S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII

TRNG THPT BN TRE NM HC 2005 - 2006

THI NGH MN HA Khi 10
Thi gian: 180 pht
Cu 1.
Hp cht Z c to bi hai nguyn t M, R c cng thc M
a
R
b
trong R chim
6,667% v khi lng. Trong ht nhn nguyn t M c n = p + 4, cn trong ht nhn ca R
c p=n, trong n, p, n, p l s ntron v proton tng ng ca M v R
Bit rng tng s ht proton trong phn t Z = 84 v a + b = 4
Tm cng thc phn t ca Z
Cu 2. (L thuyt phn ng v ha hc)
a. Xc nh bc phn ng v hng s tc phn ng pha kh (300
0
k) ca phn ng:
A(k) + B(k) C(k)
Da trn kt qu thc nghim sau y:
Th nghim [A] mol/l [B] mol/l Tc mol.l
-1
.s
-1
1 0,010 0,010 1,2.10
-4
2 0,010 0,020 2,4.10
-4
3 0,020 0,020 9,6.10
-4
b. Ngi ta trn CO v hi H
2
O ti nhit 1000k vi t l 1 : 1. Tnh thnh phn ca h
lc cn bng, bit rng:
2 2 2
2H O 2H O +
c pk
p,1
= 20,113
2 2
2CO 2CO O +
c pk
p,2
= 20,400
c. Cho cc d kin di y:
2 4 2 2 6 a
2 6 2 2 2 b
2 2 c
2 2 2 d
C H H C H H 136, 951 KJ / mol
7
C H O 2CO 3H O(l) H 1559,837 KJ / mol
2
C O CO H 393, 514 KJ / mol
1
H O H O(l) H 285,838 KJ / mol
2
+
+ +
+
+
Hy xc nh: Nhit hnh thnh v nhit t chy ca etylen C
2
H
4

Cu 3 (cn bng trong cc h axit baz, d th v to phc)
a. tan ca BaSO
4
trong dung dch HCl 2M bng 1,5.10
-4
M. Tnh tch s tan ca
BaSO
4
ri suy ra tan ca BaSO
4
trong nc nguyn cht v trong dung dch
Na
2
SO
4
0,001M.
Cho bit pka i vi nc phn li th hai ca H
2
SO
4
l 2
b. C th ha tan 0,01 mol AgCl trong 100ml dung dch NH
3
1M hay khng? Bit
T
AgCl
=1,8.10
-10
, K
bn
ca phc [Ag(NH
3
)
2
]
+
l 1,8.10
8
.
c. Tnh pH ca dung dch thu c trong cc hn hp sau:
10ml dung dch axit axtic (CH
3
COOH) 0,10M trn vi 10ml dung dch HCl
c pH = 4,0
25ml dung dch axit axtic c pH = 3,0 trn vi 15ml dung dch KOH c pH
= 11,0
10ml dung dch axit axtic c pH = 3,0 trn vi 10ml dung dch axit fomic
(HCOOH) c pH = 3,0.
Bit pKa ca CH
3
COOH v HCOOH ln lt l 4,76 v 3,75
1
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
THI NGH MN HA Khi 10
Thi gian: 180 pht
Cu 4:
A. Phn ng oxi ha kh:
1. iu khng nh sau y c ng khng? Mt cht c tnh oxi ha gp mt cht c tnh
kh nht thit phi xy ra phn ng oxi ha kh. Gii thch.
2. Hon thnh cc phng trnh phn ng sau y di dng phn t v dng ion:
a.
2
4 6 12 6 2
MnO C H O H Mn CO ...
+ +
+ + + +
b.
2
x y 4 2
Fe O H SO SO ...
+
+ + +
B. in ha hc
1. Nu mun thc hin cc qu trnh sau y:
a.
2 4
Sn Sn
+ +
b.
2
Cu Cu
+ +
c.
2
4
Mn MnO
+

d.
2 3
Fe Fe
+ +

Chng ta c th dng nc brom c khng? Bit:

3 2
0
Fe / Fe
E 0, 77v
+ +
+
; 2
0
CU / Cu
E 0, 34v
+
+
;
2
4
0
MnO / Mn
E 1, 51v
+
+
4 2
0
Sn / Sn
E 0,15v
+ +
+
;
2
0
Br / 2Br
E 1, 07v

+
Vit phng trnh phn ng nu xy ra v tnh hng s cn bng ca phn ng xy ra.
2. Ngi ta lp 1 pin gm 2 na pin sau:
3 2
( NO )
Zn / Zn (0,1M)
v
3
NO
Ag / Ag (0,1M)
c th chun tng ng bng -0,76v v 0,80v
a. Thit lp s pin v cc du 2 in cc
b. Vit phng trnh phn ng khi pin lm vic
c. Tnh E ca pin
d. Tnh cc nng khi pin khng c kh nng pht in (pin dng ht)
Cu 5:
1. Mt khang vt X gm 2 nguyn t: A (kim loi) v B (phi kim)
- Khi t X c cht rn Y (A
2
O
3
) v kh Z (BO
2
) trong phn trm khi lng ca
A trong Y l 70% v ca B trong Z l 50%
- Y tc dng va vi 1,8 (g) H
2
nhit cao.
- Z tc dng va vi 117,6(g) K
2
Cr
2
O
7
trong mi trng H
2
SO
4
d cho mui Cr
3+

Xc nh tn khang vt X v khi lng X t
2. T mui n, vi v nc, vit cc phng trnh phn ng iu ch nc Javel v
clorua vi.
2
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
P N MN HA Khi 10
Thi gian: 180 pht
Cu 1.
Hp cht Z c to bi hai nguyn t M, R c cng thc M
a
R
b
trong R chim
6,667% v khi lng. Trong ht nhn nguyn t M c n = p + 4, cn trong ht nhn ca R
c p=n, trong n, p, n, p l s ntron v proton tng ng ca M v R
Bit rng tng s ht proton trong phn t Z = 84 v a + b = 4
Tm cng thc phn t ca Z
P N
S khi ca nguyn t M: p + n = 2p + 4
S khi ca nguyn t R: p + n = 2p
% khi lng R trong M
a
R
b
=
2p' b 6, 667 1
a(2p 4) 2p' b 100 15

+ +
p' b 1
ap p' b 2a 15

+ +
(1)
Tng s ht proton trong M
a
R
b
= ap + bp = 84 (2)
a + b = 4 (3)
(1), (2)
p' b 1
84 2a 15

+

1176
2
15p' b 84 2a
a
p
(2) p' b ap 15

+

;


(3) 1 a 3
a 1 2 3
p 78,26 39,07 26
Fe
a = 3 b = 1 p = 6: cacbon
Vy CTPT Z l Fe
3
C
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
3
P N MN HA Khi 10
Thi gian: 180 pht
Cu 2. (L thuyt phn ng v ha hc)
a. Xc nh bc phn ng v hng s tc phn ng pha kh (300
0
k) ca phn ng:
A(k) + B(k) C(k)
Da trn kt qu thc nghim sau y:
Th nghim [A] mol/l [B] mol/l Tc mol.l
-1
.s
-1
1 0,010 0,010 1,2.10
-4
2 0,010 0,020 2,4.10
-4
3 0,020 0,020 9,6.10
-4
b. Ngi ta trn CO v hi H
2
O ti nhit 1000k vi t l 1 : 1. Tnh thnh phn ca h
lc cn bng, bit rng:
2 2 2
2H O 2H O +
c pk
p,1
= 20,113
2 2
2CO 2CO O +
c pk
p,2
= 20,400
c. Cho cc d kin di y:
2 4 2 2 6 a
2 6 2 2 2 b
2 2 c
2 2 2 d
C H H C H H 136, 951 KJ / mol
7
C H O 2CO 3H O(l) H 1559,837 KJ / mol
2
C O CO H 393, 514 KJ / mol
1
H O H O(l) H 285,838 KJ / mol
2
+
+ +
+
+
Hy xc nh: Nhit hnh thnh v nhit t chy ca etylen C
2
H
4

