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POLYME HA BC
hncuong@hcmus.edu.vn; hcuongpolymer@yahoo.com

S NHM CHC HOT TNH

Phn t nh

Polyme mch thng

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S NHM CHC HOT TNH

Polyme mch nhnh

S NHM CHC HOT TNH Polyme mng li ba chiu

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S NHM CHC HOT TNH f = 1: Khng to thnh polyme f = 2: Polyme mch thng f3: Polyme mng li

Polyme ha bc AB

A R B

R X
O

HO

CO2H

C
O

+ H2O
+ H 2O

H 2N

CO2H

NH

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Polyme ha bc AB
1. Polyeste t lactone (polyme ha mch) T axit -hydroxycacboxylic (polyme ha bc)
O O C
O R O C

R
Polyme ha mch m vng

O OH R CO 2H O R C + H 2O

(Polyme ha bc AB)

Polyme ha bc AB
2. Polyamid t lactam (polyme ha mch), v T axit -aminocacboxylic (polyme ha bc AB)
O NH R C NH R O C

(Polyme ha mch)
O

H2N

CO2H

NH

+ H2O

(Polyme ha bc AB)

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Polyme ha bc AB

Phn ng ng vng cnh tranh

Polyme ha bc AA/BB
A R A + B
' R

' X R

OCN R

NCO + HO R'

OH
O O

CNH R

NHCO R'

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Phng trnh Carothers

NO : s phn t/nhm chc ban u N : S phn t ti mt thi im phn ng. NO N : S phn t phn ng P : chuyn ha ca phn ng P= NO N NO Hoc N = NO(1 P)

( DP l s n v ti lp trung bnh DP = NO/N DP = 1 1-P DP = 1 1- 0.98

V d chuyn ha 98%

Polyme ha bc
Polyeste

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Polyme ha bc
Polyeste

Polyme ha bc
Polyeste

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Mt s loi polyeste

Polyme ha bc
Polyamid

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Polyamid

Polyme ha bc
Polyamid

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Polyme ha bc
Polyamid

Polyme ha bc
Polyamid

10

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Mt s loi polyamid

Polyme ha bc
Polycacbonat

11

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Polyme ha bc

Polyme ha bc
Polyuretan

12

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Polyme ha bc
Nha (keo) epoxy

Polyme ha bc
Nha Phenol-Formaldehyd

13

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Polyme ha bc
Nha Ure-Formaldehyd

Polyme ha bc
Nha Melamin

14