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CHNG III : CHUN OXI HA KH

BI 1: 0,1 g mu phn tch cha V, Cr, Mn c phn hy thnh dung dch . Sau khi ch
ha dung dch cc nguyn t tn ti di dng VO 2+ , Cr2O72- , MnO4- .Chun dung dch
bng dung dch chun Fe2+ 0,1 M ch ht 50 ml . Ion VO 2+to thnh c chun
bng dung dch chun KMnO4 0,01M th ht 5ml . Sau thm vo lng mui
pitphtphat to phc vi Mn(III) khi chun Mn 2+ bng dung dch KMnO4 trn ,
th tch tiu tn ln chun ny l 10ml . Tnh hm lng % mi kim loi trong mu
( V=50,49 ; Cr =52 ; Mn=54,94 ). Bit E 0Fe3+/Fe2+ = 0,77V ; E0VO2+/VO2+=1 V ;
E0Cr2O72-/ 2Cr3+= 1,36V ;E0MnO4-/Mn2+= 1,51V

BI GII:Tm tt s chun nh sau:

V, Cr, Mn
Ch ha
VO2+,,
Fe2+

VO2+, Cr3+, Mn2+


MnO4

VO2+, Cr3+, Mn2+


MnO4

VO2+, Cr3+, Mn3+


Trong mu phn tch cha V, Cr , Mn
2

Sau khi ch ho ta c dung dch gm: VO2 2 , Cr2 O7 , MnO4 .


* Chun dung dch bng dung dch tiu chun Fe2+ 0,1M ht 50ml.
1
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Ta c:

E o Fe3+ / Fe2+

= 0,771(V)

E o Cr2O72 / 2Cr3+

= 1,33 (V)

E oVO2+ /VO2+

= 1 (V)

E o MnO4 / Mn2+

= 1,51 (V)

Vy th t phn ng chun xy ra l:
+ u tin Fe2+ kh MnO4 thnh Mn2+:
5

Fe2+

Fe3+ + e

MnO4 + 8H+ + 5e

Mn2+ + 4H2O

5Fe2+ + MnO4 + 8H+

+ Sau : Fe2+ kh Cr2 O7


6

Fe2+

5Fe3+ + Mn2+ + 4H2O

(1)

thnh Cr3+:

Fe3+ + e
2

Cr2 O7 + 14H+ + 6e

2Cr 3+ + 7H2O

6Fe2+ + Cr2 O7 + 14H+

2Cr 3+ +6Fe3+ + 7H2O

+ Cui cng Fe2+ kh VO2 + thnh VO2+:


Fe2+

Fe3+ + e

+
VO2 + 2H+ + e

Fe2+ + VO2 + + 2H+

VO2+ + H2O
Fe3+ + VO2+ + H2O

Vy ta c:
S lg VO2 + + S lg Cr2 O7

+ S lg MnO4 = S lg Fe2+ (S lg: s ng lng gam)

SVO + + S Cr O 2 + S MnO = S 2 +
2
2 7
4
Fe

(*) (S: s ng lng gam )

Gi x, y, z ln lt l s ng lng gam ca V, Cr v Mn trong mu phn tch ban u.


2

Sau khi ch ho ta c dung dch gm: VO2 2 , Cr2 O7 , MnO4 .


2
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

SVO +

Ta c :

= SV = x

S Cr O 2 = 3 SCr = 3y
2 7
S MnO = 5 SMn = 5z
4

S Fe2 + =

5.10-3
= 5.10-3 (**)

Thay vo (*) ta c : x + 3y + 5z =

*Sau chun ion VO2+ to thnh bng dung dch chun KMnO4 0,01M ht 5ml.
5

VO2+ + H2O

+
VO2 + 2H+ + e

MnO4 + 8H+ + 5e

Mn2+ + 4H2O

5VO2+ + H2O + MnO4

Mn2+ +5 VO2 + + 2H+ (2)

Ta c:

SVO 2 + = S MnO =
4

= 2,5.10-4 = x

(***)

* Mt khc qu trnh chun VO2+ bng dung dch chun KMnO4 to ra Mn2+ , vy
Mn2+ trong dung dch lc ny c tao ra t phng trnh (1) v (2).
+ (1) : SMn2+ to ra = SMn ban u = z