P N
a. v = k[A]
x
[B]
y

Th nghim 1 1,2.10
-4
= k.0,01
x
. 0,01
y
(1)
Th nghim 2 2,4.10
-4
= k.0,01
x
. 0,02
y
(2)
Th nghim 3 9,6.10
-4
= k.0,02
x
. 0,02
y
(3)
Ly (3) chia cho (2) 2
x
= 4 x = 2
Ly (2) chia cho (1) 2
y
= 2 y = 1
[ ] [ ]
2
v k A B
Bc phn ng: x + y = 3
Th nghim 1 1,2.10
-4
= k.0,01
2
. 0,01
k = 1,20.10
2
mol
-2
. l
-2
.s
-1
(1)
b. T cc d kin bi ta c:
2 2 P,3
P,2
2 2 2 P,4 P,1
1 1
CO O CO K
2 K
1
H O H O K K
2
+
+
20,113
P,1 0,1435
2 2 2 P P,3 P,4
20,400
P,2
K
10
CO H O CO H K K .K 10 1, 392
K 10

+ +
(1)
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
P N MN HA Khi 10
4
Thi gian: 180 pht
Gi s ban u ly 1 mol CO v 1 mol H
2
O
2 2 2 P
CO H O CO H K 1, 392 + +
Ban u 1mol 1mol
Lc cu bng 1-a(mol) (1-a)mol a mol a mol
2 2
2
2
CO H
P
2
CO H O
a a
P. P
P .P
a
2 2
K
1 a 1 a
P .P (1 a)
P. P
2 2



vi P l p sut chung
P
a
K 1,1798
1 a

a 0, 54mol
2 2
a x 100%
%H %CO 27%
2

2
(1 a)x100%
%CO %H O 23%
2

(1)
c. T cc d kin bi ta c:
2 6 2 4 2 1 a
2 2 2 6 2 2 b
2 2 3 C
2 2 2 4 d
C H C H H H H 136, 951 KJ / mol
7
2CO 3H O(l) C H O H H 1559,837 KJ / mol
2
2C 2O 2CO H 2 H 787, 028 KJ / mol
3
3H O 3H O(l) H 3 H 857, 514 KJ / mol
2
+ +

+ + +

+
'
+

2C + 2H
2
C
2
H
4
H
ht
= H
1
+ H
2
+ H
3
+ H
4
= +52,246 KJ/mol (0,5)
( )
2 4 2 5 ht
2 2 3
2 2 2 6 d
C H 2C 2H H H 52, 246KJ / mol
2C 2O 2CO H 787, 028KJ / mol
2H O 2H O l H 2 H 571, 676KJ / mol
+

+ +
'

C
2
H
4
+ 3O
2
2CO
2
+ 2 H
2
O(l) H
c
= H
5
+ H
3
+ H
6
= -1410,95 KJ/mol (0,5)
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
P N MN HA Khi 10
Thi gian: 180 pht
5
Cu 3 (cn bng trong cc h axit baz, d th v to phc)
d. tan ca BaSO
4
trong dung dch HCl 2M bng 1,5.10
-4
M. Tnh tch s tan ca
BaSO
4
ri suy ra tan ca BaSO
4
trong nc nguyn cht v trong dung dch
Na
2
SO
4
0,001M.
Cho bit pka i vi nc phn li th hai ca H
2
SO
4
l 2
e. C th ha tan 0,01 mol AgCl trong 100ml dung dch NH
3
1M hay khng? Bit
T
AgCl
=1,8.10
-10
, K
bn
ca phc [Ag(NH
3
)
2
]
+
l 1,8.10
8
.
f. Tnh pH ca dung dch thu c trong cc hn hp sau:
10ml dung dch axit axtic (CH
3
COOH) 0,10M trn vi 10ml dung dch HCl
c pH = 4,0
25ml dung dch axit axtic c pH = 3,0 trn vi 15ml dung dch KOH c pH
= 11,0
10ml dung dch axit axtic c pH = 3,0 trn vi 10ml dung dch axit fomic
(HCOOH) c pH = 3,0.
Bit pKa ca CH
3
COOH v HCOOH ln lt l 4,76 v 3,75
P N
a.
4
2 2
4 4 BaSO
BaSO Ba SO T ?
+
+
( )
1
2 1 2 2
4 4 1 a2
SO H HSO K K 10 10

