Chuyn : Amin - Aminoaxit | Ha Hc 12 Nng Cao

BI TP CHUYN : AMIN - AMINOAXIT

DNG 1: NG PHN CA AMIN, AMINOAXIT
Cu 1: Vit cng thc cu to v gi tn amin c cng thc phn t C3H9N, C4H11N v C7H9N (amin cha vng benzen). Cu 2: Vit cng thc cu to v gi tn aminoaxit c cng thc phn t C3H7O2N v C4H9O2N. Cu 3: S ng phn amin c cng thc phn t C3H9N l A. 4. B. 3. C. 2. D. 5. Cu 4: S ng phn amin c cng thc phn t C4H11N l A. 5. B. 7. C. 6. D. 8. Cu 5: (H A-2012) S amin bc mt c cng cng thc phn t C3H9N l A. 3. B. 1. C. 2. D. 4. Cu 6: S ng phn amin bc mt ng vi cng thc phn t C4H11N l A. 4. B. 3. C. 2. D. 5. Cu 7: C bao nhiu amin cha vng benzen c cng cng thc phn t C7H9N ? A. 3. B. 5. C. 6. D. 7. Cu 8: C4H9O2N c my ng phn amino axit c nhm amino v tr ? A. 4. B. 3. C. 2. D. 5.

DNG 2: SO SNH TNH BAZ CA AMIN

Cu 1: Trong cc cht di y, cht no c tnh baz mnh nht ? A. C6H5NH2. B. (C6H5)2NH C. p-CH3-C6H4-NH2. D. C6H5-CH2-NH2 Cu 2: (TN-2010) Dy gm cc hp cht c sp xp theo th t tng dn lc baz l: A. CH3NH2, C6H5NH2 (anilin), NH3. B. NH3, C6H5NH2 (anilin), CH3NH2. C. C6H5NH2 (anilin), NH3, CH3NH2. D. C6H5NH2 (anilin), CH3NH2, NH3. Cu 3: (H A-2012) Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5- l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l: A. (3), (1), (5), (2), (4). B. (4), (1), (5), (2), (3). C. (4), (2), (3), (1), (5). D. (4), (2), (5), (1), (3).

DNG 3: AMIN PHN NG VI AXIT, DUNG DCH BROM

Cu 1: Cho 9,3 gam anilin (C6H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 11,95 gam. B. 12,95 gam. C. 12,59 gam. D. 11,85 gam. Cu 2: Cho 5,9 gam propylamin (C3H7NH2) tc dng va vi axit HCl. Khi lng mui (C3H7NH3Cl) thu c l A. 8,15 gam. B. 9,65 gam. C. 8,10 gam. D. 9,55 gam. Cu 3: Cho 11,8 g hn hp X gm 3 amin : n-propyl amin, etylmetylamin, trimetyl amin. Tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l : A. 100ml. B. 150 ml. C. 200 ml. D. Kt qu khc. Cu 4: Th tch nc brom 3% (d = 1,3g/ml) cn dng iu ch 4,4 gam kt ta 2,4,6 tribrom anilin l A. 164,1ml. B. 49,23ml. C. 146,1ml. D. 16,41ml. Cu 5: Cho anilin tc dng ht vi 2 lit dung dch Br2 0,3M. Khi lng kt ta thu c l A. 66.5 gam. B. 66 gam. C. 33 gam. D. 44 gam. Cu 6: Cho 9 gam C2H5NH2 tc dng va vi dung dch HCl, lng mui thu c l A. 0,85 gam. B. 16,3 gam. C. 7,65 gam. D. 8,10 gam. Cu 7: Cho 20 gam hn hpX gm ba amin no n chc l ng ng k tip nhau tc dng va vi dung dch HCl 1M, c cn dung dch thu c 31,68g mui. Xc nh th tch HCl dng ? A. 16 ml. B. 32 ml. C. 160 ml. D. 320 ml. Cu 8: trung ha 20 gam dung dch ca mt amin n chc X nng 22,5% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H7N. B. CH5N. C. C3H5N. D. C3H7N. Cu 9: (C A-07) trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l A. C3H5N. B. C2H7N. C. CH5N. D. C3H7N.

