SAMPLE AUSTRALIA SAFETY DATA SHEET

Prepared according to ASCC/NOHSC and EU CLP-GHS criteria Product Name: Fendell Cleaning Solvent Blend No. 3 Page 1 of 21 Product Code: FCSB No.3 Prepared Date: 07/02/2012 Version: 1.00 Printing Date: 07/ 03/2012 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 1.1.1 1.1.2 1.1.3 1.2 1.2.1 1.2.2 1.3 1.3.1 1.3.2 Identification of the substance or mixture Mixture name : Fendell Cleaning Solvent Blend No. 3 Product/SDS Code : FCSB No. 3 Product description : Mixture of solvents. Uses of the mixture and uses advised against Uses of the mixture : Research and Development (R&D) use only. Uses advised against : Not for personal, household or other uses. Company Identification Manufacturer/Supplier Contact information Street address

: Sao Boso Chemicals Pty Ltd. : 8000 Anabaena Avenue Castle Hill, NSW XXXX Australia : + 61 2 0000 1234 : + 61 2 0000 5678 : Productsafety@Saobosochem.com : Chemical Emergency: 1 800 033 111 Life Emergency: 000 Poisons Information Centre: 13 11 26 (24 hours/7days) Chemical Spills- EPA: 13 15 55 or 1 800 018-800 : Product Stewardship Monday to Friday: 6 am - 6 pm (AEST)

Telephone number Telefax number 1.3.3 1.4 E-mail of contact person Emergency telephone number (s)

1.4.1

Further information obtainable from

2. HAZARDS IDENTIFICATION The product is classified as DANGEROUS according to the Australian Dangerous Goods Code. Classified as Hazardous according to ASCC/NOHSC/EU criteria. Hazards : Highly flammable liquid and vapour. Irritating to eyes and respiratory tract. Harmful by inhalation, in contact with skin and if swallowed. : S5 : HAZCHEM CODE = 3[Y]E : 1210 : Printing Ink Related Material : 3 : II

POISON SCHEDULE Road Transport UN Number Proper Shipping Name Dangerous Goods Class Packing Group

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No. 3 Version: 1.00 Classification of the substance or mixture Product definition : Mixture. 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Flammable liquids, Category 2, H225 Acute toxicity (dermal), Category 4, H312 Acute toxicity (inhalation), Category 4, H332 Acute toxicity (oral), Category 4, H302 Aspiration hazard, Category 1, H304 Skin corrosion/irritation, Category 2, H315 Serious eye damage/Eye irritation, Category 1, H318 Reproductive toxicity D, Category 2, H361d Specific Target Organ Toxicity Single exposure H335 Respiratory tract irritation, Category 3, Specific Target Organ Toxicity Single exposure H336 Narcotic effects, Category 3, Specific Target Organ Toxicity H373 Repeated exposure, Category 2, 2.1.2

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Classification of the mixture according to Hazardous Substances Information System (HSIS) Risk Phrases: (R-) 10, 11, 20/21, 22, 36, 37/38, 38, 41, 48/20, 63, 65, 66, 67 Safety Phrases: (S-) 2, 7, 7/9, 9, 13, 16, 24/25, 25, 26, 36/37, 37/39, 46, 62 Hazard Category F Xi Xn

: Flammable. : Irritant. : Harmful.

2.1.3

Additional Information This material is a Scheduled S5 Poison and must be stored, handled and used according to the appropriate regulation. Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS] Product identifier: Mixture Hazard components for labeling: 3-Butanone, Toluene, Xylene GHS Label Elements GHS Symbol (Hazard Pictogram) GHS Code Description Signal Word GHS02 Flame GHS05 GHS07 GHS08

2.1

Corrosion Exclamation Mark Health Hazard DANGER

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Hazard statement(s) H225 H302 H304 H312 H315 H318 H332 H335 H336 H361d H373 Precautionary statement(s) P210 P233 P261 P264 P280 P310 P403 + P233 P501 2.3 Other hazards Substance meets the criteria for PBT according to Regulation (EC) No 1207/2006, Annex XIII Substance meets the criteria for vPvB according to Regulation (EC) No 1207/2006, Annex XIII Other hazards which do not result in classification

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: Highly flammable liquid and vapour. : Harmful if swallowed. : May be fatal if swallowed and enters airways. : Harmful in contact with skin. : Causes skin irritation. : Cause serious eye damage. : Harmful if inhaled. : May cause respiratory irritation. : May cause drowsiness or dizziness. : Suspected of damaging the unborn child. : May cause damage to organ(s) through prolonged or repeated exposure : Keep away from heat/sparks/open flames/hot surfaces No smoking. : Keep container tightly closed. : Avoid breathing dust/fume/gas/mist/vapours/spray. : Wash hands with soap and plenty of water after handling. : Wear protective gloves/protective clothing/eye protection/face protection. : Immediately call a POISON CENTER or doctor/physician. : Store in a well-ventilated place. Keep container tightly closed. : Dispose of contents/container to be in accordance with local/regional/national regulations. : No. : P: Not available. B: Not available. T: No.