+ (2) : SMn2+ to ra =

1S
1
MnO4 chun =
5
5

= 5. 10-5

Vy tng s ng lng ca Mn2+ trong dung dch lc ny l:


SMn2+ = z + 5. 10-5

*Chun Mn2+ bng dung dch chun KMnO4 0,01M ht 10ml:


3
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Mn2+

Mn3+ + e

MnO4 + 8H+ + 4e

4Mn2+ + MnO4 + 8H+

Mn3+ + 4H2O

4Mn3+ + 4H2O

Ta c:
SMn2+ = S MnO4
Hay :

z + 5. 10-5 =

= 4.10-4

z = 3,5 .10-4 (****)

T (**) ; (***) ;(****) ta c h sau :


x + 3y + 5z = 5.10-3
x = 2,5 . 10-4

y = 10-3

z = 3,5 .10-4

Vy:
+ SV = x = 2,5.10-4
v = 2,5.10-4 50,94 = 0,0127 (g )

Khi lng ca V l : mV = SV

Phn trm ca V l :

12,7 %

+ SCr = y = 10-3
Khi lng ca Cr l : mCr = SCr
Phn trm ca Cr l :

Cr

= 10-3

= 0,052 (g)

= 52 %

+ SMn = z = 3,5.10-4
Khi lng ca Mn l : mMn =SMn
Phn trm ca Mn l :

Mn

= 3,5.10-4 . 54,94 = 0,0192(g )

= 19,2%

( : ng lng gam )

4
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

BI 2: nh phn Fe , Cr ,Ti trong hn hp ngi ta ch ha v thu c 100 ml


dung dch cha Cr3+ ; Fe3+ ; TiO2+ ( Dung dch A).
Ly 20 ml dung dch A cho qua ct kh km v hng dung dch chy ra khi ct
vo mt bnh kn c kh quyn khng kh cha oxi .Chun dung dch thu c bng
dung dch chun KMnO4 0,02 M th ht 43 ml .
Ly 20ml dung dch A na, cho qua ct kh bc , chun dung dch thu c
bng dung dch chun K2Cr2O7 0,01M th ht 25,2ml .
Ly 20 ml dung dch A thm vo NH3 v H2O2 , un si phn hy ht H2O2
d , lc b kt ta , axt ha nc lc thu c v chun bng dung dch Fe2+ 0,05 M
th ht 12,4 ml .
Tnh hm lng ( s mg) ca mi kim loi trong dung dich ban u .
(Bit Cr =52 ; Fe = 56; Ti = 48 ) .Bit E0TiO2+/Ti3+ = 0,1 V ; E0MnO4-/Mn2+= 1,51V ;
E0Cr2O72-/ 2Cr3+= 1,36V ;E0Fe3+/Fe2+ = 0,77V

BI GII:
Tm tt s chun nh sau:

Fe2+, Cr2+, Ti3+

Fe, Cr, Ti

Fe3+
, Cr3+
, TiO2+
3+
3+
Fe , Cr , TiO2+

Fe2+, Cr3+, TiO2+

Fe3+Cr2O72- TiO2+

5
Trn Th M L Lp Ha 3B
3+

3+

2+

Fe , Cr , TiO

Bi tp ln
3+

3+

2+

Fe , Cr , TiO

3+

Fe , Cr3+, TiO2+

CHNG III : CHUN OXI HA KH

Ch ho

Ct kh km

ct kh bc NH3,H2O2

KMnO4 K2Cr2O7Fe2+

*Xt trong 20ml dung dch A:

Ta c:

E o Fe3+ / Fe2+

= 0,771 (V) ; E o Cr 3+ / Cr 2+ = - 0,408 (V)

6
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

E oTiO2+ /Ti3+

= 0,099 (V) ; E o Zn2+ / Zn = - 0,763 (V)

*Cho 20 ml dung dch A qua ct kh km, khi Cr3+, Fe3+, TiO2+ u b kh:

Vy th t phn ng xy ra:
+ u tin Zn kh Fe3+ v Fe2+ :

