Trng i hc s phm h ni

Khi THPT Chuyn

M : 303

thi th i hc ln iii nm 2012

mn ha hc
(Thi gian lm bi: 90

pht)
-----------------------------------------

....***.

H v tn hc sinh: o Quang Qun Lp 12A1 THPT Bc Yn Thnh

Cu1: t chy hon ton 2,24 lt (ktc) hn hp X gm C2H4 v C4H4 th th tch kh
CO2 (ktc) v khi lng hi H2O thu c ln lt l
A. 5,6 lt v 2,7 gam.
B. 8,96 lt v 3,6 gam.
C. 3,36 lt v 3,6 gam. D. 6,72 lt
v 3,6 gam.
Cu2: Dy gm tt c cc cht u phn ng vi HCOOH l
A. AgNO3/NH3 , CH3NH2, C2H5OH, KOH, Na2CO3. B. CH3NH2, C2H5OH, KOH, NaCl.
C. NH3, K, Cu,NaOH,O2, H2.
D. Na2O, NaCl, Fe, CH3OH, C2H5Cl.
Cu3: Hn hp X c 2 este n chc l ng phn ca nhau. Cho 5,7 gam hn hp X tc
dng va ht vi 100 ml dung dch NaOH 0,5M thu c hn hp Y c hai ancol bn, cng s
nguyn t cac bon trong phn t. Cho Y vo dung dch Br2 d thy c 6,4 gam brm tham
gia phn ng. Cng thc hai este l
A. C2H3COOC3H7 v C3H7COOC2H5.
B. C3H5COOC3H7 v C3H7COOC3H5 .
C. C2H3COOC3H7 v C2H3COOC3H5.
D. C3H5COOC2H5 v C3H7COOC2H3 .
Cu4: Dy no di y gm tt c cc cht u lm i mu qu tm m?
A.H2NCH2COOH ; C6H5OH; C6H5NH2.
B. H2N(CH2)2NH2; HOOC(CH2)4COOH;
C6H5OH.
C.H2NCH2COOH ; HCOOH; CH3NH2.
D. CH3NH2; (COOH)2;
HOOC(CH2)2CH(NH2)COOH.
Cu5: t chy hon ton a gam hn hp cc este no, n chc, mch h. Sn phm chy
oc dn vo bnh ng dung dch nc vi trong thy khi lng bnh tng 6,2 gam. S
mol CO2 v H2O to ra ln lt l:
A.0,05 v 0,05.
B. 0,1 v 0,1.
C. 0,05 v 0,1.
D. 0,1 v
0,15.
Cu6: loi cc kh: SO2 , NO2, HF trong kh thi cng nghip, ngi ta thng dn kh
thi i qua dung dch no di y?
A.Ca(OH)2 .
B. NaOH.
C. NaCl.
D. HCl.
Cu7: Thuc th duy nht c th dng nhn bit 3 cht lng ng trong 3 l mt
nhn : phenol, stren, ancol benzylic l
A.dung dch Br2.
B. qu tm.
C. Na.
D. dung
dch NaOH.
Cu8: Cho cc cht sau : tinh bt; glu coz; saccaroz; mantoz; xenluloz. S cht
khng tham gia phn ng trng gng l
A. 3.
B. 4.
C. 2.
D. 1.
Cu9: Ha tan hon ton 3,9 gam kali vo 36,2 gam nc thu oc dung dch c nng
A. 4,04%. B. 14,0%. C. 13,97%. D. 15,47%.
Cu10: Cho 28,8 gam bt Cu vo 200ml hn hp axit HNO3 1,0M v H2SO4 0,5M thy thot
ra V lt kh NO ( sn phm kh duy nht , o ktc).Gi tr ca V l
A.4,48 lt.
B. 1,12 lit.
C. 6,72 lt.
D. 2,24 lt.
Cu11: Ha tan hon ton 6,0 gam hn hp hai kim loi trong dung dch HCl d thy to ra
4,48 lt kh H2 (ktc). C cn dung dch sau phn ng thu c m gam mui khan. Gi tr
ca m l
A.13,1.
B. 20,.2.
C. 13,3.
D. 20,6.