Created by: Trn Vn Trung | 2012

Chuyn : Amin - Aminoaxit | Ha Hc 12 Nng Cao

Cu 10: (C A-08) Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5. B. 4. C. 2. D. 3. Cu 11: (H A-09) Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 4. B. 8. C. 5. D. 7. Cu 12: (C A-10) Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l A. C3H7NH2 v C4H9NH2. B. CH3NH2 v C2H5NH2. C. CH3NH2 v (CH3)3N. D. C2H5NH2 v C3H7NH2. Cu 13: Trung ha 3,1 gam mt amin n chc cn 100 ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H5N. B. CH5N. C. C3H9N. D. C3H7N. Cu 14: Cho 0,4 mol amin no, n chc X tc dng vi dd HCl va thu c 32,6g mui.CTPT ca X l: A. CH3NH2. B. C2H5NH2. C. C3H7NH2. D. C4H9NH2. Cu 15: Trung ha 11,8 gam mt amin n chc cn 200 ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H5N. B. CH5N. C. C3H9N. D. C3H7N. Cu 16: Cho 20 hn hp 3 amin n chc no, ng ng lin tip nhau tc dng vi dung dch HCl 1M va , sau c cn dung dch thu c 31,68 gam hn hp mui. Bit t l mol ca cc amin theo th t t amin nh n amin ln l 1:10:5 th ba amin c Cng thc phn t l: A. CH3NH2, C2H5NH2, C3H7NH2. B. C2H5NH2, C3H7NH2, C4H9NH2. C. C3H7NH2, C4H9NH2, C5H11NH2. D. B v C ng.

DNG 4: PHN NG T CHY AMIN

Cu 1: t chy mt ng ng ca metylamin, ngi ta thy t l th tch cc kh v hi V CO2 : VH2O sinh ra bng 2 : 3 Cng thc phn t ca amin l: A. C3H9N. B. CH5N. C. C2H7N. D. C4H11N. Cu 2: t chy hon ton m gam hn hp 3 amin thu c 3,36 lt CO2, 1,12 lt N2 v 5,4 gam H2O. Gi tr ca m l (th tch cc kh o iu kin tiu chun): A. 3,6. B. 3,8. C. 4. D. 3,1. Cu 3: t chy hon ton m gam mt amin n chc thu c 0,2 mol CO2 v 0,35 mol H2O. Cng thc phn t ca amin l A. C4H7N. B. C2H7N. C. C4H14N. D. C2H5N. Cu 4: t chy hon ton mt amin n chc b 1 thu c CO2 v H2O theo t l 6 : 7. Vy CT amin l: A. C3H7N. B. C4H9N. C. CH5N. D. C2H7N. Cu 5: t chy hon ton mt amin n chc cha no thu c CO2 v H2O theo t l 8 : 9. Vy CT amin l: A. C3H6N. B. C4H9N. C. C4H8N. D. C3H7N. Cu 6: t chy hon ton mt amin n chc cha no c mt lin kt i mch cacbon ta thu c CO2 v H2O theo t l mol bng 6 : 9. Vy cng thc phn t ca amin l A. CH3NH2. B. C4H9N. C. C2H7N. D. C3H9N. Cu 7: (H A-07) Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l A. C3H7N. B. C2H7N. C. C3H9N. D. C4H9N. Cu 8: t chy hon ton 6,2 gam mt amin no h n chc, cn 10,08 lt O2 ktc. CTPT l A. C4H11N. B. CH5N. C. C3H9N. D. C5H13N. Cu 9: t chy hon ton a mol amin no, n chc thu c 13,2 gam CO2 v 8,1 gam H2O.Gi tr ca a l: A. 0,05. B. 0,1. C. 0,07. D. 0,2. Cu 10: t chy hon ton 10,4 gam hai amin no, n chc, ng ng lin tip nhau, thu c 11,2 lt kh CO2 (ktc). Hai amin c cng thc phn t l A. CH4N v C2H7N. B. C2H5N v C3H9N. C. C2H7N v C3H7N. D. C2H7N v C3H9N. Cu 11: t chy hon ton a mol hn hp X gm 2 amin no n chc thu c 5,6 lit CO2 (ktc) v 7,2 gam H2O. Gi tr ca a l : A. 0 ,05 mol. B. 0,1 mol. C. 0,15 mol. D. 0,2 mol. Cu 12: t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng, thu c 22 gam CO2 v 14,4 gam H2O. CTPT ca hai amin l : A. CH3NH2 v C2H7N. B. C3H9N v C4H11N. C. C2H7N v C3H9N. D. C4H11N v C5H13N.

