INFO No. 602.

2E Page 1 of 2

Matting of Softfeel-Lacquers by use of DEUTERON MK / PERGOPAK M3 / DEUTERON PMH C

When parts inside of motorcars have to be coated since years special coating materials are used well known under the name "softfeel-lacquers". These lacquers have been produced till short time ago exclusively based on organic solvents. With development of suitable binders today also aqueous and 100 % solid UV curing systems for softfeel-lacquers in an increasing degree are developed and produced. Exceptional demands which result from their application interior of motorcars are made on these coatings. The finishing of the dashboard and with this its optical improvement is probably of the greatest importance. Great demands are made on a softfeel-lacquer for dashboard. In particular on abrasion resistance and scratch resistance of the surface. The surface has to be of low gloss, non-reflective and of luxurious look. These requirements can only be obtained by the choice of a suitable binder combined with a suitable matting agent. The binder has to be of extremely high flexibility even without the use of plasticizer to obtain the required softfeel character of the coating. When softfeel-lacquers are formulated in the optimum way they offer technical and economic advantages compared with laminating foil on dashboards. On small items in the interior of motorcars there will be in any case only the possibility of coating for the surfaces formation. Softfeel-lacquers can be designed in an optimum way based on above mentioned binder systems including organic matting agents based on micronized polymethyl urea resin, as DEUTERON MK, PERGOPAK M3 and DEUTERON PMH C. These products are used for matting. They take away from the flexible binders the tendency in thermoplasticity. This occurs in particular in coating materials on dashboards by influence of sunlight and resulting from this of heat. The presence of the organic matting agents imparts mat softfeel-lacquers abrasion resistance and scratch resistance with the required soft touch. Micronized polymethyl urea resin with its typical particle structure does practically not spoil the flexibility of the softfeel-lacquer and its required adhesion on thermoplasts even at permanent changing of temperatures. Easy incorporation of the micronized organic matting agents based on polymethyl urea resin is given with common mechanical stirrers also into aqueous coating systems. The use of wetting agents for the incorporation of DEUTERON MK, PERGOPAK M3 or DEUTERON PMH C is not required. This offers advantages with regard to water resistance of the applied coating and its behaviour with regard to the forming of micro-foam at production or application of the wet-lacquer. Especially the low influence to the viscosity of the 100 % solid UV curing softfeel-lacquers shows an important advantage for the producer. When there are special requirements on the degree of gloss at softfeel-lacquers which cannot be achieved by the sole use of micronized polymethyl urea resin the combination with small amount of inorganic matting agent based on SiO2 is recommended. The optimum in ratio of organic and inorganic matting agent has to be determined very carefully by individually laboratory trials. The presence of SiO2 can spoil the required surface properties with regard to scratch resistance and abrasion resistance.

INFO No. 602.2E Page 2 of 2 The use of organic products from the family of waxes is possible in principle to meet further individual requirements with regard to the coatings surface. It has to be taken into consideration that waxes have a certain softening point and with this they are limited in their temperature resistance. In softfeel-lacquers on dashboards this in particular can bring serious problems with insufficient temperature stability. Recommended products for the use in "aqueous softfeel-lacquers": DEUTERON MK PERGOPAK M3 DEUTERON PMH C organic matting agent based on polymethyl urea resin organic matting agent based on polymethyl urea resin organic matting agent based on polymethyl urea resin

All 3 mentioned products are different in their particle distribution and the particle structure

Our technical service offers you assistance regarding suitable binders or starting formulations on the described coating systems.

The information and recommendations contained in this INFO are given to the best of our knowledge and belief. Nevertheless, they cannot replace the user's own tests. Any third-party proprietary rights must be respected by the user. 100111 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/483227*Fax ++49 (0)421/483602 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting formulation RR 62
2 K-Softfeel-Lacquer, solvent borne, pigmented, based on Desmophen 1652 / Desmophen C 200 /
Desmodur N 75 RR 62 is corresponding to "KCS 11-20-2" from

Bayer AG, Leverkusen.

________________________________________________________________________________________

Component 1
Position weight units Product

1 2 3 4 5 6 7 8 9

14,70 14,70 10,60 2,80 4,90 1,70 2,80 1,40 39,10

Desmophen 1652 Desmophen C 200 Bayferrox 318 M Sillitin Z 86 DEUTERON MK Matting agent OK 412 Bentone 38, 10 % attack Dibutyltindilaurat, 1 % in Butylacetat Butylacetat / Xylol 1 : 1

(1) (1) (1) (2) (3) (4) (5) (6)

Component 2
Position weight units Product

10

7,30 _______ 100,00

Desmodur N 75

(1)

Paint composition in %
app. 34,90 Binder app. 40,90 Solvent app. 10,60 Pigment app. 2,80 Extender app. 6,60 Matting agent app. 4,20 Additive

RR 62 Page 2/2

Characteristics
app. 1,00 app. 60 min NCO/OH Potlife

Recommendation for production and processing

Predisperse with mechanical stirrer and after that grind on a laboratory equipment (Red Devil). After the hardener has been added the mixture is adjusted to app. 30 sec efflue time (DIN 53211), 4 mm nozzle) and sprayed conventionally.

Suppliers ( ( ( ( ( ( 1) 2) 3) 4) 5) 6) Bayer AG, Leverkusen Hoffmann & Shne, Neuburg DEUTERON GmbH, Achim Degussa, Frankfurt Kronos Titan GmbH, Leverkusen Chemische Werke, Mnchen

(Antisettling agent with thixotropic effect) 10 % attack Bentone 38 Toluene Antiterra U (Byk Chemie, Wesel) weight units 10,00 85,00 5,00

Stirr under dissolver at 15 m/sec. till gel is formed (10 min.)

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.219009 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting formulation RR 63
2 K-Softfeel-Lacquer, aqueous, pigmented, based on Bayhydrol VP LS 2244/1 / Bayhydur 3100
RR 63 is corresponding to "KCS 1-09 " from

Bayer AG, Leverkusen.

________________________________________________________________________________________

Component 1
Position weight units Product

1 2 3 4 5 6 7 8 9 10 11 12

14,30 28,50 28,30 0,20 0,40 0,30 1,20 2,70 4,10 1,40 11,00 1,40

Bayhydrol VP LS 2244/1, app. 80 % Bayhydrol PR 240, app. 40 % Water, demineralized Defoamer DNE, form supplied Byk 348, form supplied Tegowet KL 245, 50 % in Water Aquacer 535, form supplied Sillitin Z 86 DEUTERON MK Talkum IT extra Bayferrox 318 M Matting agent OK 412

(1) (1)

(2) (3) (4) (3) (5) (6) (7) (1) (8)

Component 2
Position weight units Product

13

7,30 _______ 100,00

Bayhydur 3100, 75 %ig in 1-Methoxy-2-Propylacetat

(1)

Paint composition in %
app. 27,50 app. 45,50 app. 4,40 app. 20,60 app. 2,00 Binder Water Co-Solvent Pigment/Extender Additives

RR 63 Page 2/2

Characteristics
app. 1,50 app. 60 min app. 7,0 7,5 NCO/OH Potlife pH-Value

Recommendation for production and processing

Predisperse with mechanical stirrer and after that grind on a laboratory equipment (Red Devil). Temperature of the mill base should not be above 40 C. After the hardener has been added the mixture is adjusted to app. 30 sec efflue time (DIN ISO 2431, 5 mm nozzle) and sprayed conventionally.