: Not available.

: Repeated exposure may cause skin dryness or cracking.

This product is classified as dangerous according to the Australian Dangerous Goods Code 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Description of the substance/mixture : Mixture of solvents.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Hazardous ingredients

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Classification
Chemical/ Substance Name 3-Butanone CAS No. EC No. Index No. RRN* Weight (%) HSIS

78-93-3

201-159-0 606-002-00-3

40 60

n-Butanol

71-36-3

200-751-6

603-004-00-6

30 60

Ethanol

64-17-5

200-578-6

603-002-00-5

10 40

Regulation (EC) No. 1272/2008[ CLP-GHS] F; R11 Flam. Liq. 2, Xi; R36-66-67 H225 S: (2-) 9, 16 Eye irrit. 2, H319 STOT SE 3, H336 EUH066 R10 Flam. Liq. 3, Xn; R22 H226 Xi; R37/38, Acute Tox. 4* H302 R41, R67 STOT SE 3 S: (2-)7/9, 13, H335 Skin Irrit. 2 26, 37/39, 46 H315 Eye Dam. 1 H318 STOT SE 3 H336 F; R11 Flam. Liq. 2 S: (2)7, 16 H225 F, R11 Xi; R36, R67 S: (2-) 7,16,24/25, 26 Flam. Liq. 2 H225 Eye Irrit. 2 H319 STOT SE 3 H336 Flam. Liq. 2 H225 Repr. 2 H361d*** Asp. Tox. 1 H304 STOT RE 2 H373** Skin Irrit. 2 H315 STOT SE 3 H336

Type

[1] [2]

[1] [2]

[2]

Isopropanol 67-63-0

200-661-7 603-117-00-0

10 20

[1] [2]

Toluene

108-88-3

203-625-9 601-021-00-3

15

F; R11 Repr. Cat. 3 R63 Xn; R48/20, R65 Xi; R38, R67 S; (2-) 36/37, 62

[1] [2]

Table continued on next page.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00

Page 5 of 21 Prepared Date: 07/02/2012 Printing Date: 07/03/2012 Classification

Chemical/ CAS No. Substance Name

EC No.

Index No.

RRN* Weight (%) 67/548/EEC

Xylene

1330-20-7

215-535-7

601-022-00-9

15

R10 Xi; R38 S; (2) 25

Regulation (EC) Type No. 1272/2008[ CLP] [1] Flam. Liq. 3 H226 Acute Tox. 4* [2] H332 Acute Tox. 4* H312 Skin Irrit. 2 H315 See Section 2 for the full text of the Hstatements declared above.

See Section 16 for the full text of the Rphrases declared above.
*

RRN: REACH Registration Number. Product classified according to NOHSC criteria. All hazardous substances are declared.

All other ingredients not hazardous according to ASCC/NOHSC/EU Criteria. 3.2 Additional information [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No 1207/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No 1207/2006, Annex XIII Occupational exposure limits, if available, are listed in Section 8. 4. FIRST AID MEASURES 4.1 4.1.1 Description of first aid measures General information : General first aid measures should be followed. In case of persistent adverse effects, seek immediate medical attention. Remove contaminated clothing and shoes promptly, and wash thoroughly before re-use. : NOTE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. : Emergency responders should use positive air supplied respiratory protection when removing the victim from area.

4.1.2

Following inhalation

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No.3 Version: 1.00

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Remove person to fresh air. If not breathing, administer CPR until help arrives, or the victim starts to breathe on their own. Give artificial respiration if breathing has stopped. Seek medical attention immediately. 4.1.3 Following skin contact : If exposure occurs, immediately flush the affected area thoroughly with water for at least 15 minutes. Use soap if available. Remove contaminated clothing, including shoes, after flushing has begun. Wash clothing before re-use. If irritation persists, seek medical attention. : Immediately flush affected eye with water for at least 20 minutes. ilt the head to prevent chemical from transferring to the unaffected eye. Seek medical attention without delay after flushing. : DO NOT INDUCE VOMITING if swallowed. Rinse mouth out with water. Dilute with milk or water. Never give anything to drink if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center at once. : Appropriate personal protective attire should be worn. : Suitable medical intervention should be provided based on symptoms - treat symptomatically.