DNG 5: AMIN TC DNG VI DUNG DCH MUI

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Created by: Trn Vn Trung | 2012

Chuyn : Amin - Aminoaxit | Ha Hc 12 Nng Cao

Cu 1: Cho 9,3 g mt ankyl amin X tc dng vi dd FeCl3 d thu c 10,7g kt ta. Cng thc cu to ca X l: A. CH3NH2. B. C2H5NH2. C. C3H7NH2. D. C4H9NH2. Cu 2: Cho 17,4 gam hn hp 2 amin n chc bc I c t khi so vi khng kh bng 2. Tc dng vi dung dch FeCl3 d thu c kt ta, em nung kt ta n khi lng khng i c m gam cht rn. Gi tr ca m l A. 16,0 gam. B. 10,7 gam. C. 24,0 gam. D. 8,0 gam. Cu 3: Cho hn hp 2 amin n chc bc I c t khi hi so vi hiro l 19 (bit c mt amin c s mol bng 0,15) tc dng vi dung dch FeCl3 d thu c kt ta A. em nung A n khi lng khng i thu c 8 gam cht rn. Cng thc ca 2 amin l A. CH3NH2 v C2H5NH2. B. CH3NH2 v C2H3NH2. C. C2H5NH2 v C2H3NH2. D. CH3NH2 v CH3NHCH3. Cu 4: Cho m gam hn hp hai amin n chc bc I c t khi hi so vi hiro l 30 tc dng vi FeCl 2 d thu c kt ta X. ly kt ta nung trong khng kh n khi lng khng i c 18,0 gam cht rn. Vy gi tr ca m l A. 30,0 gam. B. 15,0 gam. C. 40,5 gam. D. 27,0 gam.

DNG 6: AMINO AXIT + DD NaOH, HCl

Cu 1: 0,1 mol aminoaxit X phn ng va vi 0,2 mol HCl hoc 0,1 mol NaOH. Cng thc ca X c dng l. A. (H2N)2R(COOH)2. B. H2NRCOOH. C. H2NR(COOH)2. D. (H2N)2RCOOH Cu 2: (H B-09) Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH. Cu 3: Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. Tn gi ca X l A. axit glutamic. B. valin. C. alanin. D. Glixin Cu 4: Khi cho 3,75 gam axit amino axetic (NH2CH2COOH) tc dng ht vi dung dch NaOH, khi lng mui to thnh l A. 4,5 gam. B. 9,7 gam. C. 4,85 gam. D. 10 gam. Cu 5: (TN-2010) phn ng hon ton vi dung dch cha 7,5 gam H2NCH2COOH cn va V ml dung dch NaOH 1M. Gi tr ca V l A. 200. B. 100. C. 150. D. 50. Cu 6: (TN-2012) Cho 3,75 gam amino axit X tc dng va ht vi dung dch NaOH thu c 4,85 gam mui. Cng thc ca X l A. H2N CH(CH3) COOH. B. H2N CH2 CH2 COOH. C. H2N CH2 CH2 CH2 COOH. D. H2N CH2 COOH. Cu 7: X l mt - aminoaxit no ch cha mt nhm -NH2v mt nhm COOH. Cho 13,1 gam X tc dng vi dung dch HCl d, ta thu c 16,75 gam mui ca X. X c cng thc cu to no sau y? A. CH3CH2(NH2)COOH. B. H2N(CH2)3COOH. C. CH3(CH2)4(NH2)COOH. D. H2N(CH2)5COOH. Cu 8: (H A-07) -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCH2COOH. B. H2NCH2CH2COOH. C. CH3CH2CH(NH2)COOH. D. CH3CH(NH2)COOH. Cu 9: (C A-08) Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC3H6COOH. B. H2NCH2COOH. C. H2NC2H4COOH. D. H2NC4H8COOH. Cu 10: (H B-09) Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH. Cu 11: (H A-10) Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,70. B. 0,50. C. 0,65. D. 0,55. Cu 12: (H A-09) Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C5H9O4N. B. C4H10O2N2. C. C5H11O2N. D. C4H8O4N2. Cu 13: (C - 2011) Amino axit X c dng H2NRCOOH (R l gc hirocacbon). Cho 0,1 mol X phn ng ht vi dung dch HCl (d) thu c dung dch cha 11,15 gam mui. Tn gi ca X l A. glyxin. B. valin. C. alanin. D. phenylalanin.