Suppliers ( ( ( ( ( ( ( ( 1) 2) 3) 4) 5) 6) 7) 8) Bayer AG, Leverkusen K. Obermayer, Bad Berleburg Byk-Chemie, Wesel Tegochemie, Essen Hoffmann & Shne, Neuburg DEUTERON GmbH, Achim Norwegian Talc, Frankfurt Degussa, Frankfurt

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.219609 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting formulation RR 64
2 K-Softfeel-Finishing lacquer, black, flat, solvent borne, based on Synthalat A-HD 5667 /
Synthoester 1179 / Desmodur N 3390 RR 64 is corresponding to "Richtrezeptur S 1/11" from

Synthopol Chemie, Buxtehude.

________________________________________________________________________________________

Component 1
Position weight units Product

1 2 3 4 5 6

6,00 0,20 0,20 1,00 0,60 6,00

Synthalat A-HD 5667 Byk P 104 Aerosil R 972 FW 2 Lancowachs PE 1544 Butyl acetate

(1) (2) (3) (3) (4)

30 Min. Perlmill, degree of grinding < -- 10 Micron

7 8

4,00 2,00 ____ 20,00

Synthalat A-HD 5667 Butyl acetate

(1)

Component 2
Position weight units Product

9 10 11 12 13 14 15

36,00 12,40 0,80 0,80 4,00 4,00 8,00

Synthoester 1179 Butyl acetate Byk P 104 Aerosil 200 Syloid ED 30 PERGOPAK M3 Shellsol A

(1)

(2) (3) (5) (6)

Dissolver, degree of grinding < -- 10 Micron

RR 64 Page 2/2 16 12,00 Butyl acetate

17

2,00 _______ 80,00

DBTL 5 % in Xylene

Component 1 and Component 2 have to be mixed.

Blend of Component 1 and Component 2 is mixed with Desmodur N 3390 in a ratio 7 :1 Dilution: Adjust with app. 10 % Butyl acetate to app. 30 sec DIN 4.

Suppliers ( ( ( ( ( ( 1) 2) 3) 4) 5) 6) Synthopol Chemie, Buxtehude Byk Chemie, Wesel Degussa, Frankfurt/Main Lubrizol, Ritterhude Grace, Worms DEUTERON GmbH, Achim

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.019119 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting formulation RR 65
Aqueous 2 K-Softfeel-Finishing lacquer, black, flat, with wet touch, based on
Synthoester 98240 / Liopur 96055 / Bayhydur N 3100 RR 65 is corresponding to "Richtrezeptur S 6/119" from

Synthopol Chemie, Buxtehude.

________________________________________________________________________________________

Position

weight units

Product

1 2 3 4 5 6 7 8 9 10 11 12 13 14

42,00 3,50 1,00 0,50 1,00 1,00 2,50 6,50 0,50 1,00 2,50 30,00 4,00 4,00 _____ 100,00

Synthoester 98240 Proglyde DMM Drew Plus 4553 Byk 346 Ultraphobe 012 Aquacer 513 PERGOPAK M3 PERGOPAK M4 Tosperl 2000 Tego, Glide 410 Michem Emulsion 35160 Liopur 96055 Colanyl black N 131 Acrysol RM 8 (1 : 10)

(1)

(2)

(2) (3) (3)

(4)

(1)

15

20,00 ______ 120,00

Bayhydur N 3100 (80 % DMM)

(5)

Drying 30 Min. RT Gloss

30 Min 80 C 20 60 85 0,1 < 1,7 2,3

RR 65 Page 2/2 Crockmeter 100 x dry 10 x patrol 2 1 2

10 x Ethanol 96 %

Adhesion on ABS Cross cut test + transp. adh. tape

1/1 0/0

96 h water of condensation Adhesion after 1 h on ABS PA 0/0 0/0

Suppliers ( ( ( ( ( 1) 2) 3) 4) 5) Synthopol Chemie, Buxtehude Byk Chemie, Wesel DEUTERON GmbH, Achim Tego Chemie, Essen Bayer AG, Leverkusen

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.019119 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting formulation RR 66
Aqueous 2 K-Softfeel-Finishing lacquer, black, flat, with dry touch, based on
Synthoester 98240 / Liopur 96055 / Bayhydur N 3100 RR 65 is corresponding to "Richtrezeptur S 6/119" from

Synthopol Chemie, Buxtehude.

________________________________________________________________________________________

Position

weight units

Product

1 2 3 4 5 6 7 8 9 10 11 12

35,00 4,00 1,00 0,50 2,00 3,00 7,00 1,00 35,00 5,00 5,00 1,50 _____ 100,00

Synthoester 98240 Proglyde DMM Drew Plus 4553 Byk 346 Ultraphobe 012 PERGOPAK M3 PERGOPAK M4 Tego Glide 410 Liopur 96055 Colanyl black N 131 Acrysol RM 8 (1 : 10) dem. water

(1)

(2)

(3) (3) (4) (1)

12

20,00 ______ 120,00

Bayhydur N 3100 (80 % DMM)

(5)

Drying 30 Min. RT Gloss

30 Min 80 C 20 60 85 0,1 < 0,8 1,7

RR 66 Page 2/2 Crockmeter 100 x dry 10 x patrol 10 x Ethanol 96 % Adhesion on ABS Cross cut test + transp. adh. tape 0/0 0/0 0 1 1

96 h water of condensation Adhesion after 1 h on ABS PA 0/0 0/0

Suppliers ( ( ( ( ( 1) 2) 3) 4) 5) Synthopol Chemie, Buxtehude Byk Chemie, Wesel DEUTERON GmbH, Achim Tego Chemie, Essen Bayer AG, Leverkusen

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.019119 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting Formulation RR 69
Aqueous 2 K-Softfeel-Finishing lacquer, black,
based on Daotan VTW 6420/75NMP / Daotan VTW 6430/35WANMP / Bayhydrol N 3100

RR 69 is corresponding to "Anhaltsrezeptur A 5758" from

Vianova Resins AG, A-Graz

________________________________________________________________________________________

Part I
Position weight units Product

1 2 3 4 5

13,30 4,80 0,30 0,50 1,50

Daotan VTW 6420/75NMP dem. water Additol XL 250 Additol VXW 6208 Special black 4 (wetting- and dipersing agent) (wetting- and dipersing agent)

(1)

(1) (1) (2)

Part II 6 7 8 9 10 22,90 18,40 0,30 4,20 4,20 Daotan VTW 6430/35WANMP dem. water Defoamer DNE Matting agent OK 412 PERGOPAK M4 (3) (2) (4) (1)

Part III 11 12 13 14 19,90 7,20 0,50 2,00 ______ 100,00 Daotan VTW 6420/75NMP dem. water Byk 346 Additol VXW 6360 (substrate wetting agent) (thickening agent) (5) (1) (1)

Part IV

10,00

Bayhydur N3100

(3)

RR 69 Page 2/2

Production:
Part I is grinded for 1 h on a bead mill, Part II is dispersed with dissolver for 30 min. After that the Parts I, II and III have to be blended homogeniously with a laboratory-mixer and adjusted with the dimethylethanolamin (DMEA) on a pH-value of 7,8 - 8,0. Part IV has to be stirred in shortly before processing.