4.1.4

Following eye contact

4.1.5

Following ingestion

4.1.6 4.1.7

Self protection of the first aider Note to the doctor

In case of poisoning, contact Poisons Information Centre : In Australia call on 13 11 26 In New Zealand call on 03 47 47 000

4.2

Most important symptoms and effects, both acute and delayed

: Irritating to eyes, skin, and respiratory tract upon exposure. High vapour concentrations are irritating to eyes, nose, throat, and lungs; may cause unconsciousness or other signs of central nervous system depression. Frequent or prolonged skin contact may irritate the skin and cause skin rash (dermatitis). May cause skin sensitization, an allergic reaction which becomes evident on re-exposure to this material. Small amounts of this liquid may be drawn into the lungs by either swallowing or vomiting. This may cause severe and delayed health effects such as inflammation of the lungs (pulmonary edema) and infection of the bronchi (bronchopneumonia). Ingestion may cause irritation of digestive track and diarrhea. : Always get immediate medical attention/advice when symptoms persist.

4.3

Indication of any immediate medical attention and special treatment needed

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 5. FIRE FIGHTING MEASURES Fire Fighting Measures

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: The following applies to 3-Butanone FLASHPOINT: -3.33oC SPECIFC GRAVITY: 0.806 @ 20o C EXPLOSIVE LIMITS: LEL: 1.8%, UEL: 11.0%. AUTOIGNITION TEMPERATURE: 516.11oC. : 3[Y] E (Australia)

HAZCHEM CODE 5.1 Extinguishing media Suitable extinguishing media

: Either allow fire to burn out under controlled conditions, or extinguish with alcohol type or all purpose type foam, or dry chemical powder. Try to cover liquid spills with appropriate foam. Use water spray to cool fire exposed surfaces. Avoid spraying water directly into storage containers due to danger of boilover. Shut off fuel to fire if possible to do so without hazard. If a spill has not ignited, use water spray to disperse the vapours. : Do not use high volume water jet. : Flammable liquid; may release vapours that form flammable mixtures when temperatures are at or above the flash point. There is a danger of explosion when container is heated or in fire. Toxic gases will form upon combustion. Vapour may may accumulate in low or confined areas or travel to a considerable distance to a source of ignition and flash back. Avoid runoff into storm sewers and ditches. : Smoke, fumes, oxides of carbon, irritating or toxic vapours or gases.

Unsuitable extinguishing media 5.2 Special hazards arising from the mixture

Hazardous combustion products

5.3

Advice for fire-fighters Protective equipment for fire fighters : Respiratory and eye protection gear is required for fire fighting personnel. Full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. Use portable fire extinguisher for small outdoor fires. Use of SCBA may not be required. : Exposure to decomposition products may cause health hazards. Cool containers exposed to fire with water spray. Move unexposed containers from fire area if this can be done without risk.

5.4

Additional information

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 6. ACCIDENTAL RELEASE MEASURES 6.1 6.1.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment

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: : Wear suitable personal protective equipment (e.g. clothing, gloves, safety goggles, and mask/respirator). Ensure adequate ventilation; remove all sources of ignition. Notify the appropriate authorities immediately. : Eliminate ignition source. Shut off leak if safe to do so. Take all additional action necessary to prevent and remedy the adverse effects of the spill. Isolate hazard area and deny entry to unauthorized or unprotected personnel. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as saw dust. Absorb spill with an inert material (e.g., sand or earth). Then place in a chemical waste container. : Respiratory and eye protection gear is required for emergency responders. Full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. Use portable fire extinguisher for small outdoor fires. Use of SCBA may not be required. : Avoid dispersal of spilt material and runoff into soil, storm sewers and ditches which lead to natural waterways, or the immediate environment. Inform the relevant authorities if the product has entered into the environment.

Emergency procedures

6.1.2

For emergency responders personal protective equipment

6.2

Environmental precautions

6.2 6.3.1

Methods of containment and cleaning up On water : If spill in water, remove from water surface by skimming or with suitable absorbent material and place in appropriate disposal container. If allowed by local environmental regulatory agencies, you may use a suitable dispersant. : Contain spill and absorb with an inert material (e.g., dry sand or earth). Then place in an appropriate waste container for disposal according to local regulations. Large spills should be disposed of via a licensed waste disposal establishment/contractor. : Contaminated absorbent material may pose similar hazard as the spill product. : : Initial Emergency Response Guide (SAA/SNZ HB76: 2004) : Highly Flammable, Guide No: 14

6.3.2 On ground/floor

6.3.3

Other information

Emergency Information (Transport) Dangerous Goods For Liquids

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 6.4 Reference to other sections See Section 1 for emergency contact information. See Section 8 for information on appropriate personnel protective equipment. See Section 13 for additional disposal information.

