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Ti liu luyn thi H-C

ST V HP CHT
Cu 1: Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l A. 0,04. B. 0,075. C. 0,12. D. 0,06. Cu 2: Khi nung hn hp cc cht Fe(NO3)2, Fe(OH)3 v FeCO3 trong khng kh n khi lng khng i, thu c mt cht rn l: A. Fe3O4. B. FeO. C. Fe. D. Fe2O3. Cu 3: Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt ( ktc) hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l (cho H = 1, N = 14, O = 16, Fe = 56, Cu = 64) A. 2,24. B. 4,48. C. 5,60. D. 3,36. Cu 4: Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l A. 8. B. 5. C. 7. D. 6. Cu 5: Ho tan 5,6 gam Fe bng dung dch H2SO4 long (d), thu c dung dch X. Dung dch X phn ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V l (cho Fe = 56) A. 80. B. 40. C. 20. D. 60. Cu 6: Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M (va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l (cho H = 1, O = 16, Mg = 24, S = 32, Fe = 56, Zn = 65) A. 6,81 gam. B. 4,81 gam. C. 3,81 gam. D. 5,81 gam. Cu 7: Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp cht nng chy ca chng, l: A. Na, Ca, Al. B. Na, Ca, Zn. C. Na, Cu, Al. D. Fe, Ca, Al. Cu 8: Cho cc phn ng xy ra sau y: (1) AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag (2) Mn + 2HCl MnCl2 + H2 Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l B. Ag+ , Mn2+, H+, Fe3+. A. Mn2+, H+, Fe3+, Ag+. 2+ + + 3+ + 3+ + 2+ D. Ag , Fe , H , Mn . C. Mn , H , Ag , Fe . Cu 9: Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu c dung dch ch cha mt cht tan v kim loi d. Cht tan l A. Fe(NO3)3. B. HNO3. C. Fe(NO3)2. D. Cu(NO3)2. Cu 10: Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 s A. nhng 12 electron. B. nhn 13 electron. C. nhn 12 electron. D. nhng 13 electron. Cu 11: Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X trong dung dch HNO3 (d), thot ra 0,56 lt ( ktc) NO (l sn phm kh duy nht). Gi tr ca m l (cho O = 16, Fe = 56) A. 2,62. B. 2,32. C. 2,22. D. 2,52. Cu 12: Cho 6,72 gam Fe vo dung dch cha 0,3 mol H2SO4 c, nng (gi thit SO2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton, thu c (cho Fe = 56) A. 0,12 mol FeSO4. B. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4. C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4. D. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d. Cu 13: Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn ng, lc b phn dung dch thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hn hp bt ban u l (cho Fe = 56, Cu = 64, Zn = 65) A. 12,67%. B. 85,30%. C. 90,27%. D. 82,20%. Cu 14: Cho 0,01 mol mt hp cht ca st tc dng ht vi H2SO4 c nng (d), thot ra 0,112 lt ( ktc) kh SO2 (l sn phm kh duy nht). Cng thc ca hp cht st l A. FeO B. FeS2. C. FeS. D. FeCO3. 3+ 2+ Cu 15: kh ion Fe trong dung dch thnh ion Fe c th dng mt lng d A. kim loi Mg. B. kim loi Cu. C. kim loi Ba. D. kim loi Ag. Cu 16: Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng l (Cho H = 1; C = 12; O = 16; Fe = 56) Gio vin: Nguyn Cao Chung -1Chc cc em thnh cng !

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A. FeO; 75%. B. Fe2O3; 75%. C. Fe2O3; 65%. D. Fe3O4; 75%. Cu 17: Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c, nng n khi cc phn ng xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l A. MgSO4 v FeSO4. B. MgSO4. D. MgSO4, Fe2(SO4)3 v FeSO4. C. MgSO4 v Fe2(SO4)3. Cu 18: ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l A. 0,16. B. 0,18. C. 0,08. D. 0,23. Cu 19: Cho 11,36 gam hn hp gm Fe, FeO, Fe2 O3 v Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 49,09. B. 34,36. C. 35,50. D. 38,72. Cu 20: Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l A. 0,112. B. 0,560. C. 0,448. D. 0,224. Cu 21: X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc dng c vi dung dch 3+ 2+ + Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy th in ho: Fe /Fe ng trc Ag /Ag) A. Mg, Ag. B. Fe, Cu. C. Cu, Fe. D. Ag, Mg. Cu 22: Cho bit cc phn ng xy ra sau: 2FeBr2 + Br2 2FeBr3 2NaBr + Cl2 2NaCl + Br2 Pht biu ng l: B. Tnh oxi ha ca Br2 mnh hn ca Cl2. A. Tnh kh ca Cl mnh hn ca Br . 2+ 3+ C. Tnh kh ca Br mnh hn ca Fe . D. Tnh oxi ha ca Cl2 mnh hn ca Fe . Cu 23:a Nung mt hn hp rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh (d). Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe2O3 v hn hp kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia a v b l (bit sau cc phn ng, lu hunh mc oxi ho +4, th tch cc cht rn l khng ng k) A. a = 0,5b. B. a = b. C. a = 4b. D. a = 2b. b: Nung mt hn hp rn gm FeCO3 v FeS 2 vi s mol bng nhau trong bnh kn cha khng kh (d). Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe2O3 v hn hp kh. Bit p sut kh trong bnh trc v sau phn ng ln lt l a v b.Mi lin h gia a v b l :(bit sau cc phn ng, lu hunh mc oxi ho +4, th tch cc cht rn l khng ng k) A. a = 0,5b. B. a = b. C. a = 4b. D. a = 2b. Cu 24: Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l A. 9,75. B. 8,75. C. 7,80. D. 6,50. Cu 25: Tin hnh hai th nghim sau: - Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M; - Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M. Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr ca V1 so vi V2 l A. V1 = V2. B. V1 = 10V2. C. V1 = 5V2. D. V1 = 2V2. Cu 26: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) A. 1,0 lt. B. 0,6 lt. C. 0,8 lt. D. 1,2 lt. 3+, SO 2-, NH +, Cl-. Chia dung dch X thnh hai phn bng nhau: Cu 27: Dung dch X cha cc ion: Fe 4 4 - Phn mt tc dng vi lng d dung dch NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt ta; - Phn hai tc dng vi lng d dung dch BaCl2, thu c 4,66 gam kt ta. Tng khi lng cc mui khan thu c khi c cn dung dch X l (qu trnh c cn ch c nc bay hi) A. 3,73 gam. B. 7,04 gam. C. 7,46 gam. D. 3,52 gam. Gio vin: Nguyn Cao Chung -2Chc cc em thnh cng !