Solid including hardener VOC (ASTM D 3960-93) Efflue time DIN EN ISO 2431/4mm nozzle/23 C Pigment/Binder Spraying thinner Drying conditions Flash Point
o

: app. 51 % : app. 245 g/L : app. 180 s : app. 0,2 : 1 : dem. water : 5 min flash off, 30 min 80 C : non-inflammable

Producer/Supplier ( ( ( ( ( 1) 2) 3) 4) 5) Vianova Resins AG Degussa, Frankfurt Bayer AG, Leverkusen DEUTERON GmbH Byk Chemie GmbH

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.000930 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting Formulation RR 71
Solvent based 2 K-Softfeel-Finishing lacquer, black
Based on Synocure 868 SD, 60 % X/MPA/Desmodur N 75

RR 71 is corresponding to "231 D-0051 RZ/887" from

Cray Valley, D-Zwickau

________________________________________________________________________________________

Part A
Position weight units Product

1 2 3 4 5 6 7 8 9

36,07 7,80 2,06 3,61 1,25 2,06 1,03 38,80 0,50

Synocure 868 SD, 60 % X/MPA Bayferrox 318 M Aluminiumsilikat P 820 DEUTERON MK Matting agent OK 412 Bentone 38, 10 % preparation Dibutylzinndilaurat, 1 % in BA Butylacetat Byk 306

(1) (2) (3) (4) (3) (5) (6)

(7)

Part B
10 6,82 _______ 100,00 Desmodur N 75 (2)

Spray viscosity / ALZ DIN 4: Potlife: Drying :

app. 30 s 3,5 h Dust-dry: Through-drying: app. 30 Min 6h

RR 71 Page 2/2 Producer/Supplier ( ( ( ( ( ( ( 1) 2) 3) 4) 5) 6) 7) Cray Valley Kunstharze GmbH, Zwickau Bayer AG, Leverkusen Degussa AG, Frankfurt DEUTERON GmbH, Achim Kronos Titan GmbH, Leverkusen Chemische Werke, Mnchen Byk-Chemie GmbH, Wesel

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.100770 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting Formulation RR 72
Solvent based 2 K-Softfeel-Finishing lacquer, black
Based on Synocure 868 SD, 60 % X/MPA/Synolac 670, 80 % BA/Desmodur N 75

RR 72 is corresponding to "231 D-0052 RZ/888" from

Cray Valley, D-Zwickau

________________________________________________________________________________________

Part A
Position weight units Product

1 2 3 4 5 6 7 8 9 10

19,55 14,44 8,46 2,23 3,91 1,36 2,23 1,12 35,12 0,49

Synocure 868 SD, 60 % X/MPA Synolac 670, 80 % BA Bayferrox 318 M Aluminiumsilikat P 820 DEUTERON MK Matting agent OK 412 Bentone 38, 10 % preparation Dibutyltindilaurat, 1 % in BA Butylacetat Byk 306

(1) (1) (2) (3) (4) (3) (5) (6)

(7)

Part B
11 11,09 _______ 100,00 Desmodur N 75 (2)

Spray viscosity / ALZ DIN 4: Potlife: Drying:

app. 30 s 3h Dust-dry: Through-drying: app. 30 Min 8h

RR 72 Page 2/2

Lieferanten ( ( ( ( ( ( ( 1) 2) 3) 4) 5) 6) 7) Cray Valley Kunstharze GmbH, Zwickau Bayer AG, Leverkusen Degussa AG, Frankfurt DEUTERON GmbH, Achim Kronos Titan GmbH, Leverkusen Chemische Werke, Mnchen Byk-Chemie GmbH, Wesel

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.100770 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting Formulation RR 83
2-K water borne Soft-feel-clear lacquer, mat.
Based on Bayhydrol VP LS 2273 : Bayhydrol VP LS 2305 // Bayhydur 3100 : Bayhydur VP LS 2306 (7 : 3) RR .. is corresponding to "KCS 36-329 from Bayer AG, D-Leverkusen" ________________________________________________________________________________________

Part 1
Position weight units Product

1 2 3 4 5 6 7 8 9 10

28,90 39,60 9,90 0,20 0,50 0,50 1,60 3,70 5,60 1,90

Bayhydrol VP LS 2273, app. 55 % (form supplied) Bayhydrol VP LS 2305, app. 40 % (form supplied) Demineralized water. Defoamer DNE, Lff. Byk 348 (form supplied) Tego-Wet KL 245, 50 % solution in water Aquacer 535 (form supplied) Silitin Z 86 Pergopak M 3 Matting agent OK 412

(1) (1)

(2) (3) (4) (3) (5) (6) (7)

Part 2 12 7,60 ______ 100,00 Bayhydur 3100 / Bayhydur VP LS 2306 (7 : 3), 75 % in 1-methoxy-2-propyl acetate (1)

RR 83 Page 2/2 Lacquer composition in % Binder Water Co-solvent Matting agent Additives ca. 37,4 ca. 46,9 ca. 1,9 ca. 11,2 ca. 2,6

Paint technological characteristics: NCO/OH Potlife PH-value ca. 1,5 ca. 60 min ca. 6,5-7,5

Note on producing and processing: The base lacquer has been produced by predispersion and following grinding process with laboratory shaker (Red Devil- 10 min in max. is recommended). Temperature of the mill base should not pass 40 C. After crosslinker is added the paint-system is adjusted on 30 s flow time (DIN ISO 2431, 5 mm nuzzle) and sprayed conventional.

Producer/Supplier: ( 1) ( 2) ( 3) ( 4) ( 5) ( 6) ( 7) Bayer AG, D-Leverkusen K.Obermayer, D-Bad Berleburg BYK-Chemie, D-Wesel Tegochemie, D-Essen Hoffmann & Shne, D-Neuburg DEUTERON GmbH, D-28832 Achim DEGUSSA; D-Frankfurt

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.214002 ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting formulation RR 87
Solvent-borne

one component polyurethane-stoving soft-feel coating, grey, mat AG, D-51368 Leverkusen

based on Desmophen 1652 / Desmodur BL 3175 RR 87 is corresponding to RR 6837 from Bayer

________________________________________________________________________________________ Formula for grinding in bead mill (fineness of grind < 5 microns)
Position Weight units Product

1 2 3 4 5 6 7

301,00 86,50 4,30 0,60 0,50 24,90 62,20

Desmophen 1652, 100 % Kronos 2160 Heucodur-Gelb 5R Heucodur-Blau 4G Spezialschwarz 4 Silitin Z 86 Cellulose acetobutyrate CAB 531-1, 10 % in Solvesso 200 S/butyl diglykol (2 : 1) Acronal 4 F, 50 % in Solvesso 200 S Bentone 38, 10 % in Solvesso 200 S/Anti Terra U (85 : 5) Solvesso 200 S

