SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier Trade name CAS REACH Registration No. : : : Silquest A-1100* silane 919-30-2 01-2119480479-24-XXXX

1.2 Relevant identified uses of the substance or mixture and uses advised against 1.2.1 Usage : ES 1: Production On-site Industrial use ES 2: Intermediate Downstream industrial site ES 3: monomer Downstream industrial site ES 4: Formulation of: Coatings Downstream industrial site ES 5: Coatings Industrial use ES 6: Coatings Industrial use ES 7: Coatings Professional use Consumer use ES 8: Formulation Non-metal Surface treatment Industrial use ES 9: Non-metal Surface treatment In situ treatment ES 10: Formulation of: Sealants ES 11: Sealants Industrial use ES 12: Sealants Professional use Consumer use ES 13: Laboratory chemical None known.

1.2.2 Uses advised against

1.3 Details of the supplier of the safety data sheet Company: : Momentive Performance Materials GmbH Chempark Leverkusen Gebaeude V7 DE - 51368 Leverkusen + 40 213044229 MomentiveEMEA.productsteward@momentive.com

Telephone Information contact: 1.4 Emergency telephone 24 Hour Emergency Telephone

: :

Europe, Israel & All other: +44 (0) 1235239670; Middle East:+44 (0) 1235239671

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture: Classification according to Regulation (EC) No 1272/2008 as amended Acute toxicity Category 4; Oral; H302; Skin corrosion/irritation Category 1B; H314; Skin sensitizer Category 1; H317;

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

Classification according to Directive 67/548/EEC or 1999/45/EC as amended: Corrosive; C; R34; Harmful; Xn; R22; SENSITIZER; Xi; R43;

2.2 Label elements GHS-Labelling Regulation (EC) No. 1272/2008:

Hazard pictograms Signal words: danger

Hazard statements H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. Precautionary Statement - Prevention: P260 Do not breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves/protective clothing/eye protection/face protection. Precautionary Statement - Response: P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P303+P361+P353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Precautionary Statement - Disposal: P501 Dispose of contents/container to an approved incineration

Labelling according to EC Directives Hazardous components which must be listed on the label: gamma-Aminopropyltriethoxysilane Symbol(s) R-phrase(s) : : C Corrosive R22 R34 R43 S26 S36/37/39

Harmful if swallowed. Causes burns. May cause sensitisation by skin contact. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection.

S-phrase(s)

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

S45

S60

In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste.

2.3 Other hazards None known. Not fulfilling PBT (persistent/bioaccumulative/toxic) criteria Not fulfilling vPvB (very persistent/very bioaccummulative) criteria

3. COMPOSITION/INFORMATION ON INGREDIENTS
Pure substance/mixture Substances Hazardous Component(s) Chemical name CAS-No.; Concentration EU EC No.; % Classification REACH Registration No. >= 99,000 919-30-2; C;R34, R22, 213-048-4; R43; 01-211948047924-XXXX; Regulation (EC) No. 1272/2008

gammaAminopropyltriethoxysilane

Category 4; Acute Tox.; H302; Category 1B; Skin Corr.; H314; Category 1; Skin Sens.; H317;

4. FIRST AID MEASURES

4.1 Description of first aid measures Inhalation Skin contact : : Move the exposed person to fresh air at once. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. Wash contaminated clothing before reuse. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. If conscious, drink plenty of water. Do NOT induce vomiting.

Eye contact

Ingestion

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

4.2 Most important symptoms and effects, both acute and delayed This material reacts immediately with water in the acid contents of the stomach to produce ethanol. 4.3 Indication of any immediate medical attention and special treatment needed DO NOT induce vomiting. Get medical attention immediately. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water.

5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : : Alcohol resistant foam. Carbon dioxide Dry chemical. None known.

5.2 Special hazards arising from the substance or mixture: Material reacts with water. 5.3 Advice for firefighters: Wear self-contained breathing apparatus and protective clothing. Do not use water jet as an extinguisher, as this will spread the fire. Use water spray to keep fire-exposed containers cool.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures: Avoid contact with eyes, skin, and clothing. Avoid contact with liquid and vapors. Use personal protective equipment. 6.2 Environmental precautions: Avoid release to the environment. 6.3 Methods and material for containment and cleaning up: Absorb spillage with suitable absorbent material. Shovel up and place in a container for salvage or disposal.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling Handling : Do not taste or swallow. Avoid contact with eyes, skin, and

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

clothing. Avoid breathing mists or vapors. Wash hands after handling. Advice on protection against fire and explosion : All equipment used when handling the product must be grounded.