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Ti liu luyn thi H-C

Cu 28: Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 ( ktc). Gi tr ca V l A. 2,80. B. 3,36. C. 3,08. D. 4,48. Cu 29: Ha tan hon ton Fe3O4 trong dung dch H2SO4 long (d) c dung dch X1. Cho lng d bt Fe vo dung dch X1 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c dung dch X2 cha cht tan l B. FeSO4. C. Fe2(SO4)3. D. FeSO4 v H2SO4. A. Fe2(SO4)3 v H2SO4. Cu 30: Cho phng trnh ho hc: Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O Sau khi cn bng phng trnh ho hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca HNO3 l: A. 13x - 9y. B. 46x - 18y. C. 45x - 18y. D. 23x - 9y. Cu 31: Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c kh NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l A. 1,92. B. 3,20. C. 0,64. D. 3,84. Cu 32: Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l A. 360. B. 240. C. 400. D. 120. Cu 33: Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l A. 2,80. B. 2,16. C. 4,08. D. 0,64. Cu 34: Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l: A. 151,5. B. 137,1. C. 97,5. D. 108,9. Cu 35: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l A. 10,8 v 4,48. B. 10,8 v 2,24. C. 17,8 v 2,24. D. 17,8 v 4,48. Cu 36: Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch X v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat khan. Gi tr ca m l A. 52,2. B. 54,0. C. 58,0. D. 48,4. Cu 37: Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l A. 1,40 gam. B. 2,16 gam. C. 0,84 gam. D. 1,72 gam. Cu 38: Ho tan hon ton 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng l 1 : 2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l A. 57,4. B. 28,7. C. 10,8. D. 68,2. Cu 39: Trong cc cht: FeCl2, FeCl3, Fe(NO3 )2, Fe(NO3)3, FeSO4, Fe2(SO4)3. S cht c c tnh oxi ho v tnh kh l A. 2. B. 3. C. 5. D. 4. Cu 40: Cho m gam hn hp X gm FeO, Fe2O3, Fe3O4 vo mt lng va dung dch HCl 2M, thu c dung dch Y c t l s mol Fe2+ v Fe3+ l 1 : 2. Chia Y thnh hai phn bng nhau. C cn phn mt thu c m gam mui
1

khan. Sc kh clo (d) vo phn hai, c cn dung dch sau phn ng thu c m gam mui khan. Bit m2 m1 = 0,71.
2

Th tch dung dch HCl dng l A. 240 ml. B. 80 ml. C. 320 ml. D. 160 ml. Cu 41: Kh hon ton mt oxit st X nhit cao cn va V lt kh CO ( ktc), sau phn ng thu c 0,84 gam Fe v 0,02 mol kh CO . Cng thc ca X v gi tr V ln lt l
2

A. Fe3O4 v 0,224.

B. Fe3O4 v 0,448.

C. FeO v 0,224.

D. Fe2O3 v 0,448.

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Chc cc em thnh cng !

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Ti liu luyn thi H-C

Cu 42: Cho mt lung kh CO i qua ng s ng m gam Fe2O3 nung nng. Sau mt thi gian thu c 10.44 gam cht rn X gm Fe, FeO, Fe2O3 v Fe3O4 . Ha tan ht X trong dung dch HNO3 c, nng thu c 4.368 lt NO2 (sn phm kh duy nht iu kin chun). Gi tr ca m l A. 12 B. 24 C. 10.8 D. 16 Cu 43: A l hn hp cc mui Cu(NO3)2, Fe(NO3)2, Fe(NO3 )3, Mg(NO3)2. Trong O chim 9.6% v khi lng. Cho dung dch KOH d vo dung dch cha 50 gam mui A. Lc kt ta thu c em nung trong chn khng n khi lng khng i thu c m gam oxit. Gi tr ca m l A. 47.3 B. 44.6 C. 17.6 D. 39.2 Cu 44: Ha tan hon ton hn hp gm FeS2 0.24 mol v Cu2S vo dung dch HNO3 va thu c dung dch X (ch cha hai mui sunfat) v V lt kh NO duy nht . Gi tr ca V l A. 34.048 B. 35.84 C. 31.36 D. 25.088 Cu 45 : Cho 19,3 gam hn hp bt Zn v Cu c t l mol tng ng l 1 : 2 vo dung dch cha 0,2 mol Fe2(SO4 )3. Sau khi cc phn ng xy ra hon ton, thu c m gam kim loi. Gi tr ca m l A. 6,40 B. 16,53 C. 12,00 D. 12,80 Cu 46: Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn hp Y. Ha tan hon ton Y vo dung dch HNO3 (d), thu c 0,672 lt kh NO (sn phm kh duy nht, ktc). S mol HNO3 phn ng l A. 0,12 .B. 0,14. C. 0,16. D. 0,18. Cu 47: Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M. Ha tan ht a gam M bng dung dch H2SO4 c nng (d), thu c 20,16 lt kh SO2 (sn phm kh duy nht, ktc). Oxit MxOy B. FeO. C. Fe3O4. D. CrO. l A. Cr2O3. Cu 48: Ha tan hon ton 2,44 gam hn hp bt X gm FexOy v Cu bng dung dch H2SO4 c nng (d). Sau phn ng thu c 0,504 lt kh SO2 (sn phm kh duy nht, ktc) v dung dch cha 6,6 gam hn hp mui sunfat. Phn trm khi lng ca Cu trong X l A. 39,34%. B. 65,57%. C. 26,23%. D. 13,11%. Cu 49: t chy hon ton m gam FeS2 bng mt lng O2 va , thu c kh X. Hp th ht X vo 1 lt dung dch cha Ba(OH)2 0,15M v KOH 0,1M, thu c dung dch Y v 21,7 gam kt ta. Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l A. 23,2 B. 12,6 C. 18,0 D. 24,0 Cu 50: Hn hp X gm CuO v Fe2O3. Ho tan hon ton 44 gam X bng dung dch HCl (d), sau phn ng thu c dung dch cha 85,25 gam mui. Mt khc, nu kh hon ton 22 gam X bng CO (d), cho hn hp kh thu c sau phn ng li t t qua dung dch Ba(OH)2 (d) th thu c m gam kt ta. Gi tr ca m l A. 76,755 B. 73,875 C. 147,750 D. 78,875 Cu 51: Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi cc phn ng xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 6,72 B. 8,96 C. 4,48 D. 10,08 Cu 52: Cho 29,8 gam hn hp bt gm Zn v Fe vo 600 ml dung dch CuSO4 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v 30,4 gam hn hp kim loi. Phn trm v khi lng ca Fe trong hn hp ban u l A. 37,58%. B. 56,37%. C. 64,42%. D. 43,62%. Cu 53: Cho a gam Fe vo 100 ml dung dch hn hp gm HNO3 0,8M v Cu(NO3)2 1M. Sau khi cc phn ng xy ra hon ton, thu c 0,92a gam hn hp kim loi v kh NO (sn phm kh duy nht ca). Gi tr ca a l A. 11,0. B. 11,2. C. 8,4. D. 5,6. Cu 54:Ho tan va 10g hn hp hai kim loi X, Y (u c ho tr duy nht) vo dung dch hn hp gm hai axit HNO3 v H2 SO4, thu c 2,688 lt hn hp kh gm NO2 v SO2 ( ktc) c tng khi lng l 5,88 gam n 2 1 (khng c sn phm kh no khc). Bit SO4 (mui) . C cn dung dch khi lng mui khan thu c l: nNO (mui) 2
3