+
+
4 4
2 2
4 4 1 BaSO BaSO
BaSO H Ba HSO K K .T 10 .T
+ +
+ +
Ban u 2M
Cn bng 2-S(M) S S
Vi S = 1,5.10
-4
M
Ta c: S
2
/ (2-S) = 10
2

4
BaSO
T
( )
( )
4
2
4
2
10
BaSO
2
2 4
1, 5.10
S
T 1,125.10
10 (2 S)
10 2 1, 5.10

(0,5)
4
2 2 10
4 4 BaSO
BaSO Ba SO T 1,125.10
+
+
Cn bng S S
2 10 10 5
S' 1,125.10 S' 1,125.10 1, 061.10 M

(0,5)
2
2 4 4
Na SO 2Na SO
+
+
0,001M 0,001M
4
2 2 10
4 4 BaSO
BaSO Ba SO T 1,125.10
+
+
Ban u 0,001M
Cn bng S S+0,001
S(S+0,001)=1,125.10
-10

S
2
+ 0,001S=1,125.10
-10
S
2
+ 0,001S 1,125.10
-10
= 0
S = 1,125.10
-7
M (nhn)
S = -10
-3
M (loi) (0,5)
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
P N MN HA Khi 10
Thi gian: 180 pht
6
b.
10
AgCl
AgCl Ag Cl T 1,8.10
+
+
( )
3 3
2
Ag 2NH Ag NH
+
+
+ K
bn
= 1,8.10
8

( )
3 3
2
AgCl 2NH Ag NH Cl
+

+ + K=T
AgCl
.K
bn
= 3,24.10
-2
(0,5)
Ban u 1M
Cn bng 1-2x x x
( )
2
2
2
x
3, 24.10
1 2x

x
0,18
1 2x

x = 0,132M
100ml dung dch NH
3
2M c th ha tan c 0,1.0,132 = 0,0132 mol AgCl> 0,01 mol
AgCl
Vy 100ml dung dch NH
3
2M c th ha tan 0,01 mol AgCl. (0,5)
c.
Dung dch HCl c pH = 4,0 [H
+
] = [HCl] = 10
-4
M
Sau khi trn:
3
4
5
HCl
CH COOH
10 .10
C 5.10 M
20
0,1.10
C 0, 05M
20

HCl H
+
+ Cl
-

5.10
-5
M 5.10
-5
M
CH
3
COOH

CH
3
COO
-
+ H
+

C 0,05M 0 5.10
-5
M
C x x x
[ ] 0,05-x x 5.10
-5
+ x
( )
5
4,76
5.10 x x
10
0, 05 x

x
2
+ 5.10
-5
x 8,69.10
-7
1,738.10
-5
x
x
2
+ 6,738.10
-5
x 8,69.10
-7
= 0
x = 9,0.10
-4
M (nhn)
x = -9,646.10
-4
M(loi)
pH = -lg[H
+
] = -lg(5.10
-5
+ x) = 3,022 (0,5)
Gi C
A
l nng M ca dung dch CH
3
COOH
3 3
CH COOH CH COO H
+
+
C C
A
0 0
C x x x
[ ] C
A
x x x
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
P N MN HA Khi 10
Thi gian: 180 pht
Vi pH = 3,0 x = 10
-3
M
7
( )
3
2
3
4,76
3
A
6
3 1,24 10
A
4,76
10
10
C 10
10
C 10 10 0, 0585M
10