( 1) ( 2) ( 3) ( 3) ( 4) ( 5) ( 6)

12,40

( 7)

24,90

( 2) ( 8)

10 Let-down 11

182,70

107,50

Desmodur BL 3175, 75 % in solvent naphtha Dibutyltin dilaurate, 10 % Lanco-Wax TF 1778 DEUTERON MK ACE-matt OK 412 Solvesso 200 S

( 1)

12 13 14 15 15

12,40 19,60 36,50 14,70 109,30 ______ 1000,00

( 9) (10) (11) ( 4)

RR 87 Page 2/2 Technical data Binder Pigment Additives Matting agents Solvents NCO/OH ratio Pigment/binder ratio Solids content (% by weight) o Flow time, DIN EN ISO 2431 mit 5 mm Dse/23 C Stoving cycle o Gloss Gardner 60 Additives / Mattings agents (active substance calculated on solid binder) Dibutyltin dilaurate Cellulose acetobutyrate CAB 531-1 Acronal 4 F DEUTERON MK Lanco Wax TF 1778 ACE-matt OK 412 Remarks The PMT must be increased significantly if DBTL is not added as a catalyst. The combination of CAB 531-1 and Acronal 4 F ensures good aeration and flow properties 38,2 11,7 02,0 07,1 41,0 1:1 0,31 : 1 ca. 59 ca. 100 s o PMT 232 C ca. 4 % % by weight 0,3 1,6 1,6 9,6 5,1 3,9

Producer/Supplier: ( 1) ( 2) ( 3) ( 4) ( 5) ( 6) ( 7) ( 8) ( 9) (10) (11) Bayer AG, Leverkusen Kronos International INC, D-Leverkusen Heubach, D-Langelsheim Degussa, D-Frankfurt/Main Hoffmann Mineral GmbH, D-Neuburg Krahn Chemie, D-Hamburg BASF AG, D-Ludwigshafen Byk-Chemie GmbH, D-Wesel Brenntag, D-Mlheim/Ruhr Lubrizol, D-Ritterhude DEUTERON GmbH, D-Achim

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. ________________________________________________________________________________________

DEUTERON GmbH
Postfach 16 45*D-28822 Achim*HRB Walsrode 120187*Telefon ++49 (0)421 / 48 32 27*Telefax ++49 (0)421 / 48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting formulation RR 88
Solvent-borne

one-component polyurethane stoving soft-feel coating, redbrown, AG, D-51368 Leverkusen

mat based on Desmophen 1652 / Desmodur BL 3175 RR 88 is corresponding to guide formulation 6835 from Bayer

________________________________________________________________________________________

Formula for grinding in bead mill (fineness of grind < 5 microns)

Position Weight units Product

1 2 3 4 5 6 7

301,00 10,20 8,80 69,40 3,50 24,90 62,20

Desmophen 1652, 100 % Kronos 2160 Lichtgelb 6R Bayferrox 130M Flammru 101 Silitin Z 86 Celluloseacetobutyral CAB 531-1, 10 % in Solvesso 200 S/butyl diglykol (2 : 1) Acronal 4 F, 50 % in Solvesso 200 S Bentone 38, 10 % in Solvesso 200 S/Anti Terra U (85 : 5) Solvesso 200 S

( 1) ( 2) ( 1) ( 1) ( 3) ( 4) ( 5)

12,40

( 6)

24,90

( 2) ( 7)

10 Let-down 11

182,70

107,50

Desmodur BL 3175, 75 % in solvent naphtha Dibutyltin dilaurate, 10 % Lanco-Wax TF 1778 DEUTERON MK ACE-matt OK 412 Solvesso 200 S

( 1)

12 13 14 15 15

12,40 19,60 36,50 14,70 109,30 ______ 1000,00

( 8) ( 9) (10) ( 3)

RR 88 Page 2/2 Technical data Binder Pigment Additives Matting agents Solvents NCO/OH-ratio Pigment / binder ratio Solids content (% by wt.) o Flow time, DIN EN ISO 2431 mit 5 mm Dse/23 C Stoving cycle o Gloss Gardner 60 Additives (active substance calculated on solid binder) Dibutyltin dilaurate Cellulose acetobutyrate CAB 531-1 Bentone 34 Anti Terra U Acronal 4 F DEUTERON MK Lanco Wax TF 1778 ACE-matt OK 412 Remarks The PMT must be increased significantly if DBTL if not added as a catalyst. The combination of CAB 531-1 and Acronal 4 F ensures good aeration and flow properties. The soft-feel effect can be adjusted individually by increasing the amount of organic matting agent DEUTERON MK. Producer/supplier: ( 1) Bayer AG, Leverkusen ( 2) Kronos International INC, D-Leverkusen ( 3) Degussa AG, D-Frankfurt/Main ( 4) Hoffmann & Shne KG, D-Neuburg ( 5) Krahn Chemie, D-Hamburg ( 6) BASF AG, D-Ludwigshafen ( 7) Byk-Chemie GmbH, D-Wesel ( 8) Brenntag, D-Mlheim/Ruhr ( 9) Lubrizol, D-Ritterhude (10) Deuteron GmbH, D-Achim 38,2 11,7 03,5 05,1 41,5 1:1 0,31 : 1 ca. 59 ca. 100 s o PMT 232 C ca. 4 % % by weight 0,3 1,6 0,7 0,3 1,6 9,6 5,1 3,9

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

Starting Formulation RR 95
2-Component-Softtouch-Clearcoat, solvent borne,
based on Synthalat A-HD 5667 / Synthoester 1179 / Desmodur N 3390 RR 95 is corresponding to "Startingformulation S 1/11" from

Synthopol Chemie, Buxtehude.

____________________________________________________________________________________

Main component
Position weight units Product

Supplier (1) (1) (2) (3) (4) (4)

1 2 3 4 5 6

10,00 36,00 0,20 7,00 0,20 0,80

Synthalat A-HD 5667 Synthoester 1179 Disperbyk 163 PERGOPAK M3 Aerosil R 972 Aerosil 200

Dissolver, Fineness approx. 20 m 7 8 9 10 11 12,00 8,00 1,00 1,00 23,80 _______ 100,00 Butylacetate Shellsol A DBTL 10 %ig in Xylol Byk 333 10% in Butylacetate Butylacetate (5) (5) (6) (2) (5)

Hardener:
Mix ratio: 7 : 1 with Desmodur N 3390 (7)

RR 95 Page 2/2

Characteristics
Binder solid Resulting mixed solid content Additives Texture- Matting-Agent Solvents 42,5 % 48,4 % 2,2 % 8,0 % 48,3 %

Processing:
Thinner/Diluent Drying: 10-15%b.w. with Butylacetate to app. 30 sec DIN 4 at roomtemperature app. 20C over night or 4 hours air at roomtemperature, then forced drying at 30-50C with air circulating oven. app. 4h

Potlife:

Producers/Suppliers (1) (2) (3) (4) (5) (6) (7) Synthopol Chemie, D-Buxtehude Byk Chemie, D-Wesel DEUTERON GmbH, D-Achim Degussa GmbH, D-Frankfurt/Main Biesterfeld GmbH, D-Hamburg Air Products Nederlands BV, NL-Utrecht Bayer AG, D-Leverkusen

This starting formulation is given without obligation. Proprietary rights of third parties should be taken into consideration by the customer. 01.231007

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com *** Internet: http://www.deuteron.com

Page 1/2

D E U T E R O N MK
Micronized mattingplastic
________________________________________________________________________________________

Chemical Description
Polycondensate plastic

Application
It comes into consideration practically all waterbased and solvent-based systems; as well air-drying as stoving, but also printing inks, wood lacquers and UV-curing coatings.