A. 17,7 gam B. 17,56 gam C. 20,0 gam D. 21,18 gam Cu 55:Ho tan va 10g hn hp hai kim loi X, Y (u c ho tr duy nht) vo dung dch hn hp gm hai axit HNO3 v H2SO4, thu c 2,688 lt hn hp kh gm NO2 v SO2 ( ktc) c tng khi lng l 5,88 gam (khng c sn phm kh no khc). Bit
nH2 SO 4 nHNO 3 1 . C cn dung dch khi lng mui khan thu c l: 3

A. 17,672 gam B. 17,56 gam C. 20,0 gam D. 21,18 gam Cu 56: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung dch HNO3 th thu c 0,448 lt mt kh duy nht (o ktc) v dung dch Y. C cn cn thn dung dch Y thu c 23 gam cht rn khan T. Xc nh s mol HNO3 phn ng ? A. 0,28 B. 0,32 C. 0,36 D. 0,34 Cu 57: Ha tan 2m (gam) kim loi M bng dung dch HNO3 c, nng, d hay ha tan m (gam) hp cht X (hp cht ca M vi lu hunh) cng trong dung dch HNO3 c, nng, d th cng thu c kh NO2 (sn phm kh duy nht)

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Chc cc em thnh cng !

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c th tch bng nhau cng iu kin nhit v p sut. Gi s nguyn t lu hunh ch b oxi ha ln mc cao nht. Kim loi M v cng thc phn t ca X ln lt l A. Mg v MgS. B. Cu v Cu2S. C. Cu v CuS. D. Fe v FeS. Cu 58: Dung dch X cha 14,6 gam HCl v 22,56 gam Cu(NO3)2. Thm m (gam) bt st vo dung dch X, sau khi phn ng xy ra hon ton thu c hn hp kim loi c khi lng l 0,5m (gam) v ch to kh NO (sn phm kh duy nht ca N+5). Gi tr ca m l A. 14,88. B. 20,48. C. 9,28. D. 1,92. Cu 59. Ho tan hon ton 0,1 mol FeS2 trong dung dch HNO3 c nng. Tnh th tch kh NO2 bay ra (ktc) v s mol HNO3 (ti thiu) phn ng (bit rng lu hunh trong FeS2 b oxi ho ln s oxi ho cao nht) A. 33,6 lt v 1,4 mol B. 33,6 lt v 1,5 mol C. 22,4 lt v 1,5 mol D. 33,6 lt v 1,8 mol Cu 60. Hn hp X gm Zn, Fe, Cu. Cho 18,5 gam hn hp X tc dng vi dung dch HCl d thu c 4,48 lit H2(ktc). Mt khc cho 0,15 mol hn hp X phn ng va vi 3,92 lt kh Cl2 (ktc). S mol Fe c trong 18,5 gam hn hp X l A. 0,12 mol B. 0,15 mol C. 0,1 mol D. 0,08 mol Cu 61. Ho tan hon ton 74 gam hn hp X gm FeO, Fe3O4, Fe2O3 bng dung dch H2SO4 long d sinh ra 178 gam mui sunfat. Nu cng cho 74 gam hn hp X trn phn ng vi lng d kh CO nhit cao v dn sn phm kh qua dung dch nc vi trong d th khi lng (gam) kt ta to thnh l bao nhiu? (cc phn ng xy ra hon ton) A. 130 B. 180 C. 150 D. 240 Cu 62. Cho 10,32 gam hn hp X gm Cu, Ag tc dng va vi 160 ml dung dch Y gm HNO31M v H2SO4 0,5 M thu c kh NO duy nht v dung dch Z cha m gam cht tan. Gi tr ca m l A. 20,36 B. 18,75 C. 22,96 D. 23,06 Cu 63. Cho hn hp dng bt gm Al v Fe vo 100 ml dung dch CuSO4 0,75 M, khuy k hn hp phn ng xy ra hon ton thu c 9 gam cht rn A gm hai kim loi. ho tan hon ton cht rn A th cn t nht bao nhiu lt dung dch HNO3 1M (bit phn ng to ra sn phm kh NO duy nht)? A. 0,6 lit B. 0,5 lit C. 0,4 lt D. 0,3 lit Cu 64. Cho 11,6 gam FeCO3 tc dng va vi dung dch HNO3 thu c hn hp kh (CO2, NO) v dung dch X. Khi thm dung dch HCl d vo dung dch X th ho tan ti a c bao nhiu gam bt Cu (bit c kh NO bay ra) A. 28,8 gam B. 16 gam C. 48 gam D. 32 gam Cu 65: Nhit phn hon ton R(NO3)2 (vi R l kim loi) thu c 8 gam mt oxit kim loi v 5,04 lt hn hp kh X gm NO2 v O2 (o ktc). Khi lng ca hn hp kh X l 10 gam. Xc nh cng thc ca mui R(NO3)2 ? A. Mg(NO3 )2. B. Zn(NO3)2 . C. Cu(NO3)2 . D. Fe(NO3)2. Cu 66: Cho hn hp X gm 8,4 gam Fe v 6,4 gam Cu vo dung dch HNO3. Sau khi phn ng hon ton thu c 3,36 lt kh NO (l sn phm kh duy nht, o ktc). Khi lng mui thu c sau phn ng l A. 41,3 gam. B. 41,1gam. C. 36,3 gam. D. 42,7 gam. Cu 67: Cho kh CO qua hn hp T gm Fe v Fe2O3 nung nng thu c hn hp kh B v hn hp cht rn D. Cho B qua dung dch Ca(OH)2 d thu c 6 gam kt ta. Mt khc, ha tan hn hp D bng dung dch H2SO4 c, nng, d thu c 0,18 mol SO2 (sn phm kh duy nht) v 24 gam mui. Phn trm s mol ca Fe trong hn hp T l A. 80%. B. 45%. C. 50%. D. 75%. Cu 68: Ha tan hn hp gm Fe v FexOy cn va 0,1 mol H2SO4 c thu c 0,56 lt kh SO2 (sn phm kh duy nht, o ktc) v dung dch X ch cha mui Fe(III). C cn dung dch X thu c khi lng mui khan l A. 20,0 gam. B. 16,0 gam. C. 8,0 gam. D. 10,0 gam. Cu 69: Hn hp B gm hai kim loi Cu v Al. Ho tan hon ton 4,82 gam hn hp B vo 40 ml dung dch D gm H2SO4 15M v HNO3 1M, un nng, thu c dung dch B v 2,688 lt hn hp kh E (ktc) gm NO v mt cht kh X khng mu. Hn hp kh E c t khi so vi hiro bng 26,34. 1- Tnh khi lng mi kim loi trong hn hp B ban u. 2- Tnh khi lng mi mui trong dung dch B . Cu 70:a) Hn hp A gm CuSO4 , FeSO4 v Fe2(SO4)3 , trong % khi lng ca S l 22% . Ly 50 gam hn hp A ho tan vo trong nc. Thm dung dch NaOH d , ly kt ta thu c em nung ngoi khng kh n khi lng khng i . Lng oxit sinh ra em kh hon ton bng CO th lng Fe v Cu thu c bng : A.17 gam B.18 gam C.19 gam D.20 gam b) Hn hp A gm CuSO4 + FeSO4 + Fe2(SO4)3 c % khi lng ca O l 44%. Ly 50 gam hn hp A ho tan trong nc, thm dd NaOH d, kt ta thu c em nung ngoi khng kh ti khi lng khng i. Lng oxit sinh ra em kh hon ton bng CO thu c m gam cht rn. Gi tr ca m l: A. 17 g B. 19 g C. 20 g D. 18 g Cu 71: Cho x mol Fe tc dng vi dung dch cha y mol HNO3 to ra kh NO v dung dch X. dung dch X tn ti cc ion Fe3+, Fe2+, NO 3 th quan h gia x v y l (khng c s thy phn cc ion trong nc) A. y

x 3y

B. y

xy

4
-5-

C. x y

D. x 3y

Gio vin: Nguyn Cao Chung

Chc cc em thnh cng !