Created by: Trn Vn Trung | 2012

Chuyn : Amin - Aminoaxit | Ha Hc 12 Nng Cao

DNG 7: THY PHN PEPTIT, PROTEIN

Cu 1: (C A-09) Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 453. B. 382. C. 328. D. 479. Cu 2: (C-2012) Thy phn hon ton m gam ipeptit Gly-Ala (mch h) bng dung dch KOH va , thu c dung dch X. C cn ton b dung dch X thu c 2,4 gam mui khan. Gi tr ca m l A. 1,46. B. 1,36. C. 1,64. D. 1,22. Cu 3: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 81,54. B. 66,44. C. 111,74. D. 90,6. Cu 4: (H B-10) Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Phe-Gly-Ala-Val. B. Gly-Ala-Val-Val-Phe. C. Gly-Ala-Val-Phe-Gly. D. Val-Phe-Gly-Ala-Gly. Cu 5: (H B-2012) un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol tripeptit mch h Y vi 600 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch thu c 72,48 gam mui khan ca cc amino axit u c mt nhm COOH v mt nhm NH2 trong phn t. Gi tr ca m l A. 51,72. B. 54,30. C. 66,00. D. 44,48.

BI TP TNG HP
Cu 1: S ng phn amin c cng thc phn t C2H7N l A. 4. B. 3. C. 2. D. 5. Cu 2: Trong cc tn gi di y, tn no khng ph hp vi cht CH3CH(NH2)COOH ? A. Axit 2-aminopropanoic. B. Axit-aminopropionic. C. Anilin. D. Alanin. Cu 3: Trong cc tn gi di y, tn no khng ph hp vi cht CH3-CH(CH3)-CH(NH2)-COOH? A. Axit 3-metyl-2-aminobutanoic. B. Valin. C. Axit 2-amino-3-metylbutanoic. D. Axit -aminoisovaleric. Cu 4: Trong cc cht di y, cht no l glixin? A. H2N-CH2-COOH. B. CH3CH(NH2)COOH. C. HOOC-CH2CH(NH2)COOH. D. H2NCH2-CH2COOH. Cu 5: C bao nhiu amin bc hai c cng cng thc phn t C5H13N ? A. 4. B. 5. C. 6. D. 7. Cu 6: Trong cc tn gi di y, tn no ph hp vi cht CH3CH(CH3)NH2? A. Metyletylamin. B. Etylmetylamin. C. Isopropanamin. D. Isopropylamin. Cu 7: Trong cc tn gi di y, tn no ph hp vi cht C6H5-CH2-NH2? A. Phenylamin. B. Benzylamin. C. Anilin. D. Phenylmetylamin. Cu 8: Anilin c cng thc l A. CH3COOH. B. C6H5OH. C. C6H5NH2. D. CH3OH. Cu 9: Trong cc cht sau, cht no l amin bc 2 ? A. H2N-[CH2]6NH2. B. CH3CH(CH3)NH2. C. CH3NHCH3. D. C6H5NH2. Cu 10: Cht khng c kh nng lm xanh nc qu tm l A. Anilin. B. Natri hiroxit. C. Natri axetat. D. Amoniac. Cu 11: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. Cu 12: Dung dch ca cht no sau y khng lm i mu qu tm : A. Glixin (CH2NH2-COOH). B. Lisyn (H2NCH2-[CH2]3CH(NH2)-COOH). C. Axit glutamic (HOOCCH2CHNH2COOH). D. Natriphenolat (C6H5ONa). Cu 13: Cht X va tc dng c vi axit, va tc dng c vi baz. Cht X l A. CH3COOH. B. H2NCH2COOH. C. CH3CHO. D. CH3NH2. Cu 14: Cht no sau y va tc dng c vi H2NCH2COOH, va tc dng c vi CH3NH2? A. NaCl. B. HCl. C. CH3OH. D. NaOH. Cu 15: Cht rn khng mu, d tan trong nc, kt tinh iu kin thng l A. C6H5NH2. B. C2H5OH. C. H2NCH2COOH. D. CH3NH2. Cu 16: Cht tham gia phn ng trng ngng l A. C2H5OH. B. CH2 = CHCOOH. C. H2NCH2COOH. D. CH3COOH. 4
Created by: Trn Vn Trung | 2012

