S GIO DC V O TO TRNG THPT NAM SCH II Website: http://hoahoc.

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THI TH CHN HC SINH GII CP TNH LP 12 THPT NM HC 2012-1013 Mn thi: HA HC Thi gian: 180 pht (khng k thi gian giao ) Ngy thi: 25/10/2012

Cu 1: (2 im) 1. Vit cng thc cu to, gi tn cc hp cht hu c mch h c cng thc phn t C2H5O2N. Vit phng trnh phn ng c trng ca cc cht ng vi mi cng thc cu to tm c. 2. Khi thu phn hon 1mol pentapeptit thu c 3mol glyxin,1mol alanin v 1mol phenylalanin. Khi thu phn khng hon ton th trong hn hp sn phm thy c cc dipeptit Ala-Gly, Gly-Ala m khng thy c Phe-Gly. Xc nh cng thc cu to ca pentapeptit Cu 2: (2 im) 1. Sp xp (c gii thch) theo trnh t tng dn tnh axit ca cc cht sau:
COOH ; N ; COOH ; CH2COOH

COOH

(A)

(B)

(C)

(D)

2. Sp xp (c gii thch) theo trnh t tng dn tnh baz ca cc cht sau: -NH-CH3 , -CH2-NH2 , C6H5-CH2-NH2, p-O2N-C6H4-NH2. Cu 3: (2 im) 1. Ba hp cht mch h A, B, C c cng thc phn t tng ng l C3H6O, C3H4O, C3H4O2 c cc tnh cht sau: - A, B khng tc dng vi natri, khi tc dng vi hidro u to ra sn phm nh nhau. - B phn ng vi hidro to A . - A c ng phn A, khi b oxi ha th A to cht B. - C c ng phn C, l hp cht n chc nh C. - Khi oxi ha B th thu c C. Hy xc nh cng thc cu to ca A, A, B, C, C. 2. Bng phng php ha hc hy phn bit cc dung dch sau ng trong cc bnh mt nhn: axit glutamic, lizin, glyxin, trimetyl amin, axit fomic. Cu 4: (1 im) Trong phng th nghim c cc dung dch b mt nhn: AlCl3, NaCl, KOH, Mg(NO3)2, Pb(NO3)2, Zn(NO3)2, AgNO3.Ch dng mt thuc th, hy nhn bit mi dung dch. Vit cc phng trnh phn ng (nu c). Cu 5: (1,5 im) Mt hn hp rn A gm kim loi M v mt oxit ca kim loi , c chia thnh 3 phn bng nhau, mi phn c khi lng l 59,08 gam A. Phn th nht ho tan vo dung dch HCl thu c 4,48 lt kh hiro; phn th hai ho tan vo dung dch hn hp NaNO3 v H2SO4 thu c 4,48 lt kh NO; phn th ba em nung nng ri cho tc dng vi kh hiro d cho n khi c mt cht rn duy nht, ho tan ht cht rn bng nc cng toan th c 17,92 lt kh NO thot ra. Cc th tch kh o iu kin tiu chun. Hy tnh khi lng mol nguyn t, cho bit tn ca kim loi M v cng thc oxit trong hn hp A. Cu 6: (1,5 im) Mt hp cht c to thnh t ion M+ v X 2 . Trong phn t M2X2 c tng s 2 ht c bn bng 116, trong s ht mang in nhiu hn s ht khng mang in l 36. S khi ca M ln hn s khi ca X l 7 n v. Tng s ht trong X 2 nhiu hn ca M+ l 17 ht. 2 a) Xc nh cc nguyn t M, X v cng thc ca M2X2 . Vit cu hnh electron ca ion M+. Vit cng thc electron ca X 2 . 2 b) Cho hp cht M2X2 tc dng vi H2O. Vit phng trnh phn ng xy ra v trnh by phng php ha hc nhn bit sn phm. -----------------------------------------------------HT------------------------------------------------