Zn + Fe3+

Fe2+

Fe3+ + e

Zn

Zn2+ + 2e

Fe2+ + Zn2+

+ Sau Zn kh TiO2+ thnh Ti3+


Zn2+ + 2e

Zn

TiO2+ + 2H+ + e

Ti3+ + H2O

Zn + 2TiO2+ + 4H+

2Ti3+ + Zn2++ 2H2O

+ Cui cng Zn kh Cr3+ thnh Cr2+:


Zn2+ + 2e

Zn
2

Cr3+ +1e

Cr2+
Zn + 2Cr3+

2Cr2+ + Zn2+

*Xt trong 20ml dung dch A:


Gi s ng lng gam ca Fe3+ ,Cr3+, TiO2+ trong 20ml dung dch A ln lt l x, y, z.
Ta c :

S Fe2+ = S Fe3+ = x
S Cr 2+ = S Cr3+ = y
STi 3+ = STiO2 + = z
7

Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Vy dung dch sau khi cho i qua ct kh km l: Fe2+, Cr2+, Ti3+


Chun dung dch thu c bng dung dch chun KMnO4 0,02M ht 43ml.
Ta c:

E o MnO4 / Mn2+

= 1,51 (V) nn th t chun l:

+ u tin KMnO4 oxi ho Cr2+ thnh Cr3+


Cr2+

Cr3+ + e

MnO4 + 8H+ + 5e

5Cr2+ + MnO4 + 8H+

Mn2+ + 4H2O

5Cr3+ + Mn2+ + 4H2O

+ Sau KMnO4 oxi ho Ti3+ thnh TiO2+:


Ti3+ + H2O

MnO4 + 8H+ + 5e

5Ti3+ + H2O + MnO4

TiO2+ + 2H+ + e
Mn2+ + 4H2O
Mn2+ + 5TiO2+ + 2H+

+ Cui cng KMnO4 oxi ho Fe2+ thnh Fe3+:


Fe2+

Fe3+ + e

MnO4 + 8H+ + 5e

5Fe2+ + MnO4 + 8H+

Mn2+ + 4H2O

5Fe3+ + Mn2+ + 4H2O

Ta c: S Fe2+ + S Cr 2+ + STi 3+ = S KMnO4


x+y+z=

= 4,3.10-3 ( *)

Ta c : E0Ag+ / Ag = 0,799 V
*Ly 20ml dung dch A cho qua ct kh bc th:
Khi ch c Fe3+ b kh to thnh Fe2+:
Fe3+ + Ag

Fe2+ + Ag+

8
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Vy dung dch sau khi cho qua ct kh bc gm : Fe2+ , Cr3+, TiO2+.


*Sau chun dung dch thu c bng dung dch chun K2Cr2O7 0,01M ht 25,2 ml. Lc
ny K2Cr2O7 ch oxi ho Fe2+ thnh Fe3+:

Fe2+

Cr2O7
6Fe2+ + Cr2 O7

Fe3+ + e
2

+ 14H+ + 6e

+ 14H+

2Cr3+ + 7H2O

6Fe3+ +2 Cr3+ + 7H2O

Ta c:
S Fe2+ = S Cr2O7 2
Hay

= 1,512.10-3 (**)

x =

*Ly 20ml dung dch A, thm vo NH3 v H2O2. Khi ch c Cr3+ b oxi ho thnh
2
Cr2O7 .
3

2OH- + 2e

H2O2

2Cr3+ + 14OH- + 6e

Cr2 O7 + 7H2O

2Cr3+ + 3H2O2 + 8OH-

Cr2 O7 + 7H2O

(1)

Vy dung dch sau khi cho thm NH3 v H2O2 gm: Fe3+ , Cr2 O7

, TiO2+

Ta c:E0Cr2O72-/ 2Cr3+= 1,36V


*Chun dung dch thu c bng dung dch tiu chun Fe2+ 0,05M ht 12,4ml. Lc
ny ch c Cr2O7

b Fe2+ kh thnh Cr3+ :

Fe2+

Fe3+ + e

9
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Cr2O7

+ 14H+ + 6e

6Fe2+ + Cr2 O7

+ 14H+

S Cr O 2 = S Fe2+ =
2 7

Ta c:
V: Cr2 O7
Nn :

2Cr3+ + 7H2O

+ 14H+ + 6e

S Cr3+ =

6Fe3+ + 2Cr3+ + 7H2O

= 6,2 . 10-4
2Cr3+ + 7H2O

1 S
Cr2O7 2
6

Nhng t phng trnh (1) ta c c 2mol Cr3+ th to ra 1 mol Cr2 O7


Nn :

S Cr3+ = 2.