Physical Data
Appearance Bulk Density Density Particle size d50 Particle size d90 Flash Point fine white powder app. 150 g/l app. 1,40 g/cm
3

Dosage
The quantity depends first of all on the requested gloss and the used binder. Additions of 1,0 - 7,0 % calculated on total formulation are known from practice. The exact dosage should be determined by own trials.

app. 6,3 micron app. 13,8 micron does not apply

Processing
Because of its excellent dispersing properties DEUTERON MK can be stirred into the liquid phase with a simple stirrer. This passes for waterbased and solvent-based systems. It is also possible to grind DEUTERON MK with the mill base to obtain an optimum of dispersion in paints containing pigments or fillers.

Properties
DEUTERON MK is a micro-powder. The fineness makes possible to use DEUTERON MK in a wide field of applications for processing satin-flat and satin-gloss coatings. The small binder demand of DEUTERON MK leads only to a nonessential viscosity influence, which is significant for UV-current lacquers. DEUTERON MK is resistant against solvents and chemicals which are customary in the paint industry. Weather resistance and light stability are most favourable. DEUTERON MK has no or only a short influence on the coating transparency in the most binders. DEUTERON MK shows a heat resistance of more than 200 C. It is suitable for the use in waterbased coatings to decrease the blocking without worsening of the recoatability. The surface properties can be increased in some cases by using a combination of DEUTERON MK with a suitable wax, e.g. DEUTERON-WAX PP or DEUTERON-WAX TF.

Storage conditions
The storage stability of DEUTERON MK is at least 24 months at room temperature and dry conditions.

Packaging
Paper bag (10 kgs net)

Safety techn. characteristics

DEUTERON MK is according to the guiding principle 67/548/EEC no dangerous product and has not to be marked. Because it is a fine powder, the dust regulations must be taken into account and electrostatical charging has to be avoided.

Page 2/2

This leaflet intends to give techn. advice, but without warranty and does not claim to be complete. ________________________________________________________________________________________ Leaflet: Revision: 06-MK-M 04.283006 The current version of the leaflet can also be found in the internet under: http://www.deuteron.com e-Mail: contact@deuteron.com

Standard sample size: ca. 200 g Additional sample size(s): ca. 1000 g Technical samples: after consultation ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421 / 48 32 27*Fax ++49 (0)421 / 48 36 02

PERGOPAK M 3

Einsatzbeispiele / Applications

PERGOPAK wird als Lackhilfsmittel mit mattierenden Eigenschaftenschaften in der Lackindustrie eingesetzt. Die Hauptvorteile sind: intensive Mattierungswirkung geringe Rheologiebeeinflussung Verbesserung der Kratzfestigkeit Elastizitt, Adhsion, Witterungs-, Temperatur- und Glanzstabilitt. PERGOPAK is used as a matting and effects agent for the paint and varnish industry. Its main advantages are: high matting efficiency low impact on rheology improved scratch and abrasion resistance improvement of adhesion and elasticity excellent weather resistance and gloss retention

Durchschnittsanalyse / Typical analysis

Chemische Konstitution / Chemical composition

Polymethylharnstoffharz mit ca. 0,6 % freien Methylolgruppen Polymethyl urea resin with approx. 0.6 % reactive methylol groups [g/cm3] [kg/m3] [kg/m3] d50 d90 d100 [m] [m] [m] [m2/g] [cm3/100g] 1.47 ca. 80 ca. 200 6 8.5 15 19 36 14 22 ca. 310 1.607 [%] [C] Jahre / years 83 > 220 >1

Dichte / Density Schttdichte / Bulk density Spez. Verpackungsgewicht (gepresst) / Packed bulk density (compressed) Teilchengre (Laser Beugung) / Particle Size (laser diffraction)

Spezifische Oberflche (BET) / Specific surface (BET) laufnahme / Oil absorption Brechungsindex / Refractive index Feststoff-Gehalt / Solid content Zersetzungstemperatur / Decomposition temperature Lagerstabilitt / Storage stability

Stand / Issue: 12.02 D

Die oben genannten Werte sind nur als Richtwerte zu verstehen und nicht etwa als zugesicherte Eigenschaften. The above mentioned values should be taken only as indications and not as guaranteed properties.

Shipping Information

Transportation classification: not regulated for transportation Harmonized tariff number: 39091000 Packaging and minimum order quantity information is available from sales or customer service.

Safety and Handling Information

For specific safety, toxicity and handling information, please refer to the material safety data sheet on this product.

Chemical Registration Numbers

CAS No. : 9011-05-6 EC-/EINECS No.: Polymer Exempt ENCS: 7-576 ECL KE-35175

Vertrieb in Europa Distribution in Europe DEUTERON GmbH www.deuteron.com Fax: ++49 (0) 421 48 36 02 E-Mail: contact@deuteron.com

AMERICAS Albemarle Corporation 451 Florida Street Baton Rouge, Louisiana 70801-1765 Phone: 225-388-7402 Toll-Free: 800-535-3030 Fax: 225-388-7848

ASIA PACIFIC Albemarle Asia Pacific Company 111 Somerset Road # 13-03 Singapore 238164 Phone: 65-6732-6286 Fax: 65-6737-4155 Albemarle Asano Corporation 16th Floor, Fukoku Seimei Building 2-2, Uchisaiwaicho, 2-Chome Chiyoda-ku, Tokyo 100, Japan Phone: 81-3-5251-0791 Fax: 81-3-3500-5623 China World Tower, Room 1317 No. 1 Jian Guo Men Wai Avenue Beijing 100004 China Phone: 86-10-6505-4153 and -54 Fax: 86-10-6505-4150 INTERNET www.martinswerk.de www.albemarle.com

, ALBEMARLE, MARTINSWERK, PERGOPAK are trademarks of Albemarle Corporation The information presented herein is believed to be accurate and reliable, but is presented without guarantee or responsibility on the part of Albemarle Corporation. It is the responsibility of the user to comply with all applicable laws and regulations and to provide for a safe workplace. The user should consider any health or safety hazards or information contained herein only as a guide, and should take those precautions which are necessary or prudent to instruct employees and to develop work practice procedures in order to promote a safe work environment. Further, nothing contained herein shall be taken as an inducement or recommendation to manufacture or use any of the herein materials or processes in violation of existing or future patents.

