vi lng d dung dch AgNO3 trong NH3 thu c 0,168 mol Ag. Thnh phn %v khi lng ca saccaroz trong hn hp l: A. 60%. B. 55%. C. 40%. D. 45%. Cu 34 Khi lng phn t ca nilon-6,6 l 24860 vc v ca capron l 14690 vc.H s polime ha hay polime ha ca mi loi polime trn ln lt l : A. 110 v 130 B. 120 v 140 C. 110 v 120 D. 120 v 130 Cu 35 Khi cho a (mol) mt hp cht X c cha C, H, O phn ng hon ton vi Na hoc NaHCO 3 u sinh ra a(mol) kh. Cht X c th l : A.Axit picric B.Axit 3-hioxipropanoic C.Axit acrylic D.Axit aipic Cu 36 Trong cc nhn xt sau y, nhn xt no khng ng ? A. Tt c cc xeton no, n chc, mch h u c ng phn thuc chc anehit v ancol B. Tt c cc anehit no, n chc, mch h u c ng phn thuc chc xeton v ancol C. Tt c cc ancol n chc, mch vng no u c ng phn thuc chc anehit v xeton D. Tt c cc ancol n chc, mch h, c 1 lin kt i u c ng phn thuc chc anehit v xeton Cu 37 Cho cc pht biu sau: (a) C th dng nc brom phn bit saccaroz v mantoz. (b) C th phn bit saccaroz v mantoz bng phn ng vi dung dch AgNO3 trong NH3. (c) Trong dung dch, saccaroz v mantoz u ha tan Cu(OH)2 nhit thng cho dung dch mu xanh lam. (d) Trong dung dch, saccaroz tn ti ch yu dng mch h. (e) Trong mi trng baz, saccaroz v mantoz c th chuyn ha ln nhau. (g) Trong phn t saccaroz c nhm -OH hemiaxetal. S pht biu ng l: A. 4. B. 3. C. 5. D. 6. Cu 38 Cho cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoni clorua, ancol benzylic, p-crezol v cumen. Trong cc cht ny, s cht c th tc dng c vi dung dch NaOH l: A. 6 B. 5 C. 4 D. 7 Cu 39 phn bit cc ng phn n chc ca C3H6O2 cn dng: A. qu tm, dung dch NaOH. B. qu tm, dung dch AgNO3/NH3. C. dung dch AgNO3/NH3. D. qu tm. Cu 40 Cho 20,3 gam Gly- Ala- Gly tc dng vi 500ml dung dch KOH 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l: A. 48,3. B. 11,2. C. 35,3. D. 46,5. II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (Phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41:

 Cho phn ng sau: 2SO2(k) + O2(k) 2SO3(k) ; H < 0 cn bng trn chuyn dch theo chiu thun th: (1): tng nhit , (2): tng p sut, (3): h nhit , (4): dng xc tc l V2O5, (5): gim nng SO3. Bin php ng l: A. 1, 2, 3, 4, 5. B. 2, 3, 5. C. 1, 2, 5. D. 2, 3, 4, 5. Cu 42 Hn hp X gm mt anehit n chc, mch h v mt ankin (phn t ankin c cng s nguyn t H nhng t hn mt nguyn t C so vi phn t anehit). t chy hon ton 1 mol hn hp X thu c 2,4 mol CO2 v 1 mol nc. Nu cho 1 mol hn hp X tc dng vi dd AgNO3/NH3 th khi lng kt ta thu c ti a l: A. 230,4 gam. B. 301,2 gam. C. 308 gam. D. 144 gam. Cu 43 Cho 0,25 mol mt anehit mch h X phn ng vi lng d AgNO3/ NH3 thu c 54 gam Ag. Mt khc, khi cho X tc dng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,375 mol H2. Cht X c cng thc chung l: A. CnH2n-3CHO (n 2). B. CnH2n-1CHO (n 2). C. CnH2n(CHO)2 (n 0). D. CnH2n+1CHO (n 0). Cu 44 Cho cc nguyn t v ion sau: Cr, Fe2+, Mn, Mn2+, Fe3+ (cho ZCr = 24, ZMn= 25, ZFe = 26 ). Nguyn t v ion c cng s electron c thn l: A. Cr v Mn B. Mn, Mn2+ v Fe3+ C. Mn2+, Cr, Fe3+ D. Cr v Fe2+ Cu 45 Cho dung dch KOH d vo dung dch FeCl2 thu c 13,5 g kt ta. Nu thay dung dch KOH bng dung dch AgNO3 d th thu c bao nhiu g kt ta ? A. 43,05 g B. 59,25 g C. 53,85 g D. 48,45 g. Cu 46 