Hay

y = 2.

1 S
Cr2O7 2
6

1
.6,2 . 10-4 = 2,0667 .10-4 (***)
6

T (*) ;(**) ;(***) ta c h sau :

x + y + z = 4,3.10-3
x = 1,512.10-3

z = 2,5813.10-3

y = 2,0667 .10-4

Gi mFe , mCr , mTi ln lt l khi lng ca Fe, Cr, Ti trong hn hp phn tch

10
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Trong 20ml ta c:
S Fe3+ = x = SFe= 1,512.10-3
=1,512 .10-3 56 = 84,672.10-3 g = 84,672 mg

mFe= SFe

-4
S Cr 3+ = y = SCr = 2,0667.10

= 2,0667.10-4 52 = 10,746.10-3 g = 10,746 mg

mcr= SCr

STiO2 + = z =STi = 2,5813.10-3


.10-3 48 = 132,902 .10-3 g = 132,902 mg

mTi= STi

Vy trong 100ml dung dch A ta c:


mFe= 84,672

= 423,4 mg

macr= 10,746

= 53,73 mg

mTi= 132,902

= 619,51mg

BI 3 : Cho 1g mu lom ( thnh phn H2SO4 , SO3 v SO2 ) vo nc pha thnh 250 ml .
Chn 25 ml dung dch ht 21,2 ml NaOH 0,1 M ( chun n pH = 4) . Mc khc ,
cng chun 100 ml dung dch phn tch trn bng dung dch It ht 37 ml dung dch I2
0,025 N . Tnh thnh phn % cc cu t c trong mu
( Bit H2SO3 c pK1 =1,76 ; pK2 = 7,21 ).
BI GII :
lum ( H2SO4 ; SO3 ; SO2 ) vo nc pha thnh 250 ml ta c dung dch c cha H2SO4;
H2SO3 do:
SO3 +H2O
SO2 +H2O
Ta c :

H2SO4
H2SO3

H2SO3

H+ + HSO3-

K1 = 10-1,76

HSO3-

H+ +SO32-

K2 = 10-7,21

Nhn xt :
11
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

pH =

= 4,49

pH =4

Chun n pH = 4
H2SO4 + 2NaOH Na2SO4 + 2H2O
H2SO3 + NaOH NaHSO3 + H2O
=
SO3 =
SO2 =
Gi x l s gam H2SO4 , y l s gam SO3 , z l s gam SO2
Ta c:
S lg H2SO4 + S lg SO3 + S lg SO2 = S lg NaOH

Chun vi I2:
SO2 + 2 H2 + I2

H2SO4 + 2HI

SO2 =
S lg SO2 = S lg I2

z = 0,148

(2)

x +y +z = 1
(3)
Gii phng trnh (1) ,(2) ,(3) ta c
x= 0,5254 ; y= 0,3266 ; z = 0,1480

12
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Phn trm ca H2SO4 trong lum l :

Phn trm ca SO3 trong lum l :

Phn trm ca SO2 trong lum l :


100-52,54 -32,66 = 14,8 %

BI 4: 1,234 g cht phn tch cha PbO v PbO2 c ch ha vi 20ml H2C2O4 0,25 M
kh PbO2 thnh Pb2+ . Sau dung dch c trung ha bng NH3 kt ta ton b
ch di dng xalat ch . Chun nc lc thu c bng dung dch KMnO4 0,04M th
ht 10ml. Ho tan kt ta trong axit v chun dung dch bng dungdch KMnO4
0,04M ht30 ml.Hy tnh thnh phn % ca PbO v PbO2 trong mu phn tch bit
PbO = 223 ; PbO2 = 239 .