7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep container tightly closed. Keep away from sources of ignition - No smoking.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters Occupational exposure limits Contains no substances with occupational exposure limit values. DNEL-Values: GAMMA-AMINOPROPYLTRIETHOXYSILANE Area of use workers; Dermal; Acute, Systemic Toxicity workers; Inhalation; Acute, Systemic Toxicity workers; Dermal; long term, Systemic Toxicity workers; Inhalation; long term, Systemic Toxicity PNEC-Values: GAMMA-AMINOPROPYLTRIETHOXYSILANE Area of use Water Seawater Intermittent release Sediment Derived from PNEC(freshwater) using the equilibrium partitioning method. Soil Derived from PNEC(freshwater) using the equilibrium partitioning method. Sewage treatment plant

Value 8,3 mg/kg bw/day 59 mg/m3 8,3 mg/kg bw/day 59 mg/m3

Value 0,33 mg/l 0,033 mg/l 3,3 mg/l 0,26 mg/kg

0,04 mg/kg

13 mg/l

8.2 Exposure controls Appropriate engineering controls Provide eyewash station and safety shower. General (mechanical) room ventilation is expected to be satisfactory if handled at low temperatures or in covered equipment.

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

Personal protective equipment (ppe) Respiratory Protection Hand protection : : Respiratory protection mask with Filtertype ABEK Advice: This recommendation is valid only for our Product as delivered. If this product will be mixed with other substances you need to contact a supplier of CE approved protective gloves (e.g. KCL GmbH, D-36124 Eichenzell, Tel. 0049 (0) 6659 87300, Fax. 0049 (0) 6659 87155, email: vertrieb@kcl.de). Material: 730 Camatril Minimum break through time: 480 min Glove thickness: 0,4 mm Producer: KCL GmbH, D-36124 Eichenzell, Tel. 0049 (0) 6659 87300, Fax. 0049 (0) 6659 87155, email: vertrieb@kcl.de.

Eye protection

Face shield Safety glasses with side-shields conforming to EN166 Safety shoes Wear suitable protective clothing.

Skin and Body Protection

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties Appearance Odor Odor Threshold pH : Liquid Colorless : amine like : No data available. : 10,5 at100 g/lConcentration: 100 g/l

Melting Point Boiling point/boiling range Flash Point Evaporation Rate Lower explosion limit Upper explosion limit Vapour pressure

: <-70 C : 220 C at 1.013 hPa : 93 C Method: ASTM D 93 : <1 : Not applicable : Not applicable : 0,02 hPa at 20 C

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

Vapor Density Density Solubility(ies) Partition Coefficient: noctanol/water

: >1 : 0,9500 g/cm3 at 25 C (1,013 hPa) No data available. : Log Pow (n-Octanol/Water Partition Coefficient): 1,7 at: 20 C Method: Calculated

Autoignition Temperature

: 270 C at 1.010 hPa : Note: No decomposition if stored and applied as directed. : 2 mPa.s at 20 C

Thermal decomposition Viscosity, dynamic Viscosity, kinematic Explosive properties Oxidizing properties

: No data available. : Not classified : Not applicable

10. STABILITY AND REACTIVITY

10.1 Reactivity: Material is stable under normal conditions. 10.2 Chemical stability: Water reactive material.

10.3 Possibility of hazardous reactions: Hazardous polymerisation does not occur. No dangerous reaction if used as recommended.

10.4 Conditions to avoid: Avoid contact with: Moisture. Water

10.5 Incompatible materials: Reaction with water or other aqueous media is rapid and exothermic. The addition of small amounts of water ( can produce an exothermic reaction which generates alcohol to the extent that the resulting solution can reach

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

exceeds the flash point of the new solution. If a water solution is desired, add the product to water, and not vic

10.6 Hazardous decomposition products: Carbon oxides, Nitrogen Oxides, Oxides of silicon.

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects Acute oral toxicity : LD50 Rat males Dose: 2.830 mg/kg LD50 Rat female Dose: 1.570 mg/kg LC50 Rat males Result: 5 ppm Exposure time: 6 h Method: OECD Test Guideline 403 LC50 Rat female Result: 16 ppm Exposure time: 6 h Method: OECD Test Guideline 403 LD50 Rabbit male and female Dose: 4.290 mg/kg Rabbit Result: Corrosive Classification: Corrosive Method: OECD-Guideline 404 (Acute Dermal Irritation/Corrosion) Rabbit Result: Strongly irritating. Method: OECD-Guideline 405 (Acute Eye Irritation/Corrosion) Guinea Pig Result: positive Classification: SENSITIZER Oral Rat Dose: Daily dosage Exposure time: 90 d NOAEL: 200 mg/kg

Acute inhalation toxicity

Acute dermal toxicity

Skin irritation.