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7. HANDLING AND STORAGE 7.1 7.1.1 Precautions for safe handling Protective measures

: Wear appropriate personal protective equipment. Do not get in eyes, on skin, or on clothing. Do not breathe vapour or mist. Do not eat, drink, or smoke when using this product. Use only with adequate ventilation. Keep away from sources of ignition. Keep only in original container. Keep tightly closed when not in use. Do not reuse container. Avoid release to the environment. : Avoid eating, drinking and smoking in areas where this product is handled, used and stored. Wash hands before eating, drinking and smoking, and at the end of the working period. Contaminated work clothing and protective equipment should not be brought into eating, smoking and drinking areas. Wash soiled clothing before re-using.

7.1.2

Advice on general occupational hygiene

7.2

Conditions for safe storage, including any incompatibilities Technical measures and : Store at ambient/room temperature. Protect from extreme cold storage conditions and heat. Store in a segregated and approved area. Store away from strong oxidizing agents. Loosen closure cautiously with non-sparking tools before opening. Keep only in original container. Store and use away from sparks, heat, open flames and other ignition sources. Ground and bond containers and receiving equipment. Store locked up. Store away from direct sun -light in a dry, cool and well-ventilated area. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Ground and bond containers when transferring material. Ventilation required along storage floor [ See AS 1940]. Packaging materials : Steel drum, HDPE (High Density Poly Ethylene) -2 plastic bottles and containers. : For industrial use only. : Not available.

7.3

Specific end use(s) Recommendations Industrial sector specific solutions

8. EXPOSURE CONTROL/PERSONAL PROTECTION No exposure standards are available for this product. The following exposure standards in the table below have been assigned by ASCC/NOHSC to the components in the product.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 8.1 Control parameters

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8.1.1 Occupational Exposure Limits (OELs) : Workplace Occupational Exposure Limit(s) OELs [ASCC/NOHSC] Component Information Occupational Exposure Limits Air contaminants sampling Long term limit Short term limit (STEL) Health Hazard (8-hour TWA) (15-minutes exposure) Carcinogen Skin Chemical Name CAS No ppm mg/m3 ppm mg/m3 Designation category 3-Butanone 78-93-3 150 445 300 890 n-Butanol 71-36-3 50* 152* Sk Ethanol 64-17-5 1000 1880 Isopropanol 67-63-0 400 983 500 1230 Toluene 108-88-3 50 191 150 574 Sk Xylene 1330-20-7 80 350 150 655 * = Peak limitation Sk = Skin Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation of chemical agents and national guidance documents for methods for the determination of hazardous substances. : No information . : Not available.

Derived effect levels [DNEL] Predicted effect concentrations (PNEC Summary) 8.1 8.1.1 Exposure controls Appropriate engineering control

: Highly flammable liquid. Provide adequate local exhaust ventilation to maintain worker below exposure limits. The use of mechanical ventilation controls is recommended whenever this product is used in a confined space, is heated above ambient temperatures, or is agitated. Prevent accumulation of vapours in hollows or sumps. Eliminate any sources of ignition. Use explosion-proof ventilation

8.2 8.2.1

Personal protective equipment Eye and face protection

: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mist, or dust. Chemical goggles or spectacles with shields may be used to protect eyes.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 8.2.2 Skin protection Hand protection

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: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this in necessary. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Use approved respiratory protection equipment. Respirator selection should be based on the form and concentration of contaminants in the air, and in accordance with local regulations. Select and use respirators in accordance with AS/NZS 1715/1716. Use Self Contained Breathing Apparatus (SCBA) with positive pressure air supply complying with AS/NZS 1715/1716, or any other acceptable International Standard when entering confined spaces with unknown levels of air pollutants. : Emission from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Ensure that emission is at the acceptable level.

Body protection

Other skin protection

8.3

Respiratory protection

8.4

Environmental exposure controls

9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on physical and chemical properties Physical state : Liquid. Colour : Characteristic. Odour : Solvent odour. Odour threshold : Not determined. pH : Not available . Melting/freezing point [o C] : Not available. o Initial boiling point/range [ C] : Not available. Flash point [o C] : Not available. Evaporation rate (n-Butyl Acetate : Not available. = 1) Flammability (solid, gas) : Not available. Upper flammability : Not available. Lower flammability : Not available. o Vapour pressure, mm Hg @ 24 C : Not available. Vapour density (Air = 1) : Not available . Relative density : Not available. Solubility in water, Wt % @ 20 o C : Not available.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Partition coefficient: nOctanol/water Auto-ignition temperature Decomposition temperature Viscosity of Liquid, CST @ 25o C Explosive properties Oxidizing properties 9.2 Other information : Not available. : Not available. : Not applicable. : Not available. : Not available. : Not available. : Mixture has not been tested.