Chuyn : Amin - Aminoaxit | Ha Hc 12 Nng Cao

Cu 17: Cho dy cc cht: C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2, C6H5OH (phenol). S cht trong dy tc dng c vi dung dch HCl l A. 4. B. 2. C. 3. D. 5. Cu 18: chng minh aminoaxit l hp cht lng tnh ta c th dng phn ng ca cht ny ln lt vi A. dung dch KOH v dung dch HCl. B. dung dch NaOH v dung dch NH3. C. dung dch HCl v dung dch Na2SO4 . D. dung dch KOH v CuO. Cu 19: Cht phn ng c vi cc dung dch: NaOH, HCl l A. C2H6. B. H2N-CH2-COOH. C. CH3COOH. D. C2H5OH. Cu 20: Axit aminoaxetic (H2NCH2COOH) tc dng c vi dung dch A. NaNO3. B. NaCl. C. NaOH. D. Na2SO4. Cu 21: Dung dch ca cht no trong cc cht di y khng lm i mu qu tm ? A. CH3NH2. B. NH2CH2COOH. C. HOOCCH2CH2CH(NH2)COOH. D. CH3COONa. Cu 22: phn bit 3 dung dch H2NCH2COOH, CH3COOH v C2H5NH2 ch cn dng mt thuc th l A. dung dch NaOH. B. dung dch HCl. C. natri kim loi. D. qu tm. Cu 23: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2)-COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l A. 2. B. 5. C. 4. D. 3. Cu 34: Glixin khng tc dng vi A. H2SO4 long. B. CaCO3. C. C2H5OH. D. NaCl. Cu 35: Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phn ng ht vi dung dch HCl. Sau phn ng, khi lng mui thu c l A. 43,00 gam. B. 44,00 gam. C. 11,05 gam. D. 11,15 gam. Cu 36: Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phn ng ht vi dung dch NaOH. Sau phn ng, khi lng mui thu c l A. 9,9 gam. B. 9,8 gam. C. 7,9 gam. D. 9,7 gam. Cu 37: Cho m gam alanin phn ng ht vi dung dch NaOH. Sau phn ng, khi lng mui thu c 11,1 gam. Gi tr m dng l A. 9,9 gam. B. 9,8 gam. C. 8,9 gam. D. 7,5 gam. Cu 38: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC3H6COOH. B. H2NCH2COOH. C. H2NC2H4COOH. D. H2NC4H8COOH. Cu 39: 1 mol - amino axit X tc dng va ht vi 1 mol HCl to ra mui Y c hm lng clo l 28,287% Cng thc cu to ca X l A. CH3-CH(NH2)COOH. B. H2N-CH2-CH2-COOH. C. H2N-CH2-COOH. D. H2N-CH2-CH(NH2 )-COOH. Cu 40: Khi trng ngng 13,1 g axit - aminocaproic vi hiu sut 80%, ngoi aminoaxit cn d ngi ta thu c m gam polime v 1,44 g nc. Gi tr m l A. 10,41. B. 9,04. C. 11,02. D. 8,43. Cu 41: Este A c iu ch t ancol metylic v amino axit no B (cha mt nhm amino v mt nhm cacboxyl). T khi hi ca A so vi oxi l 2,78125. Amino axit B l A. axit amino fomic. B. axit aminoaxetic. C. axit glutamic. D. axit -amino propionic. Cu 42: C 0,01 mol aminoaxit (A) phn ng va vi 40 ml dung dch NaOH 0,25M. Mt khc 1,5 gam aminoaxit (A) phn ng va vi 80 ml dung dch NaOH 0,25M. Khi lng phn t ca A l A. 150. B. 75. C. 105. D. 89. Cu 43: 0,01 mol aminoaxit (A) tc dng va vi 50 ml dung dch HCl 0,2M. C cn dung dch sau phn ng c 1,835 gam mui khan. Khi lng phn t ca A l A. 89. B. 103. C. 117. D. 147. Cu 44: Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. Tn gi ca X l A. axit glutamic. B. valin. C. alanin. D. glixin Cu 45: Este A c iu ch t -amino axit v ancol metylic. T khi hi ca A so vi hidro bng 44,5. Cng thc cu to ca A l: A. CH3CH(NH2)COOCH3. B. H2N-CH2CH2-COOH C. H2NCH2COOCH3. D. H2NCH2CH(NH2)COOCH3. Cu 46: A l mt aminoaxit. Cho bit 1 mol A phn ng va vi 1 mol HCl, hm lng clo trong mui thu c l 19,346%. Cng thc ca A l : A. HOOCCH2CH2CH(NH2)COOH. B. HOOCCH2CH2CH2CH(NH2)COOH. C. CH3CH2CH(NH2)COOH. D. CH3CH(NH2)COOH. Cu 47: Tri peptit l hp cht 5
Created by: Trn Vn Trung | 2012