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Cu 72: A l hn hp cc mui Cu(NO3)2, Fe(NO3)2, Fe(NO3 )3, Mg(NO3)2. Trong O chim 9.6% v khi lng. Cho dung dch KOH d vo dung dch cha 50 gam mui A. Lc kt ta thu c em nung trong chn khng n khi lng khng i thu c m gam oxit. Gi tr ca m l A. 47.3 B. 44.6 C. 17.6 D. 39.2 Cu 73. Cho a (gam) st vo dung dch cha y mol CuSO4 v z mol H2SO4 long, sau phn ng hon ton thu c kh H2, a (gam) ng v dung dch ch cha mt cht tan duy nht. Mi quan h gia y v z l A. y = 5z. B. y = z. C. y = 7z. D. y = 3z. Cu 74: Ha tan ht 2,25 gam hn hp X gm 2 kim loi A (ha tr 1) v B (ha tr 2) trong lng va dung dch hn hp HNO3, H2SO4 thu c 2,205 gam hn hp kh Y gm NO2 v mt kh Z; Y chim th tch 1,008 lt (ktc). Hy tnh khong khi lng mui khan to thnh.? A. 4,77g m(mui khan) 5,505g. B. 4,78g m(mui khan) 5,505g. C. 4,77g m(mui khan) 5,55g. D.4,7g m(mui khan) 5,505g. Cu 75 : Ha tan va 6g hn hp hai kim loi X, Y c ha tr tng ng l I, II vo dung dch hn hp 2 axit HNO3 v H2SO4, th thu c 2,688 lt hn hp kh B gm NO2 v SO2(ktc) v tng khi lng l 5,88g. Hy tnh khong khi lng mui khan to thnh.? Cu 76: Cho 3,97 gam hn hp FeCl2 v CuCl2 vi t l mol 1: 2 vo dung dch AgNO3 d, khi phn ng kt thc thu c kt ta. Khi lng (gam) ca kt ta l A. 6,82 B. 9,69 C. 7,32 D. 8,61 Cu 77: Hn hp X gm hai kim loi Cu v Al. Ho tan hon ton 18,2 gam hn hp X vo 100 ml dung dch Y gm H2SO4 CM v HNO3 2 M, un nng, thu c dung dch Z v 8,96 lt hn hp kh T (ktc) gm NO v mt cht kh A khng mu. Hn hp kh T c t khi so vi hiro bng 23,5 .Khi lng mui khan trong dung dch Z . A. 66,2 B. 9,69 C. 7,32 D. 8,61 Cu 78: Ha tan hon ton hn hp gm 9,75 gam Zn v 2,7 gam Al vo 200 ml dung dch cha ng thi HNO3 2M v H2SO4 1,5M thu c kh NO ( sn phm kh duy nht) v dung dch X ch gm cc mui. C cn dung dch X thu c khi lng mui khan l: A.41,25 B.53,65 gam C.44,05 gam D.49,65 gam Cu 79: Nung 12,12g mt mui A thu c sn phm kh v 2,40g mt hp cht rn khng tan trong nc. Nu cho ton b sn phm kh trn hp th vo 100g dung dch NaOH 3,6% iu kin xc nh th va v thu c dung dch cha mt mui c nng 6,972%. Tm cng thc A. A. Fe(NO3)2 B. Fe(NO3)3.9H2 O C. Fe(NO3)3 .7H2 O D. CuSO4.5H2O Cu 80: Cho x mol Fe tan ht trong dung dch cha y mol HNO3 ( t l x : y = 16 : 61) ta thu c mt sn phm kh Y duy nht v dung dch Z ch cha mui st. S mol electron m x mol Fe nhng khi tham gia phn ng l : A. 0,75y mol B. y mol C. 2x mol D. 3x mol Cu 81: Cho hn hp gm 6,96 gam Fe3O4 v 6,40 gam Cu vo 300 ml dung dch HNO3 C (mol/l). Sau khi cc phn ng kt thc thu c dung dch X, 672 ml kh NO (l sn phm kh duy nht, ktc) v cn li 1,60 gam Cu. Gi tr C l A. 1,20 B. 1,50 C. 0,12 D. 0,15 26. Cho phn ng: FexOy + 2yHI xFeI2 + (y-x) I2 + y H2O (*) phn ng * trn khng phi l phn ng oxi hoa kh nu: A) lun lun l phn ng oxi ho kh, khng ph thuc vo gi tr x,y B) X = y = 1 C) x = 3; y = 4 D) x = 2; y = 3. Cu 82. X l qung hematit cha 60% Fe2O3. Y l qung manhetit cha 69,6% Fe3 O4. Cn trn X, Y theo t l khi lng nh th no c qung Z m t 1 tn qung Z c th iu ch c 0,5 tn gang cha 96% st? A. 3/4. B. 2/5. C. 2/3. D. 3/5. Cu 83: Cho p gam Fe vo V (mL) dung dch HNO3 1M thy Fe tan ht, thu c 0,672 lt kh NO (ktc). C cn dung dch sau phn ng thu c 7,82 gam mui Fe. Gi tr ca p v V l: A. 2,24 gam v 120 mL. B. 1,68 gam v 120 mL. C. 1,68 gam v 240 mL. D. 2,24 gam v 240 mL. Cu 84: Cho 35,48 gam hn hp X gm Cu v FeCO3 vo dung dch HNO3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton thu c NO; 0,03 mol kh CO2; dung dch Y v 21,44 gam kim loi. C cn dung dch Y thu c khi lng cht rn khan l A. 38,82 g B. 36,42 g C. 36,24 g D. 38,28 g Cu 85: Hon tan hon ton 10,44 gam oxit st bng dung dch HNO3 c, nng (d) thu c dung dch X v 1,624 lt kh NO2 ( 0oC; 2 atm v l sn phm kh duy nht). C cn dung dch X th thu c bao nhiu gam mui khan ? A. 70,18 B. 29,00 C. 35,09 D. 32,67 Cu 86: Hn hp X gm Fe v Cu c t l tng ng l 4:7 v khi lng. trung ha hon ton 24,64 gam X cn dng ti thiu V lit dung dch HNO3 nng a1 M (nu sn phm kh ch c NO2) v cng cn V lit dung dch HNO3 a2 M (nu sn phm kh ch c NO). Ki t l T = a1 : a2 l: A. 1 T 1,5. B. T = 1,5. C. 1,5 T 2. D. T = 2. Gio vin: Nguyn Cao Chung -6Chc cc em thnh cng !