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10. STABILITY AND REACTIVITY 10.1 Reactivity : Contact with incompatible or reactive materials may cause hazardous reactions. : Stable under normal conditions. : Hazardous polymerization will not occur. : Open flames and sources of ignition. : Strong oxidizing agents.

10.2 10.3 10.4 10.5 10.6

Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials

Hazardous decomposition products : Burning can produce oxides of carbon.

11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects : There is no toxicological information available for this product. No adverse effects are expected, if the product is handled in accordance with this Safety Data Sheet (SDS). Symptoms and effects may arise if the product mishandled and over exposure occur. : Relevant effects: Components. : Route of Administration Oral Oral Inhalation vapour Inhalation vapour Dermal Intra-peritoneum (i.p.) Intra venous (i.v.) Inhalation vapour

11.1.2 Mixture

11.1.2.1 (a) Acute toxicity Substance name:

Test LD50 Toluene LDLO Identifiers: LC50 TCLO EC No: 203-625-9 LD50 CAS No: 108-88-3 LD50 Index No: 601-021-00-3 LD50 LC50

Species Rat Human Mouse Human Rabbit Mouse Rat Rat

Dose/Result Exposure Remark > 636 mg/kg 50 mg/kg 6405 -7436 ppm 6 hour (s) 200 ppm 12124 mg/kg 66 mg/kg 1960 mg/kg 28.1 mg/l 4 hour (s) -

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Test LD50 Xylene LD50 Identifiers: LC50 LC50 EC No: 215-535-7 LD50 CAS No: 1330-20-7 LD50 Index No.: 601-022-00-9 LD50 TCLo Substance name: Species Rat Mouse Rat Rat Rabbit Rat Rat Human Route of Administration Oral Oral Inhalation vapour Inhalation vapour Dermal Intra-peritoneal (i.p.) Intra-peritoneal (i.p.) Inhalation vapour

Page 13 of 21 Prepared Date: 07/02/2012 Printing Date: 07/03/2012 Dose/Result Exposure Remark 4300 mg/kg 3523-8700 mg/kg 6350 ppm 4 hour (s) 47635 mg/l 4 hour (s) > 4350 mg/kg 2459 mg/kg 2608 mg/kg 200 ppm -

Substance name: 3-Butanone Identifiers: EC No: 201-159-0 CAS No: 78-93-3 Index No: 606-002-00-3

Test LD50 LC50 LD50

Species Rat Rat Rabbit

Route of Administration Oral Inhalation vapour Dermal

Dose/Result Exposure Remark 2600-5400 mg/kg > 5000 ppm 6 hour (s) 6400-8000 mg/kg -

Substance name: n-Butanol

Test LD50 LD50 Identifiers: LC50 ID50 EC No: 200-751-6 LD50 CAS No: 71-36-3 LD50 Index No: 603-004-00-6 LD50 LD100

Species Rat Mouse Rat Mouse Rabbit Rat Moue Rat

Route of Administration Oral Oral Inhalation vapour Inhalation vapour Dermal Intra-peritoneal (i.p.) Intra-petoneal (i.p.) s.c.

Dose/Result Exposure Remark 8000 mg/kg 2680 mg/kg 8000 ppm 4 hour (s) 617 ppm 3 minutes 3400 mg/kg 1122 mg/kg 603 mg/kg 5000 mg/kg -

Substance name:

Test LD50 Ethanol LD50 Identifiers: LC50 LC50 EC No: 200-578-6 LDLO CAS No: 64-17-5 LD50 Index No:603-002-00-5 LD50 LD50

Species Rat Mouse Rat Mouse Rabbit Rat Mouse Mouse

Route of Administration Oral Oral Inhalation vapour Inhalation vapour Dermal Intra-peritoneal (i.p.) Intra-peritoneal (i.p.) Sub cutaneous

Dose/Result Exposure Remark 6200 mg/kg 8300 mg/kg 5.9 mg/l 6 hour (s) 39 mg/l 4 hour (s) 20000 mg/kg 6710 mg/kg 3156 mg/kg 8700 mg/kg -

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Test LD50 Isopropanol LD50 Identifiers: LC50 LC50 EC No: 200-661-7 LD50 CAS No: 67-63-0 LD50 Index No: 603-117-00-0 LD50 LD50 Conclusion/Summary (b) Irritation Inhalation Substance name: Species Rat Mouse Rat Mouse Rat Rat Rat Mouse Route of Administration Oral Oral Inhalation vapour Inhalation vapour Dermal Intra-peritoneum (i.p.) Intra venous (i.v.) Intra-peritoneal (i.p.)