Chuyn : Amin - Aminoaxit | Ha Hc 12 Nng Cao

A. m mi phn t c 3 lin kt peptit. B. c lin kt peptit m phn t c 3 gc amino axit ging nhau. C. c lin kt peptit m phn t c 3 gc amino axit khc nhau. D. c 2 lin kt peptit m phn t c 3 gc -amino axit. Cu 48: C bao nhiu tripeptit m phn t cha 3 gc amino axit khc nhau? A. 3 cht. B. 5 cht. C. 6 cht. D. 8 cht. Cu 49: Trong cc cht di y, cht no l ipeptit ? A. H2N-CH2-CO-NH-CH2-CH2-COOH. B. H2N-CH2-CO-NH-CH(CH3)-COOH. C. H2N-CH2-CO-NH-CH(CH3)-CO-NH-CH2-COOH. D. H2N-CH(CH3)-CO-NH-CH2-CO-NH-CH(CH3)-COOH Cu 50: T glyxin (Gly) v alanin (Ala) c th to ra my cht ipeptit ? A. 1 cht. B. 2 cht. C. 3 cht. D. 4 cht. Cu 52: S ng phn tripeptit to thnh t 1 phn t glyxin v 2 phn t alanin l A. 2. B. 3. C. 5. D. 4. Cu 53: S ng phn tripeptit c cha gc ca c glyxin v alanin l A. 6. B. 3. C. 5. D. 4. Cu 54: Sn phm cui cng ca qu trnh thy phn cc protein n gin nh cht xc tc thch hp l A. -aminoaxit. B. -aminoaxit. C. axit cacboxylic. D. este. Cu 55: S ng phn ipeptit to thnh t 1 phn t glyxin v 1 phn t alanin l A. 3. B. 1. C. 2. D. 4. Cu 56: (TN-2012) Trong phn t cht no sau y c cha vng benzen? A. Phenylamin. B. Propylamin. C. Etylamin. D. Metylamin. Cu 57: (TN-2012) Cho 3,75 gam amino axit X tc dng va ht vi dung dch NaOH thu c 4,85 gam mui. Cng thc ca X l A. H2N CH(CH3) COOH. B. H2N CH2 CH2 COOH. C. H2N CH2 CH2 CH2 COOH. D. H2N CH2 COOH. Cu 58: (TN-2012) Trong phn t cht no sau y c cha nguyn t nit? A. Glucoz. B. Metylamin. C. Etyl axetat. D. Saccaroz. Cu 59: (TN-2012) Trong mi trng kim, tripeptit tc dng vi Cu(OH) cho hp cht mu A. vng. B. tm. C. xanh. D. . Cu 60: (TN-2012) Nhng giy qu tm vo dung dch metylamin, mu qu tm chuyn thnh A. . B. vng. C. xanh. D. nu . Cu 61: (TN-2012) Amin tn ti trng thi lng trong iu kin thng l A. anilin. B. etylamin. C. metylamin. D. imetylamin. Cu 62: (TN-2010) Protein phn ng vi Cu(OH)2 to sn phm c mu c trng l A. mu vng. B. mu tm. C. mu da cam. D. mu . Cu 63: (TN-2010) Cht no sau y va phn ng c vi dung dch KOH, va phn ng c vi dung dch HCl? A. H2NCH(CH3)COOH. B. C2H5OH. C. C6H5NH2. D. CH3COOH. Cu 64: (TN-2010) phn ng hon ton vi dung dch cha 7,5 gam H2NCH2COOH cn va V ml dung dch NaOH 1M. Gi tr ca V l A. 200. B. 100. C. 150. D. 50. Cu 65: (TN-2010) Dy gm cc hp cht c sp xp theo th t tng dn lc baz l: A. CH3NH2, C6H5NH2 (anilin), NH3. B. NH3, C6H5NH2 (anilin), CH3NH2. C. C6H5NH2 (anilin), NH3, CH3NH2. D. C6H5NH2 (anilin), CH3NH2, NH3. Cu 66: (TN-2010) S ng phn cu to amin bc mt ng vi cng thc phn t C3H9N l A. 2. B. 4. C. 3. D. 1. Cu 67: (C-2012) Cho dy cc dung dch: axit axetic, phenylamoni clorua, natri axetat, metylamin, glyxin, phenol (C6H5OH). S dung dch trong dy tc dng c vi dung dch NaOH l A. 4. B. 3. C. 6. D. 5. Cu 68: (C-2012) Cho 20 gam hn hp gm hai amin no, n chc, mch h tc dng va vi V ml dung dch HCl 1M, thu c dung dch cha 31,68 gam hn hp mui. Gi tr ca V l A. 320. B. 50. C. 200. D. 100. Cu 69: (C-2012) Thy phn hon ton m gam ipeptit Gly-Ala (mch h) bng dung dch KOH va , thu c dung dch X. C cn ton b dung dch X thu c 2,4 gam mui khan. Gi tr ca m l A. 1,46. B. 1,36. C. 1,64. D. 1,22. Cu 70: (C-2012) S nhm amino v s nhm cacboxyl c trong mt phn t axit glutamic tng ng l A. 1 v 2. B. 1 v 1. C. 2 v 1. D. 2 v 2. 6
Created by: Trn Vn Trung | 2012
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Chuyn : Amin - Aminoaxit | Ha Hc 12 Nng Cao