BI GII : Tm tt qu trnh phn tch mu:

PbO, PbO2
H2C2O4
Pb2+,PbC2O4

H2C2O4
H2C2O4d

PbC2O4

KMnO4Axit ho
CO2, H2O

H2C2O4

KMnO4
CO2, H2O

13
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Gi s ng lng gam ca PbO v PbO2 ln lt l x v y


Ch ho hn hp bng dung dch H2C2O4. Khi cho H2C2O4 vo th:
*Mt phn H2C2O4 dng ho tan PbO, sau to kt ta PbC2O4
PbO + H2C2O4
PbC2O4 + H2O
(1)
Gi S1 l s ng lng gam ca H2C2O4 dng trong phn ng (1).
Vy ta c:
x = S1

*Mt phn dng kh PbO2 thnh Pb2+:


2 H2C2O4

2H+ + C2O42-

PbO2 + 4H+ +2e


C2O42-

Pb2+ +2 H2O

2CO2+2e

PbO2 + 2H2C2O4

Pb2++2CO2 +2 H2O + C2O42- (2)

Gi S2 l s ng lng gam ca H2C2O4 dng trong phn ng (2).


Vy ta c:
y = S2
*Mt phn H2C2O4 dng to kt ta PbC2O4 vi Pb2+ phn ng (2)
Pb2+ + C2O42-

PbC2O4

Ta c S Pb2+ to ra phn ng (2) =

(3)

= y

Gi S3 l s ng lng gam ca H2C2O4 dng trong phn ng (3)

14
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Ta c:
y = S3

hay

S2 = S 3

*Phn H2C2O4 cn d l phn nc lc thu c, c chun bng dung dch KMnO 4


0,04M ht 10ml
5 H2C2O4

2H+ + C2O42-

2 MnO4 + 8H + 5e

5 C2O42-

Mn2+ + 4H2O

2CO2+2e

5H2C2O4 + 2MnO4- + 6H+

2Mn2+ + 10CO2 + 8H2O (4)

Gi S4 l ng lng gam ca H2C2O4 con d trong dung dch.


Ta c:
S4 = S KMnO4 =

= 2.10-3

*Phn kt ta PbC2O4 thu c l phn ng (1) v (3). Ho tan kt ta trong axit:


PbC2O4+ H+

Pb2+ + H2C2O4

(5)

V vy :
S H 2C2O4 (5) = S1 + S3
*Chun dung dch thu c bng dung dch KMnO4 0,04M ht 30 ml. Tc l chun
lng H2C2O4 to thnh:
5H2C2O4 + 2MnO4- + 6H+
Ta c:
Hay :

2Mn2+ + 10CO2 + 8H2O

S H 2C2O4 = S KMnO4
S1 + S3 =

= 6.10-3

*Mt khc : tng s ng lng gam ca H2C2O4l:


S = S1 + S2 + S3 + S4 =

= 0,01

15
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Vy ta c:
S1 = 4.10-3 =x

S1 + S2 + S3 + S4 = 0,01
S2 = S3

S2 = 2.10-3 = y

S4 = 2.10-3

S3 = 2.10-3

S1 + S3 = 6.10-3

S4 = 2.10-3

Vy :
SPbO = S1 = 4.10-3 =x
Khi lng ca PbO l : mPbO

= SPbO

4.10-3

223
= 0,446 (g)
2

Phn trm ca PbO trong mu phn tch:

S PbO2 = S2 = 2.10-3 = y
Khi lng ca PbO2 l : mPbO2 = S PbO2

= 2.10-3

239
= 0,239 (g)
2

Phn trm ca PbO2 trong mu phn tch l :

BI 5 : xc nh chun ca KOH v KMnO4 ngi ta dng kalittraxalat


( KHC2O4.H2C2O4.2H2O ) lm cht u .Nng dung dch KOH xc nh
c l 0,09963 N v ca KMnO4 l 0,1328 N . Bit rng trong c hai trng hp
trong c hai trng hp th tch ca cc dung dch KOH v KMnO4 ly chun
u bng 50ml .Hy tnh s gam oxalate16
tiu th trong phn ng trn
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

BI GII :
*Xt trng hp chun ca KOH :
3 KOH + KHC2O4.H2C2O4.2H2O K2C2O4.K2C2O4.2H2O + 3 H2O
ng lng ca KHC2O4.H2C2O4.2H2O l :

(1)

= 84,667

Ta c :
S lg KHC2O4.H2C2O4.2H2O (1) = S lg KOH =

=4,9815.10-3

Khi lng ca KHC2O4.H2C2O4.2H2O tham gia khi chun KOH l :