Page 14 of 21 Prepared Date: 07/02/2012 Printing Date: 07/03/2012 Dose/Result Exposure Remark 5280 mg/kg 4475 mg/kg 72.6 mg/l 4 hour (s) 53 mg/l 2 hour (s) 12800 mg/kg 2050 mg/kg 1099 mg/kg 3400 mg/kg -

: Vapours may cause drowsiness or dizziness.

: May cause irritation to the nose, throat, and lungs. High vapor concentrations may cause unconsciousness or other signs of central nervous system depression. : Frequent or prolonged contact may irritate the skin and cause skin rash (dermatitis). May cause skin sensitization, an allergic reaction which becomes evident on re-exposure to this material. : Severely irritating. If not removed promptly will injure eye tissue, which may result in permanent damage. : May cause irritation of the digestive tract and diarrhea. : Severely irritating to eyes. Repeated exposure may cause skin dryness or cracking. : May cause skin sensitization and or respiratory system irritation due to extended exposure of the preparation above stated occupational exposure limits. : No data available. : No data available. : No known significant effects or critical hazards. : No information but adverse effects unlikely. : No known significant effects or critical hazards. : No known significant effects or critical hazards.

Skin contact

Eye contact

Ingestion (c) Corrosivity

(d)

Sensitization

(e) (f) (g) (h) (i)

Single dose toxicity Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction

11.1.2.2 CMR effects (carcinogenic, mutagenic or toxic for reproduction)

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 11.2 Potential adverse health effects

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: Small amounts of this liquid may be drawn into the lungs by either swallowing or vomiting. This may cause severe and delayed health effects such as inflammation of the lungs ( pulmonary edema) and infection of the bronchi(bronchopneumonia). Ingestion may cause irritation to the digestive tract or diarrhea. : There is no evidence that exposure to 3-Butanone alone causes progressive or irreversible neurotoxic effects. However, simultaneous over-exposure to 3-Butanone and n-Hexane can potentiate the known irreversible neurotoxic effects of n-Hexane. There is no reported human evidence that these neurotoxic effects occur when exposure to both chemicals is maintained below established regulatory limits. : The mixture is not likely to be carcinogen in humans.

11.3

Potential chronic health effects

11.4

Other information

12. ECOLOGICAL INFORMATION There is no ecological information available for this product. Ecotoxicological information on components of this product is presented below. 12.1 Toxicity :

3-Butanone [CAS#: 78-93-3] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC3 n-Butanol [CAS#: 71-36-3] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC50 Ethanol [CAS#: 64-17-5] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity LC50 Acute algae toxicity EC50 Isopropanol [CAS#: 67-63-0] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC50

Exposure time (h) 96 hour (s) 48 hour (s) 7 days

Species Pimephales promelas Daphnia magna Scenedesmus quadricauda

Value (mg/l) 3220 > 520 4300

Exposure time (h) 96 hour (s) 48 hour (s) 96 hour (s)

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Value (mg/l) < 1630 1983 > 500

Exposure time (h) 96 hour (s) 48 hour (s) Not specified

Species Alburnus alburnus Daphnia magna Chlorella pyrenoidosa

Value (mg/l) 10000 - 11500 9268 - 14221 9310

Exposure time (h) 96 hour (s) 48 hour (s) 96 hour (s)

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Value (mg/l) 9640 13299 > 1000

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Toluene [CAS#: 108-88-3] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC50 Xylene [CAS #: 1330-20-7] Aquatic toxicity Acute fish toxicity Acute invertebrate toxicity Acute algae toxicity 12.2

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Exposure time (h) 96 hour (s) 48 hour (s) 48 hour (s)

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Value (mg/l) 28 11.5 125 - 160

Effect dose LC50 LC50 Mortality

Exposure time (h) 96 hour (s) 48 hour (s) Unknown

Species Cyprinus carpio Palaemonetes pugio Scenedesmus quadricauda

Value (mg/l) > 780 0.85 > 200

Persistence and degradability

: No data available for this product.