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Cu 87: Hn hp X gm FeS2 v Cu2 S. Ho tan hon ton X trong dung dch H2SO4 c nng, va thu c dung dch Y v 8,96 lit SO2 ( kc). Ly mt na dung dch Y cho tc dng vi dung dch Ba(NO3)2 d thu c 11,65 gam kt ta, nu ly mt na dung dch Y cn li tc dng vi dung dch Ba(OH)2 d khi lng kt ta thu c l A. 31,5gam. B. 34,5 gam. C. 15,75 gam. D. 17,75 gam. Cu 88: Cho hn hp X gm Fe, FeO, Fe3O4 c khi lng 4,04 gam phn ng vi dung dch HNO3 d thu c 336 ml kh NO (ktc, sn phm kh duy nht). S mol HNO3 tham gia phn ng l: A. 0,125 mol. B. 0,18 mol. C. 0,036 mol. D. 0,06 mol. Cu 89: Ngm 8,4 gam Fe trong 400 ml dung dch HNO3 1M kt thc phn ng thu c dung dch A v kh NO duy nht. Khi lng mui c trong dung dch A l: A. 27,0 gam B. 23,5 gam C. 24,2 gam D. 37,5 gam Cu 90: Hon tan 0,1 mol FeS2 trong 1 lt dung dch HNO3 1,2M, sau khi phn ng hon ton thu c dung dch X. Tnh khi lng Cu ti a c th tan trong X, bit sn phm kh HNO3 trong cc qu trnh trn l NO duy nht. A. 12,8 gam B. 25,6 gam C. 22,4 gam D. 19,2 gam Cu 91: Nhit phn hon ton 54,8 gam hn hp Fe(NO3)2 v Cu(NO3)2 trong iu kin khng c khng kh thu c 24 gam hn hp cht rn A v hn hp kh X. Sc X vo dung dch NaOH d n phn ng hon ton thu c dung dch Y. Khi lng mui c trong dung dch Y l A. 49,4 gam. B. 30,8 gam. C. 17 gam. D. 34 gam. Cu 92: Ha tan mt lng Fe3O4 trong lng d dung dch H2SO4 long, thu c dung dch X. Chia X lm 2 phn bng nhau. Phn 1 cho phn ng vi lng d dung dch NaOH, lc ly kt ta em nung trong khng kh n khi lng khng i th thu c 14,4 gam cht rn khan. Phn 2 phn ng va vi V ml dung dch K2 Cr2O7 1M. Gi tr ca V l A. 50. B. 20. C. 75. D. 10. Cu 93: Khi cho 2,00 gam hn hp X gm Mg, Al, Zn v Fe phn ng hon ton vi lng d dung dch HCl th thu c 1,12 lt kh hidro (ktc). Nu cho 2,00 gam hn hp X nh trn phn ng hon ton vi lng d kh Cl2 th thu c 5,763 gam hn hp mui. Thnh phn % v khi lng ca Fe c trong hn hp X l A. 8,40%. B. 22,40%. C. 19,20%. D. 16,80%. Cu 94: Cho hh X gm 2,4 gam Mg v 2,8 gam Fe vo 200 ml dd cha H2SO4 1M v HCl 0,5 M thu c dd Y. Cho tip 200ml dd Z cha Ba(OH)2 1M v NaOH 1 M vo dd Y th khi lng kt ta thu c l: A. 52,4 gam B. 51,1 gam C. 56,9 gam D. 46,6 gam Cu 95: Nhit phn 50,56 gam KMnO4 sau mt thi gian thu c 46,72 gam cht rn. Cho ton b lng kh sinh ra phn ng ht vi hn hp X gm Mg, Fe thu c hn hp Y nng 13,04 gam. Ha tan hon ton hn hp Y trong dung dch H2 SO4 c, nng d thu c 1,344 lt SO2 (ktc). % khi lng Mg trong X l: A. 28,15% B. 39,13% C. 46,15% D. 52,17% Cu 96: Hn hp X gm Cu, Fe, Mg. Nu cho 10,88 gam X tc dng vi clo d th sau phn ng thu c 28,275g hn hp mui khan. Mt khc 0,44 mol X tc dng vi dung dch HCl d th thu c 5,376 lt H2 (ktc). % khi lng ca Cu trong X l: A. 58,82% B. 43,52% C. 37,23% D. 67,92% Cu 97: Oxi ho chm a gam st ngoi khng kh, sau mt thi gian thu c 12,56 gam hn hp X gm Fe, FeO, Fe3O4 v Fe2O3. ho tan ht lng hn hp X trn cn va 440 ml dung dch HCl 1M, thu c dung dch Y v 672 ml kh (ktc). Cho dung dch Y tc dng vi dung dch AgNO3 d, thu c b gam kt ta. Gi tr ca a v b ln lt l A. 10,08 g v 74,2 g B. 9,52 gam v 70,7 gam C. 9,52 gam v 63,14 gam D. 11,2 gam v 76,4 gam Cu 98:Cho a gam CuFeS tc dng vi dung dch HNO c, nng, d thu c dung dch X v kh NO . Cho dung
2 3 2

dch X tc dng vi dung dch BaCl d thu c 34,95 gam kt ta khng tan trong dung dch axit mnh. Cho a gam
2

CuFeS2 tc dng vi dung dch H2SO4 c, nng, d thu c V lt kh SO2 ( ktc). Gi tr ca a v V ln lt l: A. 13,8 v 14,28 B.27,6 v 22,4 C. 13,8 v 17,64 D. 27,6 v 20,16 Cu 99: m gam phi st ngoi khng kh, sau 1 thi gian Fe b oxi ho thnh hn hp X gm 4 cht rn c khi lng 27,2 gam. Ho tan va ht X trong 300 ml dung dch HCl nng a mol/l thy thot ra 3,36 lt H2 (ktc) v dung dch Y. Cho tip dung dch HNO3 ti d vo dung dch Y c dung dch Z cha hn hp FeCl3 , Fe(NO3)3 , HNO3 d v c 2,24 lt NO duy nht thot ra (ktc). Gi tr ca m v a ln lt l: A. 22,4 gam v 2M B. 16,8 gam v 3M C. 22,4 gam v 3M D. 16,8 gam v 2M Cu 100. Xt phn ng : Cu2S + H+ + NO Cu2+ + SO 2 + NO + H2O 3 4 S mol H+ cn dng phn ng va vi 0,03 mol Cu2S l: A. 0,08 mol B 0,16 mol C. 0,1 mol D. 0,32 mol Cu 101: Cho m(g) bt Fe vo 800ml dd hn hp gm AgNO3 0,2M v HNO3 0,25M.Sau khi cc phn ng xy ra hon ton thu c 1,4m (g) hh kim loi v V(l) kh NO ( duy nht, ktc).Gi tr ca m(g) v V(l) ln lt l Gio vin: Nguyn Cao Chung -7Chc cc em thnh cng !