EUROPE, MIDDLE EAST, AFRICA Albemarle Europe SPRL Parc Scientifique Einstein Rue du Bosquet 9 B-1348 Louvain-la-Neuve Sud, Belgium Phone: 32-10-48-1711 Fax: 32-10-48-1717 Martinswerk GmbH Klner Strae 110 D-50127 Bergheim Phone: 49-2271-902-424 Fax: 49-2271-902-557

(03/03) 2003 Albemarle Corporation

Page 1/2

D E U T E R O N PMH C
Organic matting agent / micronized thermoset
________________________________________________________________________________________

Chemical Description
Polymethylurea

DEUTERON PMH C is resistant to most of customary solvents being used in the coating industry. The product offers also good chemical resistance. DEUTERON PMH C is resistant to temperature above 200 C. Colour fastness and weather resistance are excellent. The use in exterior application is possible practically without limitation. The coatings are recoatable. DEUTERON PMH C is free of waxes. In certain fields of application the product effectiveness in matting can be increased by combination with small amount of Si02.

Physical Data
Appearance Oil absorption value fine, white powder app. 167 g/100 g DIN ISO value 787/5 with Palatinol N app. 220 kg/m ca. 1,4 g/cm
3 3

Bulk density Density Water absorption value Particle size d50 Particle size d90 Flashpoint

app. 215 g/100 g

Application
DEUTERON PMH C can be used as matting agent in aqueous and solvent based coating systems. With partially use of SiO2 a suitable matting agent combination can be created for solvent free, radiation curing varnishes. With its favourable oil absorption value the product is predestinated for coatings with high flexibility, for instance coil coatings and leather finishes.

app. 5,5 micron app. 12,1 micron does not apply

Properties
DEUTERON PMH C (compact) is a micronized, pure thermoset with compact particle structure. Due to its excellent fineness the product can be used in a wide application for matting of varnishes and coatings or as an additive. The products specific oil absorption value gives even at high dosage favourable results regarding viscosity increase. Flexibility of the coating will be spoiled only insignificant by the use of DEUTERON PMH C as matting agent. As a thermoset DEUTERON PMH C increases in many cases the blocking stability of coatings, when the character of the used binder shows tendency to thermoplasticity.

In powder coatings the presence of DEUTERON PMH C can improve fluidity and spraying property of the powder coating.

Dosage
The optimum in dosage is depending on the required degree of gloss and the character of the used binder. The addition can be in the range of 1.0 7.0 %. The optimum in dosage should be determined by own trials.

Processing
Due to its excellent dispersing properties DEUTERON PMH C can be easily incorporated with mechanical stirrer or dissolver. Attention has to be paid on sufficient rate of shear. This applies also for aqueous lacquers systems. Use of wetting

Page 2/2

(still) Processing
agent is generally not necessary. Due to the good temperature resistance DEUTERON PMH C can be also added to the mill base.

Safety techn. characteristics

DEUTERON PMH C is according to the guiding principle 67/548/EEC no dangerous product and has not to be marked. Because it is a fine powder, the dust regulations must be taken into account and electrostatical charging has to be avoided.

Storage conditions
The storage stability of DEUTERON PMH C is at least 24 months at room temperature and dry conditions.

Packaging
Paper bag (15 kgs net)

This leaflet intends to give techn. advice, but without warranty and does not claim to be complete. ________________________________________________________________________________________ Leaflet: Revision: 06-PMH C-M 03.283006 The current version of the leaflet can also be found in the internet under: http://www.deuteron.com e-Mail: contact@deuteron.com

Standard sample size: app. 200 g Additional sample size(s): app. 1000 g Technical samples: after consultation ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421 / 48 32 27*Fax ++49 (0)421 / 48 36 02

Safety data sheet in accordance with 2001/58/EEC.

DEUTERON MK 01. Identification of the substance/preparation and company. Product name: DEUTERON version: 17.06.2002 Page 1 of 3

MK

DEUTERON GmbH In den Ellern 2 D - 28832 Achim

Application Micronized mattingplastic Divisions : technical office, 0421 / 483227 Emergency telephone number : laboratory, 0421 / 483227

02. Composition/information on ingredients.

chemical characterisation Methylendiaminomethylether-polycondensate

03. Hazards possibilities.

No particular hazards known. Does not require a hazard labelling warning label, but the normal safety precautions for handling of chemicals must be observed.

04. First aid measures.

general information No toxic effects observed in human beings. skin contact Rinse with lots of water. eye contact In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice. Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Let plenty of water be drunk in small gulps. Call in a physician immediately and show him the Safety Data Sheet.

05. Fire-fighting measures.

Suitable extinguishing media Water / foam / ABC powder / carbon dioxide. Extinguishing media that must not be used for safety reasons None Special exposure hazards arising from the substance or preparation itself, its combustion products or from resulting gases In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO). Combustion gases of organic materials must in principle be graded as inhalation poisons. Special protective equipment for firefighting Use self-contained breathing apparatus. Additional information Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

06. Accidental release measures.

personal precautions Use personal protective clothing. Avoid dust formation. Knock down dust with water spray jet. environmental precautions not determined methods for cleaning up/taking up Pick up mechanically. When picked up, treat material as prescribed under heading "Disposal". Additional information Information regarding Safe handling, see chapter 7. Information regarding personal protective measures see, chapter 8. Information regarding Waste Disposal, see chapter 13.

Safety data sheet in accordance with 2001/58/EEC.

DEUTERON MK 07. Handling and storage.
Observe the usual precautions for handling chemicals. Hints on safe handling Air cleaning with filter of room for dust removable. Hints for protection against fire and explosion Observe the general rules of industrial fire protection. Requirements for storage rooms and vessels No special measures required. Storage stability Storage time: 24 months.

version: 17.06.2002 Page 2 of 3

08. Limit exposure and provide personal protection equipment for personnel.
Additional hints on technical system design See chapter 7; no measures exceeding the ones mentioned are necessary. Hygienic measures Do not eat or drink during work time. Do not smoke during work time. EINECS 271-898-1 components urea-formaldehyde-copolymer Dust mask Gloves safety glasses light protective clothing value unit 6,00 mg/m3

Respiratory protection: Hand protection: Eye protection: Skin protection_

09. Physical and chemical properties.

Appearance Form: Colour: Odour: Safety data method Flash point Density Ignition temperature Lower explosion limit Upper explosion limit Vapour pressure (20C) Solubility in water n.a.: not applicable >200 C app. 1,40 g/cm3 >350C n.a. n.a. n.a. insoluble DIN 51757 (20C) Powder white slightly perceptible

10. Stability and reactivity.

Hazardous reactions The product is not a dust explosion risk as supplied; however the build-up of fine dust can lead to a risk of dust explosions. Hazardous decomposition products No hazardous decomposition products known.

11. Toxicological information.

other data From factory experience: No skin or mucous membrane irritation or sensitisation.

12. Ecological information.

Product is insoluble in water.

Safety data sheet in accordance with 2001/58/EEC.

DEUTERON MK 13. Disposal considerations.
Product May be taken to waste disposal site or incineration plant, with household waste. Rules of the local authorities must be observed. European wastecataloge The declaration of the wastenumber must be specified by the branch or process in accordance with the EWC regulations. contaminated packagings Completely empty packaging may be treated as household waste.

version: 17.06.2002 Page 3 of 3

14. Transport information.

GGVSee/IMDG-Code : GGVE/GGVS : not classified UN-NR : ADR/RID : not classified ICAO/IATA : ADNR : -

Dispatch by post (for Germany only) : Permitted.