Ha tan 25 g CuSO4.5H2O vo nc ct c 500ml dd A. nh gi gn ng pH v nng mol ca dd A l: A. pH=7, [CuSO4] = 0,2M. B. pH>7, [CuSO4] = 0,3125M. C. pH<7, [CuSO4] = 0,2M. D. pH>7, [CuSO4] = 0,2M. Cu 47 nhn bit ion Ba2+ khng dng ion: A. SO42-. B. S2-. C. CrO42-. D. Cr2O72-. Cu 48 Cho phn ng sau( c un nng): o-C6H4(CH2Cl)Cl + NaOH long d sn phm hu c X + NaCl. X l cht no sau y? A. o-C6H4(CH2OH)(ONa) B. o-C6H4(CH2OH)(Cl) C. o-C6H4(CH2ONa)(ONa) D. o-C6H4(CH2OH)(OH) Cu 49 iu ch axit picric (2,4,6trinitrophenol) ngi ta i t 4,7gam phenol v dng mt lng HNO3 ln hn 50% so vi lng HNO3 cn thit. S mol HNO3 dng v khi lng axit picric thu c ln lt l(cc phn ng xy ra hon ton): A. 0,225 mol v 13,85g B. 0,15 mol v 9,16 g C. 0,2 mol v 11,45g D. 0,225 mol v 11,45g Cu 50 Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng nhau l: A. Gly, Ala, Glu, Tyr B. Gly, Val, Lys, Ala C. Gly, Ala, Glu, Lys D. Gly, Val, Tyr, Ala. B. Theo chng trnh Nng cao (t cu 51 n cu 60)
Cu 51 Cho phn ng ha hc : CO (k) + Cl2 (k) COCl2 (k) Bit rng nhit T, nng cn bng ca CO l 0,2M v ca Cl2 l 0,3M v hng s cn bng l 4. Nng cn bng cua cht to thnh (COCl2) nhit T ca phn ng c gi tr no di y ? A. 0,015M B. 0,24M C. 0,5M D. 0,3M Cu 52 H Cho s : Etilen + O 2 , to X1 HCN X2 H 2O / X3 H X4 / PdCl 2 CuCl 2, + 2O X4 l 1 axit cacboxylic n chc. Vy CTCT ca X4 l: A. CH3CH2COOH B. CH3COOH C. CH2=CHCOOH D. CH3CH=CHCOOH

Cu 53 Cho cc cht axetilen, vinyl axetilen, phenyl axetilen, anehit fomic, axit fomic, glucozo, natri fomat. S cht kh c ion Ag+ trong dung dch AgNO3/ NH3 l: A. 5. B. 4. C. 7. D. 6. Cu 54 Khi in phn dung dch CuSO4 (cc dng lm bng ng, cc m lm bng than ch) th A. cc m xy ra qu trnh oxi ha ion Cu2+ v cc dng xy ra qu trnh kh H2O. B. cc m xy ra qu trnh kh ion Cu2+ v cc dng xy ra qu trnh oxi ha Cu. C. cc m xy ra qu trnh kh ion Cu2+ v cc dng xy ra qu trnh oxi ha H2O. D. cc m xy ra qu trnh oxi ha ion Cu2+ v cc dng xy ra qu trnh kh Cu. Cu 55 Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s mol NO (duy nht) to thnh ln lt l: A. 0,03 v 0,02. B. 0,06 v 0,01. C. 0,03 v 0,01. D. 0,06 v 0,02. Cu 56 Cho 19.2 gam Cu vo 500 ml dd NaNO3 1M, sau thm tip 500ml dd HCl 2M n khi phn ng xy ra hon ton thu c dd X v sn phm kh l NO duy nht. Phi thm bao nhiu ml dd NaOH 1M vo X kt ta ht ion Cu2+? A. 120 B. 400 C. 600 D. 800 Cu 57 Ion icromat Cr2O72- trong mi trng axit oxi ha c mui Fe2+ thnh Fe3+ cn icromat b kh to mui Cr3+. Cho bit 10 ml dd FeSO4 phn ng va vi 12 ml dd K2Cr2O7 0,1M, trong mi trng c d H2SO4. Nng mol/l ca dd FeSO4 l: A. 0,52M. B. 0,62M. C. 0,72M. D. 0, 82M. Cu 58 Cho s sau: xenluloz X1 X2 X3 polime X. Bit rng X ch cha 2 nguyn t. S cht ng vi X3 l: A. 2 B. 1 C. 3 D. 4 Cu 59 Cho 36,5 gam hn hp X gm hiroquinon, catechol v axit axetic tc dng vi kali (d) thu c 7,28 lt (ktc) kh H2. Thnh phn phn trm v khi lng ca axit axetic trong hn hp X l: A. 32,877%. B. 41,096%. C. 14,438%. D. 24,658%. Cu 60. X l este ca glyxin. Cho m gam X tc dng vi dung dch NaOH d, hi ancol bay ra i qua ng ng CuO un nng. Cho sn phm thc hin phn ng trng gng thy c 8,64 gam Ag. Bit phn t khi ca X l 89. Gi tr ca m l: A. 3,56. B. 2,67. C. 1,78. D. 2,225.