Cu 71: (C-2012) Cho cc cht hu c: CH3CH(CH3)NH2 (X) v CH3CH(NH2)COOH (Y). Tn thay th ca X v Y ln lt l A. propan1amin v axit 2aminopropanoic. B. propan1amin v axit aminoetanoic. C. propan2amin v axit aminoetanoic. D. propan2amin v axit 2aminopropanoic. Cu 72: (C-2012) Cng thc chung ca amin no, n chc, mch h l A. CnH2n-5N (n 6). B. CnH2n+1N (n 2). C. CnH2n-1N (n 2). D. CnH2n+3N (n 1). Cu 73: (C-2012) Pht biu no sau y l ng? A. Axit glutamic l thnh phn chnh ca bt ngt. B. Amino axit thuc loi hp cht hu c tp chc. C. Cc amino axit thin nhin hu ht l cc -amino axit. D. nhit thng, cc amino axit u l nhng cht lng. Cu 74: (C-2012) Cho 14,55 gam mui H2NCH2COONa tc dng hon ton vi dung dch HCl d, thu c dung dch X. C cn ton b dung dch X, thu c bao nhiu gam mui khan? A. 16,73 gam. B. 8,78 gam. C. 20,03 gam. D. 25,50 gam. Cu 75: Anilin v phenol u p vi: A. dd HCl. B. dd NaOH. C. dd Br2. D. dd NaCl. Cu 76: C 3 cht lng: benzen, anilin, stiren ng ring bit trong 3 l mt nhn . Thuc th phn bit 3 cht lng trn l : A. dd phenolphtalein. B. dd Br2. C. dd NaOH. D. Qu tm. Cu 77: Cho cc cht sau: (1) NH3 ; (2) CH3NH2; (3) (CH3)2NH; (4) C6H5NH2; (5) (C6H5)2NH. Th t tng dn tnh bazo ca cc cht trn l : A. (4) < (5) < (1) < (2) < (3). B. (1) < (4) < (5) < (2) < (3). C. (5) < (4) < (1) < (2) < (3). D. (1) < (5) < (2) < (3) < (4). Cu 78: Hp cht khng lm i mu giy qu m l : A. CH3NH2. B. C6H5ONa. C. H2N CH2 CH(NH2) COOH. D. H2NCH2 COOH. Cu 79: Axit glutamic (HCOO(CH2)2CH(NH2)COOH) l cht A. ch c tnh axit. B. ch c tnh baz. C. lng tnh. D. trung tnh. Cu 80: Trong cc cht sau cht no c lin kt peptit? A. Alanin. B. Protein. C. Xenluloz. D. Glucoz. Cu 81: Cho 0,1 mol A ( amino axit H2N-R-COOH) phn ng ht vi HCl to 11,15 gam mui. A l A. Valin. B. Phenylalani. C. Alanin. D. Glyxin. Cu 82: Amino axit X cha mt nhm COOH v 2 nhm NH2.Cho 1 mol X tc dng ht vi dung dch NaOH, thu c 154 gam mui. Cng thc phn t ca X l: A. C4H10N2O2. B. C5H10N2O2. C. C5H12N2O2. D. C6H14N2O2. Cu 83: Hp cht no sau y khng phi l Amino axit A. H2NCH2COOH. B. CH3CH2CONH2. C. CH3NHCH2COOH. D. HCOOCCH2CH(NH2)COOH. Cu 84: C 3 cht: butylamin, anilin v amoniac. Th t tng dn lc baz l A. NH3 < C6H5NH2 < C4H9NH2. B. C6H5NH2 < NH3 < C4H9NH2. C. C4H9NH2 < NH3 < C6H5NH2. D. C4H9NH2 < C6H5NH2 < NH3. Cu 85: t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6g CO2 v 12,6g H2O v 69,44 lt nit. Gi thit khng kh ch gm nit v xi, trong oxi chim 20% th tch. Cc th tch o ktc. Amin X c cng thc phn t l: A. C2H5NH2. B. C3H7NH2. C. CH3NH2. D. C4H9NH2. Cu 86: Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l : A. 15,65 g. B. 26,05 g. C. 34,6 g. D. Kt qu khc. Cu 87: (C-2012) Cho 20 gam hn hp gm hai amin no, n chc, mch h tc dng va vi V ml dung dch HCl 1M, thu c dung dch cha 31,68 gam hn hp mui. Gi tr ca V l A. 320. B. 50. C. 200. D. 100. Cu 88: (C-2012) Cng thc chung ca amin no, n chc, mch h l A. CnH2n-5N (n 6). B. CnH2n+1N (n 2). C. CnH2n-1N (n 2). D. CnH2n+3N (n 1). Cu 89: (C-2012) Pht biu no sau y l ng? A. Axit glutamic l thnh phn chnh ca bt ngt. B. Amino axit thuc loi hp cht hu c tp chc. C. Cc amino axit thin nhin hu ht l cc -amino axit. D. nhit thng, cc amino axit u l nhng cht lng. Cu 90: (C-2012) Cho 14,55 gam mui H2NCH2COONa tc dng hon ton vi dung dch HCl d, thu c dung dch X. C cn ton b dung dch X, thu c bao nhiu gam mui khan? A. 16,73 gam. B. 8,78 gam. C. 20,03 gam. D. 25,50 gam.

