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Acids
The table below shows the names of some common acids, their
formulae and the ions they produce in aqueous solution.
⇒ Complete the table below.
All acids contain hydrogen but not all compounds that contain
hydrogen are acids. For example, both ammonia, (NH3) and methane
(CH4) contain hydrogen, but they are not acids because they do not
produce hydrogen ions in water.
Properties of acids
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For example, when magnesium ribbon is added to dilute sulphuric
acid, bubbles of hydrogen gas can be seen. The equation for this
reaction is:
⇒ What do you call the salts formed from the following acids:
Sulphuric acid, sulphates
Nitric acid, nitrates
Hydrochloric acid? Chlorides
Quick Questions:
⇒ Complete the word equations and then write a balanced chemical
equation for each.
a) hydrochloric acid + zinc metal
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Most dilute acids react with carbonates to produce a salt, carbon
dioxide and water.
The general equation for the reaction is:
⇒ Using the set-up shown above , what would you expect your
observation of the limewater? Explain your observation.
Observation:The limewater will turn chalky.
Explanation: This shows that carbon dioxide is produced in the reaction.
Quick Questions:
⇒ Complete the word equations and then write a balanced chemical
equation for each.
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Quick Questions:
⇒ Complete the word equations and then write a balanced chemical
equation for each.
a) hydrochloric acid + lithium oxide
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e) Ethanoic acid + Aluminium hydroxide
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Citric acid is a solid acid. It has no effect on a piece of dry blue litmus
paper. Also, the solid does not react with a piece of magnesium ribbon.
Similar results occur with all acids. For example, hydrogen chloride
gas, HCl(g) behaves differently when dissolved in alcohol and in water.
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Again, we find that water is needed for an acid to show acidic
properties. How can we explain this?
Acids can only show the properties of acids when they are dissolved in
water. This is because acids dissociate in water to produce hydrogen
ions which are responsible for the acidic properties.
Quick Questions:
1. Explain why solid citric acid does not react with magnesium metal and
has no effect on litmus paper.
Because solid citric acid cannot dissociate to form hydrogen ions in the
absence of water.
Basicity of an Acid
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Some acids form just one hydrogen ion when dissolved in water
whereas others form more than one.
Quick questions:
In a solution of strong acid, all the acid molecules become ions in the
water.
For example, a solution of hydrochloric acid only contains H+(aq) and Cl-
(aq) ions and no HCl molecules. The HCl molecules have all ionized in
water.
HCl(aq) H+(aq) + Cl-(aq)
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Few acid molecules are ionized to become hydrogen ions. An example is
a solution of ethanoic acid, CH3COOH.
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Weak acids are often found in foods and drinks. Vinegar is a weak
acid; it contains ethanoic acid. Soft drinks contain carbonic acid.
Quick Questions:
1. The equation for the dissociation of ethanoic acid contains a double
arrow . What do you think it means?
It means the reaction is a reversible reaction.
⇒ Between strong acids and weak acids, which one will react more
vigorously? Strong acids
Comparing Strong and Weak Acids with Concentrated and Dilute Acids
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Similarly, the term ‘weak’ DOES NOT have the same meaning as
‘dilute’.
Quick Questions:
1. For each of the following bottles of acids, label them as either
‘concentrated solution’ or ‘dilute solution’ and also as either ‘strong acid’
or ‘weak acid’.
Uses of Acids
⇒ List the uses of the following acids.
Bases
The table below shows the names of some common bases and their
formulae.
⇒ Complete the table below.
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Bases are a group of compounds that act differently from acids.
As we shall see, when we mix an acid and a base, each destroys the
properties of the other.
“Neutralisation”
For this reason, we often think of acids and bases as chemical
opposites.
Some bases are insoluble in water. Others are soluble. For example,
copper(II) oxide is insoluble in water, so it is a base but not an alkali.
All alkalis are bases, but not all bases are alkalis.
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Properties of Alkalis
For example,
4. All alkalis can react with acids to form a salt and water.
This reaction is called neutralisation.
In this reaction, the hydrogen ions from the acid react with the
hydroxide ions of the alkali. The ionic equation for this reaction is:
H+(aq) + OH-(aq) H2O(l)
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If more alkali is then added, the temperature does not increase as
there is no more acid to react.