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A. 21,5(g) v 11,2(l) B. 16,8 gam v 3L C. 22,4 gam v 3L D. 16,8 gam v 2L Cu 102: Nhit phn hon ton m gam hn hp Fe(NO3)2 v AgNO3 thu c 117,6 lt hn hp kh X. Cho X hp th vo nc d thu c dung dch Y v 5,6 lt mt cht kh thot ra(ktc). % khi lng ca Fe(NO3)2 trong hn hp l A. 34,62%. B. 65,45%. C. 55,667%. D. 34,62% hoc 65,45%. Cu 103: Ho tan hon ton hn hp gm Fe, FeO, Fe3O4 trong dung dch HNO3 va , thu c 4,48 lt hn hp kh gm NO2 v NO (ktc) v 96,8 gam mui Fe(NO3 )3. S mol HNO3 phn ng l A. 1,1 mol B. 1,2 mol C. 1,3 mol D. 1,4 mol Cu 104: Ho tan 10,71 gam hn hp nhm, km, st trong 4 lt HNO3 x mol/lit va thu c dung dch A v 1,792 lt hn hp kh gm N2 v N2O c t l mol 1:1(khng c cc sn phm kh khc). C cn dung dch A thu c m gam mui khan. Gi tr ca x v m tng ng l: A. 0,11 M v 25,7 gam B. 0,22 M v 55,35 gam C. 0,11 M v 27,67 gam D. 0,33M v 5,35gam Cu 105 : Ho tan hon ton 7 g Fe trong 100 ml dung dch HNO3 4M thu c V lt kh NO (ktc) duy nht. un nh dung dch thu c m gam mui khan. Gi tr ca m v V l: A. 2,56gam v 1,12 lt B. 12,8gam v 2,24 lt C. 25,6gam v 2,24 lt D. 38,4gam v 4,48 lt Cu 106. Ha tan hon ton m gam hn hp D (gm Fe3 O4 v FeO vi s mol bng nhau) vo dung dch H2SO4 long, d, thu c dung dch X. Dung dch X phn ng va vi 400 gam dung dch Br2 2%. Ga tr ca m l A. 30,4. B. 11,6. C. 15,2. D. 22,8. Cu 107. Cho 27,25 gam hn hp X gm Mg, Al, Fe, Cu tc dng vi O2 thu c m gam hn hp cht rn Y. Cho ton b Y tc dng vi dung dch H2SO4 c, nng, thu c dung dch Z (cha 5 mui, vi tng khi lng mui l 96,85 gam) v 10,64 lt (ktc) kh SO2 duy nht. Ga tr ca m l A. 34,85. B. 20,45. C. 38,85. D. 31,25. Cu 108. Cho m gam hn hp FeCO3 v Fe(NO3 )2 c t l mol l 1:1 vo bnh kn khng c khng kh ri tin hnh nung cho n khi phn ng xy ra hon ton. Ly cht rn thu c hon tan trong dung dch HCl 1M th thy tn ht 600 ml. Tnh m? A. 29,60 B. 47,20 C. 48,80 D. 24,68 H 85% H 80% H 95% Cu 109: Cho s sau: FeS2 SO2 SO3 H2SO4 . Khi lng H2SO4 98% thu c t 1 tn qung pirit cha 60% FeS2 theo s trn l A. 1 tn. B. 1,055 tn. C. 1,548 tn. D. 0,646 tn Cu 110: Nung mt lng sunfua kim loi ha tr hai trong oxi d th thot ra 1,7584 lt kh (ktc). Cht rn cn li c nung nng vi bt than d to ra 13 gam kim loi. Nu cho kh thot ra i chm qua ng nung nng th th tch gim i 20%. Cng thc mui sunfua l A. NiS B. PbS C. SnS D. ZnS Cu 111: Cho a gam hn hp A gm (Fe, Cu, Ag, Al, Zn, Cr, Ni) tc dng vi dung dch HNO3 d, sau phn ng thu c dung dch B ( khng c mui amoni) v hn hp kh C gm ( x mol NO2, y mol NO, z mol N2O, t mol N2). C cn dung dch B thu c b gam mui khan. Mi lin h gia a, b, x, y, z, t l: A. b = a + 62(x + 3y + 8z + 10t ) B. b = a + 62(x + 3y + 4z + 5t ) C. b = a + 62(x + y + z + t ) D. b = a + 62(x + y + 2z + 2t ) Cu 112: t 24 gam hn hp X gm Fe v Cu trong khng kh thu c m gam hn hp cht rn Y gm Fe, Cu, CuO, Fe3O4. Cho hn hp Y vo dung dch H2SO4 c, nng d thu c 6,72 lt SO2 (ktc) v 72,0 gam mui sunfat khan. Xc nh gi tr ca m ? A. 26,4 B. 27,2 C. 28,8 D. 25,6 Cu 113: Ho tan ht 4,8 gam hn hp 2 kim loi M, N vo cc ng m gam dung dch cha HNO3 v H2SO4 (va ) thu c dung dch ch cha mui ca 2 kim loi v 2,1504 lt (ktc) hn hp 2 kh gm NO2 v X, sau phn ng khi lng dung dch trong cc tng thm 0,096 gam so vi m Khi lng mui khan thu c l: A. 5,648 gam. B. 11,296 gam. C. 12,750 gam. D. 13,250 gam. Cu 114: Cho mt lng dd cha 12,7 (g) FeCl2 vo mt lng nc Brom cha 4,8 (g) Br2 nguyn cht . Sau khi phn ng kt thc , cho dd AgNO3 d vo dd to thnh thu dc a(g) kt ta . Tnh a : A. 28,5 (g) B. 55,58(g) C. 44,3(g) D. 39,98(g) Cu 115: Ha tan hn hp X nng m gam gm Fe, FeCl2, FeCl3 trong HNO3 c nng c 8,96 lit NO2 (sn phm kh duy nht ktc) v dung dch Y. Thm NaOH d vo Y c 32,1 gam kt ta. Gi trr m l . A. 16,8 B. 25,675 C. 34,55 D. 17,75 Cu 116. Cho m gam X gm Fe, FeO, Fe3O4, Fe2O3 vo 400 ml dung dch HCl 2M , sau phn ng thu c 2,24l H2 (ktc), dung dc Y, v 2,8 gam Fe khng tan. Gi tr m l. A.30,0 B.31,6 C.27,2 D.24,4 Cu 117. Ho tan hon ton 34,8 gam hn hp X ( Gm FeO, Fe3O4, Fe2 O3) cn ti thiu Vml dung dch H2SO424,25% (D=1,2 g/ml), sau phn ng thu c hn hp hai mui c s mol bng nhau. Gi tr ca V l. Gio vin: Nguyn Cao Chung -8Chc cc em thnh cng !