Trang 1/5 M thi 303

Cu12: Cho X l mt aminoaxit. Khi cho 0,01 mol X tc dng vi HCl th dng ht 80 ml
dung dch HCl 0,125M v thu c 1,835 gam mui khan. Khi cho 0,01 mol X tc dng vi
dung dch NaOH th cn dng 25 gam dung dch NaOH 3,2%. Cng thc cu to ca X l
A.(NH2)2C5H9COOH.
B. NH2C3H6COOH.
C. (NH2)2C3H5COOH. D.
(NH2)2C3H5(COOH)2.
Cu13: Cho x gam hn hp bt cc kim loi Ni v Cu vo dung dch dung dch AgNO3 d,
khuy k cho n khi phn ng kt thc thu c 54 gam kim loi. Mt khc cng cho x
gam hn hp bt kim loi trn vo dung dch CuSO4 d , khuy k cho n khi phn ng kt
thc thu c ( x + 0,5) gam kim loi. Gi tr ca x l
A.15,5.
B. 32,4.
C. 9,6.
D. 5,9.
Cu14: Trong dy bin ha:
C2H6 C2H5Cl C2H5OH CH3CHO CH3COOH CH3COOC2H5 C2H5OH.
S phn ng oxi ha- kh trn dy bin ha trn l
A. 3.
B. 4.
C. 5.
D. 2.
Cu15: Cho 100 ml dung dch aminoaxit X 0,2M tc dng va vi 80 ml dung dch
NaOH 0,25M. Mt khc 100 ml dung dch aminoaxit trn tc dng va vi 80 ml dung
dch HCl 0,5M. Bit X c t khi hi so vi H2 bng 52. Cng thc phn t ca X l
A.H2NC2H3(COOH)2.
B. (H2N)2C2H3COOH.
C. (H2N)2C2H2(COOH)2. D.
H2NC3H5(COOH)2.
Cu16: Cho cc cht sau: HCl; NaOH; Na3PO4; Na2CO3; Ca(OH)2. S cht ti a c th lm
mm nc cng tm thi l
A.4.
B. 2.
C. 3.
D. 5.
Cu17: Hn hp X gm 2 ancol. t chy hon ton 8,3 gam X bng 10,64 lt O2 thu c
7,84 lt CO2, cc th tch kh u o ktc. Hai ancol trong X l
A.HO(CH2)3OH v HO(CH2)4OH.
B. HO(CH2)3OH v CH3(CH2)3OH.
C. CH3(CH2)2OH v HO(CH2)4OH.
D. CH3(CH2)2OH v CH3(CH2)3OH.
Cu18: Cho kh CO (d) i qua ng s ng hn hp X gm : Al2O3, MgO, Fe3O4, CuO nung
nng thu c hn hp Y . Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn
khng tan Z. Gi s cc phn ng xy ra hon ton. Phn khng tan Z gm:
A. MgO, Fe3O4, Cu.
B. MgO, FeO, Cu.
C. Mg, Fe, Cu.
D. MgO, Fe, Cu.
Cu19: Phn ng no di y khng dng chng minh c im cu to phn t
glucoz?
A.Phn ng trng gng d chng t trong phn t glucoz c nhm CHO.
B.Tc dng vi Na chng minh phn t c 5 nhm OH .
C.Phn ng vi 5 phn t CH3COOH chng minh c 5 nhm OH trong phn t.
D.Ha tan Cu(OH)2 chng minh phn t c nhiu nhm chc OH.
Cu20: Ha tan hon ton m gam hn hp X gm Al, Fe, Zn bng dung dch HCl d. Dung
dch thu c sau phn ng tng ln so vi ban u ( m 2) gam. Khi lng (gam) mui
clorua to thmh trong dung dch l
A.m+71.
B. m + 35,5.
C. m+ 73.
D. m +
36,5.
Cu21: t mt lng Al trong 6,72 lt O2. Cht rn thu c sau phn ng cho ha tan
hon ton vo dung dch HCl thy thot ra 6,72 lt H2 ( cc th tch kh o ktc ).
Khi lng Al dng l
A.8,1 gam.
B. 16,2 gam.
C. 5,4 gam.
D. 10,8
gam.
Cu22: Nguyn t nguyn t A c tng s phn t cu to l 36. Trong ion A2+ cha s
electron s l:
A.4.
B. 2.
C. 8.
D. 6.
63
65
Cu23: ng c hai ng v l Cu v Cu. Nguyn t khi trung bnh ca ng l
63,5. Thnh phn % v khi lng ca ng v 65Cu c trong mui CuSO4 l:

Trang 2/5 M thi 303

A. 30,56%.

B. 28,98%.
C. 10,19%.
D. 9,95%.
Cu24: trung ha 500ml dung dch X cha hn hp HCl 0,1M v H2SO4 0,3M cn bao
nhiu ml dung dch hn hp gm NaOH 0,3M v Ba(OH)2 0,2M ?
A.125 ml.
B. 250 ml.
C. 500 ml.
D. 750 ml.
Cu25: Cho 18,5 gam hn hp X gm Fe, Fe3O4 tc dng vi 200 ml dung dch HNO3 long
un nng v khuy u. Sau khi phn ng xy ra hon ton c 2,24 lt kh NO duy
nht (ktc), dungdch Y v cn li 1,46 gam kim loi. Khi lng mui trong Y v nng
mol ca dung dch HNO3 l:
A.48,6 gam ; 2,7M.
B. 65,34 gam ; 2,7M.
C. 65,34 gam ; 3,2m.
D. 48,6
gam ; 3,2M.
Cu26:Trong cng nghip ngi ta tng hp NH3 theo phng trnh ha hc sau:
N2 (k) + 3 H2 (k) 2 NH4 (k)
Khi tng nng H2 ln hai ln ( gi nguyn nng ca kh nit v nhit phn
ng ) th tc phn ng tng ln bao nhiu ln?
A.2 ln.
B. 8 ln.
C. 16 ln.
D. 4 ln.
Cu27: Khi cho ankan X ( trong phn t c %C= 83,72) tc dng vi clo ch thu c 2
dn xut monoclo ng phn ca nhau. Tn ca X l:
A. 2- metylpropan.
B. 2,3 - imetylbutan.
C. n hexan.
D. iso
pentan.
Cu28: X mch h c cng thc C3Hy . Mt bnh c dung tch khng i cha hn hp
kh X v O2 d 1500C v c p sut 2 atm. Bt tia la in t chy X sau a
bnh v 1500C, p sut trong bnh vn l 2 atm . Ngi ta trn 9,6 gam X vi 0,6 gam
hiro ri cho qua bnh ng Ni nung nng ( H= 100%) th thu chn hp Y . Khi lng
mol trung bnh ca Y l:
A. 52,5.
B. 46,5.
C. 48,5.
D. 42,5.
Cu29: C cc l ring bit ng cc dung dch khng mu : AlCl3, ZNCl2. FeSO4.
Fe(NO3)3. NaCl. Ch dng dung dch no di y phn bit cc l mt nhn trn ?
A. Na2CO3 .
B. Ba(OH)2.
C. NH3 .
D. NaOH.
Cu30: Nung m gam bt st trong oxi thu c 3,0 gam hn hp cht rn X. Ha tan ht
hn hp X trong dung dch HNO3 (d) , thot ra 0,56 lt kh NO (l sn phm kh duy nht,
o ktc). Gi tr ca m l:
A. 2,52.
B. 2,10.
C. 4,20.
D. 2,8 0
Cu31: Dy ion no sau y sp xp theo chiu tng dn ca bn knh ion?
A. Mg2+ , Na+ , O2-, F-. B. Mg2+, Na+, F-, O2-.
C. O2-, F-, Na+, Mg2+.
D. Na+, Mg2+, O2-,
F-.
Cu32: Hn hp X gm HCOOH, v CH3COOH trn theo t l mol 1 : 1 . Cho 10,6 gam hn
hp X tc dng vi 11,5 gam C2H5OH (c H2SO4 c lm xc tc) thu c m gam este
( hiu sut phn ng este ha t 80%). Gi tr ca m l:
A.16,2.
B. 14,08.
C. 17,6.
D. 12,96.
Cu33: Thy phn m gam tinh bt , sn phm thu c em ln men sn xut ancol
etylic, ton b kh CO2 sinh ra cho qua dung dch Ca(OH)2 d, thu c 750 gam kt ta.
Nu hiu sut qu trnh sn xut ancol l 80% th m c gi tr l:
A. 486,0.
B. 949,2.
C. 759,4.
D. 607,5.
Cu34: Cho ancol X tc dng vi axit Y c este E. Lm bay hi 8,6 gam E thu c th
tch hi ng bng th tch ca 3,2 gam O2 ( o cng iu kin). Bit MX > MY. Cng
thc cu to ca E l:
A.CH2=CHCOOCH3.
B. CH2=CHCOOC2H5.
C. HCOOCH2CH=CH2. D.
HCOOCH=CHCH3.
Cu35: Oxi ha m gam mt hn hp X gm fomanehit v axetanehit bng oxi iu
kin thch hp thu c hn hp Y ch gm cc axit hu c. T khi hi ca Y so vi X bng
x. Khong bin thin ca x l:

Trang 3/5 M thi 303

A. 1,36 < x < 1,50.

B. 1,30 < x < 1,50.
C. 1,36 < x < 1,53.
D. 1,30 <
x < 1,53.
Cu36: Ha tan hon ton 13,92 gam Fe3O4 bng dung dch HNO3 thu c 448 ml kh
NxOy (ktc). NxOy l kh no di y?
A. NO.
B. N2O.
C. N2O5.
D. NO2.
Cu37: un nng 7,6 gam hn hp X gm C2H2 , C2H4 v H2 trong bnh kn vi xc tc Ni
thu c hn hp kh Y. t chy hon ton hn hp Y , dn sn phm chy thu c ln lt
qua bnh 1 ng H2SO4 c, bnh 2 ng Ca(OH)2 d thy khi lng bnh 1 tng 14,4
gam.. Khi lng tng ln bnh 2 l:
A.6,0 gam.
B. 35,2 gam.
C. 22,0 gam.
D. 9,6 gam.
Cu38: TNT ( 2,4,6 trinitrotoluen) c iu ch bng phn ng ca toluen vi hn hp
HNO3 c v H2SO4 c, trong iu kin un nng. Bit hiu sut ca ton b qu
trnh tng hp l 80%. Lng TNT to thnh t 230 gam toluen l:
A. 550,0 gam.
B. 454,0 gam.
C. 687,5 gam.
D. 567,5
gam..
Cu39: X l hn hp kim loi Ba v Al . Ha tan m gam X vo lng d nc thu c 8,96 lt H2
(ktc). Cng ha tan m gam X vo dung dch NaOH d th thu c 12,32 lt kh H2 (ktc).
Gi tr ca m l:
A. 57,50.
B. 13,70. C. 21,80.
D. 58,85.
Cu40: Cho 100ml dung dch hn hp CuSO4 1M v Al2(SO4)3 1,5M tc dng vi dung dch
NH3 d, lc ly kt ta em nung n khi lng khng i thu c cht rn c khi lng
l:
A.23,3 gam.
B. 30,6 gam.
C. 15,3 gam.
D. 8,0 gam.
Cu41: X phng ha hon ton 2,22 gam hn hp X gm hai este ng phn ca nhau
cn dng va ht 30 ml dung dch NaOH 1M. Mt khc khi t chy hon ton hn hp X
thu c kh CO2 v hi H2O vi th tch bng nhau ( cng iu kin). Cng thc cu to
ca hai este l:
A. CH3COOCH=CH2 v CH2=CHCOOCH3.
B. CH3COOC2H5 v C2H5COOCH3
C. HCOOCH2CH2CH3 v HCOOCH(CH3)CH3.
D. CH3COOCH3 v HCOOC2H5.
Cu42: Dy no sau y gm cc ng v ca cng mt nguyn t ha hc?
40
28
A. 40
B. 14
X, 29
C. 146 x , 147 Y.
D. 199 X, 20
18 X , 19 Y.
10 Y.
14 Y.
+
-
2+
Cu43: Cho phn ng : Cu + H + NO 3
Cu + NO + H2O .
Tng cc h s cn bng (ti gin , c ngha) ca phn ng trn l:
A.28.
B. 10.
C. 23.
D. 22.
Cu44: Hn hp X c C2H5OH , C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s
mol. t chy m gam hn hp X thu c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc
13,2 gam hn hp X thc hin phn ng trng bc thy c p gam Ag kt ta. Gi tr ca p
l
A.9,72.
B. 8,64.
C. 10,8.
D. 2,16.
Cu45:Ha tan 4,0 gam hn hp Fe v kim loi X ( ha tr II ng trc hidro trong dy
in ha) bng dung dch HCl d, thu c 2,24 lt kh H2 (ktc). ha tan 2,4 gam X
th cn dng cha n 250 ml dung dch HCl 1M. X l kim loi no di y?
A.Mg.
B. Ca.
C. Ba.
D. Zn.
Cu46: Trn 3 dung dch HCl 0,3M; H2SO4 0,2M v H3PO4 0,1M vi nhng th tch bng
nhau thu c dung dch X. Dung dch Y gm NaOH 0,1M v Ba(OH)2 0,2M. trung ha
300 ml dung dch X cn va V ml dung dch Y. Gi tr ca V l:
A.600.
B. 1000.
C. 333,3.
D. 200.
Cu47: Chn cu ng trong cc cu sau:
A.Phng php chung iu ch ancol no, n chc bc 1 l cho anken cng nc.
B.Khi oxi ha ancol no n chc th thu c anehit.
C.un nng ancol metylic vi H2SO4 c 1700C thu c ete.

