I HC QUC GIA TP.

HCM TRNG I HC BCH KHOA CNG THI TUYN SAU I HC NM 2012 Chuyn ngnh o to Thc s ngnh: -

CNG NGH VT LIU V C (60 52 90) CNG NGH VT LIU KIM LOI (60 52 91) CNG NGH VT LIU CAO PHN T V T HP( 60 52 94)

Mn thi c s: C S KHOA HC VT LIU thi tuyn sinh gm 2 phn: Bt buc (6 im), t chn (4 im)

I) PHN KIN THC CHUNG 1) Cu to nguyn t v lin kt trong cht rn 1.1 Cu to nguyn t 1.2 Cc dng lin kt trong cht rn: dng lin kt, lc lin kt, cu trc min nng lng ca cht rn 2) Cc khi nim c bn v mng tinh th 2.1 Mng tinh th, c s 2.2 Cc php i xng c bn, 2.3 By h tinh th v 14 mng Bravais 2.4 K hiu phng, mt theo Miller 2.5 Khong cch mt, lp li, gc gia hai phng, phng mt 2.6 Cch xc nh cu trc tinh th 3) Cu trc 3.1 Cu trc c trt t (cu trc tinh th) - Cu trc gm cc nguyn t cng loi: lp phng tm khi, lp phng tm mt, lc gic xp cht, kim cng, graphit - Cu trc gm cc nguyn t khc loi: + Dung dch rn, pha trung gian + Cc hp cht c lin kt ion: AB (NaCl, CsCl, ZnS; AmBn (CaF2, Cu2O); AmBnXp (Perovskiste, Spinel) + Silicat trng thi tinh th 3.2 Khuyt tt trong tinh th - Nguyn nhn xut hin khuyt tt - Khuyt tt im
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- Khuyt tt ng - Khuyt tt mt v khuyt tt khi - nh hng ca khuyt tt n tnh cht vt liu 3.3 Cu trc khng trt t (v nh hnh) - Du hiu nhit vt l phn bit gia trng thi tinh th v v nh hnh: nhit nng chy Tf v khong nhit bin mm Tf - Tg - Polyme: khi lng phn t, cu hnh, cu trng, phn loi, hnh dng mch polyme, cu trc vt l, cu trc ngoi vi phn t 4) Qu trnh khuch tn - C ch khuch tn - Khuch tn n nh: nh lut Fick I - Khuch tn khng n nh: nh lut Fick II - Cc yu t nh hng n khuch tn 5) Gin pha - Quy tc pha, cn bng pha - Cc loi gin pha + H 1 cu t + H 2 cu t Ha tan v hn trng thi lng, ha tan v hn trng thi rn to dung Ha tan v hn trng thi lng, khng ha tan vo nhau trng thi rn, Ha tan v hn trng thi lng, ha tan c gii hn trng thi rn, to Ha tan v hn trng thi lng, ha tan c gii hn trng thi rn, to H c chuyn bin ng dng H Fe- cacbon dch rn to hn hp cng tinh (eutectic) hn hp cng tinh (eutectic) nn pha trung gian (pha in t, hp cht ha hc)

+ H 3 cu t 6. Qu trnh chuyn pha - Gii thiu - Nhit ng hc ca qu trnh chuyn pha - ng hc qu trnh chuyn pha - Qu trnh kt tinh t pha lng - Bin i th hnh 7) C tnh ca vt liu
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- ng sut, bin dng, ng cong ng sut - bin dng - Bin dng n hi - Bin dng do - Cc dng ph hy ca vt liu, c ch ph hy, ng sut ph hy - Cc phng php kim tra c tnh vt liu 8) Tnh cht in - C ch dn in t - Phn b Fermi-Dirac - Phn loi vt liu theo tnh cht in - C ch dn ion - Bn dn nguyn cht, bn dn c ph gia 9) Tnh cht t - Thun t, nghch t, st t, phn st t - Domain v chu trnh t tr - Mt s ng dng ca vt liu t TI LIU THAM KHO: [1] William D. Callister, Jr., Material Science & Engineering - An introduction, 7th edition, John Wiley & Son. Inc., New York, USA, 2007 [2] L Cng Dng,Vt liu hc, NXB Khoa Hc - K Thut, H Ni, 1997. [3] J.P. Schaffer et al., The Science and Design of Engineering Materials, Irwin, USA, 1995.

B) PHN KIN THC NGNH 1) Cng ngh Vt liu Cao phn t v t hp ni dung trong mn Ha l polyme a) Cu to, cu trc ca polyme Cc trng thi pha (tinh th, v nh hnh) Cc trng thi vt l ca polyme v nh hnh (thy tinh, mm cao, chy) Cc yu t nh hng

b) Bin dng polyme: n hi, mm cao v do (chy) c) Hi phc ca polyme: cc dng hi phc v cc yu t nh hng d) Trng v ha tan polyme Trng Ha tan Cc yu t nh hng

2) Cng ngh Vt liu Kim loi ni dung trong mn Kim loi hc a) Chuyn pha trong kim loi v hp kim Gin pha 2 cu t ca kim loi v hp kim Kt tinh kim loi t trng thi lng, mm t sinh, k sinh, pht trin mm, bin tnh Chuyn pha khi nung v lm ngui kim loi & hp kim Gin ng sut bin dng khi ko kim loi Bin dng do kim loi Nung kim loi sau bin dng do Ph hy Cc phng php nng cao c tnh tng hp ca kim loi hp kim Nhng bi ton khuch tn tnh chiu dy, thi gian v nng cht thm, thiu kt
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b) Bin dng do v c tnh ca kim loi

c) Khuch tn trong kim loi hp kim

Khuch tn tng h v hiu ng KirKendall v Frenkel

d) Bn cht cc pha trong kim loi v hp kim: dung dch rn v pha trung gian 3) Cng ngh Vt liu v c ni dung trong mn Ha hc cht rn Khi nim dung dch rn trong vt liu v c Cu trc cc hp cht silicat v alumo-silicat Cc cht rn trng thi thy tinh: khi nim, nh ngha, cc gi thuyt v cu trc thy tinh, gii thch mt s tnh cht theo cu trc thy tinh, kt tinh t pha lng nng chy v t pha thy tinh C ch phn ng trong pha rn: khuch tn trong cht rn, cc phng php nghin cu c ch phn ng pha rn, m hnh phn ng pha rn C ch bin i khng thay i thnh phn: bin i th hnh, qu trnh kt khi, ti kt tinh v pht trin ht, kt khi khi c mt pha lng ng hc phn ng pha rn: khi nim v phng php nghin cu ng hc pha rn, m hnh ng hc v phng trnh ng hc ng nhit, m hnh tc nhn bt c h s khuch tn bin i theo thi gian, ng hc phn ng iu khin bi qu trnh to mm, ng hc phn ng pha rn trong h a phn tn, s ph thuc hng s tc phn ng vo nhit Trng thi hot ha ca pha rn: bn cht, phng php nh gi, cc phng php hot ha tc nhn rn TI LIU THAM KHO:
1. Nguyn Hu Niu, Trn Vnh Diu, Ha l Polyme, NXB i hc Quc Gia

TPHCM, 2004.
2. L Cng Dng, Kim loi hc, i hc Bch Khoa H Ni, 1986. 3. Quang Minh, Ha hc cht rn, NXB i hc Quc Gia TPHCM, 2005