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A.300 B.400 C.250 D.200 Cu 118. t chy hon ton 176 gam FeS v 12gam FeS2 cho ton b kh thu c vo Vml dung dch NaOH 25% (D=1,28 g/ml) Gi tr ti thiu ca V cn dng l. A.100 B.150 C.200 D.50 Cu 119. Ho tan hon ton hn hp X ( gm x mol Fe, Y mol Cu, Z mol Fe2O3 v t mol Fe3O4 ) trong dung dch HCl khng thy kh c kh bay ra khi khi bnh, dung dch thu c ch cha 2 mui . Mi quan h gia s mol cc cht c trong hn hp Xl. A.x+y =2z +2t B.x+y =2z +3t C.x+ y = 2z +2t D.x +y = Z +t Cho hn hp cht rn R nng 7,52 gam gm Fe, FeO, Fe3O4 v Fe2O3. Ha tan hon ton R trong H2SO4 c, Cu 120. nng thu c 0,672 lt kh SO2 (ktc) v dung dch X. Khi lng mui thu c trong dung dch X bng: A. 20,0 gam B. 40,0 gam C. 24,8 gam D. 12,4 gam Cu 121: Ho tan hon ton mt lng hn hp X gm Fe3O4 v FeS2 trong 63 gam HNO3, thu c 1,568 lt NO2(ktc). Dung dch thu c cho tc dng va vi 200ml dung dch NaOH 2M, lc kt ta em nung n khi lng khng i thu c 9,76 gam cht rn. Nng % ca dung dch HNO3 c gi tr l A. 47,2%. B. 46,2%. C. 46,6%. D. 44,2%. Cu 122: em nung 116 gam qung Xierit (cha FeCO3 v tp cht tr) trong khng kh (coi nh ch gm oxi v nit) cho n khi lng khng i. Cho hn hp kh sau phn ng hp th vo bnh ng dung dch nc vi c ha tan 0,4 mol Ca(OH)2, trong bnh c to 20 gam kt ta. Nu un nng phn dung dch, sau khi lc kt ta, th thy c xut hin thm kt ta na. Hm lng (Phn trm khi lng) FeCO3 c trong qung Xierit l: A. 50% B. 90% C. 80% D. 60% Cu 123: Cho 11,36 gam hn hp gm Fe, FeO, Fe2 O3, Fe3O4 phn ng ht vi dung dch HNO3 long d thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. Dung dch X c th ha tan ti a 12,88 gam Fe (to kh NO duy nht). S mol HNO3 c trong dung dch u l A. 0,88 mol B. 0,94 mol C. 1,04 mol D. 0,64 mol Cu 124: Ha tan m gam hn hp X gm FeO, Fe(OH)2, Fe(OH)3 ( nFeO nFe (OH )2 ) trong dung dch HNO3 va thu c dung dch Y (sn phm kh duy nht, ktc). C cn dung dch Y v ly cht rn thu c nung n khi lng khng i thu c 30,4 gam cht rn khan. Nu cho 11,2 gam Fe vo dung dch Y thu c dung dch Z v p gam cht rn khng tan. p c gi tr l: A. 0,84 gam B. 0,56 gam C. 1,12 gam D. 0,28 gam Cu 125: Cho m gam Fe tan ht trong 400 ml dung dch FeCl3 1M thu c dung dch Y. C cn dung dch Y thu c 71,72 gam cht rn khan. ha tan m gam Fe cn ti thiu bao nhiu ml dung dch HNO3 1M(sn phm kh duy nht l NO) A. 540 ml B. 320 ml C. 480 ml D. 160ml -3 -3 Cu 126: Ha tan hn hp X gm 2.10 mol FeS2 v 3.10 mol FeS vo dung dch H2SO4 c d thu c kh X. Cho ton b kh X hp th ht vo dung dch KMnO4 va thu c dung dch Y khng mu c pH=2. Th tch ca dung dch Y l: A. 2,28 lit B. 2 lit C. 1,14lit D. 1,5 lit Cu 127: t chy hon ton hn hp gm FeS2 v Ag2S vi s mol bng nhau thu c 3,696 lt SO2 (ktc) v cht rn B. Cho B tc dng vi H2SO4 long d, sau phn ng hon ton thy cn li m gam cht rn khng tan. Gi tr ca m l: A. 13,64 gam B. 11,88 gam C. 17,16 gam D. 8,91gam Cu 128: Ho tan hon ton 21,1gam hn hp gm FeCl2 v NaF (c t l mol l 1:2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l: A. 28,7g B. 39,5g C. 57,9g D. 68,7g Cu 129: Nhit phn mui Fe(NO3)2 trong bnh kn khng c khng kh, phn ng xong thu c 5,04 L hn hp kh ktc v m gam cht rn, m s nhn gi tr no sau y? A. 8. B. 12. C. 6,48. D. 10,36. Cu 130: Ha tan ht 5,36 gam hn hp FeO, Fe2O3. Fe3O4 trong dung dch cha 0,03 mol HNO3 v 0,18 mol H2SO4, kt thc phn ng thu c dung dch X v 0,01 mol kh NO (sn phm kh duy nht). Cho 0,02 mol Cu tc dng ht vi dung dch X, thu c dung dch Y. Khi lng Fe2(SO4)3 cha trong dung dch Y l. A. 20 gam B. 10 gam C. 24 gam D. 5 gam Cu 131: Ha tan ht 1,08 gam Ag vo dung dch HNO3 c, un nng thu c kh X (sn phm kh duy nht). Hp th ton b kh X vo 20ml dung dch KOH 1M thu c dung dch Y. C cn dung dch Y ri nung n khi lng khng i th khi lng cht rn cn li l. A. 1,994 gam B. 1,914 gam C. 1,41 gam D. 2,26 gam Cu 132: Ha tan ht 4 gam hn hp A gm Fe v 1 oxit st trong dung dch axit HCl (d) thu c dung dch X. Sc kh Cl2 cho n d vo X thu c dung dch Y cha 9,75 gam mui tan. Nu cho 4 gam A tc dng vi dung dch Gio vin: Nguyn Cao Chung -9Chc cc em thnh cng !