15. Regulatory information.

Labelling in accordance with GefStoffV/EC. The product does not require a hazard warning label in accordance with EC directives/German regulations on dangerous substances. National requirements VbF - class : BAG-T No.: 614100

16. Other information.

Observe national and local legal requirements Sources of documentation Technical safety Constants Sorbe Merck Index Welzbacher Listings All materials involved of the product are specified in the following lists: TSCA(USA) EINECS(EUROPE) DSL(CANADA) ENCS(JAPAN) AICS(AUSTRALIA) ECL(KOREA) PICCS(Philippins) Laws, guidelines and recommendations This product corresponds to the following guidelines: - Lebensmittel- und Bedarfsgegenstndegesetz 30 und 31 - BGVV XL - BGVV XXXVI - DIN EN 71 Chapter 3 - FDA 21 CFR Ch I, 176.170 und 176.180 - 90/128/EWG Changes to the previous version Modification to the guideline (RL 2001/58/EG of 27.07.2001) Modification in Chapter 1, 2, 15, 16

All information in this document are concerning the safety requirements of the product. All details are based on our best knowledge to the current situation. However, they do not apply as assurance for quality of the product with regard to liability resp. Guarantee. All details are given without obligation.

Safety data sheet in accordance to 2001/58/EEC.

P E R G O P A K M3 01. Identification of the substance/preparation and company. Trading name: P revised on 10.10.2002 page 1 of 4

E R G O P A K M3

Martinswerk GmbH Klner Str. 110 D-50127 Bergheim

Application Micronized mattingplastic Divisions: Environmental department Tel.: ++49-2271-902-223 Quality department Tel.: ++49-2271-902-301 Emergency telephone number : Stand-by duty Tel.: ++32 (0)70 233 201

02. Composition/information on ingredients.

chemical characteristic Urea-formaldehyde condensation polymer with app. 15 % water CAS-No. : 9011-05-6 and 68611-64-3 EINECS-No. : 271-898-1 UN-No. : none CAS 50-00-0 component Formaldehyde (H2CO) part % <0,1% symbol R-phrases/other

03. Hazards possibilities.

The product contains no substances classified as hazardous to health in concentrations which should be taken into account.

04. First aid measures.

general information No toxic effects observed in human beings. Inhalation Move to fresh air. If symptoms persist, consult a physician. skin contact Wash off immediately with soap and plenty of water. In case of irritations consult a physician. eye contact Rinse eyes with plenty of water. If eye irritation persists, consult a specialist. ingestion Rinse mouth, drink plenty of water. Do not induce vomiting. Consult a physician.

05. Fire-fighting measures.

Suitable extinguishing media Extinguish with carbon dioxide, dry chemical, foam or waterspray. Extinguishing media that must not be used for safety reasons None. Special exposure hazards arising from the substance or preparation itself, its combustion products or from resulting gases In case of combustion, noxious or irritating gases may be formed. Special protective equipment for firefighting Wear self-containing breathing apparatus and protective suit.

06. Accidental release measures.

personal precautions Avoid dust formation. Use personal protective equipment. methods for cleaning up/taking up Remove spilt product using normal cleaning devices.

Safety data sheet in accordance to 2001/58/EEC.

P E R G O P A K M3 07. Handling and storage.
Observe the usual precautions for handling chemicals. Hints on safe handling Avoid dust formation. Requirements for storage rooms and vessels Keep tightly closed in a dry and well-ventilated place. No shelf-life limitation under suitable conditions; no chemical alteration. Storage stability Storage time: 24 months.

revised on 10.10.2002 page 2 of 4

08. Limit exposure and provide personal protection equipment for personnel.
Additional hints on technical system design See chapter7; no measures exceeding the ones mentioned are necessary. Hygienic measures General industrial hygiene practice. CAS 50-00-0 Respiratory protection Hand protection Eye protection Skin protection component Formaldehyde General dust exposure limi exposure limit 0,6 mg/m3 6,0 mg/m3 fine dust (alveoli accessible)

Wear dust mask in case of intense formation of dust. Wear impervious gloves in case of direct skin contact. Protective glasses Lightweight protective clothing

09. Physical and chemical properties.

Appearance Form: Colour: Odour: Safety data method melting point flash point density upper explosive properties lower explosive properties solubility in water pH-value Not meltable; thermal decomposition >200C app.1,47 g/cm3 not explosive not explosive practically insoluble app. 8 Powder. white. slightly perceptible.

10. Stability and reactivity.

Thermal decomposition At temperatures above 200 C; decomposition without melting. Hazardous reactions None Hazardous decomposition products Formaldehyde

Safety data sheet in accordance to 2001/58/EEC.

P E R G O P A K M3 11. Toxicological information.
General information In animal tests (rabbits) no eye or skin irritation was observed. Nevertheless sensitization / irritation by frequent skin contact may be possible. The product is (e. g. in packaging materials) suitable for use with foodstuffs. For formaldehyde: On the basis of animal tests (rats, mice) formaldehyde is considered a possible carcinogen. Acute oral toxicity PERGOPAK M3 Experiences from practice Eye irritation caused by mechanical effect. LD50 > 5000 mg/kg (rat)

revised on 10.10.2002 page 3 of 4

12. Ecological information.

Elimination Product of low solubility; mechanical separation.

13. Disposal considerations.

Disposal / product May be taken to waste disposal site or incineration plant, with household waste. Rules of the local authorities must be observed. Disposal / contaminated packagings Completely empty packaging may be treated as household waste.

14. Transport information.

GGVSee/IMDG-Code : GGVE/GGVS : not classified not classified UN-NR. : ADR/RID : not classified ICAO/IATA : ADNR : not classified n. d.

Transport / dispatch by post (for Germany only). Permitted n. d.: not declared

15. Regulatory information.

Labelling in accordance with GefStoffV/EC The product does not require a hazard warning label in accordance with EC directives/the relevant national laws. National regulations Wassergefhrdungsklasse WGK 1 (self estimation) WGK = classification in accordance with the German Water Resources Act

Safety data sheet in accordance to 2001/58/EEC.

P E R G O P A K M3 16. Other information
Observe national and local legal requirements. Laws, directives and recommendations The products are in compliance with the following rules: - Lebensmittel- und Bedarfsgegenstndegesetz 30 und 31 - BGVV XL - BGVV XXXVI - Tabakverordnung - DIN EN 71 Part 3 - FDA 21 CFR Ch I, 176.170 und 176.180 - 90/128/EEC - Warenwet Sources of documentation Technical safety Constants. Sorbe Merck Index Welzbacher. Changes to the previous version Modification to the guideline (RL 2001/58/EG of 27.07.2001) Modification in Chapter 1, 16 Note Because this safety data sheet deals with products which are non-hazardous substances / preparations, the EC directives mentioned in the heading do not apply to them. They are used for orientation only. The safety data sheet was printed in order to meet the customers requirements for information. No service of exchange is maintained as long as the classification of the products in the register of hazards is not changed. This safety data sheet was printed from computer data. It is valid without signature.

revised on 10.10.2002 page 4 of 4

The information contained herein is believed to be reliable and based on the current state of our knowledge. However, no guarantees of any kind can be given to its accuracy.