Created by: Trn Vn Trung | 2012

Chuyn : Amin - Aminoaxit | Ha Hc 12 Nng Cao

Cu 91: (H A-07) t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca X l A. H2N-CH2-COO-C3H7. B. H2N-CH2-COO-CH3. C. H2N-CH2-CH2-COOH. D. H2N-CH2-COO-C2H5. Cu 92: (H A-09) Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaOH. B. dung dch NaCl. C. Cu(OH)2 trong mi trng kim. D. dung dch HCl. Cu 93: (H B-09) Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH. Cu 94: (H B-09) Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3OH v NH3. B. CH3OH v CH3NH2. C. CH3NH2 v NH3. D. C2H5OH v N2. Cu 95: (H B-09) S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 3. B. 1. C. 2. D. 4. Cu 96: (C A-10) Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l A. C3H7NH2 v C4H9NH2. B. CH3NH2 v C2H5NH2. C. CH3NH2 v (CH3)3N. D. C2H5NH2 v C3H7NH2. Cu 97: (C A-10) Dung dch no sau y lm qu tm chuyn mu xanh? A. Phenylamoni clorua. B. Anilin. C. Glyxin. D. Etylamin. Cu 98: (H B-10) ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 120. B. 60. C. 30. D. 45. Cu 99: (H B-10) t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l A. 0,1. B. 0,4. C. 0,3. D. 0,2.
Cu 100: (H A-07) Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 16,5 gam. B. 14,3 gam. C. 8,9 gam. D. 15,7 gam.

Created by: Trn Vn Trung | 2012