(Biochemical Oxygen Demand BOD values) Substance name Quantity Degradation rate (%) 3-Butanone Unknown 83 n-Butanol Unknown 66 Ethanol 10 mg/l 74 Isopropanol 10 mg/l 78* Toluene Unknown Completely Xylene Isomers 72 * Theoretical Oxygen Demand (ThOD) value. 12.3

Incubation time 5 days 5 days 5 days 20 days Short duration 20 days

Evaluation (inoculum) Sewage Sewage sludge Filtered sewage seed Filtered sewage seed Sewage seed Activated sewage

Bioaccumulative potential : No data available for this product. (BCF Bio Concentration Factor). log n-octanol/water partition coefficient (log Kow) estimate Substance name Estimated BCF log Kow Remarks 3-Butanone 3 0.29 Low bioaccumulation n-Butanol 3 0.88 Low bioaccumulation Ethanol 3 -0.31 Low bioaccumulation Isopropanol 3 0.05 Low bioaccumulation Toluene 13 (eel) , 90 (Golden ide) 2.73 Low to moderate bioaccumulation Xylene 6 23.4 3.2 Low bioaccumulation Mobility in soil : No data available for this product.

12.4

Koc The soil absorption coefficient Substance name Koc value 3-Butanone 29 n-Butanol 72 Ethanol 1 Isopropanol 25 Toluene variable Xylene 39 365 for individual isomers

Remarks (soil mobility) Very high mobility High mobility Very high mobility Very high mobility High to moderate mobility Very high to moderate mobility

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 12.5 Results of PBT and vPvB assessment PBT : No data available. vPvB : No data available. Other adverse effects

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12.6

: No known significant effects or critical hazards.

13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product Methods of disposal

: The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Waste product residue should not be disposed of via the foul sewer. Consult an expert on the disposal of recovered and surplus material. Incinerate, or recover by distillation. Ensure disposal is in compliance with current government requirements and ensure conformity with local authority regulations. : The generation of waste should be avoided or minimized whenever possible. Waste packaging should be recycled, or dispose of according to state and local authority regulations. Consult your State/Local Land Waste Management Authority. : H3 15 01 01 15 01 02 : flammable liquid (organic solvents) [Australia] : paper and cardboard packaging [EU]. : plastic packaging [EU]

Packaging waste Methods of disposal

Waste codes/ waste designation

: The listed waste numbers according to the European Waste Code (EWC) are intended as recommendation for users. The final classification has to be worked out together with the local waste disposal company/authority. Note: The generator of waste should consult their Environmental Protection Authority for classification assistance and coding. Special precautions : This material and its container must be disposed of according to local authority regulations. Empty containers or packaging may contain some product residue. Avoid dispersal of spilt material and runoff to come in contact with soil, waterways, drains and sewers.

14. TRANSPORTATION INFORMATION

Transportation information is provided on the next page.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 ADG/ADR/RID 1210 Printing Ink Related Material ADN/ADNR 1210 Printing Ink Related Material

Page 18 of 21 Prepared Date: 07/02/2012 Printing Date: 07/03/2012 IMDG ICAO-TI/IATA-DGR 1210 1210 Printing Ink Printing Ink Related Related Material Material

14.1 UN No. 14.2 Proper Shipping Name 14.3 Transport hazard class 14.4 Classification code 14.5 Packing group 14.6 Hazard label 14.7 Environmental hazard 14.8 Special provision(s) Additional Information

3 F1 II

3 F1 II

3 F1 II

3 F1 II

No 163 640C Hazard identification number 33 HC: 3[Y]E Transport Category 2 Ltd. Qty LQ6 Excpt. Qty E2 Packaging P001, PP1, MP19 Portable Tanks and Bulk Cont. T4; TP1, TP8 Tunnel code D/E

No 163 640C -

Marine pollutant: No 163 Emergency schedules (EmS) Fire F-E Spillage S-D

No Not available Passenger and Cargo Aircraft Quantity limitation: 1.0L Packing instructions: Y341 353 5.0L

Ltd. Qty LQ6

Excpt. Qty. E2 -

Ltd. Qty 5l Excpt. Qty E2 -

Cargo Aircraft only Quantity limitation: 60.0 L

Packaging instruction: 364

14.9

Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not applicable.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 15. REGULATORY INFORMATION 15.1

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Safety, health and environmental regulations/legislation specific for the substance or mixture Poison Schedule : S5

This product is a Schedule S5 Poison and must be stored, handled and used according to the appropriate regulation. Inventory Status Australia (AICS) United States (TSCA) Europe (EINECS/ELINCS) : : Y : Y : Y

Y = all ingredients are on the inventory or exempt. International regulations

Chemical Weapons Convention List Chemical Weapons Convention List Chemical Weapons Convention List Schedule I Chemicals Schedule II Chemicals Schedule III Chemicals Not listed Not listed Not listed

15.2

Chemical Safety Assessment : No Chemical Safety Assessment has been carried out for this product.

16. OTHER INFORMATION NOTE : This Safety Data Sheet was created as a training document for Australian freelance safety data sheet writers. The mixture is unreal. : The product has been classified and marked in accordance with ASCC/NOHSS/EU criteria.

