SMK METHODIST SG.

SIPUT (U) CHEMISTRY REVISION PROGRAMME 2011 ( AIM FOR A+ IN CHEMISTRY ) A Name of cation / positive ion Hydrogen Lithium Sodium Potassium Calcium Magnesium Aluminium Zinc Copper (I) Copper (II) Silver Iron (II) Iron (III) Lead (II) Lead (IV) Ammonium Stanum (II) Stanum (IV) B. Formula Name of anion / negative ion chloride bromide iodide hydroxide nitrate carbonate sulphate oxide Formula

Construct chemical formulae for the chemical compounds (as many as possible )

Total .. C Name Hydrochloric acid Sulphuric acid Nitic acid Ammonia gas Chlorine gas Hydrogen sulphide gas

Formula

Name Sodium hydroxide Potassium hydroxide Barium hydroxide Sulphur dioxide gas Nitrogen dioxide gas Sulphur trioxide gas

Formula

CHEMICAL PROPERTIES OF ACID ACID ACID ACID ACID + ALKALI + + + METAL SALT SALT + + WATER HYDROGEN SALT + WATER + CARBON DIOXIDE SALT + WATER

METAL CARBONATE BASIC OXIDE

Write a balance chemical and ionic eguation using symbol and formula Chemical eguation Ionic equation 1. Hydrochloric acid + Sodium hydroxide 2. Sulphuric acid + Barium hydroxide 3. Nitric acid + Potassium hydroxide 4. Hydrochloric acid + Magnesium 5. Sulphuric acid + Zinc 6. Nitric acid + Ferum 7. Hydrochloric acid + sodium carbonate 8. Sulphuric acid + Copper (II) carbonate 9. Sulphuric acid + Ammonium carbonate 10. Nitric acid + Lead (II) carbonate 11. Hydrochloric acid + Zinc oxide 12. Sulphuric acid + Copper (II) oxide 13. Nitric acid + Lead (II) oxide

F. From E catergories chloride salts, nitrate salts and sulphates salts using formula Chloride salts Nitrate salts Sulphate salts

G. The above salts are all soluble in water. Therefore soluble salts can be prepared by 4 methods ( refer to A ). All nitrate salts are soluble in water. H. Name and write the formulae of all the insoluble salts for chlorides, sulphates and carbonates. Chlorides . ................. . ( PAMeR ) Sulphates . . ( BaCaP ) carbonates All carbonates are insoluble except carbonates of group 1, that is Li2CO3, Na2CO3, K2CO3...

I. Insoluble salts can be prepared by precipitation or double decomposition method. The reactants are 2 aqueous soluble salts mix together to form 2 salts, soluble and insoluble salt. Soluble salt + Soluble salt Insoluble salt + Soluble salt

J. Write down the chemical equations and ionic equations for formation of (i) Insoluble Salts of Chlorides. (PAMer) Chemical equation 1.Pb(NO3)2 + 2NaCl 2. (ii) Insoluble Salts of Sulphates (BaCaP) Chemical equation 1.Ba(NO3)2 + Na 2SO4 2. 3. BaSO4 + 2NaNO3 Ionic equation 1. Ba2+ + 2SO422. 3. BaSO4 PbCl2 + 2NaNO3 1. Pb2+ + 2. Ionic equation 2ClPbCl2

(iii) Insoluble Salts of Carbonates Chemical equation 1.Pb(NO3)2 + Na2CO3 2. 3. 4. K. Displacement reaction. The metal which is higher in the electrochemical series will displace the metal which is lower in the electrochemical series from its salt solution. ( A more electropositive metal will displace a less electropositive metal from its salt solution ) Suggest the reactants needed and write a balance chemical equation and ionic equation for the following, Chemical equation 1.Magnesium + Zinc sulphate 2. 3. 4. 5. Ionic equation PbCO3 + 2NaNO3 Ionic equation 1. Pb2+ + CO322. 3. 4. PbCO3

L. Electrochemical Series

Na

Ca

Mg

Al

Zn

Fe

Sn

Pb

Cu

Ag

More electropositive

L.Heating of Salts Write down the balance chemical equation using symbol and formula for the following salt. State the colour changes. (i) Carbonates Salts Chemical equation 1.Zinc carbonate Zinc oxide + carbon dioxide . 2. Copper (II) carbonate . 3. Lead (II) carbonate .. Observation

(ii) Nitrate salts Chemical equation 1.Zinc nitrate Zinc oxide + nitrogen +oxygen dioxide . 2. Copper (II) nitrate . 3. Lead (II) nitrate .. 4. 2NaNO3 2NaNO2 + O2 Sodium nitrite (i.Carbonates of group 1 do not decompose on heating, that is Na2CO3 , K2CO3.. ) ii. Nitrates of group 1 decompose to nitrite and oxygen on heating. Observation