4,9815.10-3 84,667 = 0,4218 (g)
*Xt trng hp chun ca KMnO4 :

2H+ + C2O42-

H2C2O4

2 MnO4 + 8H + 5e

Mn2+ + 4H2O

5 C2O42-

2CO2+2e

5H2C2O4 + 2MnO4- + 6H+

2Mn2+ + 10CO2 + 8H2O (2)

Ta c :

S lg MnO4 = S lg H2C2O4 =

= 6,64.10-3

S lg ca KHC2O4.H2C2O4.2H2O tham gia khi chun KMnO4 =S lg H2C2O4 =6,64.10-3

ng lng ca KHC2O4.H2C2O4.2H2O l :

= 63,5

Khi lng ca KHC2O4.H2C2O4.2H2O tham gia khi chun KMnO4 l :


6,64.10-3

63,5 = 0,4216 (g)


17

Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

Vy :
Khi lng ca KHC2O4.H2C2O4.2H2O tiu th trong cc qu trnh chun trn l :
0,4218 + 0,4316 = 0,8434 (g)

BI 6: Mt mu phn tch c cha MnO2 v tp cht tr . xc nh % MnO2 c trong


mu , ngi ta ch ha 0,25 g mu phn tch vi 25 ml H2C2O4 0,25 N .Cho thm 5ml
dung dch HNO3 1M kt ta hon ton , sau cho vo dung dch 1ml KI 10% v
0,5 ml h tinh bt .Chun hn hp trn bng K2Cr2O7 0,02 M th ht 10,75 ml dung
dch chuyn t mu xanh nht sang mu xanh m .
a) Hy gii thch ni dung th nghim trn bng phng trnh phn ng .
b) Tnh % MnO2 trong mu phn tch .

BI GII :
a) Cc phn ng ln lt l:

MnO2 + 2e +4H+
H2C2O4

2H+ + C2O42-

C2O42-

2CO2+2e

Mn2+ + 2H2O

18
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

H2C2O4 +MnO2 + 2H+ Mn2+ + 2CO2 +2H2O

(1)

H2C2O4 +MnO2 MnCO3 + 2CO2 +H2O

2H+ + C2O42-

3 H2C2O4
3 C2O42-

2CO2+2e

HNO3 + 3H+ + 3e

(2)

NO + 2H2O

3H2C2O4 +2HNO3 6CO2 + 4H2O + 2NO

6 Mn2+ + 4H2O

(3)

MnO4- + 8H+ + 5e

5 Cr2 O7 + 14H+ + 6e

2Cr3+ + 7H2O

5Cr2O72- +6Mn2+ + 22H+10Cr3+ + 6MnO4- + 11H2O

Cr2O7 + 14H+ + 6e
3

(4)

2Cr3+ + 7H2O
2I-

I2 + 2e

Cr2O72-+ 6I- + 14H+ 2Cr3+ + 3I2 + 7H2O

(5)

T phng trnh ta c: mu xanh nht l mu ca ion Cr3+ , cn xanh m l do iot sinh ra (5)
kt hp vi h tinh bt nn c mu xanh m . Nn ta thy hin tng dung dch chuyn t
mu xanh nht sang mu xanh m

19
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

b) Ta c :

=
=

= 6,25 10-3
= 1,29

10-3

= 2,48 10-3

Khi lng MnO2 trong mu phn tch l : 2,48 10-3 87 = 0,215 (g)
Vy phn trm MnO2 trong mu phn tch l :
%

= 86 %

20
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

TRNG I HC S PHM HU
KHOA HA HC

Cn b hng dn
Thy Nguyn Hu Hin

Sinh vin Trn Th M L


Lp: Ha 3B

HU, 11 /2011

21
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

TRNG I HC S PHM HU
KHOA HA HC

Cn b hng dn
Thy Nguyn Hu Hin

Sinh vin Trn Th M L


Lp: Ha 3B

HU, 11 /2011

22
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

TRNG I HC S PHM HU
KHOA HA HC

HU, 11 /2011

23
Trn Th M L Lp Ha 3B

Bi tp ln

CHNG III : CHUN OXI HA KH

24
Trn Th M L Lp Ha 3B

Bi tp ln

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