Product

16.1

Indication of changes Date of previous issue Revisions Nature of version Version Date of issue Prepared by

: : : : : :

No previous validation. To complies with NOHSC criteria. Conforms to ASCC Guidelines. 1.00 July 03, 2012 Theodore M. Amet, Regulatory Research Analyst.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 16.2

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Abbreviations and acronyms ADG: Autralian Dangerous Goods [Int]; ADN: Accord europen relative au transport international des marchandises dangereuses par voie de navigation intrieure [Int]; ADNR: Accord europen relative au transport international des marchandises dangereuses par marine sur le Rhin [Int]; ADR: Accord europen sur le transport des merchandises dangereuses par route (European Agreement concerning the International Carriage of Dangerous Goods by Road) [Int]; AICS: Australian Inventory of Chemical Substances [Aust]; ASCC: Australian Safety and Compensation Council [Aust]; AS/NZS 1715: Selection, use and maintenance of respiratory devices [Aust/NZ]; AS/NZS 1716: Respiratory protective devices [Aust/NZ]; AS 1940: The storage and handling of flammable and combustible liquids [Aust]; Aust/NZ: Australia/New Zealand CAS: Chemical Abstracts Service [Int]; CLP: Regulation on the Classification, Labelling, and Packaging of substances and mixtures [Int] [CLP Document - REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December, 2008 on classification, labeling, and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC and amending Regulation (EC) No 1907/2006]; DGR: Dangerous Goods Regulation [Int]; EC: European Commission [Int]; EINECS: European Inventory of Existing Commercial chemicals Substances [Int]; ELINCS: European List of Notified Chemical Substances [Int]; EmS: Emergency Schedule [Int]; ESIS: Existing chemical Substances Information System [Int]; EU: European Union [Int]; GHS: Globally Harmonized System of Classification and Labelling of Chemicals [Int]; Hazchem Code: Fire fighters designation [Aust]; IATA: International Air Transport Association [Int]; IBC Code: International Code for the Construction and equipment of Ships Carrying Dangerous Chemicals in Bulk [Int]; ICAO: International Civil Aviation Organization [Int]; IMDG: International Maritime Dangerous Goods [Int]; TSCA: Toxic Substances Control Act TI: Technical Instructions for the Safe Transport of Dangerous Goods by Air {Int]; USA: United States of America Full text of Risk and Hazard Phrases/Codes in Section 2 Risk (R)-phrase(s) R11 R20/21 R22 R36 R37/38 R38 R41

16.3

: Highly flammable. : Harmful by inhalation and in contact with skin. : Harmful if swallowed. : Irritating to eyes. : Irritating to respiratory system and skin. : Irritating to skin. : Risk of serious damage to eyes.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 R48/20 R63 R65 R66 R67 Safety (S)-phrase(s) S2 S7/9 S13 S16 S24/25 S26 S36/37 S37/39 S46 S62

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: Harmful: danger of serious damage to health by prolonged exposure through inhalation. : Possible risk of harm to the unborn child. : Harmful: may cause lung damage if swallowed. : Repeated exposure may cause skin dryness or cracking. : Vapours may cause drowsiness and dizziness.

: Keep out of the reach of children. : Keep container tightly closed and in a well ventilated place. : Keep away from food, drink and animal feedingstuff. : Keep away from sources of ignition No smoking. : Avoid contact with skin and eyes. : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : Wear suitable protective clothing and gloves. : Wear suitable gloves and eye/face protection. : If swallowed, seek medical advice immediately and show this container or label. : If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. :

16.3

Key literature references and sources of data

ECHA (European Chemicals Agency) http://echa.europa.eu/ ESIS (Existing chemical Substances Information System) http://ecb.jrc.ec.europa.eu/esis/. GESTIS International Limit values Database http://www.dguv.de/ifa/en/gestis/limit_values/index.jsp Guidance on the compilation of safe data sheets http://guidance.echa.europa.eu/docs/draft_documents/draft_guidance_on_safety_data_sheets_20100324.pdf TOXNET: Toxicology Data Network. http://toxnet.nlm.nih.gov Information from technical literature Internet research. DISCLAIMER This guide was compiled as a service to expat freelance Australian Safety Data Sheets writers. Information in this document is based on data gathered from various Internet sites. No warranty is expressed regarding the accuracy of data obtained from various chemical, health, toxicological, and environmental databases. Responsibility for the accuracy and completeness of information contained herein rests with users who must satisfy themselves that the data is appropriate for their needs. The author specifically disclaims any or all forms of liability and/or responsibility for the use of this guide. It is always a good practice to consult a sectional expert when writing sections of the safety data sheets to clarify and simplify technical matters. END OF SAMPLE SAFETY DATA SHEET