Trang 4/5 M thi 303

D.Ancol a chc ha tan Cu(OH)2 to thnh dung dch mu xanh.

Cu48: t chy 0,27 gam cht hu c X thu c 0,22 gam CO2; 0,18 gam H2O v 56 ml
N2 (ktc). Bit t khi hi ca X so vi oxi l 3,375. Khi cho X tc dng vi dung dch NaOH
d ri c cn thu c mt cht hu c Y n chc v hn hp cht v c. X l:
A.Mui ca amin.
B. Amino este.
C. Mui amni.
D. Amino axit.
Cu49: T phn ng: Fe(NO3)2 + AgNO3 Fe(NO3)3 + Ag. Pht biu no di y l
ng?
A. Fe3+ c tnh oxi ha mnh hn Ag+.
B. Fe2+ kh c Ag+.
C. Ag+ c tnh kh mnh hn Fe3+.
D. Fe2+ c tnh oxi ha mnh hn
3+
Fe .
Cu50: Nguyn t R to vi hyr hp cht kh cng thc RH4. Trong oxit cao nht ca R,
oxi chim 53,33% v khi lng. Vy R l:
A.N.
B. C.
C. P.
D. Si.
..Ht..
p n:
Cu
p n
Cu
p n
Cu
p n
Cu
p n
Cu
p n
1
D
11
B
21
B
31
C
41
D
2
A
12
D
22
A
32
D
42
B
3
C
13
A
23
C
33
C
43
D
4
D
14
A
24
C
34
C
44
B
5
B
15
B
25
D
35
C
45
A
6
A
16
A
26
B
36
A
46
D
7
A
17
A
27
B
37
C
47
C
8
A
18
D
28
D
38
B
48
A
9
B
19
B
29
C
39
C
49
B
10
D
20
A
30
A
40
C
50
D

Trang 5/5 M thi 303