+
Dung dch K
OH
c pH = 11,0 [OH
-
] = [KOH] =
14
3
11
10
10 M
10

Sau khi trn:
3
2
CH COOH
3
4
KOH
3 3 2
0, 0585x25
C 0, 03656M 3, 66.10 M
40
10 x15
C 3, 75.10 M
40
CH COOH KOH CH COOK H O

+ +
Phn ng 3,66.10
-2
3,75.10
-4
0 0
Sau phn ng (3,66.10
-2
3,75.10
-4
)0 3,75.10
-4
3,75.10
-4

3 3
CH COOH CH COO H
+
+
Dung dch thu c l dung dch m
3
3
3
4
CH COOK
CH COOH
2 4
CH COOH
C
3, 75.10
pH pK lg 4, 76 lg
C 3, 66.10 3, 75.10

+ +

pH = 6,745 (0,5)
Tng t vi cu trn:
- Dung dch CH
3
COOH c pH = 3,0 ng vi
3
CH COOH
C 0, 0585M
- Dung dch HCOOH c pH = 3,0 ng vi nng axit fomic
( )
2
pH
6
pH 3 2,25 3 3
HCOOH
3,75
HCOOH
10
10
C 10 10 10 10 6, 62.10 M
K 10

+ + +
Sau khi trn ln:
3
CH COOH
3
3
HCOOH
0, 0585.10
C 0, 02925M
20
6, 62.10 .10
C 3, 31.10 M
20

Tnh gn ng:
3 3
CH COOH CH COOH HCOOH HCOOH
H K .C K .C
+
1 +
]

4,76 3,75 3
10 .0, 02925 10 .3, 31.10

+

6
1, 0969.10

[H
+
] 1,047.10
-3
pH = -lg (1,047.10
-3
)
pH 2,98 (0,5)
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
P N MN HA Khi 10
Thi gian: 180 pht
Cu 4:
A. Phn ng oxi ha kh:
8
1. iu khng nh sau y c ng khng? Mt cht c tnh oxi ha gp mt cht c tnh
kh nht thit phi xy ra phn ng oxi ha kh. Gii thch.
2. Hon thnh cc phng trnh phn ng sau y di dng phn t v dng ion:
a.
2
4 6 12 6 2
MnO C H O H Mn CO ...
+ +
+ + + +
b.
2
x y 4 2
Fe O H SO SO ...
+
+ + +
B. in ha hc
1. Nu mun thc hin cc qu trnh sau y:
a.
2 4
Sn Sn
+ +
b.
2
Cu Cu
+ +
c.
2
4
Mn MnO
+

d.
2 3
Fe Fe
+ +

Chng ta c th dng nc brom c khng? Bit:

3 2
0
Fe / Fe
E 0, 77v
+ +
+
; 2
0
CU / Cu
E 0, 34v
+
+
;
2
4
0
MnO / Mn
E 1, 51v
+
+
4 2
0
Sn / Sn
E 0,15v
+ +
+
;
2
0
Br / 2Br
E 1, 07v