Safety data sheet in accordance with 2001/58/EEC.

DEUTERON PMH C 01. Identification of the substance/preparation and company. Product name: DEUTERON version: 18.06.2002 Page 1 of 3

PMH C

DEUTERON GmbH In den Ellern 2 D - 28832 Achim

Application Organic matting agent / micronized thermoset. Divisions : technical office, 0421 / 483227 Emergency telephone number : laboratory, 0421 / 483227

02. Composition/information on ingredients.

chemical characterisation Methylendiaminomethylether-polycondensate

03. Hazards possibilities.

No particular hazards known. Does not require a hazard labelling warning label, but the normal safety precautions for handling of chemicals must be observed.

04. First aid measures.

general information No toxic effects observed in human beings. skin contact Rinse with lots of water. eye contact In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice. Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Let plenty of water be drunk in small gulps. Call in a physician immediately and show him the Safety Data Sheet.

05. Fire-fighting measures.

Suitable extinguishing media Water / foam / ABC powder / carbon dioxide. Extinguishing media that must not be used for safety reasons None Special exposure hazards arising from the substance or preparation itself, its combustion products or from resulting gases In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO). Combustion gases of organic materials must in principle be graded as inhalation poisons. Special protective equipment for firefighting Use self-contained breathing apparatus. Additional information Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

06. Accidental release measures.

personal precautions Use personal protective clothing. Avoid dust formation. Knock down dust with water spray jet. environmental precautions not determined methods for cleaning up/taking up Pick up mechanically. When picked up, treat material as prescribed under heading "Disposal". Additional information Information regarding Safe handling, see chapter 7. Information regarding personal protective measures see, chapter 8. Information regarding Waste Disposal, see chapter 13.

Safety data sheet in accordance with 2001/58/EEC.

DEUTERON PMH C 07. Handling and storage.
Observe the usual precautions for handling chemicals. Hints on safe handling Air cleaning with filter of room for dust removable. Hints for protection against fire and explosion Observe the general rules of industrial fire protection. Requirements for storage rooms and vessels No special measures required. Storage stability Storage time: 24 months.

version: 18.06.2002 Page 2 of 3

08. Limit exposure and provide personal protection equipment for personnel.
Additional hints on technical system design See chapter 7; no measures exceeding the ones mentioned are necessary. Hygienic measures Do not eat or drink during work time. Do not smoke during work time. EINECS 271-898-1 components urea-formaldehyde-copolymer Dust mask Gloves safety glasses light protective clothing value unit 6,00 mg/m3

Respiratory protection: Hand protection: Eye protection: Skin protection_

09. Physical and chemical properties.

Appearance Form: Colour: Odour: Safety data method Flash point Density Ignition temperature Lower explosion limit Upper explosion limit Vapour pressure (20C) Solubility in water n.a.: not applicable >200 C app. 1,40 g/cm3 >350C n.a. n.a. n.a. insoluble DIN 51757 (20C) Powder white slightly perceptible

10. Stability and reactivity.

Hazardous reactions The product is not a dust explosion risk as supplied; however the build-up of fine dust can lead to a risk of dust explosions. Hazardous decomposition products No hazardous decomposition products known.

11. Toxicological information.

other data From factory experience: No skin or mucous membrane irritation or sensitisation.

12. Ecological information.

Product is insoluble in water.

Safety data sheet in accordance with 2001/58/EEC.

DEUTERON PMH C 13. Disposal considerations.
Product May be taken to waste disposal site or incineration plant, with household waste. Rules of the local authorities must be observed. European wastecataloge The declaration of the wastenumber must be specified by the branch or process in accordance with the EWC regulations. contaminated packagings Completely empty packaging may be treated as household waste.

version: 18.06.2002 Page 3 of 3

14. Transport information.

GGVSee/IMDG-Code : GGVE/GGVS : not classified UN-NR : ADR/RID : not classified ICAO/IATA : ADNR : -

Dispatch by post (for Germany only) : Permitted.

15. Regulatory information.

Labelling in accordance with GefStoffV/EC. The product does not require a hazard warning label in accordance with EC directives/German regulations on dangerous substances. National requirements VbF - class : -

16. Other information.

Observe national and local legal requirements Sources of documentation Technical safety Constants Sorbe Merck Index Welzbacher Listings All materials involved of the product are specified in the following lists: TSCA(USA) EINECS(EUROPE) DSL(CANADA) ENCS(JAPAN) AICS(AUSTRALIA) ECL(KOREA) PICCS(Philippins) Laws, guidelines and recommendations This product corresponds to the following guidelines: - Lebensmittel- und Bedarfsgegenstndegesetz 30 und 31 - BGVV XL - BGVV XXXVI - DIN EN 71 Chapter 3 - FDA 21 CFR Ch I, 176.170 und 176.180 - 90/128/EWG Changes to the previous version Modification to the guideline (RL 2001/58/EG of 27.07.2001) Modification in Chapter 1, 16

All information in this document are concerning the safety requirements of the product. All details are based on our best knowledge to the current situation. However, they do not apply as assurance for quality of the product with regard to liability resp. Guarantee. All details are given without obligation.

The delivery program of DEUTERON GmbH includes different additives of the following product groups:
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1 - Matting Agents .... based on urea condensation polymers 2 - Mar and Slip Agents .... based on urea condensation resins, silicone resins or waxes / paraffins 3 Surface Additives (Micro PMU-Pastes - (polymethylurea)) .... finest grinding of non thermoplastic polycondensation resin (free of wax and silicone) 4 - Conductivity Agents .... based on quaternary ammonium compounds 5 - UV-Initiators
for cationic curing (no benzene, low odour, high curing speed)

... based on bis-(dodecylphenyl) iodonium hexafluoroantimonate or bis-(4-methyl-phenyl) iodonium hexafluorophosphate - in various reactive thinners - suitable also in native raw materials 6 Thickening- and Thixotropy Agents .... based on Xanthan Gums 7 - Wetting- and Dispersing Agents .... based on amin oleates, Sodiumpolyaldehydcarboxylates 8 - Air Release Agents and Defoamers .... based on fatty acids / N-heterocyclus-derivatives 9 - Specialities
among other things... Structure Agents

.... based on duroplastic (thermosetting) polymers - no melting point - temperature resistant depending on the time more than 200C
________________________________________________________________________________________ This leaflet intends to give techn. advice, but without warranty and does not claim to be complete. ________________________________________________________________________________________

....The staff of DEUTERON GmbH is at your disposal!....

Further information on our WEB-site: http://www.deuteron.com ________________________________________________________________________________________

DEUTERON GmbH
P.O.Box 16 45*D-28822 Achim*HRB Walsrode 120187*Phone ++49 (0)421/48 32 27*Fax ++49 (0)421/48 36 02 e-Mail: contact@deuteron.com
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