Quick questions:
⇒ Complete the word equations and then write a balanced chemical
equation for each.
a) calcium hydroxide + ammonium chloride
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6. Alkalis can react with a solution of one metal salt to give metal
hydroxide and another metal salt.
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Alkali + salt(of metal A) metal hydroxide + salt( of metal B)
Quick questions:
⇒ Complete the word equations and then write a balanced chemical
equation for each.
a) sodium hydroxide + copper sulphate
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The pH Scale
⇒ What is an indicator?
An indicator is a substance that has different colours in acidic and
alkaline solutions.
⇒ Using the bench reagents, use the following indicators and write
down your observation of the colour when the indicator is in acid
and in alkali in the table below.
Indicator Colour in acids Colour in alkalis
Phenolphthalein
Methyl Orange
Screened methyl
orange
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The pH of a solution is calculated based on the number of hydrogen
ions or hydroxide ions present in a solution.
⇒ The diagram below shows the pH scale and colour chart for
Universal Indicator. On the diagram, indicate the position of the
following substances in the pH scale:
Hydrochloric acid Nitric acid Sulphuric Acid Ethanoic Acid
Pure water Aqueous ammonia Sodium hydroxide
1. Universal Indicator
It contains a mixture of dyes. It gives different colours in solutions
of different pH.
2. pH meter
Universal Indicator gives only approximate values. We can use a pH
meter to obtain accurate values.
The probe is dipped into the solution and the meter shows the pH
either on a scale or digitally.
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A pH sensor connected to a computer through an interface can be
used to measure the pH of a solution.
The pH reading is displayed on the computer screen.
The Importance of pH
3. pH in the garden
The pH of soil is important for good plant growth. Here are examples
of the pH of soil in which plants grow best:
- Orchids – more acidic soil (pH 4-5)
- Azaleas, strawberries, apples, potatoes – weakly acidic soil (pH 5-6)
- Common vegetables, e.g. beans, peas, lettuce, onion – about neutral
soil (pH 6-8)
4. pH and hair
Normal hair is weakly acidic with a pH of about 5. At this pH, the hair
is smooth, strong and healthy. Alkaline solutions make hair curly.
⇒ What do you think the pH of shampoo?Alkaline (pH more than 7)
⇒ Why do you think we use conditioners after we shampoo our hair?
To restore the pH of hair to its normal value because most hair
conditioners contain weak natural acids.
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Types of Oxides
Many acids and alkalis are formed by dissolving oxides in water.
Most oxides can be grouped into four types: acidic oxides, basic
oxides, amphoteric oxides and neutral oxides.
Acidic oxides
Oxides of non-metals are acidic oxides.
Most acidic oxides dissolve in water to form an acid.
⇒ Give examples of acidic oxides.
Sulphur trioxide, carbon dioxide, sulphur trioxide and nitrogen dioxide.
Acidic oxides do not react with acids. However, they react with alkalis
to form a salt and water.
⇒ Construct a balance chemical equation for the reaction between
carbon dioxide and sodium hydroxide.
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Basic oxides
Oxides of metals are basic oxides.
⇒ Give examples of basic oxides.
Magnesium oxide, copper (II) oxide and calcium oxide
Basic oxides react with acids to form a salt and water.
⇒ Construct a balance chemical equation for the reaction between
calcium oxide and nitric acid.
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Amphoteric oxides
Amphoteric oxides are metallic oxides that react with both acids and
bases to form salts and water.
⇒ Give examples of amphoteric oxides.
Aluminium oxide, zinc oxide and lead(II) oxide
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Na2ZnO2 + H2O
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Salts
A salt is obtained from an acid by replacing the acid hydrogen atoms
with metal ions (or with ammonium ions)
e.g. sodium chloride, NaCl, is obtained by replacing the H of HCl with a
sodium ion, Na+.
Ammonium sulphate, (NH4)2SO4, is obtained by replacing the two H
atoms of H2SO4 with two ammonium ions, NH4+.
Acid salts only have some (but not all) of the acid hydrogen atoms
replaced by metal atoms.
e.g. Sodium hydrogensulphate, NaHSO4, is an acid salt from sulphuric
acid (only one H atom of H2SO4 is replaced; one H remains).
Although salts are ionic compounds, not all salts are soluble in water.
Figure below summarises the solubilities of the common salts in water
at room temperature.
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Preparation of Salts
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