+
Vit phng trnh phn ng nu xy ra v tnh hng s cn bng ca phn ng xy ra.
2. Ngi ta lp 1 pin gm 2 na pin sau:
3 2
( NO )
Zn / Zn (0,1M)
v
3
NO
Ag / Ag (0,1M)
c th chun tng ng bng -0,76v v 0,80v
e. Thit lp s pin v cc du 2 in cc
f. Vit phng trnh phn ng khi pin lm vic
g. Tnh E ca pin
h. Tnh cc nng khi pin khng c kh nng pht in (pin dng ht)
P N
A.
1. iu khng nh trn khng phi lc no cng ng.
+ Mun c phn ng xy ra gia 1 cht oxi ha A v 1 cht kh B th cht kh to thnh
phi yu hn B v cht oxi ha sinh ra phi yu hn A
VD: Cu + 2Ag
+
= Cu
2+
+ 2Ag
Trong :
- Cht oxi ha Cu
2+
yu hn cht oxi ha ban u l Ag
+
- Cht kh sinh ra l Ag yu hn cht kh ban u l Cu
+ Ngc li, phn ng khng xy ra khi:
2Ag + Cu
2+
= Cu + 2Ag
+

Cht kh yu cht oxi ha yu cht kh mnh cht oxi ha mnh
+ Ngoi ra phn ng oxi ha kh cn ph thuc nng , nhit , cht xc tc,
2.
a.
2
4 6 12 6 2
MnO C H O H Mn CO ...
+ +
+ + + +
x 24
7 2
Mn 5e Mn
+ +
+
(
4
MnO

: cht oxi ha)

x 5
0 4
6C 6.4e 6C
+

( C
6
H
12
O
6
: cht kh)
2
4 6 12 6 2 2
24MnO 5C H O 72H 24Mn 30CO 66H O
+ +
+ + + +
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
P N MN HA Khi 10
Thi gian: 180 pht
Phng trnh di dng phn t:
24KMnO
4
+ C
6
H
12
O
6
+ 36 H
2
SO
4
24 MnSO
4
+ 30 CO
2
+ 66 H
2
O + 12 K
2
SO
4

b.
2
x y 4 2
Fe O SO H SO ...
+
+ + +
9
x 2
( )
2y
3
x
x Fe 2y 3x e x Fe
+
+
+
(Fe
x
O
y
: cht kh)
x(3x-2y)
6 4
S 2e S
+ +
+
(
2
4
SO

: cht oxi ha)
( ) [ ] ( ) ( )
3
2
x y 4 2 2
2Fe O 3x 2y SO 12x 4y H 2x Fe 3x 2y SO 6x 2y H O
+
+
+ + + +
Dng phn t:
2Fe
x
O
y
+ (6x 2y)H
2
SO
4
= x Fe
2
(SO
4
)
3
+ (3x 2y)SO
2
+ (6x 2y) H
2
O
B.
1. Sp xp cc na phn ng theo chiu tng dn ca th in cc chun, ta c:
4 2
2
3 2
2
2
4
4 2 0
Sn / Sn
2 0
Cu / Cu
3 2 0
Fe / Fe
0
2 Br / 2Br
2 0
4 2
MnO / Mn
Sn 2e Sn E 0,15v
Cu e Cu E 0, 34v
Fe e Fe E 0, 77v
Br 2e 2Br E 1, 07v
MnO 8H 5e Mn 4H O E 1, 5v
+ +
+ +
+ +
+
+ +
+ +
+ +

+ +
+ +
+ +
+ +
+ +
+ + + +

Theo qui tc ta thy c th thc hin cc qu trnh a), b), d)

a. Sn
2+
+ Br
2
Sn
4+
+ 2Br


E
0
= +1,07 (+0,15) = +0,92v
2.0,92
31 0,059
K 10 1, 536.10
(0,25)
b. 2Cu
+
+ Br
2
2Cu
2+
+ 2Br

E
0
= +1,07-(+0,34) = +0,73v
2.0,73
24 0,059
K 10 5, 569.10
(0,25)
c. 2Fe
2+
+ Br
2
2Fe
3+
+ 2Br