Eye irritation

Sensitization

Repeated dose toxicity

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

Oral Rat Dose: Daily dosage Exposure time: 90 d LOAEL: 600 mg/kg Test type: Ames-Test Result: negative Test type: Chinese Hamster Ovary (CHO) Result: negative Test type: Chromosomal aberration Result: negative

Genetic Toxicity in vitro

12. ECOLOGICAL INFORMATION

12.1 Toxicity The product degrades through hydrolysis into alcohols and silanol- and/or siloxanol compounds. Ecotoxicity effects Toxicity to fish : static test LC50 Species: Brachydanio rerio Dose: > 934 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 static test EC50 Species: Daphnia magna Dose: 331 mg/l Exposure time: 48 h Method: OECD-Guideline 202 static test EC50 Species: Desmodesmus subspicatus (green algae) Dose: > 1.000 mg/l Exposure time: 72 h static test NOEC Species: Desmodesmus subspicatus (green algae) Dose: 1,3 mg/l Exposure time: 72 h static test EC10 Species: Pseudomonas putida Dose: 13 mg/l Exposure time: 5,75 h static test EC50 Species: Pseudomonas putida

Toxicity to other organisms

Toxicity to algae

Toxicity to microorganisms

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

Dose: 43 mg/l Exposure time: 5,75 h 12.2 Persistence and degradability Elimination information (persistence and degradability) Persistence and degradability : Exposure time: 28 d 67 % Not readily degradable. hydrolyses

12.3 Bioaccumulation : Species: Cyprinus carpio Bioconcentration factor (BCF): 3,4 Method: Measured The product is not bioaccumulating.

12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment Not fulfilling PBT (persistent/bioaccumulative/toxic) criteria Not fulfilling vPvB (very persistent/very bioaccummulative) criteria 12.6 Other adverse effects None known.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods Product Contaminated packaging : : Can be incinerated when in compliance with local regulations. Dispose of as unused product.

14. TRANSPORT INFORMATION

Land transport ADR: UN-Number Class Packing group Classification Code Hazard identification No ADR/RID-Labels Proper Shipping Name Contains 3267 8 II C7 80 8 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. gamma-Aminopropyltriethoxysilane

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

RID Class No.:

UN-Number Class Packing group Classification Code Hazard identification No ADR/RID-Labels Proper Shipping Name Contains

3267 8 II C7 80 8 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. gamma-Aminopropyltriethoxysilane

Inland waterway transport ADNR: UN-Number Class Packing group Classification Code Hazard identification No ADNR-Labels Proper Shipping Name Contains 3267 8 II C7 80 8 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. gamma-Aminopropyltriethoxysilane

Sea transport IMDG: UN-Number Class Packing group IMDG-Labels EmS Proper Shipping Name Contains 3267 8 II 8 F-A, S-B CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. gamma-Aminopropyltriethoxysilane

Air transport ICAO/IATA: UN-Number Class Packing group ICAO-Labels Proper Shipping Name Contains 3267 8 II 8 Corrosive liquid, basic, organic, n.o.s. gamma-Aminopropyltriethoxysilane

Further Information

Keep away from food, drink and animal feedingstuffs. Protect from moisture.

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture None known. 15.2 Chemical safety assessment A Chemical Safety Assessment has been performed on this substance.

Inventories
Australia Inventory of y (positive listing) Chemical Substances (AICS) EU list of existing chemical y (positive listing) substances Japan Inventory of Existing & y (positive listing) New Chemical Substances (ENCS) China Inventory of Existing y (positive listing) Chemical Substances Korea Existing Chemicals y (positive listing) Inventory (KECI) Canada DSL Inventory y (positive listing) Canada NDSL Inventory n (Negative listing) New Zealand Inventory of y (positive listing) Chemicals Philippines Inventory of y (positive listing) Chemicals and Chemical Substances (PICCS) TSCA list y (positive listing) For inventories that are marked as quantity restricted or special cases, please contact Momentive.

16. OTHER INFORMATION

Wording of the R-phrases and H-statements in section 2 and 3 H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction. H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction.

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SAFETY DATA SHEET Silquest A-1100* silane

Version 10.0 Revision date 13.08.2012

according to Regulation (EC) No. 1907/2006

Print Date 28.12.2012 OSI000000006

R22 R34 R43

Harmful if swallowed. Causes burns. May cause sensitisation by skin contact.

Momentive Products are intended for industrial application only. They are not intended for specific medical applications, neither for long-lasting (> 30 days) implantation into the human body, injected or directly ingested, nor for the manufacture of multiple usable contraceptives.

Further Information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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