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HNO3 long d th thu c V lt NO ( sn phm kh duy nht ,ktc). Tnh V ? A.0,896 B.0,726 C.0,747 D.1,120 Cu 133: Hn hp X gm Al v mt kim loi R. Cho 1,93 gam X tc dng vi dung dch H2 SO4 long (d) thu c 1,456 lt H2 (ktc). Nu cho 1,93 gam X tc dng ht vi dung dch HNO3 c nng, (d) thu c 3,36 lt kh NO2 ( sn phm kh duy nht, ktc). Kim loi R l C. Zn D. Sn A. Mg B. Fe Cu 134. Cho a gam mui FeBr2 tc dng vi H2SO4 c nng d thu c 6,72 lit SO2 l sn phm kh duy nht (ktc). Tnh a A. 43,2 B. 97,2 C. 129,6 D. 64,8 Cu 135: Cho mt lng FexSy vo dung dch HNO3 d thu c dung dch A v 3,36lt kh NO2 ktc. Cho dung dch A tc dng vi dung dch BaCl2 thy c kt ta trng; cn khi cho dung dch A tc dng vi dung dch NH3 d thy c kt ta mu nu . Khi cho dung dch A tc dng vi dung dch Ba(OH)2 d thy xut hin 5,73g kt ta. Cng thc ca FexSy cho l: A. FeS B. FeS2 C. Fe2S3 D. Fe2S Cu 136: Ho tan hon ton 0,775 gam n cht A trong 50 ml dung dch HNO3 c c mt hn hp gm hai kh (tn ti trong iu kin thch hp) c khi lng l 5,75 gam, c t khi hi ca hn hp so vi hiro l 115/3 v mt dung dch gm 2 axit c oxi vi hm lng oxi ln nht. trung ho hai axit ny cn dng va ht 0,1 mol NaOH. Nng mol/lit ca dung dch HNO3 dng l A. 4 M B. 5 M C. 2 M D. 2,5M Cu 137: Cho 18,6g hn hp Fe v Zn vo 500ml dd HCl x(M). Sau phn ng hon ton c cn c 34,575g cht rn. Nu cho hn hp trn tc dng vi 800ml dd HCl x(M) c cn thu oc 39,9g cht rn. Gi tr ca x v khi lng ca Fe trong hn hp l A. x = 0,9 v 5,6 gam B. x = 0,9 v 8,4 gam C. x = 0,45 v 5,6 gam D. x = 0,45 v 8,4 gam Cu 138: Ha tan ht 51,6 gam hn hp Fe v Fe2O3 bng dung dch HNO3 nh nht thu c dung dch A trong s mol Fe(NO3)2 bng 4 ln s mol Fe(NO3)3 v V lt kh NO(ktc). Th tch HNO3 1M dung l: A 2,24 lt B 1,8 lt C 1,6 lt D 2,4 lt Cu 139: Ha tan ht 10,24 gam Cu bng 200 ml dung dch HNO3 3M c dung dch A. Thm 400 ml dung dch NaOH 1M vo dung dch A. Lc b kt ta, c cn dung dch ri nung cht rn n khi lng khng i thu c 26,44 gam cht rn. S mol HNO3 phn ng vi Cu l: A. 0,48 mol B. 0,58 mol C. 0,56 mol D. 0,4 mol Cu 140. Chia 9,76 gam hn hp X gm Cu v oxit st lm hai phn bng nhau. Ho tan hon ton phn th nht vo dung dch HNO3 thu c dung dch A v 1,12 lt (ktc) hn hp kh B (NO v NO2) c t khi so vi hidro bng 19,8. C cn dung dch A thu c 14,78 gam hn hp mui khan. Khi lng oxit st l A. 16 gam B. 4,64 gam. C. 7,2 gam D. 14,4 gam Cu 141: Nhit phn hon ton mt hn hp X gm x mol Fe(NO3)2 v y mol Cu(NO3)2 thu c hn hp kh B c t khi so vi H2 bng 22. T s x/y bng: A. 1/2. B. 2. C. 1/3. D. 3/2. Cu 142: un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht rn, dung dch X v 5,6 lt hn hp kh (ktc) gm NO v NO2 (khng c sn phm kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca m l A. 44,8. B. 40,5. C. 33,6. D. 50,4. Cu 143: Ha tan hn hp bt gm m gam Cu v 4,64 gam Fe3O4 vo dung dch H2SO4 (long, rt d) sau khi cc phn ng kt thc ch thu c dung dch X. Dung dch X lm mt mu va 100 ml dung dch KMnO4 0,1M. Gi tr ca m l: A. 1,24 B. 3,2 C. 0,64 D.0,96 Cu 143: Ha tan hon ton 26,4 gam hn hp Cu, Fe c t l mol tng ng l 1:2 bng dung dch HNO3 th thu c 0,3 mol NO (sn phm kh duy nht) v dung dch X. Khi lng mui st c trong X l A. 16 gam. B. 72,6 gam. C. 54 gam. D. 32 gam. Cu 144: Cho 2,8 gam bt st tc dng hon ton vi V ml dung dch HNO3 0,5M thu c sn phm kh NO duy nht v dung dch X. X c th tc dng va vi dung dch cha 0,03 mol AgNO3 . Gi tr ca V l: A. 280 ml B. 320 ml C. 340 ml D. 420 ml Cu 145: Hn hp X gm 2 kim loi (Cu v Ag). Ha tan hon ton m gam hn hp X trong dung dch cha 2 axit HNO3, H2SO4 c (va ) trong t l s mol ca HNO3, H2SO4 l 2:3 thu c dung dch Y cha 12,82 gam mui v hn hp kh Z cha 0,05 mol NO2 v 0,01 mol SO2. Gi tr ca m l A. 8,76. B. 3,32. C. 4,52. D. 2,58. Cu 146: Hn hp X gm FeCO3 v FeS2 .Cho X cng vi 1 lng Oxi vo bnh kn c th tch V(l). t nng bnh cho phn ng xy ra (gi thit kh nng phn ng ca 2 mui nh nhau ,sn phm phn ng l Fe2O3 ) sau phn ng a v iu kin ban u thu c rn Y v hn hp X, p sut bnh l P. ha tan ht rn Y cn 200 ml dd HCl Gio vin: Nguyn Cao Chung - 10 Chc cc em thnh cng !

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0.3M thu c kh M v sn phm E cn li, nu a M vo binh kn V(l) cng iu kin vi Z th p sut trong bnh l P/2 .Thm NaOH d vo sn phm E thu c rn F, lc F lm kh ngoi khng kh thu c 3.85 g. % FeCO3 trong X l: A.42.03% B.50.06% C.40.1% D.45.45% Cu 147. Cho lung kh H2 i qua 14,4gam MO (M l kim loi) nung nng thu c 12,8gam hn hp rn X. Cho hn hp X tan ht trong dung dch HNO3 d, sn phm kh thu c l 4,48 lt ( ktc) hn hp kh Y(gm NO v NO2). T khi ca Y so vi H2 l 19. Cng thc phn t ca MO l A. CuO. B. FeO. C. MgO. D. CrO. Cu 148. Trn mt oxit kim loi km th vi FeO theo t l mol 2:1 c hn hp A. Cho H2 d qua 15,2 g hn hp A un nng, phn ng hon ton c hn hp B . Cho B vo dung dch cha 0,8 mol HNO3 (va ) c Vlt NO l sn phm kh duy nht . Vy cng thc ca oxit kim loi kim th l: A.BeO B. MgO C. CaO D. BaO Cu 149. Nung 23,2 gam hn hp X FeCO3 v FexOy trong khng kh hon ton c kh A v 22,4 gam Fe2 O3 duy nht. Cho kh A hp th hon ton vo dung dch Ba(OH)2 d thu c 7,88 gam kt ta. Mt khc , ha tan ht 23,2 gam X cn va V ml dung dch HCl 2M . Gi tr ca V l : A. 200 B. 230 C. 250 D. 360

Gio vin: Nguyn Cao Chung

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Chc cc em thnh cng !