E
0
= +1,07-0,77=+0,3v
2.0,3
10 0,059
K 10 1, 477.10
(0,25)
2.
a. ( )
3 2
( NO ) 3
Zn | Zn (0,1M) || AgNO (0,1M) | Ag( ) +
(0,25)
b. Ti (-) c s oxi ha Zn 2e Zn
2+
Ti (+) c s kh Ag
+
: Ag
+
+ e Ag
Phn ng tng qut khi pin lm vic:
Zn + 2Ag
+
Zn
2+
+ 2Ag (0,25)
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
P N MN HA Khi 10
Thi gian: 180 pht
c. 2 2
0 2
Zn / Zn Zn / Zn
0, 059
E E lg Zn
2
+ +
+
1 +
]
0
Ag / Ag Ag / Ag
0, 059
E E lg Ag
1
+ +
+
1 +
]
10
E
pin
=
( ) 2 2
2
0 0
Ag / Ag Zn / Zn Ag / Ag Zn / Zn 2
Ag
0, 059
E E E E lg
2
Zn
+ + + +
+
+
1
]
+
1
]

( ) ( )
( )
2
1
1
10
0, 059
0, 80 0, 76 lg 1, 56 0, 0295 1, 53v
2 10

+ +
(0,25)
d. Khi ht pin E
pin
= 0
Gi x l nng M ca ion Ag
+
gim i trong phn ng khi ht pin. Ta c:
( )
2
pin
0,1 x
0, 059
E 0 lg 1, 53
x
2
0,1
2

+

( )
2
51,86
0,1 x
10 0
x
0,1
2

+

x 0,1M
2
x
Zn 0,1 0,15M
2
+
1 +
]
51,86 27
x
Ag 0,1 .10 4, 55.10 M
2
+
_
1 +

]
,
(0,5)
S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII
TRNG THPT BN TRE NM HC 2005 - 2006
P N MN HA Khi 10
Thi gian: 180 pht
Cu 5:
3. Mt khang vt X gm 2 nguyn t: A (kim loi) v B (phi kim)
- Khi t X c cht rn Y (A
2
O
3
) v kh Z (BO
2
) trong phn trm khi lng ca
A trong Y l 70% v ca B trong Z l 50%
- Y tc dng va vi 1,8 (g) H
2
nhit cao.
11
- Z tc dng va vi 117,6(g) K
2
Cr
2
O
7
trong mi trng H
2
SO
4
d cho mui Cr
3+

Xc nh tn khang vt X v khi lng X t
4. T mui n, vi v nc, vit cc phng trnh phn ng iu ch nc Javel v
clorua vi.
P N
1.
0
2 3 t
x y
(X) 2
A O (Y)
A B
BO (Z)

'

2A.100
%A 70 A 56 A Fe
2A 16.3

+
B.100
%B 50 B 32 B S
B 16.2

+
Y + H
2
:
0
2 3 2 2
Fe O 3H t 2Fe 3H O + +
2 3 2
2 3
Fe O H
Fe Fe O
1 1 1, 8
n n . 0, 3(mol)
3 3 2
n 2.n 0, 3.2 0, 6(mol)


K
2
Cr
2
O
7
+ 3 SO
2
+ H
2
SO
4
= K
2
SO
4
+ Cr
2
(SO
4
)
3
+ H
2
O
0,4(mol) 1,2(mol)
2 2 7
2
K Cr O
S SO
117, 6
n 0, 4(mol)
294
n 1, 2mol n


Vi cng thc Fe
x
O
y
ta c t l:
X : y = 0,6 : 1,2 hay 1 : 2
X l FeS
2
(pyrit st)
( ) ( )
2
FeS
m 56.0, 6 32.1, 2 72(g) +
2. 2NaCl + 2 H
2
O 2 NaOH + H
2
+ Cl
2
Cl
2
+ 2 NaOH = NaCl + NaClO + H
2
O
Nc Javel
0
3 2
2 2
2 2 2 2
CaCO t CaO CO
CaO H O Ca(OH)
Cl Ca(OH) CaOCl H O
+
+
+ +
Clorua vi
12